• Journal of environmental and Sanitary engineering
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• v.14 no.1
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• pp.97-102
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• 1999

This study was carried out view that reuse of sludge of adsorbent for benzene in carbonized cast compare with activated carbon. Not only the carbonized cast is good than carbonized carbon in cation exchange capacity and 12 adsorption capacity, but also benzene adsorption capacity is no differences compare to activated carbon. As results, benzene adsorption capacity of carbonized cast and activated carbon are decreased as temperature increase($25~70^{\circ}C$).It is compatible in Lamgmuir model. Therefore, carbonized cast is applied general adsorbent. From experimental results and data regression, in model concerning effect of temperature, relative errors between the experimental data and those calculated by the model are within the range of 1.2~7.8%. In relative humidity effect (RH 0.25~0.50) of benzene adsorption, modified Freundlich model : $QB_{enzene}{;\}QB_{enzene},{\}_{RH=0}=1-kRH^{IN}$, relative errors between the experimental data and those calculated by the model are within are range of 0.5-5.1%. The constants k and l/n in equation were found to be 1.25, 1.89 in carbonized cast.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.5
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• pp.549-555
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• 2015

Objective of this study was to investigate the effect of carbonized biomass from crop residues on chemical properties of soil and soil carbon pools during soybean cultivation. The carbonized biomass was made by field scale mobile pyrolyzer. A pot experiment with soybean in sandy loam soil was conducted for 133 days in a greenhouse, by a completely randomized design with three replications. The treatments consisted of four levels including the control without input and three levels of carbonized biomass inputs of $9.75Mg\;ha^{-1}$, C-1 ; $19.5Mg\;ha^{-1}$, C-2 ; $39Mg\;ha^{-1}$, C-3. Soil samples were collected and analyzed pH, EC, TC, TN, inorganic-N, available phosphorus and exchangeable cations of the soils. Soil pH, Total-N and available phosphorus contents correspondingly increased with increasing the carbonized material input. The contents of soil carbon pools were $19.04Mg\;C\;ha^{-1}$ for C-1, $26.19Mg\;C\;ha^{-1}$ for C-2, $33.62Mg\;C\;ha^{-1}$ for C-3 and $12.01Mg\;C\;ha^{-1}$ for the control at the end of experiment, respectively. Increased contents of soil carbon pools relative to the control were estimated at $7.03Mg\;C\;ha^{-1}$ for C-1, $14.18Mg\;C\;ha^{-1}$ for C-2 and $21.62Mg\;C\;ha^{-1}$ for C-3 at the end of experiment, respectively, indicating that the soil carbon pools were increased with increasing the input rate of the carbonized biomass. Consequently, it seems that the carbonized biomass derived from the agricultural byproducts such as crop residues could increase the soil carbon pools and that the experimental results will be applied to the future study of soil carbon sequestration.

• Journal of Environmental Health Sciences
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• v.33 no.5
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• pp.456-461
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• 2007

This study was carried out two point view that reuse of sludge and adsorption of benzene, toluene and o-xylene of VOCs in cast, carbonized cast and activated carbon. The cation exchange capacity of cast and carbonized cast were 59.2, 112 meq/100g, respectively. The specific surface were 560, $800m^2/g$, respectively. The average removal rates of benzene by 50g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 15.0, 41.2, 88.2, 99.4% in 60min of retention time. The average removal efficiency of toluene by 50 g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 12.5, 34.2, 88.2, 99.5% in 60 min of retention time. The average removal rates of o-xylene 50 g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 8.8, 28.5, 84.8, 98.1% in 60min of retention time. The adsorption efficiency of test absorbent was in order of Activated Carbon > Carbonized Cast > Cast.

• Carbon letters
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• v.16 no.1
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• pp.62-66
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• 2015

In this study, carbonized fibers were prepared by using acidically cross-linked LDPE fibers. The surface morphologies of the carbonized fibers were observed by SEM. The effects of cross-linking process temperatures were studied using thermal analyses such as DSC and TGA. The melting and heating enthalpy of the fibers decreased as the cross-linking temperature increased. The cross-linked fibers had a carbonization yield of over 50%. From SEM results the highest yield of carbonized LDPE-based fibers was obtained by cross-linking at a sulfate temperature ($170^{\circ}C$). As a result, carbonation yield of the carbonized fibers was found to depend on the functions of the cross-linking ratio of the LDPE precursors.

• Korean Journal of Environmental Agriculture
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• v.35 no.3
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• pp.159-165
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• 2016

BACKGROUND: Carbonized biomass is increasingly used as a tool of soil carbon sequestration. The objective of this study was to evaluate soil carbon storage to application of carbonized biomass derived from pear tree pruning.METHODS AND RESULTS: The carbonized biomass was a mobile pyrolyzer with field scale, which a reactor was operated about 400~500℃ for 5 hours. The treatments were consisted of a control without input of carbonized biomass and two levels of carbonized biomass inputs as 6.06 Mg/ha, C-1 and 12.12 Mg/ha, C-2. It was shown that the soil carbon pools were 49.3 Mg/ha for C-1, 57.8 Mg/ha for C-2 and 40.1 Mg/ha for the control after experimental periods. The contents of accumulated soil carbon pool were significantly (P < 0.001) increased with enhancing the carbonized biomass input amount. The slopes (1.496) of the regression equations are suggested that carbon storage from the soil was increased about 0.1496 Mg/ha with every 100 kg/ha of carbonized biomass input amount.CONCLUSION: Our results suggest that application of carbonized biomass would be increased the soil carbon contents due to a highly stable C-matrix of carbonized biomass. More long-term studies are needed to be proved how long does carbon stay in orchard soils.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.6
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• pp.486-490
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• 2014

This study was conducted to investigate the effect of carbonized biomass from crop residues on soil carbon storage during soybean cultivation. The carbonized biomass was made by field scale mobile pyrolyzer. The treatments consisted of control without input and three levels of carbonized biomass inputs as $59.5kg10a^{-1}$, C-1 ; $119kg10a^{-1}$, C-2 ; $238kg10a^{-1}$, C-3. Soil samples were collected during the 113 days of experimental periods, and analyzed soil pH and moisture contents. Soil carbon contents and soybean yield were measured at harvesting period. For the experimental results, soil pH ranged from 6.8 to 7.5, and then increased with increasing carbonized material input. Soil moisture contents were slightly higher by 0.1~1.5% than the control, but consistent pattern was not observed among the treatments. Soil carbon and organic carbon contents in the treatments increased at 24 and 15% relative to the control at 15 days after sowing, respectively. Loss rate of SOC (soil organic carbon) relative to its initial content was 7.2% in control followed by C-1, 6.8%> C-2, 3.5%>C-3, 1.1% during the experimental periods. The SOC change rate decreased with increasing carbonized biomass rate. It was appeared that soybean yields were $476.9kg10a^{-1}$ in the control, and ranged from 453.6 to $527.3kg10a^{-1}$ in the treatments. However, significant difference was not found among the treatments. It might be considered that the experimental results will be applied to soil carbon sequestration for future study.

• Carbon letters
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• v.3 no.3
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• pp.127-132
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• 2002

Unidirectional polymer composites were prepared using high-strength carbon fibers as reinforcement and phenolic resin as matrix precursor with keeping fiber volume fraction at 30, 40, 50 and 60% respectively. These composites were carbonized at $1000^{\circ}C$ and graphitised at $2600^{\circ}C$ in the inert atmosphere. The carbonized and graphitised composites were characterized for mechanical properties as well as microstructure. Microscopic studies were carried out of the polished surface of carbonized and graphitised composites after etching by chromic acid, to understand the effect of fiber volume fraction on oxidation at fiber-matrix interface. It is found that the flexural strength in polymer composites increases with fiber volume fraction and so does for the carbonised composites. However, the trend was found to be reversed in graphitised composites. In all the carbonized composites anisotropic region has been observed at fiber-matrix interface which transforms into columnar type microstructure upon graphitisation. The extension of strong and weak columnar type microstructure is function of fiber volume fraction. SEM microscopy of the etched surface of the sample reveal that composites containing 40% fiber volume has minimum oxidation at the interface, revealing a strong interfacial bonding.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.1
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• pp.1-6
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• 2016

Carbonized biomass could be used as a mechanism for long-term storage of C in soils. However, experimental results are variable. Objective of this study was carried out to evaluate the effect of carbonized biomass made from soybean residue on soil organic carbon and seed yield during soybean cultivation. The carbonized biomass was made by field scale mobile pyrolyzer. Pyrolyzer was performed in a reactor operated at $400{\sim}500^{\circ}C$ for 2 hours using soybean residue. The treatments consisted of four levels as the control without input and three levels of carbonized biomass inputs as $357kg\;ha^{-1}$, C-1 ; $714kg\;ha^{-1}$, C-2 ; $1,428kg\;ha^{-1}$, C-3. It was appeared that seed yield of soybean was $2,847kg\;ha^{-1}$ for control, $2,897kg\;ha^{-1}$ for C-1, $2,946kg\;ha^{-1}$ for C-2 and $3,211kg\;ha^{-1}$ for C-3 at the end of experiment. It was shown that the contents of SOC were $5.21g\;kg^{-1}$ for C-1, $5.93g\;kg^{-1}$ for C-2, $7.00g\;kg^{-1}$ for C-3 and $4.73g\;kg^{-1}$ for the control at the end of experiment. Accumulated SOC contents linearly significantly (P < 0.001) increased with increasing the carbonized biomass input. The slopes (0.00162) of the regression equations suggest that SOC contents from the soil increase by $0.162g\;kg^{-1}$ with every $100kg\;ha^{-1}$ increase of carbonized biomass rate. Consequently the carbonized biomass for byproducts such as soybean residue could increase SOC. It might be considered that the experimental results will be applied to soil carbon sequestration for future study. More long-term studies are needed to prove how long does SOC stay in agricultural soils.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.10a
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• pp.133-136
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• 2001

The effect of pre-carbonization condition on the mechanical properties of nonwoven needle-punched carbon/phenolic composite was studied. The nonwoven Oxi-PAN felt was pre-carbonized at different temperature. The pre-carbonized Oxi-PAN felt was needle-punched and then carbonized. Needle-punched nonwoven carbon preforms were formed into composites with phenol resin. The tensile and flexural strengths showed maximum value with pre-carbonization temperature of $500^{\circ}C$. Compared with the non-pre-carbonized composite, the mechanical properties were slightly improved.

• Korean Journal of Environmental Agriculture
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• v.36 no.2
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• pp.73-79
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• 2017

BACKGROUND: Carbonized biomass is a carbon-rich solid product obtained by the pyrolysis of biomass. It has been suggested to mitigate climate change through increased carbon storage and reduction of greenhouse gas emission. The objective of this study was to evaluate carbon dioxide ($CO_2$) and nitrous oxide ($N_2O$) emissions from soil after carbonized biomass addition. METHODS AND RESULTS: The carbonized biomass was made from a pyrolyzer, which a reactor was operated about $400{\sim}500^{\circ}C$ for 5 hours. The treatments were consisted of a control without input of carbonized biomass and two levels of carbonized biomass inputs as 6.06 Mg/ha for CB-1 and 12.12 Mg/ha for CB-2. Emissions of $CO_2$ and $N_2O$ from orchard soil were determined using closed chamber for 13 weeks at $25^{\circ}C$ of incubation temperature. It was shown that the cumulative $CO_2$ were $209.4g\;CO_2/m^2$ for CB-1, $206.4g\;CO_2/m^2$ for CB-2 and $214.5g\;CO_2/m^2$ for the control after experimental periods. The cumulative $CO_2$ emission was similar in carbonized biomass input treatment compared to the control. It was appeared that cumulative $N_2O$ emissions were $4,478mg\;N_2O/m^2$ for control, $3,227mg\;N_2O/m^2$ for CB-1 and$ 2,324mg\;N_2O/m^2$ for CB-2 at the end of experiment. Cumulative $N_2O$ emission contents significantly decreased with increasing the carbonized biomass input. CONCLUSION: Consequently the carbonized biomass from byproducts such as pear branch residue could suppress the soil $N_2O$ emission. The results fromthe study imply that carbonized biomass can be utilized to reduce greenhouse gas emission from the orchard field.