• Title/Summary/Keyword: Carbonation Velocity

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CO2 Emission and Storage Evaluation of RC Underground Structure under Carbonation Considering Service Life and Mix Conditions with Fly Ash (탄산화 환경에 노출된 RC 지하구조물의 내구수명과 플라이애쉬 배합 특성을 고려한 탄소 배출 및 흡착 평가)

  • Kim, Seong-Jun;Mun, Jin-Man;Lee, Hack-Soo;Kwon, Seung-Jun
    • The Journal of the Korea Contents Association
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    • v.14 no.12
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    • pp.999-1009
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    • 2014
  • In this paper, $CO_2$ emission and storage amount are evaluated for real RC (Reinforced Concrete) underground structure considering $CO_2$ amount including material manufacturing, moving, and construction, repairing timing stage regarding extended service life. Four mix proportions with mineral admixtures are prepared and $CO_2$ diffusion coefficient are obtained based on a micro modeling. Referred to carbonation durability limit state, $CO_2$ emission and storage amount are evaluated, which shows higher initial $CO_2$ emission is caused due to larger unit content of cement and the storage increases with more rapid carbonation velocity. Furthermore various $CO_2$ concentration is adopted for simulation of $CO_2$ evaluation including measured $CO_2$ concentration (600ppm). With higher concentration of $CO_2$ outside, carbonation velocity increases. In order to reduce $CO_2$ emission through entire service life, reducing initial $CO_2$ emission through mineral admixture like fly ash is more effective than increasing $CO_2$ storage through OPC since $CO_2$ is significantly emitted under manufacturing OPC and $CO_2$ storage in cover concrete of RC structure is not effective considering initial concrete amount in construction.

The Prediction model of Carbonation Process Using the Air Permeability Coefficient for Concrete (콘크리트의 투기계수를 이용한 중성화진행 예측모델)

  • Lim, Chang-Hyuck;Kim, Gyu-Yong;Lee, Tae-Gyu;Lee, Eui-Bae;Didolkar, Rahul B.;Kang, Suk-Pyo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.221-222
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    • 2010
  • In this study an expression is obtained the model equation for the prediction of carbonation based on the time and interaction velocity between $CO_2$ and $Ca(OH)_2$ diffusion coefficient.

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A Long-term Durability Prediction for RC Structures Exposed to Carbonation Using Probabilistic Approach (확률론적 기법을 이용한 탄산화 RC 구조물의 내구성 예측)

  • Jung, Hyun-Jun;Kim, Gyu-Seon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.5
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    • pp.119-127
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    • 2010
  • This paper provides a new approach for durability prediction of reinforced concrete structures exposed to carbonation. In this method, the prediction can be updated successively by a Bayes' theorem when additional data are available. The stochastic properties of model parameters are explicitly taken into account in the model. To simplify the procedure of the model, the probability of the durability limit is determined based on the samples obtained from the Latin Hypercube Sampling(LHS) technique. The new method may be very useful in design of important concrete structures and help to predict the remaining service life of existing concrete structures which have been monitored. For using the new method, in which the prior distribution is developed to represent the uncertainties of the carbonation velocity using data of concrete structures(3700 specimens) in Korea and the likelihood function is used to monitor in-situ data. The posterior distribution is obtained by combining a prior distribution and a likelihood function. Efficiency of the LHS technique for simulation was confirmed through a comparison between the LHS and the Monte Calro Simulation(MCS) technique.

Examining and Refining the Code for Durability Design Criteria of Concrete Carbonation (개정 콘크리트 탄산화 내구성 설계기준의 적용상 문제점 분석)

  • Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.3
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    • pp.285-293
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    • 2023
  • In this research, we embarked on a meticulous analysis of the challenges inherent in real-world scenarios relating to the durability design standards of engineered concrete structures and the assessment of carbonation durability in concrete guidelines. Our investigation brought to light substantial issues concerning constructability and quality assurance. The genesis of these problems is the exclusive application of prescribed strength to exterior walls, neglecting other elements to facilitate smoother licensing procedures. While this methodology aims to mitigate financial constraints in alignment with enhanced standards, it invariably invites complications. Furthermore, it is imperative to resolve the uncertainty surrounding durability evaluations by establishing a clear and definitive objective. Alongside this, actionable steps must be formulated to forestall the emergence of fissures between the floors of residential buildings, particularly apartment complexes. It is equally essential to tackle issues connected to application by devising a comprehensive management strategy for potential cracking during the phase of maintenance.

Fundamental Performance Evaluation of Recycled Aggregate Concrete with Varying Amount of Fly Ash and Recycled Fine Aggregate (순환잔골재 및 플라이애쉬 혼입률에 따른 순환골재 콘크리트의 압축강도, 염소이온 투과 및 중성화 저항성 평가)

  • Sim Jongsung;Park Cheolwoo;Moon Il-Whan;Lee Hee-Chul
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.793-801
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    • 2005
  • This study investigates fundamental properties of recycled aggregate concrete which incorporated 100% recycled coarse aggregate and various amount of recycled fine aggregate. In addition, for the purpose of the improvement of long term strength and durability, a part of cement was replaced with fly ash. Compressive strength and resistance to chloride ion penetration and carbonation were investigated. When the coarse aggregate was completely replaced with the recycled the replacement ratio of the fine aggregate with the recycled was recommended to be limited below 60% in the consideration of strength. The strength of the steam-cured specimen was very comparable to the wet-cured at 28 days. As fly ash content increased the resistance to chloride ion penetration was increased. The chloride ion penetrability based on the charge passed was found to be low at 21 days and very low at 56 days, respectively. Carbonation depth and carbonation velocity coefficient increased as the fly ash content increased and the relationship between the carbonation depth and recycled fine aggregate replacement ratio was not clear. Up to 28days, however, the measured carbonation depth was mostly less than 10mm which could be considered as low.

An Experimental Study on the Durability Evaluation of Polymer Cement Restoration Materials for Deteriorated Reinforced Concrete Structures (성능저하된 철근콘크리트구조물 폴리머시멘트계 보수용 단면복구재의 내구성 평가에 관한 실험적 연구)

  • Kim, Moo-Han;Kim, Jae-Hwan;Cho, Bong-Suk;Park, Jong-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.1
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    • pp.123-130
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    • 2006
  • The duties of the restorative materials are to bear up against stress and to protect reinforcement corrosion. So the restorative materials are estimated by various kinds of strength, permeability and etc, But, in case of existing performance evaluation of restorative materials, because various deterioration factors are separately acted, the system of performance evaluation is different from that of combined deterioration of real structure and it is difficult to evaluate the exact performance of restorative materials. In this study, to evaluate Performance of restorative materials, we compare their korea standard properties in terms of compressive and bending strength and permeability of water and air with real durability for carbonation, salt damage and actual reinforcement corrosion like ratio of corrosion area. weight reduction and corrosion velocity of steel bar under environment of combined deterioration. The results showed that strength and permeability of restorative materials are similar but their resistance to carbonation, salt damage and actual reinforcement corrosion are very different.

An Empirical Estimation Procedure of Concrete Compressive Strength Based on the In-Situ Nondestructive Tests Result of the Existing Bridges (공용중 교량 비파괴시험 결과에 기반한 경험적 콘크리트 압축강도 추정방법의 제안)

  • Oh, Hong-Seob;Oh, Kwang-Chin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.4
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    • pp.111-119
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    • 2016
  • Rebound hammer test, SonReb method and concrete core test are most useful testing methods for estimate the concrete compressive strength of deteriorated concrete structures. But the accuracy of the NDE results on the existing structures could be reduced by the effects of the uncertainty of nondestructive test methods, material effects by aging and carbonation, and mechanical damage by drilling of core. In this study, empirical procedure for verifying the in-situ compressive strength of concrete is suggested through the probabilistic analysis on the 268 data of rebound and ultra-pulse velocity and core strengths obtained from 106 bridges. To enhance the accuracy of predicted concrete strength, the coefficients of core strength, and surface hardness caused by ageing or carbonation was adopted. From the results, the proposed equation by KISTEC and the estimation procedures proposed by authors is reliable than previously suggested equation and correction coefficient.

Study on the Characterization of the Methane Stream Reforming in the High Pressure Using Reforming Catalyst (개질촉매를 이용한 고압에서 메탄 수증기 개질 특성연구)

  • 조종훈;백일현
    • Journal of Energy Engineering
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    • v.12 no.2
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    • pp.145-153
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    • 2003
  • In order to develop the carbonation process as a core technology of zero emission coal power plant, study on characterization of methane steam reforming (MSR) which is main reaction of this process was carried out. The effects of gas hourly space velocity (GHSV), steam/carbon (S/C) ratio and pressure in the MSR using reforming catalyst were investigated. The equilibrium composition of the gases produced in the MSR were obtained below GHSV 7,000 hr$\^$-1/. The operating conditions of carbonation process using hybrid reaction (MSR+CO$_2$ adsorption using CaO) were 700∼800$^{\circ}C$ and S/C ratio of 2.5∼3. The equilibrium mixture of gases composed of 75∼78% H$_2$ and 8∼9% CO$_2$ at atmospheric pressure and 60∼78% H$_2$ and 9∼l1% CO$_2$ at 1∼30 atm respectively under above operating conditions.

The Evaluation of Durability Performance in Mortar Curbs Containing Activated Hwangtoh (활성 황토를 혼입한 모르타르 기반 경계석의 내구성능 평가)

  • Kwon, Seung-Jun;Kim, Hyeok-Jung;Yoon, Yong-Sik
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.520-527
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    • 2020
  • Hwangtoh is the rich resource that accounts for about 15.0% of the domestic soil, and can be used as the admixture of concrete with Pozzolan characteristics if activated by rapidly freezing after burning with high temperature. In this study, the mortar curbs containing active hwangtoh were produced, based on the mixture for the mortar curbs sold on the market. The substitution rate of active hwangtoh were considered 10.0% and 25.0%, and the test items were selected to compressive and flexural strength tests, freezing/thawing resistance tests, accelerated carbonation tests, and accelerated chloride diffusion tests. In the results of the mechanical performance, it was showed that the highest strength was evaluated in OPC mixture, and the increase in strength was small by the increase of age, which was believed to be due to the fact that most of the strength in each mixture was created in three days of steam curing. The results of the freezing/thawing tests for 28 aged days showed the reduction rate of compressive strength was 85.0% or higher for all specimen, meeting the criteria presented. The accelerated carbonation tests were carried out on the specimen at 28 days of age, and the results showed that the mortar with active hwangtoh had lower carbonation resistance performance than mortar with OPC. The passed charge of each mixture was assessed in accordance with ASTM C 1202 on 28 and 91 aged days. The OPC mixture had "Low" rate and the mortar with active hwangtoh had "Moderate" rate. So it was thought that the mortar with active hwangtoh had appropriate resistance performance for chloride attack.

Preparation of Regenerated Cellulose Fiber via Carbonation (II) - Spinning and Characterization -

  • Oh Sang Youn;Yoo Dong Il;Shin Younsook;Kim Hak Yong;Kim Hwan Chul;Chung Yong Sik;Park Won Ho;Youk Ji Ho
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.95-102
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    • 2005
  • Sodium cellulose carbonate (CC-Na) dissolved in $8.5\;wt\%$ NaOH/ZnO (100/2-3, w/w) aqueous solution was spun into some acidic coagulant systems. Diameter of regenerated cellulose fibers obtained was in the range of $15-50\;{\mu}m$. Serrated or circular cross sectional views were obtained by controlling salt concentration or acidity in the acid/salt/water coagulant systems. Velocity ratio of take-up to spinning was controlled up to 4/1 with increasing spinning velocity from 5 to 40 m/min. Skin structure of was developed at lower acidity or higher concentration of coagulants. Fineness, tenacity and elongation of the regenerated cellulose fibers were in the range of 1.5-27 denier, 1.2-2.2 g/d, and $8-11.3\;\%$, respectively. All of CC-Na and cellulose fibers spun from CC-Na exhibited cellulose II crystalline structure. Crystallinity index was increased with increasing take-up speed.