• Journal of Korean Society for Atmospheric Environment
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• v.18 no.E1
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• pp.1-12
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• 2002

One technique for determining dry acid deposition fluxes involves measurement of time - averaged ambient concentrations of dry acid deposition species using filter packs (FP) coupled with estimates of mean deposition velocities for the exposure period. A critical problem associated with filter pack data comparisons between various field sampling networks is the use of diverse sampling flow rates and duration protocols. Field experiments were conducted to evaluate the effects of varying sampling flow rates, from 1.5 to 10 standard liters per minute, on total nitrate and sulfate measurements of specific dry acid deposition species . Collocated FP samplers were used to determine sampling and analysis data reproducibility and representativeness . Ambient air samples were simultaneously collected using groups of filter packs operated at various flow rates over identical 7 day periods. The species measured were sulfur dioxide, particulate sulfate , nitric acid and particulate nitrate. Statistical results (ANOVA; alpha level 5%) showed that neither the low nor high sampling flow rates caused a significant difference in the measurements of total sulfate and adjusted total nitrate (ATN) . However, it was concluded that for high flow rate sampling measurements, total nitrate (TN) could be affected during extended sampling durations because of potential nitric acid overloading and breakthrough. Although the previous workers (Costello, 1990; Quillian, 1990) used much higher sampling flow rates (~ 17 sLpm) than employed here, it was assumed that for a high loading (> 50$\mu\textrm{g}$ HNO$_3$) of nitric acid on the Nylon filters, a significant fraction (~10%) of nitric acid could pass through the Nylon filters and be collected on the carbonate impregnated filters. It was concluded that even at the highest sampling flow rate employed (10 sLpm) at the Cary Forest site, nitric acid breakthrough was less than 10% of the total HNO$_3$ collected. However, for a heavily polluted urban airshed or with longer sampling times , higher filter loadings could result in substantial nitric acid breakthrough and HNO$_3$concentrations would be underestimated.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.45 no.3
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• pp.262-270
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• 2012

Seaweeds provide habitats in which marine animals can spawn and develop, and serve as a food supply for algaegrazing species such as sea urchins and abalone. Recently, seaweed species have disappeared from coastal ecosystems, leaving barren ground, defined as habitats that have lost their algae forests and where coralline algae containing calcium carbonate components have become encrusted on rocks. The biological causes of barren ground include grazing by herbivores and excessive seaweed harvest. The environmental harm caused by the spread of barren ground includes accelerated eutrophication following the reduction in seaweed, which plays an important role in oceanic purification. In the present study, we identified the relationships between various seaweed species and the occurrence of barren ground. Subtidal benthic macroalgal flora and community structure were observed seasonally on barren ground along vertical transects of rocky shores of Bihwa, Samchuck, and the east coast of Korea from February to November 2006. Fifty-eight seaweed species were identified, including 7 green, 15 brown, and 36 red algae species. There were between 6 and 28 species among seasons. Over the whole study period, average seaweed biomass (g wet wt $m^{-2}$) was 241.90 g, with a seasonal range of 25.26 to 760.34 g. Seaweed biomass declined with increasing seawater depth and ranged between 91.26 and 422.08 g. The vertical distribution of algae was characterized by Undaria pinnatifida and Sargassum honeri at 5 m, S. honeri and U. pinnatifida at 10 m, and U. pinnatifida and Agarum clathratum at 15 m depth. Seasonal patterns in community indices were not found. Community indices showed different patterns along vertical shoreline gradients; the dominance index increased but the richness, evenness, and diversity indices decreased with seawater depth. Sea urchin density was 8 to 24 individ. $m^{-2}$ in Bihwa. These urchin populations had significantly aggregated spatial patterns and recurrent destructive grazing appeared to be occurring.

• Korean Journal of Environment and Ecology
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• v.20 no.4
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• pp.436-447
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• 2006

Recently, there is increasing demand on enhancing the efficiency of hydro-seed spraying in afforestation for damaged or degraded land including forest road slopes. In this study, we focus on how seed coating and molding may affect seed germination and seedling growth. Plant species used in the study are Lespedeza cyrtobotrya, Indigofera pseudotinctoria, Arudineila hirta, Poa pratensis, and Lolium perenne. The results of seed germination and seedling growth with and without seed coating and molding are analyzed as follows: 1. For all the species and in both seeding with molding covered with soil and seeding without molding in which seeds were over sown, the increment of germination ratio by seed coating method is greater than by non·coating one. Seed coating increases average germination ratios observed in seeding with molding and without molding by 11.2% and 21.4%, respectively. Germination force may decrease from 0.8 to 3.7 days depending on the plant species and the treatments. The $LD_{50}$ decreased by $0.8{\sim}2.6$ days. However, seed coating delays the start of germination by approximate 1 day for all of the observed plants. 2. Seed coating may have the effect of accelerating the growth of stem and leaf and root. The experimental result shows that seed coating leads to 21.7% and 34.8% increment of average stem and leaf growth by seeding with molding and without molding, respectively. In terms of root growth, seeding with molding results in 22.0% increment while seeding without molding produces 26.2% increased root growth. 3: Compared to seeding without molding, germination starts on an average of 1.3 days later in seeding coated seeds with molding. However. the germination ratio is increased by 5%, and germination force and $LD_{50}$ are observed to shorten by 1.0 day and 1.4 days, respectively. Meanwhile, whether seeds are coated or not may be more related with germination and seedling growth in seeding without molding than with those in seeding with molding. 4. In this study, coating materials are examined to look at which ones are better in each treatment. Coating with Vermiculite+Talcum is the most effective in germination and seedling growth for overall plants. Seed coating using Bentonite, Calcium Carbonate, and Calcium Hydroxide shows better results than non-coating does. 5. When seeds are coated, the greatest enhancement of seed germinations was observed in Indigofera pseudotinctoria and, in the case of seedling growth, Lespedeza cyrtobotrya has the most increasing observation value among the 5 examined species. These results may indicate that woody plant seeds, having greater sizes of seeds than ones of grass seeds, may have greater relation with seed coating than grass plant seeds may have. 6. Therefore, if seeds cannot be molded up after hydro-seeding on forest road slopes, it is recommended that seeds for restoration be pre-coated with Vermiculite+Talcum and then be sowed, in order to quickly stabilize the damaged slope and achieve successful afforestation.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.4
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• pp.403-408
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• 2006

The plate reformer consisting of combustion chamber and reforming chamber for 25 kW MCFC stack has been operated and computational fluid dynamics was applied to estimate reactions and thermal fluid behavior in the reformer. The methane air 2-stage reaction was assumed in the combustion chamber, and three step steam reforming reactions were included in the calculation. Flow uniformity, reaction rate and species distribution, and temperature distribution were analyzed. In particular, temperature distribution was compared with the measurements to show good agreement in the combustion chamber, however, inappropriate agreement in the reformer chamber.

• Environmental Engineering Research
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• v.11 no.1
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• pp.54-61
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• 2006

An electron probe microanalysis (EPMA) investigation can provide quantitative and qualitative insight into the nature of the surface and bulk chemistry on solidified waste forms(SWF). The proportion of Pb in grain areas is below 0.3 wt. %, and the proportion near the border of the grain slightly increases to 0.98 wt. % but in the inter-particle areas farther from the grain, the concentration of Pb markedly increases. It is apparent that very little Pb diffuses into the tricalcium silicate($C_3S$) particles and most of the Pb exists as precipitates of sulfate, hydroxide, and carbonate in the cavity areas between $C_3S$ grains. Calcite additions on Pb-doped SWF are also observed to induce deeper incorporation of lead into the cement grains with EPMA line-analysis of cross-sections of cement grains. The line-analysis reveals the presence of $0.2{\sim}5$ weight % Pb over $5\;{\mu}m$ from cement grain boundaries. In the inter-particle areas, the ratio of Ca, Si, Al and S to Pb is relatively similar even at some distance from the grain border and the Pb (wt. %) ratio is reasonably constant throughout the whole inter-particles area. It is apparent that the enhanced development of C-S-H on addition of calcite can increasingly absorbs lead species within the silica matrix.

• Journal of the Korean Wood Science and Technology
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• v.30 no.3
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• pp.109-115
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• 2002

Mycelial growth of L. edodes by pretreatments of softwood was studied on a sawdust medium. The sawdust used was from the following softwood species : Larix leptolepis, Pinus densiflora and Pinus koraiensis. The pretreatment consisted of cold-water (48 h), hot-water (3 h) and steam extractions (3 h) at a ratio of 500 g : 3,000 mL (sawdust : distilled water). The sawdust medium was a mixture of 76% sawdust, 20% rice bran, 3% glucose, 0.4% potassium nitrate and 0.6% calcium carbonate. Following sawdust pretreatments proved most suitable : L. leptolepis (steam extraction), P. densiflora (hot-water extraction) and P. koraiensis (hot-water extraction). Mycelial growth on P. koraiensis sawdust increased in proportion to an increase in hot-water extraction time. Mycelial growth was optimum on the sawdust extracted for 12 hours, hot-water extraction beyond this period proved unsuitable. With the exception of P. densiflora at 100 ㎍/mL, antifungal activity occurred in every sample. Maximum inhibition of mycelial growth was obtained from following concentration of hot-water extractives : P. densiflora (10⁴ ㎍/mL) and P. koraiensis (10⁴ ㎍/mL). This study has provided useful preliminary information for the cultivation of L. edodes.

• Journal of Electrochemical Science and Technology
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• v.14 no.3
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• pp.272-282
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• 2023

Ni-rich layered oxides cathode has recently gained attention as an advanced cathode material due to their applicable energy density. However, as the Ni component in the layered site is increased, the high reactivity of Ni⁴⁺ results in parasitic reaction associated with decomposing electrolyte, which leads to a rapid decreasing the lifespan of the cell. The electrolyte additive triallyl borate (TAB) improves interfacial stability, leading to a stable cathode-electrolyte interphase (CEI) layer on the LNCM83 cathode. A multi-functionalized TAB additive can produce a uniformly distributed CEI layer via electrochemical oxidation, which implies an increase in long-term cycling performance. After 100 cycles at elevated temperature, the cell tested by 0.75 TAB retained 88.3% of its retention ratio, whereas the cell performed by TAB-free electrolyte retained 64.1% of its retention. Once the TAB additive formed CEI layers on the LNCM83 cathode, it inhibited the decomposition of carbonate-based solvents species in addition to the dissolution of transition metal components from the cathode. The addition of TAB to LNCM83 cathode material is believed to be a promising way to increase the electrochemical performance.

• Journal of the Mineralogical Society of Korea
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• v.15 no.3
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• pp.231-240
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• 2002

Microbial metal reduction influences the biogeochemical cycles of carbon and metals as well as plays an important role in the bioremediation of metals, radionuclides, and organic contaminants. The use of bacteria to facilitate the production of magnetite nanoparticles and the formation of carbonate minerals may provide new biotechnological processes for material synthesis and carbon sequestration. Metal-reducing bacteria were isolated from a variety of extreme environments, such as deep terrestrial subsurface, deep marine sediments, water near Hydrothemal vents, and alkaline ponds. Metal-reducing bacteria isolated from diverse extreme environments were able to reduce Fe(III), Mn(IV), Cr(VI), Co(III), and U(VI) using short chain fatty acids and/or hydrogen as the electron donors. These bacteria exhibited diverse mineral precipitation capabilities including the formation of magnetite ($Fe_3$$O_4$), siderite ($FeCO_3$), calcite ($CaCO_3$), rhodochrosite ($MnCO_3$), vivianite [$Fe_3$($PO_4$)$_2$ .$8H_2$O], and uraninite ($UO_2$). Geochemical and environmental factors such as atmospheres, chemical milieu, and species of bacteria affected the extent of Fe(III)-reduction as well as the mineralogy and morphology of the crystalline iron mineral phases. Thermophilic bacteria use amorphous Fe(III)-oxyhydroxide plus metals (Co, Cr, Ni) as an electron acceptor and organic carbon as an electron donor to synthesize metal-substituted magnetite. Metal reducing bacteria were capable of $CO_2$conversion Into sparingly soluble carbonate minerals, such as siderite and calcite using amorphous Fe(III)-oxyhydroxide or metal-rich fly ash. These results indicate that microbial Fe(III)-reduction may not only play important roles in iron and carbon biogeochemistry in natural environments, but also be potentially useful f3r the synthesis of submicron-sized ferromagnetic materials.

• Atmosphere
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• v.29 no.4
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• pp.403-416
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• 2019

Precipitation samples were collected at the GAW Stations in Anmyeon-do and Gosan for 10 years (2008-2017) to analyze pH, electrical conductivity and NH₄⁺, Na⁺, K⁺, Mg²⁺, Ca²⁺, SO₄^2-, NO₃^-, Cl^-, and F^- ions. From the analysis, the correlation between pH and rainfall, the composition of precipitation and comparison with other regions, and the results of neutralization characteristics by seasonal and pH were determined. In the comparison of ion balance and conductivity for the validation of analytical data, the correlation coefficients were within the range of 0.996~0.999, implying good linear relationship. The volume-weighted pH of the Anmyeon-do and Gosan areas were 4.7 and 4.9, respectively. The pH of the rainfall was affected by washout and rainout in both areas. The ionic strength of precipitation at Anmyeondo and Gosan were 0.42 ± 0.63 mM and 0.37 ± 0.75 mM, indicating about 27.6% and 35.3% of the total precipitation as per a pure precipitation criterion (10^-4 M), respectively. The composition ratio of ionic species were 44.7% and 57.5% for marine sources (Na⁺, Mg²⁺, Cl^-), 40.6% and 22.2% for the secondary inorganic components (NH₄⁺, nss-SO₄^2-, NO₃^-), and 5.6% and 4.0% for the soil source (nss-Ca²⁺), respectively. The neutralization factor of Anmyeon-do and Gosan were 0.43~0.65 and 0.34~0.48, and the neutralization factors of calcium carbonate were 0.15~0.34 and 0.25~0.30, respectively. Thus, both regions have the highest rate of neutralization caused by ammonia. As pH increased in Anmyeon-do and Gosan, change in calcium carbonate became greater than that in ammonia.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.4
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• pp.197-203
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• 2015

Particulate matter (PM) has emitted in many regions of the world and is causing many health-related problems. Thus reasonable politics and solutions are needed to reduce PM in Seoul. Further it is required to clearly explain the major portions of chemical components contained in $PM_{10}$ to figure out the characteristics of $PM_{10}$, and to develop effective reduction measures in order to decrease the adverse effects of $PM_{10}$. $PM_{10}$ samples were collected in Seoul and analyzed their ions to examine the physical and chemical characteristics of ionic species. Since hydrogen ion ($H^+$) and carbonate ion (${CO_3}^{2-}$)) cannot be analyzed by Ion chromatography (IC), concentrations of $H^+$ and ${CO_3}^{2-}$ were initially estimated by pH and equivalent differences between anions and cations in this study. Starting from the study findings, good combination results for compositional patterns between anions and cations were obtained by applying a mathematical modelling technique that was based on the mass balance principle. The ions in $PM_{10}$ were combined with $H^+$, ${CO_3}^{2-}$, and supplement for $NO_3{^-}$, $Cl^-$ formed such compounds $NH_4Cl$, $NH_4NO_3$, $CaSO_4$, $(NH_4)_2SO_4$, $NaNO_3$, NaCl, $Na_2CO_3$, and $(NH_4)_2CO_3$ in the study area.