• Journal of Korean Society on Water Environment
• /
• v.37 no.6
• /
• pp.483-492
• /
• 2021

This study evaluated the removal efficiencies of methylene blue (MB) and humic acids (HA) using a rice husk (RH) biochar and powdered activated carbon (PAC). The pseudo-second-order model better presented the adsorption of MB and HA onto a RH biochar than the pseudo-first-order model. Furthermore, better description of the adsorption behavior of MB and HA by the Langmuir isotherm model (R² of the RH biochar: MB = 0.986 and HA = 0.984; R² of PAC: MB = 0.997 and HA = 0.989) than the Freundlich isotherm model (R² of the RH biochar: MB = 0.955 and HA = 0.965; R² of PAC: MB = 0.982 and HA = 0.973) supports the assumption that monolayer adsorption played key roles in the removal of MB and HA using the RH biochar and PAC. Batch experiments were performed on the effects of dosage, temperature, and pH. For all experiments, PAC showed higher efficiencies than RH biochar and MB adsorption efficiencies were higher than those of HA. Adsorption efficiencies increased with increasing amounts of adsorbents and temperature. As the pH increased, adsorption efficiencies of MB were increased while adsorption efficiencies of HA were decreased.

• Applied Chemistry for Engineering
• /
• v.8 no.2
• /
• pp.204-210
• /
• 1997

Zeolite 4A-impregnated complex molecular sieve was prepared by hydrothermal reaction after aluminosilicate gel was penetrated into the pore of activated carbon granule. The crystals of zeolite 4A mainly were formed in the macropore of activated carbon, and their average diameter is $0.8{\mu}m$. The pore volume of activated carbon granule is $0.67m{\ell}/g$, and the pore volume of the sample including 21.6wt% of zeolite 4A crystal is $0.41m{\ell}/g$ decreasing the pore volume by 40% due to the crystallization of zeolite 4A crystals on the internal surface of activated carbon. The calcium ion exchange capacity of zeolite 4A-impregnated sample is 320mg $CaCO_3/g$ zeolite, and this value is almost the same as that of zeolite 4A powder. The crystal of zeolite 4A was not separated from the support of activated carbon granule in the course of ultrasonic dispersion. The adsorption isotherm of water on zeolite 4A-impregnated sample shows the intermediate shape between types, I and III. In addition, zeolite 4A-impregnated sample shows the hydrophilic and hydrophobic properties simultaneously.

• Smart Media Journal
• /
• v.12 no.5
• /
• pp.36-45
• /
• 2023

Recently, in digital agriculture, the types and utilization of greenhouses based on IoT are spreading, and greenhouses are being modernized, enlarged, and even factoryized using smart technology. However, a specific standardization plan has not been proposed according to the equipment for data collection in the smart greenhouse and the size or shape of the greenhouse. In other words, there is a lack of standard data for facility equipment, such as the type and number of sensors and equipment according to the size of the greenhouse, the type of greenhouse construction film and materials suitable for crops and carbon neutrality. Therefore, in this study, the suitability of the implementation, installation and quantity of IoT equipment for data collection was tested, and some standard technologies were presented through the implementation of data collection and communication methods. In addition, impact strength, tensile, tear, elongation, light transmittance, and lifespan issues for PE, PVC, and EVA, which account for about 90% of existing greenhouses, were presented, and the shape, size, and environmental problems of greenhouses made of films were presented. presented in the text. In this research paper, a standardized carbon-neutral modular smart greenhouse using nano-material film was implemented as a solution to environmental problems such as greenhouse size, farm crop type, greenhouse lifespan, and film, and its performance with existing greenhouses was analyzed and presented. Through this, we propose a modularized greenhouse that can be expanded or reduced freely without distinction in the size of the greenhouse or the shape of farmhouse crops, and the lifespan is extended and standardized. Finally, the average characteristics of greenhouses using existing PE, PVC, and EVA films and the characteristics of greenhouses using new carbon-neutral nanomaterials are compared and reviewed, and a plan to implement an expandable IoT greenhouse that supports carbon neutrality is proposed.

• Proceedings of the KSR Conference
• /
• 2011.10a
• /
• pp.1059-1065
• /
• 2011

In line with the expansion of electric railway, reducing carbon emission and optimal train operation are required by economical, eco-friendly and efficient management. Most of the energy consumption in electric railway is consumed by train operation. So it is important that minimize the energy consumption in train operation. An analysis of the operation performance of the new model vehicle which in South Korea, Korail introduced shows that the energy consumption is different in line with the skill level of the engine driver. In this study, the know-how of train operation of a skilled engine driver is systematized by using artificial intelligence, and the technique which supports engine drivers with train operation was offered. As a result of applying in South Korea, the Gyeongbu line by using simulation, it confirmed that the maximum 20% can reduce the energy consumption in comparison with unskilled engine drivers in case of applying the Expert System.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.19 no.2
• /
• pp.75-80
• /
• 2020

In this study, we designed car frames for collision analysis using carbon fiber reinforced polymer (CFRP) as the lighter composite material. The impact conditions were 100 percent frontal impact, 40 percent frontal impact, and 90 degrees side impact. The impact analysis measured the maximum stress at velocities of 20km/h and 40km/h for each condition and evaluated the vulnerable points in the car frame. Additional supports have been designed both to improve the weak points in existing vehicle frames, and to be taken into account when new parts are assembled. Our impact analysis compared the results of maximum stress on the car frame with and without the support.

• Steel and Composite Structures
• /
• v.34 no.4
• /
• pp.599-613
• /
• 2020

In this article, free vibration attributes of double-walled carbon nanotubes based on nonlocal elastic shell model have been investigated. For this purpose, a nonlocal Flügge shell model is established to observe the small scale effect. The wave propagation is employed to frame the governing equations as eigenvalue system. The influence of nonlocal parameter subjected to different end supports has been overtly examined. A suitable choice of material properties and nonlocal parameter been focused to analyze the vibration characteristics. The new set of inner and outer tubes radii investigated in detail against aspect ratio and length. The dominance of boundary conditions via nonlocal parameter is shown graphically. The results generated furnish the evidence regarding applicability of nonlocal shell model and also verified by earlier published literature.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.11
• /
• pp.3145-3150
• /
• 2010

Ruthenium catalysts modified by selenium have been introduced as alternative materials to Pt in Direct methanol fuel cells (DMFCs). RuSe nano-particles were synthesized on the Vulcan XC72R carbon supports via polyol method. The prepared catalysts were electrochemically and physically characterized by cyclic voltammetry (CV,) linear sweep voltammetry, methanol tolerance test, X-ray diffraction (XRD), Transmission electron microscopy (TEM), Energydispersive Spectrometer (EDS) and X-ray photoelectron spectroscopy (XPS). Increasing the Se concentration up to 20 at % increased the electro-catalytic activity for the oxygen reduction. By increasing Se amount, Ru metallic form on the surface was increased. The $Ru_{80}Se_{20}$/C catalysts showed the highest oxygen reduction reaction (ORR) activity and outstanding methanol tolerant property in half cell tests as well as single cell test.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.10
• /
• pp.2973-2979
• /
• 2010

The newly synthesized homogeneous chiral Co(III) salen complexes were anchored non-covalently on the acidic sites of mesoporous Al-SBA-15. The Bronsted and Lewis acidic sites are attributed to the immobilization of fluorine functionalized chiral salen complexes on the supports. XRD, BET, TEM, FT-IR and ESCA (XPS) analyses were performed to characterize the property of support, and the structure of new homogeneous and heterogeneous chiral Co salen catalyst. The homogeneous and heterogeneous catalysts could be applied in asymmetric ring opening of epichlorohydrine (ECH) by water. They showed very high enantioselectivity and a good yield up to 99% in the catalytic synthesis of optically active products.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.06a
• /
• pp.107-109
• /
• 2006

This study focuses on a determination of amount of Pt in the Pt/C for catalysts of polymer electrolyte membrane fuel cells (PEMFC). PEMFC offer low weight and high power density and being considered for automotive and stationary power applications. The PEMFC performance is influenced by several factors, including catalysts and structure of electrode and membrane type. Catalyst of electrode is important factor for PEMFC. One of the obstacles prevent ing polymer electrolyte membrane fuel cells from commercialization is the high cost of noble metals to be used as catalyst, such as platinum To effectively use these metals, they have to be will dispersed to small particles on conductive carbon supports. The optimal amount of Pt in Pt/C for cathode catalyst was investigated by using polarization curves in single cell with $H_2/O_2$ operation.

• Computers and Concrete
• /
• v.25 no.4
• /
• pp.343-354
• /
• 2020

In this paper, vibration characteristics of chiral double-walled carbon nanotubes entrenched on Kelvin's model. The Eringen's nonlocal elastic equations are being combined with Kelvin's theory to observe small scale response. A nonlocal model has been formulated to explore the frequency spectrum of chiral double-walled CNTs along with diversity of indices and nonlocal parameter. Wave propagation is proposed technique to establish field equations of model subjected to four distinct end supports. The significance of scale effect in relevance of length-to-diameter and thickness- to- radius ratios are discussed and displayed in detail.