• Journal of the Semiconductor & Display Technology
• /
• v.4 no.3 s.12
• /
• pp.11-15
• /
• 2005

This paper shows that carbon nanotubes can be applied to a nanopipette. Nano space in atomic force microscope multi wall carbon nanotube tips is filled with molecules and atoms with charges and then, the tips can be applied to nanopipette when the encapsulated media flow off under applying electrostatic farces. Since the nano space inside the tips can be refilled, the tips can be permanently used in ideal conditions of no chemical reaction and no mechanical deformation. Molecular dynamics simulations for nanopipette applications demonstrated the possibility of nano-lithography or single-metallofullerene-transistor array fabrication.

• Ceramist
• /
• v.22 no.3
• /
• pp.316-327
• /
• 2019

Carbon nitride has drawn broad interdisciplinary attention in diverse fields such as catalyst, energy storage, gas adsorption, biomedical sensing and even imaging. Intensive studies on carbon dioxide (CO₂) capture using carbon nitride materials with various nanostructures have been reported since it is needed to actively remove CO₂ from the atmosphere against climate change. This is mainly due to its tunable structural features, excellent physicochemical properties, and basic surface functionalities based on the presence of a large number of -NH or -NH₂ groups so that the nanostructured carbon nitrides are considered as suitable materials for CO₂ capture for future utilization as well. In this review, we summarize and highlight the recent progress in synthesis strategies of carbon nitride nanomaterials. Their superior CO₂ adsorption capabilities are also discussed with the structural and textural features. An outlook on possible further advances in carbon nitride is also included.

• 한국태양에너지학회:학술대회논문집
• /
• 2012.03a
• /
• pp.406-409
• /
• 2012

Recently, enormous research efforts have been focused on the development of non-precious catalysts to replace Pt for electrocatalytic oxygen reduction reaction (ORR), and to reduce the cost of proton exchange membrane fuel cells (PEMFCs). In recent years, heteroatom (N, B, and P) doped carbon nanostructures have been received enormous importance as a non-precious electrode materials for oxygen reduction. Doping of foreign atom into carbon is able to modify electronic properties of carbon materials. In this study, nitrogen and boron doped carbon nanostructures were synthesized by using a facile and cost-effective thermal annealing route and prepared nanostructures were used as a non-precious electrocatalysts for the ORR in alkaline electrolyte. The nitrogen doped carbon nanocapsules (NCNCs) exhibited higher activity than that of a commercial Pt/C catalyst, excellent stability and resistance to methanol oxidation. The boron-doped carbon nanostructure (BC) prepared at $900^{\circ}C$ showed higher ORR activity than BCs prepared lower temperature (800, $700^{\circ}C$). The heteroatom doped carbon nanomaterials could be promising candidates as a metal-free catalysts for ORR in the PEMFCs.

• Composites Research
• /
• v.29 no.4
• /
• pp.138-144
• /
• 2016

Recently, electromagnetic interference (EMI) shielding materials have been extensively developed and significantly considered to protect electronic systems from harmful electromagnetic waves. Although, metal-based materials show high electrical conductivity and EMI shielding effectiveness, they have several challenging problems such as high density and corrosion. Carbon-based materials have been acclaimed as alternative EMI materials due to light weight, high mechanical properties, resistance to corrosion and excellent electrical conductivity. Here, we introduce 1-phase and 2-phase carbon materials as well as 3-phase hybrid carbon materials. The 3-phase hybrid carbon materials composed of metal nanoparticles, carbon nanotubes and graphene can be used as a promising EMI shielding material.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.16 no.8
• /
• pp.723-730
• /
• 2003

The CN(carbon nitrogen) nanofibers were formed by HIP(high isostatic pressure) process. From the field emission measurement, CN nanofibers shows an excellent characteristics of emitter, better than CNTs and carbon nanofibers. The structures obtained can be divided into three groups : bamboo-like fibers, corrugated structures and bead necklace-like fib res. Emission properties of CN nanofibers were investigated for spacing, between anode and cathode, variation. Turn-on fields was 1.4 v/$\mu\textrm{m}$. The time reliability and light emission test were carried out for about 100 hours. We suggest that CN nanofibers can be possibly applied to the high brightness flat lamp because of low turn-on field and time reliability

• Advances in concrete construction
• /
• v.3 no.1
• /
• pp.15-37
• /
• 2015

Ongoing efforts for improved fracture toughness of engineered cementitious materials address the inherent brittleness of the binding matrix at several different levels of the material's geometric scale through the addition of various types of reinforcing fibers. Crack control is required for crack widths that cover the entire range of the grain size spectrum of the material, and this dictates the requirement of hybrid mixes combining fibers of different size (nano, micro, macro). Use of Carbon Nano-Tubes (CNT) and Carbon Nano-Fibers (CNFs) as additives is meant to extend the crack-control function down to the nanoscale where cracking is believed to initiate. In this paper the implications of enhanced toughness thus attained at the material nanostructure are explored, with reference to the global smeared constitutive properties of the material, through consistent interpretation of the reported experimental evidence regarding the behavior of engineered cementitious products to direct and indirect tension.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.8
• /
• pp.2535-2538
• /
• 2012

$SnO_2@carbon$ tube-core nanowire was synthesized via a facile self-organized method, which was in situ by one step via Chemical Vapor Deposition. The resulting composite was characterized by scanning electron microscopy, X-ray diffraction and transmission electron microscope. The diameter of the single nanowire is between 5 nm and 60 nm, while the length would be several tens to hundreds of micrometers. Then X-ray diffraction pattern shows that the composition is amorphous carbon and tin dioxide. Transmission electron microscope images indicate that the nanowire consists of two parts, the outer carbon tube and the inner tin dioxide core. Meanwhile, the possible growth mechanism of $SnO_2@carbon$ tube-core nanowire is also discussed.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.377-377
• /
• 2016

Under nanosecond-pulsed laser irradiation, light-absorbing thin films have been used for photoacoustic transmitters for ultrasound generation. Especially, nanostructured absorbers are attractive due to high optical absorption and efficient thermoacoustic energy conversion: for example, 2-dimensional (2-D) gold nanostructure array, synthetic gold nanoparticles, carbon nanotubes (CNTs), and reduced graphene oxides. Among them, CNT has been used to fabricate a composite film with polydimethylsiloxane (PDMS) that exhibits excellent photoacoustic conversion performance for high-frequency, high-amplitude ultrasound generation. Previously, CNT-PDMS nanocomposite films were made by using a high-temperature chemical vapor deposition (HTCVD) process for CNT growth. However, this approach is not suitable to fabricate large-area CNT films (>several cm2). This is because a chamber dimension of HTCVD is limited and also the process often causes nonuniform CNT growth when the film area increases. As an alternative approach, a solution-based process can be used to overcome these issues. We develop PDMS composite transmitters, based on the solution process, using several nanostructured light-absorbers such as CNTs, nanoink powders, and imprinted regular arrays of gold nanostructure. We compare fabrication processes of each composite transmitters and photoacoustic output performance.

• Applied Microscopy
• /
• v.46 no.1
• /
• pp.37-44
• /
• 2016

In this study $TiO_2$/reduced graphene oxide ($TiO_2/rGO$) bipyramid with tunable nanostructure was fabricated by two-step solvothermal process and subsequent heat-treatment in air. The as-synthesized anatase $TiO_2$ nanocrystals possessed morphological bipyramid with exposed dominantly by (101) facets. Polyethylenimine was utilized during the combination of $TiO_2$ and graphene oxide (GO) to tune the surface charge, hindering the restack of graphene during solvothermal process and resulting in 1 to 5 layers of rGO wrapped on $TiO_2$ surface. After a further calcination, a portion of carbon quantum dots (CQDs) with a diameter about 2 nm were produced owing to the oxidizing and cutting of rGO on $TiO_2$. The as-prepared $TiO_2/rGO$ hybrid showed a highly photocatalytic activity, which is about 3.2 and 7.7 times enhancement for photodegradation of methyl orange with compared to pure $TiO_2$ and P25, respectively. We assume that the improvement of photocatalysis is attributed to the chemical bonding between rGO/CQDs and $TiO_2$ that accelerates photogenerated electron-hole pair separation, as well as enhances light harvest.

• Korean Chemical Engineering Research
• /
• v.45 no.3
• /
• pp.264-268
• /
• 2007

The filtration performance of micron-sized metal fibrous filter was improved by synthesizing carbon nanotubes grown on the surface of metal fibers. The carbon nanotubes are grown with bush-like nanostructures covered around the micron-fibers or web-like nanostructures crossing between the fibers at different synthetic conditions. Filtration efficiency of CNT-metal-filter was measured and compared with the efficiency of the raw metal filter without CNTs. The developed CNT-metal-filter has higher filtration efficiency without significant difference in pressure drop compared with the conventional metal filter, which is because the carbon nanotubes function as the trap of pollutant nanoparticles.