• Title/Summary/Keyword: Carbon flow

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입자상 활성탄에 의한 Eosin Y의 홉착제거 (Adsorption Removal of Eosin Y by Granular Activated Carbon)

  • 이종집
    • 청정기술
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    • 제16권4호
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    • pp.277-283
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    • 2010
  • Eosin Y는 식용색소와 염료로 사용되지만 유해한 독성 물질이다. 본 연구에서는 입상활성탄에 의한 eosin Y의 흡착특성을 조사하였다. 활성탄의 양을 고정한 상태에서 초기농도, 접촉시간, pH 및 흡착온도 등이 eosin Y의 흡착에 미치는 영향을 회분식 빛 흡착칼럼실험을 통하여 연구하였다. Eosin Y에 대한 활성탄의 흡착능은 pH 조절에 의해 크게 개선되었으며, pH=3에서 초기농도 10 mg/L의 99%를 제거할 수 있었다. 회분식 흡착실험을 통해 흡착등온선을 구한 결과 eosin Y의 흡착평형관계는 293~333K 범위에서 Freundlich식이 잘 적용되었다. 흡착등온식으로 부터 평가된 k와 ${\beta}$값은 각각 19.56~134.62, 0.442~0.678이었다. 고정층의 운전조건이 파괴곡선에 미치는 영향을 조사하였다. 층높이 3 cm, 유속 2 g/min에서 eosin Y의 유입농도가 10 mg/L에서 30 mg/L로 증가함에 따라 파괴시간은 470분에서 268분으로 감소하였으며, 층높이 3 cm, 유입농도 10 mg/L에서 eosin Y의 초기유속이 l 에서 3 g/min로 증가함에 따라 파괴시간은 272분에서 140분으로 감소하였다. 또한 층높이가 증가함에 따라 파괴시간도 증가하였는데, 흡착대의 길이는 비슷한 양상을 나타냈다.

경계조건에 따른 나노파이프의 안정성 특성 (Effect of Boundary Conditions on the Stability Characteristics of Nanopipes)

  • 최종운;송오섭
    • 한국소음진동공학회논문집
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    • 제18권10호
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    • pp.1057-1064
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    • 2008
  • In this paper, static and oscillatory instability of nanopipes conveying fluid and modelled as a thin-walled beam is investigated. Effects of boundary conditions and non-classical transverse shear and rotary inertia are incorporated in this study. The governing equations and the three different boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extend Galerkin method which enables us to obtain more exact solutions compared with conventional Galerkin method. Variations of critical flow velocity for different boundary conditions of carbon nanopipes are investigated and pertinent conclusion is outlined.

Nonlocal 효과를 고려한 나노파이프의 안정성 해석 (Stability Analysis of Nanopipes Considering Nonlocal Effect)

  • 최종운;송오섭
    • 한국소음진동공학회논문집
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    • 제23권4호
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    • pp.324-331
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    • 2013
  • In this paper, static and oscillatory instability of a nanotube conveying fluid and modeled as a thin-walled beam is investigated. Analytically nonlocal effect, effects of boundary conditions, transverse shear and rotary inertia are incorporated in this study. The governing equations and boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extended Galerkin method which enables us to obtain more accurate results compared with conventional Galerkin method. Variations of critical flow velocity of carbon nanopipes with two different boundary conditions based on the analytically nonlocal theory and partially nonlocal theory are investigated and pertinent conclusions are outlined.

디젤 soot의 크기 측정을 위한 TIER-LII 센서헤드 설계기술 개발 (A Development of TIER-LII Sensor Head Design for Diesel Soot Size Measurement)

  • 서동규;김덕진;정재우;윤여성;이춘범
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.215-220
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    • 2004
  • The TIER-LII system was established and evaluated using carbon black for diesel particulate size measurement. It contains a new designed sensor head which makes it easier to be measured. Through LII signal analysis of some parameters, we can understand that there were few correlations observed in effect of temperature, shield gas flow rate, and mixture flow rate.. However, an amount of difference was observed in different size of particulates.

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유기물 박막에서 일어나는 친핵성 반응에 대한 연구 (Study on the nucleophilic reaction on Orgniac Thin Films)

  • 오데레사;김홍배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.170-171
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    • 2006
  • The chemical shift of SiOC film was observed according to the flow rate ratio. SiOC film has the broad main band of $880{\sim}1190cm^{-1}$ and the sharp Si-$CH_3$ bond at $1252cm^{-1}$, and the infrared spectra in the Si-O-C bond moved to low frequency according to the increasing of an oxygen flow rate. The chemical shift affected the carbon content in the SiOC film, and the decreasing of carbon atoms elongated the C-H bonding length, relatively. The main bond without the sharp Si-$CH_3$ bond at $1252cm^{-1}$ consisted of Si-C, C-O and Si-O bonds, and became the bonding structure of the Si-O-C bond.

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The flow of $CO_{2}$ and $N_{2}$ gases through Asymmetric polytherimide Membrane

  • Park, You-In;Lee, Kew-Ho
    • 한국막학회:학술대회논문집
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    • 한국막학회 1995년도 제3회 심포지움 (분리막 연구의 최신동향)
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    • pp.73-85
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    • 1995
  • The asymmetric hollow fiber membranes were prepared by the wet spining of polyetherimide dope solution and the effect of hollow fiber structures on the permeation characteristics of carbon dioxide and nitrogen gases through these membrane were investigated. As the concentration of the $\gamma$-butyrolactone (GBL) in dope solution, acting as a swelling agent was increased, the structure of hollow fiber was changed from the finger to sponge type. The permeabilities of gases (CO$_{2}$, N$_{2}$) through these membrane were measured over the wide range of pressure under different temperature. The effect of water vapor on the permeabilities of gases was also investigated. The measured permeabilities showed the different characteristics depending on the structure of membranes. It was found that the flow through the pores were dominant over the polymers matrix. Blocking effect by water vapor in the pores of skin layer greatly improved the ideal separation factor of carbon dioxide/nitrogen.

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차량용 Wheel Nut 소재의 보론강적용을 위한 단조공정에 관한 연구 (Study of a Forging Process for the Application of Boron Steel for Automotive Wheel Nut Material)

  • 이권수;안용식
    • 동력기계공학회지
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    • 제21권2호
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    • pp.41-47
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    • 2017
  • Boron steel (51B20) was cold forged using by new designed dies to apply for automotive aluminum wheel nut. The formability and mechanical properties of boron steel were compared with carbon steel(S45C) which has been used up to date for the wheel nut material. The formability was investigated on the dies designed with various types of punch nose using by FEM. The metal flow and compressive stress on the dies during cold forging were investigated and compared each other. The forging process with a new designed die showed the improved metal flow with a reduced forging load which resulted in the significant increase of the die life. It was recommended that the carbon steel for automotive wheel nut material could be substituted by the boron steel.

자기촉매 특성을 이용한 탄소나노튜브의 연소합성 연구 (Combustion synthesis of carbon nanotubes using their self-catalytic behavior)

  • 우상길;홍영택;권오채
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.1815-1820
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    • 2008
  • Self-catalytic behavior of combustion-synthesized carbon nanotubes (CNTs) is evaluated using a double-faced wall stagnation flow burner with a CNT-deposited stainless steel plate wall. CNT formation is observed using field-emission scanning and transmission electron microscopies and Raman spectroscopy. A self-catalytic behavior of multi-walled CNTs (MWCNTs) shows the enhanced ratio of channel diameter to tube wall thickness and the enhanced intensity ratio of G-band to D-band in Raman spectroscopy, implying that the quality of metal-catalytic, flame-synthesized MWCNTs can be much improved via a CNT self-catalytic flame-synthesis process. Thus, using a DWSF burner through the self-catalytic process has potential in mass production of CNTs having much improved quality.

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W-B-C-N 확산방지막에서 질소농도에 따른 Stress 에 대한 연구

  • 소지섭;이창우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.72-73
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    • 2005
  • Stress behavior was studied to investigate the internal behaviors of boron, carbon, and nitrogen in the 1000${\AA}$-thick tungsten boron carbon nitride (W-B-C-N) thin films. The impurities in the W-B-C-N thin films provide stuffing effects that were very effective for preventing the interdiffusion between interconnection metal and silicon substrate during the subsequent high temperature annealing process. The resistivity of W-B-C-N thin film decreases as an annealing temperature increase. The W-B-C-N thin films have compressive stress, and the stress value decreased up to $4.11\times10^{10}dyne/cm^2$ as an $N_2$ flow rate increases up to 3 sccm.

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Carbon/PVC 복합전극의 제조 및 전 바나듐계 레독스-흐름전지에의 응용 (Preparation of the Carbon/PVC Composite Electrode and application to All-Vanadium Redox Flow Battery)

  • 유철휘;장인영;정현철;김종철;강안수
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2002년도 추계학술대회
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    • pp.279-284
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    • 2002
  • All-vanadium redox flow battery(VRFB) has been studied actively as one of the most promising electrochemical energy storage systems for a wide range of applications such as electric vehicles, photovoltaic arrays, and excess power generated by electric power plants at night time. CPCS has been shown to have the characteristics as an excellent current collector for VRFB and electrochemical properties of specific resistivity 0.31 $\Omega$cm, which were composed of G-1028 80 wt%, PVC 10 wt%, DBP 5 wt% and FS 5 wt%. Energy efficiencies of VRFB with the CPCE and the existing electrode assembly were 84.14 % and 77.24 % respectively, in charge/discharge experiments at constant current of 200 mA, and the CPCE was confirmed to be suitable as the electrode of VRFB.

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