• 제목/요약/키워드: Carbon film

검색결과 1,327건 처리시간 0.029초

생분해성 고분자 코팅 조림묘목용 mulching mat 원지의 적용성 평가 (The applicable evaluation of biodegradable polymer coated-mulching paper for afforestation seedlings)

  • 이금자;유영정;고승태;김형진
    • 펄프종이기술
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    • 제42권1호
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    • pp.54-63
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    • 2010
  • Recently, as the function of largest supplier of biomass for "low carbon green growth", the necessity for systematic management of afforestation areas is emphasizing. The forestation of seedling, besides the afforestation cost itself, is required some additional follow-up management costs, like mowing and fertilizing of forestation area, and removal of bindweed. The mulching mat for afforestation seedlings is available for rooting of little seedlings as well as initial forestation expenses. Mulching technique is also used to control soil temperature and moisture by covering the surface of ground. In this study, the paper based-mulching film coated with biodegradable polymer and functional additive was specially produced using laboratory bar coater, and analyzed for its degradable behavior. Coating colors were prepared by dissolving PE (polyester) 80 % and PLA(polylactic acid) 20 % in chloroform and finally applied to handsheet prepared by preceding study conditions. Base paper and polymer-coated paper were artificially aged by 2 kinds of degradation methods, which are soil degradation by microorganism and light degradation by 257 nm UV wavelengths. Strength property, oxidation index and morphological property were evaluated by reduction rates of tensile strength, FTIR spectra ratio of carboxyl and carbonyl group and SEM micrograph. As these results, polymer coated-paper was superior to base paper in degradation behaviors, having results with lower reduction rate of strength properties.

Electrodeposition of Silicon in Ionic Liquid of [bmpy]$Tf_2N$

  • 박제식;이철경
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.30.1-30.1
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    • 2011
  • Silicon is one of useful materials in various industry such as semiconductor, solar cell, and secondary battery. The metallic silicon produces generally melting process for ingot type or chemical vapor deposition (CVD) for thin film type. However, these methods have disadvantages of high cost, complicated process, and consumption of much energy. Electrodeposition has been known as a powerful synthesis method for obtaining metallic species by relatively simple operation with current and voltage control. Unfortunately, the electrodeposition of the silicon is impossible in aqueous electrolyte solution due to its low oxidation-reduction equilibrium potential. Ionic liquids are simply defined as ionic melts with a melting point below $100^{\circ}C$. Characteristics of the ionic liquids are high ionic conductivities, low vapour pressures, chemical stability, and wide electrochemical windows. The ionic liquids enable the electrochemically active elements, such as silicon, titanium, and aluminum, to be reduced to their metallic states without vigorous hydrogen gas evolution. In this study, the electrodeposion of silicon has been investigated in ionic liquid of 1-butyl-3-methylpyrolidinium bis (trifluoromethylsulfonyl) imide ([bmpy]$Tf_2N$) saturated with $SiCl_4$ at room temperature. Also, the effect of electrode materials on the electrodeposition and morphological characteristics of the silicon electrodeposited were analyzed The silicon electrodeposited on gold substrate was composed of the metallic Si with single crystalline size between 100~200nm. The silicon content by XPS analysis was detected in 31.3 wt% and the others were oxygen, gold, and carbon. The oxygen was detected much in edge area of th electrode due to $SiO_2$ from a partial oxidation of the metallic Si.

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LM 가이드의 내마모성 향상을 위한 Me-DLC 코팅박막의 성능평가 (The Performance Test on Me-DLC Films for Improving Wear Resistance of LM-Guide)

  • 강은구;이동윤;김성영
    • 한국정밀공학회지
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    • 제29권4호
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    • pp.409-416
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    • 2012
  • Recently, surface modification technology is of importance to improve the wear resistance and the corrosive resistance for high accurate mechanical parts such as LM guide, Ball Screw and Roller Bearing etc., Those has generally featured on rolling contact mechanism to improve not only the wear and the friction, but also the accuracy and the corrosion performances. For surface modifications of high accurate mechanical parts, normally thermal spray, PVD, CVD and E.P. processes have been used with many materials such as DLC, raydent, W, Ni, Ti etc. Diamondlike carbon (DLC) films possess a combination of attractive properties and have been largely employed to modify the tribological behaviors such as friction, wear, corrosion, fretting fatigue, biocompatibility, etc. However, for rolling contact mechanism mechanical parts DLC films are needed to study for commercial benefit. Rolling contact mechanism has features on effects of cyclic motions and stresses, and also not simply sliding motions. The papers focused on the performance test of wear and corrosive resistance according to Me-DLC film thickness. And also, its thickness effect of wear analysis was carried out through the simulation of the maximum shear stress under the rolling contact surface. As the results, Me-DLC films have more potential to improve the wear resistance for high precision mechanical parts than raydent films.

Metal Grids Embedded Transparent Conductive Electrode with Flexibility and Its Applications

  • Jung, Sunghoon;Lee, Seunghun;Kim, Jong-Kuk;Kang, Jae-Wook;Kim, Do-Geun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.314-314
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    • 2013
  • Recently, flexibility is one of the hottest issues in the field of electronic devices. For flexible displays or solar cells, a development of transparent conductive electrodes (TCEs) with flexibility, bendability and foldability is an essential element. Hundreds of nanometers indium-tin-oxide (ITO) films have been widely used and commercialized as a transparent electrode, but their brittleness make them difficulty to apply flexible electronics. Many researchers have been studying for flexible TCEs such as a few layers of graphene sheets, carbon nanotube networks, conductive polymer films and combinations among them. Although gained flexibility, their transmittance and resistivity have not reached those of commercialized ITO films. Metal grids electrode cannot act as TCEs only, but they can be used to lower the resistance of TCEs with few losses of transmittance. However, the possibility of device shortage will be rise at the devices with metal grids because a surface flatness of TCEs may be deteriorated when metal grids are introduced using conventional methods. In our research, we have developed hybrid TCEs, which combined tens of nanometers ITO film and metal grids which are embedded in flexible substrate. They show $13{\Omega}$/${\Box}f$ sheet resistance with 94% of transmittance. Moreover, the sheet resistance was maintained up to 1 mm of bending radius. Also, we have verified that flexible organic light emitting diodes and organic solar cells with the TCEs showed similar performances compared to commercial ITO (on glass substrate) devices.

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포장조건에 따른 청매실의 호흡생리 및 선도유지 특성 (Respiratory Characteristics and Quality Attributes of Mature-Green Mume (Prunus mume Sieb. et Zucc) Fruits as Influenced by MAP Conditions)

  • 차환수;홍석인;박정선;박용곤;김관;조재선
    • 한국식품영양과학회지
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    • 제28권6호
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    • pp.1304-1309
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    • 1999
  • The respiratory characteristics and quality attributes of mature green mume fruits as influenced by modified atmosphere packaging(MAP) conditions during storage at 25oC for 8 days were investigated. The quality attributes of mume fruits were evaluated in terms of fresh weight loss, physiological injury and yellowing. The packaging materials used for MAP were low density polyethylene(LDPE) films with various different thicknesses. Yellowing and fresh weight loss of mume fruits were noticeably reduced by the packaging treatments with LDPE A and B. The physiological injury of the fruits during storage was found to be more severe in LDPE C than others. For LDPE A and B, the oxygen and carbon dioxide contents within the packages of Mume fruits maintained at the levels of 2~3% and 7~8%, respectively. With respect to visual quality, MAP prolonged the shelf life of the fruits much longer compared with the unsealed control. From the experimental results, it is suggested that the LDPE films with the gas trans mission rates of about 2,100 O2 ml/m2.day.atm and 6,700 CO2 ml/m2.day.atm would be proper for MAP of mature green mume fruits during storage at ambient temperature.

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Li 이차전지용 유황 양극의 방전 전위에 따른 퇴화거동에 관한 연구 (A study on the Capacity Fading Mechanism of Sulfur Cathode Depending on Discharge Potential for Li Rechargeable Battery)

  • 김현석;한상철;송미상;김진호;안효준;이재영
    • 한국수소및신에너지학회논문집
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    • 제14권1호
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    • pp.46-52
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    • 2003
  • 유황 양 전극과 액체 전해질, 리튬 금속을 음극으로 사용한 리튬 유황 전지를 제조하여 그 특성을 조사하였다. 유황 전극은 유황파우더와 carbon black 을 도전재로, 그리고 바인더로 PVdF를 사용하여 제조하였다. 이렇게 제조된 셀은 두개의 다른 전압 구간에서 충방전 실험을 행하였다. 첫 번째 셀은 $S_8+{\chi}Li{\leftrightarrow}Li_2S_x(X=4{\sim}12)$ 반응만을 일어나 게 하기 위하여 2.1V 와 2.5V 사이에서, 그리고 두 번째 셀은 $Li_2S_x+{\chi}Li{\leftrightarrow}Li_2S(x=2{\sim}4)$의 반응만을 일어나게 하기 위하여 1.5V 와 2.5V 에서 충방전 하였다. 그 결과 첫 번째 셀이 더 좋은 싸이클 특성을 가지는 것을 확인 탈 수 있었다. 각 전압구간에서 각 셀이 충방전 되는 동안, 전해질 내로 녹아난 유황의 양은 큰 차치가 없는 것을 확인하였다. 그리고, 전압에 따른 전극의 임피던스를 측정한 결과, 방전이 끝난 후 큰 저항성분이 새로 생긴 것을 확인 할 수 있었다. 이는 사이클이 진행된 후의 전극표면을 SEM 분석을 행한 결과로부터 사이클이 진행된 후 전극 표면에 최종 반응 산물인 $Li_2S$ 가 피막형태로 형성된것을 확인 할 수 있었다.

Ag-Pd 후막도체와 솔더범프 사이의 접합특성 및 계면반응 (Characteristics of Joint Between Ag-Pd Thick Film Conductor and Solder Bump and Interfacial Reaction)

  • 김경섭;한완옥;이종남;양택진
    • 마이크로전자및패키징학회지
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    • 제11권1호
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    • pp.1-6
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    • 2004
  • 자동차 전장품의 시험환경 조건이 엄격해짐에 따라, 전장품 개발 기술자들은 이에 부합하는 성능, 신뢰성, 비용 등을 고려한 보다 효과적인 제품 설계를 위해 노력하고 있다. 본 논문에서는 ECM 알루미나 기판의 플라즈마 세척 영향과 리플로우 후 Sn-37wt%Pb 솔더와 패드 접합부 계면에서 형성되는 금속간 화합물을 관찰하였다. 기판의 플라즈마 세척은 계면 접착력을 저해하였던 C에 의한 유기 잔류물 층이 제거되어 계면 접착력을 향상시키는 효과가 있다. 또한 AFM 분석 결과 도체 패드의 표면 거칠기는 304 nm에서 330 m로 증가하였다. 리플로우 과정에서 솔더와 TiWN/Cu 패드 계면에서 형성된 $Cu_6/Sn_5$는 리플로우 횟수가 증가할 수록 결정립의 크기도 조대화되었다. 솔더와 Ag-Pd 도체패드 계면에서는 세포질 형태의 $Ag_3Sn$화합물이 관찰되었다. $Ag_3Sn$은 지름이 약 0.1∼0.6 $\mu\textrm{m}$이며, 솔더 내부에서는 침상 모양도 관찰되었다.

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유연전자소자를 위한 차세대 유연 투명전극의 개발 동향 (Technology of Flexible Transparent Conductive Electrode for Flexible Electronic Devices)

  • 김주현;천민우;좌성훈
    • 마이크로전자및패키징학회지
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    • 제21권2호
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    • pp.1-11
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    • 2014
  • Flexible transparent conductive electrodes (TCEs) have recently attracted a great deal of attention owing to rapid advances in flexible electronic devices, such as flexible displays, flexible photovoltanics, and e-papers. As the performance and reliability of flexible electronics are critically affected by the quality of TCE films, it is imperative to develop TCE films with low resistivity and high transparency as well as high flexibility. Indium tin oxide (ITO) has been the most dominant transparent conducting material due to its high optical transparency and electrical conductivity. However, ITO is susceptible to cracking and delamination when it is bent or deformed. Therefore, various types of flexible TCEs, such as carbon nanotube, conducting polymers, graphene, metal mesh, Ag nanowires (NWs), and metal mesh have been extensively investigated. Among several options to replace ITO film, Ag NWs and metal mesh have been suggested as the promising candidate for flexible TCEs. In this paper, we focused on Ag NWs and metal mesh, and summarized the current development status of Ag NWs and metal mesh. The several critical issues such as high contact resistance and haze are discussed, and newly developed technologies to resolve these issues are also presented. In particular, the flexibility and durability of Ag NWs and metal mesh was compared with ITO electrode.

방사선투과필름에서 Density Profile을 이용한 배관의 두께 평가 (Thickness Evaluation of Pipeline Using Density Profile on a Radiograph)

  • 이성식;장병규;김영환
    • 비파괴검사학회지
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    • 제22권5호
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    • pp.483-489
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    • 2002
  • 내부가 비어 있거나 유체로 절반 채워진 보온 및 비보온 배관에 대해 방사선 조사 방향에 따른 투과두께와 농도 변화를 전산 시뮬레이션 하였다. 결과적으로 내부가 비어있는 배관의 경우 투과필름에서 농도 변화가 연속적이며 대칭적인 반면, 유체가 절반 채워진 배관의 경우는 방사선 조사 방향에 따라 농도 변화가 비대칭적이며 크게 달라질 수 있음을 알았다. 인공 결함을 가공한 탄소강 배관 시편을 방사선원 Ir-192로 방사선투과시험 한 뒤 농도 변화를 측정하고 이론적으로 계산한 농도 변화와 비교한 결과 산란 방사선에 의한 영향이 큰 가장자리를 제외한 부분에서는 농도 변화를 이용한 두께 평가가 가능함을 확인하였다.

Pd 및 CNT 첨가에 따른 $SnO_2$ 박막의 이산화질소 감지특성 ($NO_2$ gas sensing properties of $SnO_2$ thin films dopped with Pd and CNT)

  • 김형균;이임렬
    • 마이크로전자및패키징학회지
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    • 제15권4호
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    • pp.101-106
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    • 2008
  • 이산화질소를 감지할 수 있는 센서물질로 Pd과 탄소 나노튜브(CNT)가 첨가된 $SnO_2$ 박막을 스핀코팅으로 제조하였으며, 동 시편의 이산화질소에 대한 감지 특성을 $200^{\circ}C$$1ppm{\sim}5ppm$$NO_2$ 농도 하에서 측정하였다. 센서시편의 전기저항은 $NO_2$ 기체의 노출과 농도에 따라 증가 하였으며, Pd이 3wt%로 첨가된 시편의 감도는 26.5로 첨가전의 감도에 비하여 10배 증가하였다. 또한 $SnO_2$ 모체에 첨가한 CNT의 량에 따라서도 감도는 증가 하였으며, 0.225wt% CNT 첨가 시 5ppm의 $NO_2$ 농도에서 감도 값은 72이었다.

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