• Title/Summary/Keyword: Carbon film

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Comparative Study on Adsorption Properties of Carbons Derived from Lignin and Polymer/Lignin Composite Precursors (리그닌 및 고분자/리그닌 복합소재 탄화 생성물의 흡착 특성 비교)

  • Young Soon Im;Ahyeon Jin;Sun Young Park;Mijung Kim;Joonwon Bae
    • Applied Chemistry for Engineering
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    • v.34 no.5
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    • pp.488-492
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    • 2023
  • In this study, a carbon film derived from a polymer/lignin composite precursor was produced by a carbonization cycle with a controlled temperature profile. The feasibility of successful formation of the carbon film using the carbonization cycle was monitored. The adsorption behavior of the carbon film toward various molecules, such as nonpolar and polar organic molecules, and dyes was investigated using ultraviolet/visible (UV/Vis) spectroscopy compared with that of carbonized lignin. Cyclic voltammetry (CV) analysis proved that a robust carbon film was prepared by the carbonization cycle. It was also demonstrated that the carbonized lignin and carbon film showed adsorption capability toward all types of organic molecules, in particular organic dyes, owing to the carbonized lignin. This work provides important information for future relevant research.

Clinical In Vivo Bio Assay of Glucose in Human Skin by a Tattoo Film Carbon Nano Tube Sensor

  • Ly, Suw Young;Lee, Chang Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.595-601
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    • 2017
  • In vivo assay of glucose detection was described using a skin tattoo film electrode (STF), and the probe was made from carbon nano tube paste modification film paper. Here in the square-wave stripping anodic working range obtained of $20-100mgL^{-1}$ within an accumulation time of 0 seconds only in sea water electrolyte solutions of pH 7.0. The relative standard deviations of 50 mg glucose that were observed of 0.14 % (n=12), respectively, using optimum stripping accumulation of 30 sec, the low detection limit (S/N) was pegged at 15.8 mg/L. The developed results can be applied to the detect of in vivo skin sensing in real time. Which confirms the results are usable for in vitro or vivo diagnostic clinical analysis.

Improved Conductivity by Effective Wetting of Single Walled Carbon Nanotubes Film

  • Manivannan, S.;Ryu, Je-Hwang;Jeong, Il-Ok;Jang, Jin;Park, Kyu-Chang
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1598-1601
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    • 2008
  • We describe the fabrication of transparent conducting single-walled carbon nanotubes (SWCNTs) film on flexible substrate following the conventional spin coating method. The fabricated film was post treated with diluted acid solution and its electrical and optical characterizations were performed. The electrical conductivity of SWCNTs film was enhanced and the film was found to be attached strongly with substrate after the post treatment.

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Thermal Conduction in Transparent Carbon Nanotube Films

  • Zhu, Lijing;Kim, Duck-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.201-201
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    • 2012
  • Using materials with high thermal conductivity is a matter of great concern in the field of thermal management. In this study, we present our experimental results on an important physical property of carbon nanotube (CNT) films, two-dimensional thermal conductivity obtained by using an optical method based on Raman spectroscopy. We prepared four kinds of CNT films to investigate the effect of CNT type on heat spreading performance of films. This first comparative study using the optical method shows that the arc-discharge single-walled carbon nanotubes yield the best heat spreading film. And we observed thermal conductivity values of CNT films with various transmittances and found that the Raman method works as long as the sample is a transparent film. This study provides useful information on characterization of thermal conduction in transparent CNT films and could be an important step toward high-performance carbon-based heat spreading films.

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Enhanced Performance of Li Metal Negative Electrode using Protection Film by Carbon Black and Polymeric Binder (카본블랙과 고분자 바인더로 구성된 보호필름을 통한 리튬금속 음극의 성능개선)

  • Noh, Seong Ho;Ryu, Da Young;Jang, Young Seok;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.25 no.1
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    • pp.42-49
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    • 2022
  • In this study, the surface protection film based on organic-inorganic composite is manufactured for suppressing lithium dendrite growth, and the film is applied on the surface of Li metal negative electrode for lithium metal batteries (LMBs). The film is consist of the polyvinylidene fluoride (PVDF) polymeric binder which has good mechanical strength and high electrochemical stability, and carbon black (Super-P) which has outstanding electrical conductivity as the inorganic compound. First, in order to confirm the suppression of the internal short circuit by the lithium dendrite, the time required for the short circuit is measured while a constant current is continuously applied. As a result, the internal short circuit is delayed in proportion to the carbon black content of the film, and it is significantly delayed than bare Li metal electrode which does not use protection film. The cycle performance of the thick protection film (8 ㎛), is worse than that of the thin film (4 ㎛). However, as the carbon black content of the film increased, the cycle performance is improved. Thus, the surface protection film based on carbon black/PVDF composite can delay the internal short circuit, and has low overvoltage during the cycle. However, more stable cycle performance needs to be built through further improvements.

Effect of Conducting Carbon Layer on AC Thin Film EL Device

  • Park, Lee-Soon;Baek, Jeong-Ju;Park, Jin-Woo;Kim, Dae-Yong;Bae, Sung-Choon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.917-919
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    • 2003
  • The effect of conducting carbon layer on the performance of AC thin film EL display was examined. It was found that incorporation of small amount of carbon nano-tube and conducting additive greatly improve the luminance of the inorganic EL compared to the one with only conducting carbon black.

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Friction Properties of Carbon Coated Ultra-thin Film using Taguchi Experimental Design (다구찌 실험계획법을 이용한 탄소코팅 초박막의 마찰특성)

  • 안준양;김대은;최진용;신경호
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.4
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    • pp.143-150
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    • 2003
  • Frictional properties of ultra-thin carbon coatings on silicon wafer were investigated based on Taguchi experimental design method. Sensitivity analysis was performed with normal load, relative humidity, deposition process, and coating thickness as the variables. It was found that despite low thickness, the carbon coating resulted in relatively low friction coefficient. Also, the frictional behavior was affected significantly by humidity and normal load.

The Bildegradability of Carrageenan-based Film by Microorganisms (Carrageenan 필름의 미생물에 의한 생분해도 측정)

  • Kang, Seong Gook;Jung, Soon-Teck;Park, Hyun Jin;Rhim, Jong Whan
    • Microbiology and Biotechnology Letters
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    • v.23 no.6
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    • pp.702-709
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    • 1995
  • Degradation Of $\kappa $-carrageenan-based film by microorganisms screened from carrageenan source and activated sludge of a carrageenan producing factory was investigated by measuring changes of pH, viscosity, total sugar and total organic carbon (TOC) of the medium containing $\kappa $-carrageenan as a carbon source. Initially fifteen strains of microorganism were isolated from carrageenan source and activated sludge and then three organisms among them were selected based on the ability of growing in the medium including 0.3% $\kappa $-carrageenan as a sole carbon source. They were identified as Escherichia coli, Saccharomyces cerevisiae and Aspergillus niger. As indices of biodegradability Of $\kappa $-carrageenan based film, the changes of pH, viscosity, total sugar, and TOC of the carrageenan film-based medium were tested by the cultivation of single or mixed strains of the identified organisms. Mixed culture showed the highest biodegradability, which resulted in the changes of pH from 6.5 to 3.0, viscosity from 164 cps to 15.6 cps, total sugar content from 2.35 g/l to 0.53 g/l and TOC from 5721 ppm to 232 ppm after 30 days of cultivation. The biodegradability determined as the reduction rate of TOC by pure cultures of Asp. niger, E. coli, Sacch. cerevisiae and mixed culture of the three organisms were 94%, 86%, 80% and 96%, respectively.

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Liquid Crystal Alignment Effects by UV Alignment Method on a Diamond-Like-Carbon Thin Film Surface (Diamond-Like-Carbon 박막표면에 UV 배향법을 이용한 액정 배향 효과)

  • Jo, Yong-Min;Hwang, Jeoung-Yeon;Hahn, Eun-Joo;Paek, Seung-Kwon;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.526-529
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    • 2002
  • We studied the nematic liquid crystal (NLC) aligning capabilities by the UV alignment method on a diamond like carbon (DLC) thin film surface. A good LC alignment by UV exposure on the DLC thin film surface at $200\AA$ of layer thickness was achieved. Also, a good LC alignment by the UV alignment method on the DLC thin film surface was observed at annealing temperature of $180^{\circ}C$. However, the alignment defect of the NLC was observed above annealing temperature of $200^{\circ}C$. Consequently, the good thermal stability of LC alignment by the UV alignment method on the DLC thin film surface can be achieved.

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Oxygen Barrier Coating with Carbon Interlayer on Polypropylene

  • Kim, Seong-Jin;Song, Eun-Gyeong;Jo, Gyeong-Sik;Yun, Tae-Gyeong;Mun, Myeong-Un;Lee, Gwang-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.210-210
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    • 2012
  • Gas barrier coating from dense thin film deposition has been one of the important applications such as food-packaging and organic display. Especially for food-packaging, plastic container has been widely used due to its low price and high through-put in mass production. However, the plastic container with low surface energy like polypropylene (PP) has been limited to apply gas barrier coating. That is because a gas barrier coating could not adhere to PP due to its too low surface energy and high porosity of PP. In this research, we applied carbon coating consisting of Si and O as an interlayer between silicon oxide (SiOx) and PP. A carbon layer was found to provide better adhesion, which was experimentally proved by oxygen transmission rate (OTR) and SEM images. However, we also found that there is a limitation in the maximum thickness of a carbon layer and SiOx film due to their high stress level. For this conflict, we obtain the optimal thickness of a carbon layer and SiOx film showing optimal gas barrier property.

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