• 제목/요약/키워드: Carbon equivalent

검색결과 360건 처리시간 0.022초

고성능 감수제가 혼입된 기경성 석회 모르타르의 탄산화 반응 및 강도발현 특성 (Carbonation Reaction and Strength Development of Air Lime Mortar with Superplasticizer)

  • 강성훈;황종국;권양희
    • 대한건축학회논문집:구조계
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    • 제35권7호
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    • pp.179-186
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    • 2019
  • Air lime is a traditional building material of Korea. It had been used in roofs, walls, floors and masonry joints of traditional buildings until the advent of Portland cement. However, due to its low strength and durability, the lime is currently avoided as a repair or restoration material for the preservation of architectural heritage. Furthermore, due to the current practice of using hydraulic materials such as Portland cement, understanding of the material characteristics of air lime is very poor in practice. In this context, this study intended to improve the mechanical properties of the air lime mortar by reducing water contents, and also the carbonation reaction of the mortar was quantitatively evaluated to clearly understand the characteristics of this material. Accordingly, air lime mortar with a water-to-binder ratio of 0.4 was manufactured using polycarboxylate-type superplasticizer. During the 7 days of sealed curing period, the mortar did not harden at all. In other words, there was no reaction required for hardening since it could not absorb carbon dioxide from the atmosphere. However, once exposed to the air, the compressive strength of the mortar began to rapidly increase due to the carbonation reaction, and the strength increased steadily until the 28th day; after then, the strength development was significantly slowed down. On the 28th day, the mortar exhibit a compressive strength of about 5 MPa, which is equivalent to the European standard regarding strength of hydraulic lime used for preservation of architectural heritage.

지방산 변성 에폭시수지 합성과 성능평가 (Synthesis and performance assessment of modified epoxy resins containing fatty acid)

  • 이동찬;김진욱;최중소
    • 한국응용과학기술학회지
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    • 제33권4호
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    • pp.634-646
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    • 2016
  • 본 논문에서는 약용매에서 용해될 수 있는 지방산 변성 에폭시수지를 합성하였고, 합성한 수지의 용해도 평가가 이루어졌다. 지방산 변성 에폭시수지를 합성하기 위하여 비스페놀A형, 페놀 노볼락형 및 오르소 크레졸 노볼락형의 3종류 에폭시수지를 사용하였고, 여기에 지방산, dodecyl phenol (DP), toluene diisocyanate (TDI)를 도입하였다. 합성조건은 당량기준으로 에폭시수지/지방산 = 1/0.5, 지방산/DP = 0.25/0.25, TDI 0.5이었고, 에폭시수지 종류에 따라 12종류의 지방산 변성 에폭시수지가 합성되었다. 합성된 지방산 변성 에폭시수지에 대하여 점도 및 용매${\surd}$가용성을 평가한 결과, 벤젠고리와 글리시딜기의 함량 및 알킬기의 탄소수가 증가할수록 약용매에 대한 용해성이 우수한 것으로 나타났다. 또한 약용매에 용해성이 우수한 지방산 변성 에폭시수지를 사용하여 투명 도료를 제조하여 물성을 평가한 결과, 비스페놀A형 에폭시수지/지방산/DP/TDI의 당량비가 1.0/0.25/0.25/0.5인 것과 페놀 노볼락형 에폭시수지/지방산/DP의 당량비가 1.0/0.25/0.25인 조성에서 건조시간, 접착력, 도막경도, 내충격성, 내알칼리성에서 양호한 물성을 나타내었다.

400 MeV/u 탄소 이온에 대한 방사선치료 선량 측정용 고체비적검출기의 교정 (Calibration of CR-39 for Hadron Radiotherapy using 400 MeV/u C ions)

  • 김성환;남욱원;이재진;박원기;표정현;문봉곤
    • 대한방사선기술학회지:방사선기술과학
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    • 제39권1호
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    • pp.43-49
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    • 2016
  • 본 연구에서는 탄소이온을 이용한 고LET 방사선 치료시 CR-39 고체비적검출기(SSNTD)를 선량계로 사용하기 위하여 일본 중입자가속기연구소(HIMAC)의 400 MeV/u 탄소 이온을 이용한 교정실험을 수행하였다. 탄소 이온을 조사한 CR-39 검출기는 일본 우주항공연구개발기구(JAXA)의 고체비적검출기 전처리 프로토콜에 따라 화학적 에칭을 하였고, 에칭된 CR-39 검출기의 표면에 형성된 트랙은 디지털 카메라로 촬영한 후 Image J를 이용하여 분석하였다. 분석결과 400 MeV/u 탄소 이온의 ${\bar{y_F}}$${\bar{y_D}}$는 각각 $8.5keV/{\mu}m$$10.1keV/{\mu}m$이었으며, 이 결과는 한국천문연구원의 조직등가비례계수기(TEPC)로 측정한 값 및 GEANT4 몬테칼로 시뮬레이션으로 계산한 값과 잘 일치하였다. 본 연구를 통하여 CR-39의 선량 및 LET 교정인자를 결정할 수 있었으며, 고LET 방사선 치료시 CR-39를 이용한 선량평가의 가능성을 확인하였다.

Formation of Hydroxyapatite in Portland Cement Paste

  • Chung, Chul-Woo;Lee, Jae-Yong;Kim, Ji-Hyun
    • 한국건축시공학회지
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    • 제14권1호
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    • pp.68-75
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    • 2014
  • In order to increase the integrity of the wellbore which is used to prevent the leakage of supercritical $CO_2$, it is necessary to develop a concrete that is strongly resistant to carbonation. In an environment where the concentration of $CO_2$ is exceptionally high, $Ca^{2+}$ ion concentration in pore solution of Portland cement concrete will drop significantly due to the rapid consumption of calcium hydroxide, which decreases the stability of the calcium silicate hydrate. In this research, calcium phosphates were used to modify Portland cement system in order to produce hydroxyapatite, a hydration product that is strongly resistant to carbonation under such an environment. According to the experimental results, calcium phosphates reacted with Portland cement to form hydroxyapatite. The formation of hydroxyapatite was verified using X-ray diffraction analyses with selective extraction techniques. When using dicalcium phosphate dihydrate and tricalcium phosphate, the 28-day compressive strength was lower than that of plain cement paste. However, the specimen with monocalcium phosphate monohydrate showed equivalent strength to that of plain cement paste.

Size-dependent forced vibration response of embedded micro cylindrical shells reinforced with agglomerated CNTs using strain gradient theory

  • Tohidi, H.;Hosseini-Hashemi, S.H.;Maghsoudpour, A.
    • Smart Structures and Systems
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    • 제22권5호
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    • pp.527-546
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    • 2018
  • This article presents an analysis into the nonlinear forced vibration of a micro cylindrical shell reinforced by carbon nanotubes (CNTs) with considering agglomeration effects. The structure is subjected to magnetic field and transverse harmonic mechanical load. Mindlin theory is employed to model the structure and the strain gradient theory (SGT) is also used to capture the size effect. Mori-Tanaka approach is used to estimate the equivalent material properties of the nanocomposite cylindrical shell and consider the CNTs agglomeration effect. The motion equations are derived using Hamilton's principle and the differential quadrature method (DQM) is employed to solve them for obtaining nonlinear frequency response of the cylindrical shells. The effect of different parameters including magnetic field, CNTs volume percent and agglomeration effect, boundary conditions, size effect and length to thickness ratio on the nonlinear forced vibrational characteristic of the of the system is studied. Numerical results indicate that by enhancing the CNTs volume percent, the amplitude of system decreases while considering the CNTs agglomeration effect has an inverse effect.

폐타이어 건류 소각에서 발생되는 재와 배기 가스에서의 독성 오염 물질의 정량 (Characterization of Toxic Pollutants in Ash and Flue Gas from Gasification Incinerator of Waste Tires)

  • 구자공;서영화;김석완;유동준
    • 대한토목학회논문집
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    • 제13권1호
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    • pp.213-220
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    • 1993
  • 본 논문에서는 해마다 수 십만 개씩 발생되는 폐타이어의 열적 처리 방법인 건류 소각 처리 방법에서 발생되는 이차 오염 물질을 정량하여 폐타이어의 안전한 최종 처리 방법까지 고찰하였다. 건류-소각처리 방법에서 발생되는 배기 가스에서 이차 독성 오염 물질을 화학 평형 모델을 응용하여 예측하였고 실질적인 잔류 물질인 건류재와 소각재에서 유기성 독성 물질과 중금속을 정량하였다. 건류재에서는 폐타이어의 불완전 연소에 따른 유기성 이차 오염 물질이 다량 포함되어 있는 반면에 소각재에서는 납과 카드뮴과 같은 중금속 화합물의 함량이 높았다. 건류재 및 소각재의 안전한 최종 매립을 위하여는 서로 다른 전처리 방법이 요구된다.

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변형된 삼원촉매에 의한 저온시동조건에서의 메탄올엔진 배가스 정화효과에 관한 연구 (Studies on the Emission control of methanol engine exhaust with modified 3-way catalyst at cold start condition)

  • 홍종성;정석진
    • 한국대기환경학회지
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    • 제9권2호
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    • pp.160-167
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    • 1993
  • As the major methanol fueled vehicle exhaust components, formaldehyde & methanol conversion over the existing commercial 3-way catalyst was examined in a labolatory tains different Ag loadings on commercial 3-way catalyst, and german commercial catalysts for methanol engine exhaust manufactured by a commercial manufacturer. Silver catalysts were prepared by the wet impregnation of silver nitrate solution on commercial 3-way catalyst. These catalysts were characterized with BET Surface area and pore size distribution. In general, the formaldehyde(HCHO) conversion of the tested catalysts was similar to that of methanol$(CH_3OH)$. At 100$^\circ$C, which is equivalent to the cold start condition, 5wt% Ag cat. showed the most excellent HCHO and $CH_3OH$ conversion. The order of activity for conversion of HCHO & $CH_3OH$ to carbon dioxide and water vapor was as follows ; 5wt% Ag/3-way cat.>2wt% Ag/3-way cat.>german cat. front(1) > german cat. rear(2) > 10wt% Ag/3-way cat.> commercial 3-wat catalyst. However there was no significant activity difference between those tested catalysts in the hot run condition of 400$^\circ$C. Therefore, it could be concluded that the Ag-modified 3-way catalyst was the most effective and practical catalyst system which could be capable of removal the HCHO and methanol at the special condition of low temperature such as cold start condition.

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A Study on Mode I Interlaminar Fracture Toughness of Foam Core Sandwich Structures

  • Sohn, Se-Won;Kwon, Dong-Ahn;Hong, Sung-Hee
    • International Journal of Precision Engineering and Manufacturing
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    • 제2권3호
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    • pp.47-53
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    • 2001
  • This paper investigates the characteristics of interlaminar fracture toughness of foam core sandwich structures under opening mode by using the double cantilever beam (DCB) specimens which are Carbon/Epoxy and foam core composites. Instead of using a DCB specimen of symmetric geometry, a non-symmetric DCB specimen was used to calculate the interlaminar fracture toughness. Three approaches for calculating the energy release rate(G$\sub$IC/) were used and fracture toughness of foam core sandwich structures made by autoclave, vacuum bagging and hotpress were compared. Experiment, analysis using nonlinear beam bending theory, and numerical work by FEM methods were performed. Bonding surface compensation and equivalent moment of inertia were used to calculate the energy release rate in nonlinear analytical work. Conclusions of experimental, nonlinear analytical and FEM methods were compared. It is, also, shown that the vacuum bagging forming can substitute the method of autoclave without serious loss of Mode I energy release rate(G$\sub$I/).

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자동차 브레이크용 디스크의 미세조직에 따른 편마모 특성에 관한 연구 (Wear Characteristics of Automotive Disc Brakes: Effect of Gray Cast Iron Microstructures)

  • 이재영;김성진;한창주;장호
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 제35회 춘계학술대회
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    • pp.235-239
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    • 2002
  • The objective of the experiment is to investigate the effect of microstructures of gray cast iron oil wear characteristics of automotive disc brakes. Six different gray cast iron rotors were manufactured by changing carbon equivalent and cooling rate. The change of DTV (disc thickness variation) before and after wear tests was measured to examine the wear properties according to the microstructures of gray iron discs since the DTV generation is caused by the circumferential uneven wear. Experimental results showed that the morphology of graphite flake and hardness in gray cast iron were crucially associated with the change of DTV. In particular, the DTV changes of rotor decrease when the length and area fraction of graphite flake in brake rotors increase and hardness of brake discs reduces.

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AH36-TMCP강의 용접후열처리 효과에 관한 연구 (A Study on Effect of PWHT in AH36-TMCP Steel)

  • 유효선;장원상;안병국;정세희
    • Journal of Welding and Joining
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    • 제16권6호
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    • pp.44-51
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    • 1998
  • It is well known that the fine bainitic microstructure obtained by TMCP(thermo-mechanical control process) secures the high toughness of base metal. Besides, TMCP steel is very suitable for high heat input in welding as it has low carbon equivalent. In HAZ, however, the accelerated cooling effect imparted on the matrix by the weld thermal cycles is relieved and thus the weldment of TMCP steel has softening zone which shows low fracture toughness compared with base metal. Therefore, PHWT of weldment is carried out to improve the fracture toughness in weldment of TMCP steel which has softening zone. In this study, the effects of PWHT on the weldment of AH36-TMCP steel are investigated by the small punch (SP) test. From the several results such as SP energy and displacement at room temperature, the behavior of transition curves, the fracture strength at -196$^{\circ}C$, distribution of (DBTT)sp and (DBTT)sp, the PWHT condition of A.C. after 85$0^{\circ}C$-1 sec W.C. was suitable condition for recovering a softening zone of HAZ as welded.

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