• Title/Summary/Keyword: Carbon emission efficiency

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Electrochemical Degradation of Benzoquinone in a Flow through Cell with Carbon Fibers

  • Yoon, Jang-Hee;Yang, Jee-Eun;Shim, Yoon-Bo;Won, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.28 no.3
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    • pp.403-407
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    • 2007
  • The anodic degradation of benzoquinone(BQ), a model compound for wastewater treatment was carried out using a home-made flow-through electrochemical cell with carbon fibers. To optimize the controlled current electrolysis condition of an aqueous BQ solution, the experimental variables affecting the degradation of BQ, such as the applying current, pH, reaction time, and flow rate of the BQ solution were examined. The degradation products of the oxidation reaction were identified by High Performance Liquid Chromatography and Inductively Coupled Plasma Atomic Emission Spectrometer. Low molecular weight aliphatic acids, and CO2 were the major products in this experiment. The removal efficiency of BQ from the solution increased with the applying current and time. 99.23% of 1.0 × 10-2 M BQ was degraded to aliphatic acids and CO2 when the applying current is 175 mA in a 12 hr electrolysis.

A Study on the Environmental Efficiency of the Container Terminals in South Korea Considering Carbon Dioxide Emissions (이산화탄소 배출량을 고려한 국내 컨테이너터미널 환경 효율성 분석)

  • Min-Seop Sim;Yul-Seong Kim
    • Journal of Navigation and Port Research
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    • v.48 no.3
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    • pp.171-180
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    • 2024
  • Recently, there has been a global emphasis on decarbonization in order to address climate change and achieve carbon neutrality by 2050. In line with government regulations, domestic port authorities have also started participating in this global agenda. Since 2010, when decarbonization became an important task in ports, there have been studies analyzing the environmental efficiency of container terminals, taking into account undesirable outputs. However, most of these previous studies only measured carbon dioxide emissions based on Tier 1, whereas this study is the first to analyze the environmental efficiency of South Korea's container terminals based on Tier 3, as presented in the IPCC guidelines. The study considered 17 container terminal operators in South Korea as decision-making units and used the DEA-SBM Model. Subsequently, an Undesirable Outputs Model was conducted to calculate the environmental efficiency.

The Optimal Operation of Distributed Generation Possessed by Community Energy System Considering Low-Carbon Paradigm (저탄소 패러다임에 따른 구역전기사업자의 분산전원 최적 운영에 관한 연구)

  • Kim, Sung-Yul;Shim, Hun;Bae, In-Su;Kim, Jin-O
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.8
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    • pp.1504-1511
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    • 2009
  • By development of renewable energies and high-efficient facilities and deregulated electricity market, the operation cost of distributed generation(DG) becomes more competitive. The amount of distributed resource is considerably increasing in the distribution network consequently. Also, international environmental regulations of the leaking carbon become effective to keep pace with the global efforts for low-carbon paradigm. It contributes to spread out the business of DG. Therefore, the operator of DG is able to supply electric power to customers who are connected directly to DG as well as loads that are connected to entire network. In this situation, community energy system(CES) having DGs is recently a new participant in the energy market. DG's purchase price from the market is different from the DG's sales price to the market due to the transmission service charges and etc. Therefore, CES who owns DGs has to control the produced electric power per hourly period in order to maximize the profit. If there is no regulation for carbon emission(CE), the generators which get higher production than generation cost will hold a prominent position in a competitive price. However, considering the international environment regulation, CE newly will be an important element to decide the marginal cost of generators as well as the classified fuel unit cost and unit's efficiency. This paper will introduce the optimal operation of CES's DG connected to the distribution network considering CE. The purpose of optimization is to maximize the profit of CES and Particle Swarm Optimization (PSO) will be used to solve this problem. The optimal operation of DG represented in this paper is to be resource to CES and system operator for determining the decision making criteria.

Effects of hydrogen-enriched LPG fuelled engine on exhaust emission and thermal efficiency (LPG 엔진에서 수소첨가에 따른 배기 성능과 열효율에 미치는 영향)

  • Kim, jinho;Cho, unglae;Choi, gyeungho
    • Transactions of the Korean hydrogen and new energy society
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    • v.12 no.3
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    • pp.169-176
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    • 2001
  • The purpose of study is to obtain low-emission and high-efficiency in LPG engine with hydrogen enrichment. The test engine was named heavy-duty variable compression ratio single cylinder engine (VCSCE). The fuel supply system provides LPG/hydrogen mixtures based on same heating value. Various sensors such as crank shaft position sensor (CPS) and hall sensor supply spark timing data to ignition controller. Displacement of VCSCE is $1858.2cm^3$. VCSCE was runned 1400rpm with compression ratio 8. Spark timing was set MBT without knocking. Relative air-fuel ratio(${\lambda}$) of this work was varied between 0.76 and 1.5. As a result, i) Maximum thermal efficiency occurred at ${\lambda}$ value 1.0. It was shown that thermal efficiency was increased approximately 5% with hydrogen enrichment at same ${\lambda}$ value. ii) Engine-out carbon monoxide (CO) emissions were decreased at a great rate under LPG/hydrogen mixture fuelling. iii) Total hydrocarbon (THC) emission was much exhausted in rich zone, same as CO. But THC was exhausted a little bit more in lean zone. iv) Finally, engine-out oxides of nitrogen (NOx) was increased with ${\lambda}$ value 1.0 zone at a greater rate with hydrogen enrichment due to high adiabatic flame temperature.

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Composting Chemical Treated Hog Wastewater Excess Sludge Amended with Sawdust and Compost Biofiltration (화학적처리 양돈폐수 잉여오니와 톱밥 혼합물 퇴비화 및 퇴비탈취처리)

  • Hong Ji-Hyung;Park Keum-Joo
    • Journal of Animal Environmental Science
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    • v.12 no.1
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    • pp.29-34
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    • 2006
  • The effects of turning frequency were examined on the efficiency of composting lime treated excess sludge amended with sawdust from the activated sludge process after a liquid/solids separation process. The raw and excess sludge from the activated sludge process associated with the hog wastewater treatment system is a significant problem and composting is an effective method far reducing the pollution potential of hog wastewater sludge. The coagulant used sludge composting and ammonia emissions from composting are not well established. The effect of compost properties such as high total carbon, C/N ratio and pH value on performance of composting sludge and biofiltration of ammonia from composting process were investigated. The ammonia emission was not significantly increased during composting. The ammonia concentrations of the exhaust air of composter were ranged from 0.5 and 7 ppm about 12 days after composting. The performance of the hog wastewater sludge composting was the most sensitive to chemical treated sludge properties such as high total carbon and high C/N ratio of the initial compost mixes. Temperature in compost and ammonia emission were not greatly affected by the turning frequency.

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The Economic Value Analysis of the Potential Wind Farm Site Using the Black-Scholes Model (블랙 숄즈 모델을 이용한 잠재적 풍력발전 위치의 경제적 가치분석)

  • Jaehun Sim
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.45 no.4
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    • pp.21-30
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    • 2022
  • To mitigate the environmental impacts of the energy sector, the government of South Korea has made a continuous effort to facilitate the development and commercialization of renewable energy. As a result, the efficiency of renewable energy plants is not a consideration in the potential site selection process. To contribute to the overall sustainability of this increasingly important sector, this study utilizes the Black-Scholes model to evaluate the economic value of potential sites for off-site wind farms, while analyzing the environmental mitigation of these potential sites in terms of carbon emission reduction. In order to incorporate the importance of flexibility and uncertainty factors in the evaluation process, this study has developed a site evaluation model focused on system dynamics and real option approaches that compares the expected revenue and expected cost during the life cycle of off-site wind farm sites. Using sensitivity analysis, this study further investigates two uncertainty factors (namely, investment cost and wind energy production) on the economic value and carbon emission reduction of potential wind farm locations.

Effects of SO2 Mixture in Inlet Air on Combustion and Exhaust Emission Characteristic in diesel engine (디젤엔진에 있어서 흡기 중에 SO2혼입이 연소 및 배기배출물 특성에 미치는 영향)

  • Yoo, Dong-Hoon
    • Journal of Power System Engineering
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    • v.19 no.2
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    • pp.64-69
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    • 2015
  • Marine diesel engines with high thermal efficiency and fuel diversity used for propulsive power have been taking charge of important position on marine transport. However, marine environment has recently focused on emissions such as nitrogen oxide and sulfur oxide which is generated from combustion of low grade fuels. EGR(Exhaust gas recirculation) system is one of effective methods to reduce the nitrogen oxide emission from marine diesel engines. In general, it is considered that recirculating gas influences fuel combustion and emissions in diesel engines. However, along with positive effects of EGR, the EGR system using fuels of including high sulfur concentration should be considered about re-combustion and activation of sulfur dioxide in recirculating gas. Therefore, in experimental study, an author investigates effects of sulfur dioxide mixture concentration in intake air on combustion and exhaust emission characteristics in a direct injection diesel engine. In results, change of sulfur dioxide concentrations in intake air had negligible impact on combustion chamber pressure, rate of heat release and emissions compared with effects of oxygen decreasing and carbon dioxide increasing of EGR.

Numerical Study for the Design of Biogas-fired Low Emission Cyclone Incinerator (바이오 가스 소각용 저공해 사이클론 소각기 개발을 위한 수치 해석적 연구)

  • 전영남;김시욱;백원석
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.5
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    • pp.401-410
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    • 2002
  • Concerns for energy conservation, environmental pollution, and the fact that organic wastes account for a major portion of our waste materials, have created the interest of biogas, which usually contains about 60 to 70 percent methane, 30 to 40 percent carbon dioxide, and other gases, including ammonia, hydrogen sulfide, mercaptans and other noxious gases. Cyclone combustors are used for homing a wide range of fuels such as low calorific value gas, waste water, sludge. coal, etc. The 3-dimensional swirling flow, combustion and emission in a tangential inlet cyclone incinerator under different inlet conditions are simulated using a standard k-s turbulence model and ESCRS (Extended Simple Chemically-Reacting System) model. The commercial code Phoenics Ver.3.4 was used for the present work. The main parameters considered in this work are inlet velocity and air to fuel ratio. The results showed that the change of operating conditions had an influence on the shape and size of recirculation zones, mixture fraction and axial velocity which are important factors for combustion efficiency and emission behavior. The application of this kind of computer program seams to be promising as a potential tool for the optimum design of a cyclone combustor with low emission.

Study on Real-Time Weld Quality Evaluation by Acoustic Emission for Production of Drills by Friction Weldiing (마찰용접에 의한 드릴 생산에서의 AE에 의한 실시간 품질평가에 관한 연구)

  • 오세규;윤인진;오정환;오명석
    • Journal of Ocean Engineering and Technology
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    • v.7 no.2
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    • pp.121-130
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    • 1993
  • A study off riction welding of high speed steel(SKH 51) bar for blade side to carbon steel(STC 3)bar for shank side was carried out experimentally through tensile test, hardness test, microstructure, and acoustic emission (AE) test. So, this paper deals with optimizing the welding conditions and the real-time quality (strength) evaluation of friction weleded joints by acoustic emission technique. The results obtained are summarized as follows: (1) For friction welded joints of SKH 51to STC 3 steel bars, the total upset (U) increases linearly with an increase of heating time (t sub(1)). (2) The determined optimum welding conditions are heating time (t sub(1)) 7-9 sec, upsetting time (t sub(2)) 5 sec, heating pressure(P sub(1)) 12 kg sub(f)mm supper(2), upsetting pressure (P sub(2)) 15 kg sub(f) mm supper(2) and rotating speed (n) 2, 000 rpm, resulting in a computed relationship between the tensile strength of the joint .sigma. (kg sub(f) mm supper(2)) and the heating time t sub(1) (sec) as the following. sigma.=2.39t sub(1)

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Application of Newly PAC Selection Method Based on Economic Efficiency (경제성을 고려한 새로운 PAC 선정방법의 적용)

  • Kim, Young-Il;Bae, Byung-Uk
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1141-1147
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    • 2006
  • In order to applicate a newly method for powdered activated carbon(PAC) selection based on economic efficiency, PAC adsorption tests were performed for removal of MIB and dissolved organic carbon(DOC) in drinking water supplies. The removal rate of MIB increased when the PAC dose increased. The Coal-based PACs were superior for adsorption of MIB compared to wood-based PACs. PAC adsorption of DOC and $UV_{254}$ were a little different for different PACs and types of raw water, but both were lower than adsorption of MIB. Among the tested PACs, the one called P-1000 was most effective for removal of MIB, DOC and $UV_{254}$. Most of the organics in the tested samples were proven by excitation emission matrix(EEM) results to be fulvic-like materials. Especially, fulvic-like materials, humic-like materials, and soluble microbial byproduct(SMP)-like materials decreased after contact with PAC. P-1000 which had the lowest MIB cost index(MCI) was selected as the optimum PAC for the target water. PAC efficiency and treatability, particle size and distribution, and the cost associated with PAC dosing for MIB removal according to DOC concentration should all be considered before making the final selection of the best PAC for the target water.