• 제목/요약/키워드: Carbon distribution

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Neutron Radiography를 이용한 고탄소흑연강에서 붕소 분석 (Boron Analysis in High Carbon Graphitized Steel using Neutron Autoradiography)

  • 우기도;양창호;박희찬;이창희;심철무;장진성;김현경
    • 한국재료학회지
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    • 제11권12호
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    • pp.1074-1079
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    • 2001
  • To study the distribution of boron and the boron effect for nucleation of graphite in high carbon steel, neutron induced autoradiography method is used. High carbon steel is easy to make the graphitization by addition of boron. It is easy to analysis of boron distribution using neutron radiography with neutron fluence of $1.9$\times${\times}10^{13}/cm^2$in the boron added high carbon steel. By the neutron induced autoradiography technique, it was found that the distribution of boron depended on boron content, graphitiging temperature and time. And by the analysis of secondary ion mass spectroscopy (SIMS) and electron probe micro analysis (EPMA), boron or boride were acted at nucleation site of graphite in high carbon steel.

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Distribution of Organic Carbon in Pitch Pine Plantation in Kongju, Korea

  • Han, A-Reum;Mun, Hyeong-Tae
    • Journal of Ecology and Environment
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    • 제32권1호
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    • pp.27-31
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    • 2009
  • Organic carbon (OC) distribution in 32-year-old pitch pine plantation at Mt. Hotae in Kongju, Korea, was studied from August 2007 to July 2008. In order to investigate the OC distribution, OC in plant biomass, litterfall, litter layer on forest floor, and soil within 50cm depth were estimated. The density of P. rigida plantation was 3,200 trees/ha, average DBH was $18.7{\pm}5.53cm$ and average tree height was $11.1{\pm}1.85m$. Organic carbon stored in plant biomass, litterlayer on forest floor and soil in 2008 was 89.46 ton C/ha (46.09%), 4.32 ton C/ha (2.23%) and 100.32 ton C $ha^{-1}$ 50cm-$depth^{-1}$ (51.68%), respectively. Amount of OC returned to forest floor via litterfall was 2.21 ton C $ha^{-1}\;yr^{-1}$. Total amount of OC stored in this P. rigida plantation was 194.1 ton C/ha. Net increase of OC in above- and below-ground biomass in this pitch pine plantation was 4.82 ton C $ha^{-1}\;yr^{-1}$.

Effect of oxygen distribution for hot spot and carbon deposition minimization in a methane autothermal reforming reactor

  • Lee, Shin-Ku;Bae, Joong-Myeon;Kim, Yong-Min;Park, Joong-Uen;Lim, Sung-Kwang
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.1996-2000
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    • 2008
  • In autothermal reforming reaction, oxygen to carbon ratio (OCR) and steam to carbon ratio (SCR) are significant factors, which control temperature and carbon deposition into the reactor. The OCR is more sensitive than the SCR to affect the temperature distribution and reforming efficiency. In conventional operation, hydrocarbon fuel, steam, and oxygen was homogeneously mixed and injected into the reactor in order to get hydrogen-rich gas. The temperature was abruptly raised due to fast oxidation reaction in the former part of the reactor. Deactivation of packed catalysts can be accelerated there. In the present study, therefore, the effect of the oxygen distribution is introduced and investigated to suppress the carbon deposition and to maintain the reactor in the mild operating temperature (e.g., $700{\sim}800^{\circ}C$). In order to investigate the effect numerically, the following models are adopted; heterogeneous reaction model and two-medium model for heat balance.

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Carbon/Epoxy 복합재료의 피로수명예측에 관한 신뢰성 해석 (A Reliability Analysis on the Fatigue Life Prediction in Carbon/Epoxy Composite Material)

  • 장성수
    • 한국산업융합학회 논문집
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    • 제10권3호
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    • pp.143-147
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    • 2007
  • In recents years, the statistical properties has become an important quantity for reliability based design of a component. The effects of the materials and test conditions for parameter estimation in residual strength degradation model are studied in carbon/epoxy laminate. It is shown that the correlation between the experimental results and the theoretical prediction on the fatigue life distribution using the life distribution convergence method is very reasonable.

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소석회와 CO2를 이용한 상수관로의 부식제어(II) - 관종별 부식특성 평가 (Corrosion Control in Water Distribution System using Lime and Carbon Dioxide(II) - Evaluation on the Characteristics of Corrosion as a Function of Pipe Material)

  • 이두진;김영일;송영일;박현아
    • 상하수도학회지
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    • 제22권3호
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    • pp.379-387
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    • 2008
  • The pH & alkalinity adjustment method by lime and carbon dioxide($CO_2$) for corrosion control in water distribution system was investigated to evaluate the corrosion characteristics of metal pipes, such as galvanized iron, copper, stainless steel, and carbon steel. When the pH in sand filtered and ozone+GAC treated water was increased with lime and $CO_2$ from 7.5 to 8.0, the concentration of residual chlorine decreased at higher pH and longer reaction time; the concentration of trihalomethane increased. The corrosion rate of coupons with corrosion control using lime and carbon dioxide was showed much smaller than those without corrosion control using pilot-scale simulated distribution system. The galvanized iron was corroded much faster than carbon steel, copper, and stainless steel. Especially, copper and stainless steel coupons were hardly corroded. The galvanized iron and carbon steel coupons with corrosion control were produced the corrosion products less than those without corrosion control by the results of environmental scanning electron microscope(ESEM) and energy dispersive x-ray spectroscopy(EDS) analyses. The galvanized iron coupon with pH and alkalinity adjustment by lime and carbon dioxide was detected about 30 percent of zinc, when the carbon steel was detected about 30 percent of calcium by calcium carbonate products formation. For the results of X-ray diffraction(XRD) analyses, the goethite(${\alpha}$-FeOOH) was identified as primary corrosion product of galvanized iron without corrosion control, while the Zinc oxide(ZnO) was found on corrosion products of galvanized iron coupon with corrosion control as the results of EDS analyses. However, the carbon steel corrosion products regardless of corrosion control were composed predominantly of maghemite(${\gamma}-Fe_2O_3$) and hematite(${\alpha}-Fe_2O_3$).

Microscopic analysis of metal matrix composites containing carbon Nanomaterials

  • Daeyoung Kim;Hye Jung Chang;Hyunjoo Choi
    • Applied Microscopy
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    • 제50권
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    • pp.4.1-4.10
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    • 2020
  • Metallic matrix composites reinforced with carbon nanomaterials continue to attract interest because of their excellent mechanical, thermal, and electrical properties. However, two critical issues have limited their commercialization. Uniform distribution of carbon nanomaterials in metallic matrices is difficult, and the interfaces between the nanomaterials and matrices are weak. Microscope-based analysis was recently used to quantitatively examine these microstructural features and investigate their contributions to the composites' mechanical, thermal, and electrical properties. The impacts of the microstructure on these properties are discussed in the first section of this review. In the second section, the various microscopic techniques used to study the distribution of carbon nanomaterials in metallic matrices and their interfaces are described.

탄소 방적사의 열전도도 모델링 (Modeling of Thermal Conductivity of Carbon Spun Yarn)

  • 조영준;설인환;강태진;박종규
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2004년도 춘계학술발표대회 논문집
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    • pp.186-189
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    • 2004
  • A thermal model of carbon spun yam is presented. The unit cell of spun carbon yam is divided into a number of volume elements and the local material properties have been given to each element. By using Finite Difference Method (FDM), temperature distribution in the unit cell can be obtained. Effective thermal conductivity of the spun carbon yam unit cell is calculated using the temperature distribution and thermal conductivities of local elements.

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Electrochemical Properties of EDLC Electrodes Prepared by Acid and Heat Treatment of Commercial Activated Carbons

  • Wu, Jin-Gyu;Hong, Ik-Pyo;Park, Sei-Min;Lee, Seong-Young;Kim, Myung-Soo
    • Carbon letters
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    • 제9권2호
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    • pp.137-144
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    • 2008
  • The commercial activated carbons are typically prepared by activation from coconut shell char or coal char containing lots of inorganic impurities. They also have pore structure and pore size distribution depending on nanostructure of precursor materials. In this study, two types of commercial activated carbons were applied for EDLC electrode by removing impurities with acid treatments, and controlling pore size distribution and contents of functional group with heat treatment. The effect of the surface functional groups on electrochemical performance of the activated carbon electrodes was investigated. The initial gravimetric and volumetric capacitance of coconut based activated carbon electrode which was acid treated by $HNO_3$ and then heat treated at $800^{\circ}C$ were 90 F/g and 42 F/cc respectively showing 94% of charge-discharge efficiency. Such a good electrochemical performance can be possibly applied to the medium capacitance of EDLC.

배수관망에서 수처리에 의한 AOC, BDOC및 세균성장의 특성 (Characterizations of Assimilable Organic Carbon, Biodegradable Dissolved Organic Carbon, and Bacterial Regrowth in Distribution Systems by Water Treatment)

  • Chang, Young-Cheol;Kweon Jung;Yoo, Young-Sik;Kang, Mi-Hye;Andrew A. Randall
    • 한국환경보건학회지
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    • 제28권5호
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    • pp.42-52
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    • 2002
  • 배수관망에서의 박테리아 재 증식은 큰 현안문제로 대두되고 있으며 이를 억제하기 위한 염소소독 또한 발암성의 부산물인 THMs(trihalomethanes)등을 생성시킬 우려 때문에 미국에서는 오존살균처리 또는 나노여과 (nanofiltration) 법으로 대체해 오고 있다. 그러나 종래의 많은 bench scale 실험결과를 통해 이러한 처리 이후에 잔존하는 미량의 유기물(assimilable organic carbon)이 박테리아 재 증식에 계속하여 영향을 주고 있다는 결과가 AOC(assimilable organic carbon)와 박테리아 재증식의 상관관계를 통하여 밝혀지고 있다. 그러나 현재까지 이러한 연구결과를 full-scale규모의 현장시설에서 직접 검토한 예는 없다. 따라서 본 실험은 미국플로리다주에 위치한 두 지역의 full-scale배수관망 시설을 선정하여 실시하였다. 첫 번째 시설은 오존 살균처리를 그리고 다른 한곳은 나노여과와 석회 연수법 (lime softening)을 병행한 처리법을 사용하고 있다. 박테리아 증식은 R2A 배지를 사용하는 HPC(heterotrophic plate counts)법으로 평가했으며 오존이 공급된 배수관망에서의 HPC 는 각 셈플링 지점의 AOC값을 이용한 지수모델과 높은 상관관계가 있음이 판명되었다($R^2$=0.97). 또한 오존처리는 100%이상의 AOC 농도증가를 나타냈다. 나노여과법과 석회연수법을 병행하고 있는 시설에서도 AOC에 근거한 지수모델과 상관관계를 나타냈다($R^2$=0.75). 그러나 BDOC(biodegradable dissolved organic carbon)는 박테리아 증식에 있어 매우 낮은 상관관계 값을 표시했다($R^2$=0.11). 결과적으로 종래의 많은 bench scale실험결과와 같이 AOC는 배수관망에서의 박테리아 증식과 크게 상관관계를 갖고 있는 것으로 밝혀졌다.

열화손상이 발생된 전도성시멘트모르타르의 미세구조 특성 (Microstructure Characteristics of Conductive Cement Mortar with Deterioration Damage)

  • 김영민;이건철;윤현도;권현우
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 봄 학술논문 발표대회
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    • pp.195-196
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    • 2021
  • The pore distribution of the cement mortar mixed with carbon nanotubes was found to have a large number of pores at (370~80)㎛, and the distribution ratio was larger as the carbon nanotubes were mixed. However, the pores with a fine particle diameter of (10-0.5) ㎛ were found to be larger as the carbon nanotubes were incorporated. However, the distribution of pores of the test specimens of conductive cement mortar with deterioration damage was found to be distributed in a number of particle diameters of (500 to 100) ㎛ and (10 to 0.5) ㎛. It is judged that the particle diameter of the internal pores increased due to the damage. However, as the mixing ratio of the test specimen with carbon nanotubes increased, the distribution of voids was relatively lower than that of plain, and it was judged to have excellent resistance to deterioration damage.

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