• Title/Summary/Keyword: Carbon dioxide contents

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The Extraction of Metal Contaminants using Supercritical CO2 (초임계이산화탄소를 이용한 방사성 금속이온 추출)

  • Ju, Minsu;Kim, Jung-Hoon;Kang, Se-Sik
    • The Journal of the Korea Contents Association
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    • v.16 no.5
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    • pp.660-667
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    • 2016
  • Conventional decontamination methods utilize water-based systems, which generate high amounts of secondary wastes. Herein, we describe an environmentally benign decontamination method using liquid and supercritical $CO_2$. The use of $CO_2$ as a solvent affords effective waste reduction by its ability to be recycled, thereby leaving be hind only the contaminants upon its evaporation. In this study, a $CO_2$ solution process was assessed using t-salen(t-butylsalen), DC18C6 (dicyclohexano-18Crown6), 8-HQN(8-hydroxyquinoline), NEt4PFOSA(perfluoro-1-octanesulfonic acid tetra-ethyl ammonium salt), and NEt4PFOA(pentadecafluorooctanoic acid ammonium salt) to extract spiked radioactive contaminants(Nb,Zr,Co,Sr) from an inert sample matrix, namely filter paper. With the static extraction method, Sr was extracted with a maximum extraction rate of 97%, and Nb was extracted with a maximum extraction rate of 75%. Additionally, we were also able to extract Co and Zr with maximum extract ion ratesof 73% and 64%, respectively.

A Design and Implementation of CO2 Infuser for a Carbon Dioxide (카복시 테라피용 CO2 주입기의 설계 및 구현)

  • Park, Sung-Kon;Ahn, Chan-Jin
    • Journal of Digital Contents Society
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    • v.16 no.3
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    • pp.483-492
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    • 2015
  • This thesis analysis the CARBO 3000 that is one of a $CO_2$ infuser and improve its effectiveness. The thesis designs H/W and S/W that controls the $CO_2$ infusing mass compared to the CARBO 3000. Specially the designed H/W has a newly CPU, LCD, a flow velocity controller, a solenoid valve and a flow sensor. Also the designed S/W is composed of GUI and the algorithm to control the $CO_2$ infusing mass. The designed and implemented the $CO_2$ Infuser in this thesis is tested for the performance. The commercial measuring sensor is used for the test. The testing results say that the designed and implemented the $CO_2$ Infuser in this thesis is much more accurate compared to the CARBO 3000 on $CO_2$ infusing.

Numerical analysis on performances and emission characteristics of HCCI engine fueled with hydrogen added biogas (반응 메커니즘 기반의 수소 첨가 바이오가스 HCCI 엔진 성능 및 배출가스에 대한 수치 해석적 연구)

  • Park, Jungsoo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.41-46
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    • 2018
  • In this research, numerical analysis was performed to determine the effects of hydrogen on biogas combustion for homogeneous charged compression ignition (HCCI) engines. The target engine specifications were a 2300cc displacement volume, 13:1 compression ratio, 15kW of electricity, and 1.2 bar boost pressure. The engine speed was fixed to 1800rpm. By varying the excess air ratio and hydrogen contents, the cylinder pressure, nitric oxide, and carbon dioxide were measured as a function of the hydrogen contents. According to preliminary studies related to the reaction mechanism for methane combustion and oxidation, a GRI 3.0 mechanism as the base mechanism was selected for HCCI combustion calculations describing the detailed reaction mechanism. By adding hydrogen, NO was increased while $CO_2$ was decreased. The cylinder pressure was also increased, having advanced timing for the maximum cylinder pressure and pressure rise region. Furthermore, lean operation limits were extended by adding hydrogen to the HCCI engine.

Phase Equilibria of Ionic Liquid/Organic Compound/Supercritical CO2 Systems (이온성액체/유기화합물/초임계이산화탄소계의 상평형)

  • Lim, Bang-Hyun;Kim, Jong-Won;Paek, Sang-Min;Son, Bo-Kook;Lee, Yong-Rok;Lee, Chul Soo;Lee, Huen;Ra, Chun-Sup;Shim, Jae-Jin
    • Clean Technology
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    • v.12 no.3
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    • pp.128-137
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    • 2006
  • The volume change of an ionic liquid and the phase separation behavior of room temperature ionic liquid(RTIL)/organic compound mixture in supercritical carbon dioxide were measured in a high pressure view cell. 1-Butyl-3-methylimidazolium hexafluorophosphate ([bmim][$PF_6$]) and 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][$BF_4$]) was used as ionic liquid(IL). and methanol and dimethyl carbonate were used as organic compound. For a fixed amount of [bmim][$PF_6$] the lower critical endpoint (LCEP) pressure, where the liquid phase is split, decreased as increasing the amount of organic compound. The LCEP pressure became higher as the water content of ionic liquid was higher. However, for water contents above a certain value, no LCEP was formed. LCEP appeared 1.0 MPa higher for a mixture with [bmim][$BF_4$] than with [bmim][$PF_6$]. There was almost no difference in the K-point pressures for different types of ionic liquid and for different amounts of organic liquid. When the concentration of ionic liquid([bmim][$PF_6$]) (IL/(IL+MeOH)) in the initial liquid mixture was larger than 5.9 mol% at the LCEP of the mixture, the volume of $L_1$ because larger than the volume of $L_2$. When it was smaller, however, the volume became smaller, too. The volume change of ionic liquid in the presence of carbon dioxide decreased as increasing the temperature, while it increased as increasing the pressure. For temperatures between 313.15 to 343.15K at 300 bar, it was about 123~125 % of the original volume.

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Impact of Elevated Carbon Dioxide, Temperature, and Drought on Potato Canopy Architecture and Change in Macronutrients (상승된 이산화탄소와 온도 그리고 한발 영향에 따른 감자의 군락 형태와 무기영양 변화)

  • Lee, Yun-Ho;Cho, Hyeoun-Suk;Kim, Jun-Hwan;Sang, Wan-Gyu;Shin, Pyong;Baek, Jae-Kyeong;Seo, Myung-Chul
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.63 no.2
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    • pp.164-173
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    • 2018
  • Elevated atmospheric carbon dioxide concentration ($CO_2$) is a major component of climate change, and this increase can be expected to continue into the crop and food security in the future. In this study, Soil-Plant-Atmosphere-Research (SPAR) chambers were used to examine the effect of elevated $CO_2$, temperature, and drought on the canopy architecture and concentration of macronutrients in potatoes (Solanum tuberosum L.). Drought stress treatments were imposed on potato plants 40 days after emergence. Under AT+2.8C700 (30-year average temperature + $2.8^{\circ}C$ at $700{\mu}mol\;mol^{-1}$ of $CO_2$), at maximum leaf area, elevated $CO_2$, and no drought stress, a significant increase was observed in both the aboveground biomass and tuber, and for the developmental stage. Even though $CO_2$ and temperature had increased, AT+2.8C700DS (30-year average temperature + $2.8^{\circ}C$ at $700{\mu}mol\;mol^{-1}$ of $CO_2$ under drought stress) under drought stress showed that the leaf area index (LAI) and dry weight were reduced by drought stress. At maturity, potatoes grown under $CO_2$ enrichment and no drought stress exhibited significantly lower concentrations of N and P in their leaves, and of N, P, and K in tubers under AT+2.8C700. In contrast, elevated $CO_2$ and drought stress tended to increase the tuber Mg concentration under AT+2.8C700DS. Plants grown in AT+2.8C700 had lower protein contents than plants grown under ATC450 (30-year average temperature at $400{\mu}mol\;mol^{-1}$ of $CO_2$). However, plants grown under AT+2.8C700 showed higher tuber bulking than those grown under AT+2.8C700DS. These findings suggest that the increase in $CO_2$ concentrations and drought events in the future are likely to decrease the macronutrients and protein concentrations in potatoes, which are important for the human diet.

Hygienic Superiority of Kimchi (김치의 위생학적 우수성)

  • Kim, Yong-Suk;Shin, Dong-Hwa
    • Journal of Food Hygiene and Safety
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    • v.23 no.2
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    • pp.91-97
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    • 2008
  • Kimchi is a representative traditional food in Korea and a type of vegetable product that is the unique complex lactic acid fermentation in the world. It can be considered as a unique fermented food generated by various flavors, which are not included in raw materials, that can be generated by mixing and fermenting various spices and seasonings, such as red pepper powder, garlic, ginger, and salted fish, added to Chinese cabbages. Functionalities in Kimchi have been approved through several studies and the probiotic function that is mainly based on lactic acid bacteria including their physical functions in its contents has also verified. Studies on the verification of the safety of Kimchi including its physiological functions have been conducted. In particular, the function of lactic acid bacteria, which is a caused of the fermentation of Kimchi. Although the lactic acid bacteria contributed to the fermentation of Kimchi is generated from raw and sub-materials, the lactic acid bacteria attached on Chinese cabbages has a major role in the process in which the fermentation temperature and dominant bacteria are also related to the process. The salt used in a salt pickling process inhibits the growth of the putrefactive and food poisoning bacteria included in the fermentation process of Kimchi and of other bacteria except for such lactic acid bacteria due to the lactic acid and several antimicrobial substances generated in the fermentation process, such as bacteriocin and hydrogen peroxide. In addition, the carbon dioxide gas caused by heterolactic acid bacteria contributes to the inhibition of aerobic bacteria. Furthermore, special ingredients included in sub-materials, such as garlic, ginger, and red pepper powder, contribute to the inhibition of putrefactive and food poisoning bacteria. The induction of the change in the intestinal bacteria as taking Kimchi have already verified. In conclusion, Kimchi has been approved as a safety food due to the fact that the inhibition of food poisoning bacteria occurs in the fermentation process of Kimchi and the extinction of such bacteria.

Characteristics Evaluation and Development of Peach Washing System (복숭아의 세척시스템 개발 및 특성 평가)

  • Lee, Hyun-Seok;Kwon, Ki-Hyun;Jeong, Jin-Woong;Kim, Byeong-Sam;Cha, Hwan-Soo
    • Journal of Biosystems Engineering
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    • v.34 no.6
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    • pp.446-453
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    • 2009
  • This study was conducted to find condition of improving the quality of peach by using surfacing washing system. The rate of weight loss of A,B groups were showed slower decreasing trend than CT group and the value of soluble solid degree was not different significantly among all groups from the results of stored peach treat with surface washing system of peach in the first experiment. The colory value of surface were increased with increasing storage period in all treatments. Browning pace of A,B groups were slower than control. Emission of carbon dioxide was increased from the results of respiration rate, 6-10 mL/kg/hr $(10^{\circ}C)$ and 32-41 mL/kg/hr $(25^{\circ}C)$. In second experiment with surface washing system of peach, the value of soluble solid was showed with similar value from 10 $Brix^{\circ}$ to 13 $Brix^{\circ}$. The pace of soft rot of EW groups were lower than CT groups from the results of hardness during storage period. The results of colory value was not showed with significant difference in $15^{\circ}C$ and $20^{\circ}C$ storage temperature but changed to browning in EW groups. The moisture contents was from 85% to 90% in all groups. And the count of total microorganism of EW groups were lower than control. Also total coliform of EW groups were negative. In sensory evaluation, washing peach was showed higher value with significant difference in all acceptability.

Flavor Components in the Filefish Processing (말쥐치 가공중 향기성분에 관하여)

  • LEE Jong-Ho;CHOI Byeong-Dae;LEE Kang-Ho;LEE Kun-Tae;KIM Tae-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.22 no.3
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    • pp.121-128
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    • 1989
  • Volatile compounds were collected by simultaneous distillation extraction and carbon dioxide method, and analyzed by GC and GC-MS. The neutral fraction obtained from the whole steam volatile concentrate 55 kinds of components, phenolic fraction had 4 kinds of components, basic fraction had 13 kinds of components and 10 kinds of components were in acidic fraction. Alcohols, propanols, butanols, octanols, dodecanols etc. and aldehydes, pentanals, hexanal, 2-methyl-1-propanal, heptenal etc. were highly increased after boiled and roasted. And these compounds were contributed to formation of filefish flavor. The molecular ion peak of phenolic fraction was generally appeared in the range 100 to about 160. From the basic fraction, 2-methylpyrazine, 2,5-dimethylpyrazine, 2-ethyl-3,5-di-methylpyrazine and 2-methylpyridine were identified. The contents of basic compounds and furans obtained from the neutral fraction were increased at the higher heating temperature. The flavor of acidic fraction was influenced by the low molecular as isovaleric and valeric acid.

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Botryococcus braunii 배양에서 탄화수소의 two-stage 동시추출공정

  • An, Jin-Yeong;Choe, Jeong-Gyu;Sim, Sang-Jun;Kim, Byeong-U
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.229-232
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    • 2000
  • The carbon dioxide, nitrogen, and phosphate removals from wastewater using microalgae have extensively been studied. Especially, the green colonial algae Botryococcus braunii is characterized by unusual high hydrocarbon contents, ranging from 15 to 75% of dry weight, as long-chain unsaturated hydrocarbons. These hydrocarbons suggest that the possibility of renewable biofuels to be converted into useful fuels such as gasoline by simple catalytic cracking. The poor recovery (18 - 32%) of hydrocarbon from B. braunii culture in two-phase bubble column seems to be caused by insufficient mixing between two phases, which was operated using only aeration on the narrow interface between hydrophobic solvent and cell suspension. In addition, hydrocarbon was entrapped tightly in cell-matrix (formed by exopolysaccharide) of algal colony, which make difficult to extract using two-phase system. In order to overcome low recovery efficiency, two-stage extraction culture system including culture vessel and two-phase separator is now under development, resulted improving contact between solvent phase and cell suspension. Hydrocarbon recovery using this process was more than two times as that using two-phase extraction culture.

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Respiratory Characteristics and Quality Attributes of Mature-Green Mume (Prunus mume Sieb. et Zucc) Fruits as Influenced by MAP Conditions (포장조건에 따른 청매실의 호흡생리 및 선도유지 특성)

  • Chan, Hwan-Soo;Hong, Seok-In;Park, Jung-Sun;Park, Yong-Kon;Kim, Kwan;Jo, Jae-Sun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.6
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    • pp.1304-1309
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    • 1999
  • The respiratory characteristics and quality attributes of mature green mume fruits as influenced by modified atmosphere packaging(MAP) conditions during storage at 25oC for 8 days were investigated. The quality attributes of mume fruits were evaluated in terms of fresh weight loss, physiological injury and yellowing. The packaging materials used for MAP were low density polyethylene(LDPE) films with various different thicknesses. Yellowing and fresh weight loss of mume fruits were noticeably reduced by the packaging treatments with LDPE A and B. The physiological injury of the fruits during storage was found to be more severe in LDPE C than others. For LDPE A and B, the oxygen and carbon dioxide contents within the packages of Mume fruits maintained at the levels of 2~3% and 7~8%, respectively. With respect to visual quality, MAP prolonged the shelf life of the fruits much longer compared with the unsealed control. From the experimental results, it is suggested that the LDPE films with the gas trans mission rates of about 2,100 O2 ml/m2.day.atm and 6,700 CO2 ml/m2.day.atm would be proper for MAP of mature green mume fruits during storage at ambient temperature.

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