• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.1
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• pp.153-160
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• 2021

Nitrous oxide is a global warming substance and is known as the main cause of the destruction of the ozone layer because its global warming effect is 310 times stronger than carbon dioxide, and it takes 120 years to decompose. Therefore, in this study, we investigated the characteristics of NOx emission from N2O reduction by thermal decomposition of N2O. Bunsen premixed flames were adopted as a heat source to form a high-temperature flow field, and the experimental variables were nozzle exit velocity, co-axial velocity, and N2O dilution rate. NO production rates increased with increasing N2O dilution rates, regardless of nozzle exit velocities and co-axial flow rates. For N2O, large quantities were emitted from a stable premixed flame with suppressed combustion instability (Kelvin Helmholtz instability) because the thermal decomposition time is not sufficient with the relatively short residence time of N2O near the flame surface. Thus, to improve the reduction efficiency of N2O, it is considered effective to increase the residence time of N2O by selecting the nozzle exit velocities, where K-H instability is generated and formed a flow structure of toroidal vortex near the flame surface.

• Journal of the Korean Institute of Landscape Architecture
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• v.44 no.4
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• pp.45-56
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• 2016

In this study, an analysis has been conducted on the evaluation criteria of current G-SEED(Green Standard for Energy and Environmental Design) and on the 78 buildings, certified by G-SEED, for 3 years from November, 2012 to November, 2015. Based on the results of this analysis, four issues are driven and proposed hereinafter. Issue 1 : Nowadays, the psychological proportion of landscape architecture in building is getting greater than ever so that it shows reliable reduction of carbon dioxide. Therefore, so far as the eight kinds of buildings are concerned, the evaluation items of G-SEED must include those of landscape architecture mandatorily through its enlargement. Issue 2 : It is undesirable factor that inhibits precise evaluation on landscaping area to let other areas appraise landscape architecture because it requires outstanding professionalism. So, G-SEED should not only ensure landscaping professionalism for the correct evaluation but also let landscape area participate in assessing other areas. Issue 3 : Many previous researches turned out that landscape planting technique has excellent effect on saving energy and reducing temperature of buildings. Thus, landscape planting technique of landscape area is required to be one of the evaluation items of energy sector. Issue 4 : Tree management also has to be newly included as one of the evaluation factor for the maintenance relating to the landscape architecture. G-SEED, enacted and enforced by the Green Building Creation Support Act in 2013, surely is effective system to reduce carbon dioxide in buildings. This is a special Act in its nature that is superior to Construction Law and must be observed by all means to construct buildings. Under the umbrella of this legal system, various of researches and products are contributing to creating new jobs in construction area. However, it is a well-known fact that landscape architecture area has shown less interest on this Act than that of construction area. In conclusion, it is necessary that landscape industry should conduct continuous researches on G-SEED and pay more attention to the Act enough to harvest related products and enlarge its work area.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.378-387
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• 2023

Petrochemical is an energy consuming industry that consumes about 30% of total industrial energy consumption and is a representative carbon dioxide (CO₂) emission source. Among them, the Naphtha Cracking Center (NCC), which produces ethylene, propylene, propane and mixed C4, consumes large amounts of energy and emits significant amounts of CO₂. For this reason, an integrated techno economic- environmental impact assessment aimed at reducing energy consumption and environmental impact factors is necessary to ensure efficiency in terms of economics and environment. This study aims to analyze the efficiency of the heat exchanger network used in the existing NCC base on the pinch analysis and select an improvement plan that can reduced energy consumption. In order to reduces the utility consumption in the process, an optimal heat exchanger network considering the high-temperature and low-temperature stream was derived, and the economic evaluation was conducted by considering the trade-off between the reduction in utility consumption and the increase in heat exchanger installation cost. In addition, an environmental impact assessment was conducted on the reduced CO₂ emission in consideration of the environmental aspect, and the economic environmental impact assessment used the payback period to recover the invested funds to come up with an energy saving plan that can be applied based on the actual process. As a result of considering the economic-environmental impact assessment, when the environmental impact assessment was not considered, it was 4.29 months, 3.21 months, and 3.39 months for each case, and when considering the environmental impact assessment, it was 4.24 months, 3.17 months, and 3.35 months for each case. These results appeared equally both when the environmental impact assessment was not include and when it was include. In addition, a sensitivity analysis was conducted for each case to determine how important factors affect the payback period. As a result of the sensitivity analysis, the cost of the heat exchanger was identified as a major factor influencing the overall cost.

• Korean Journal of Agricultural and Forest Meteorology
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• v.25 no.4
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• pp.346-358
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• 2023

Due to the acceleration of climate change or global warming, it is important to predict rice productivity in the future and investigate physiological changes in rice plants. The research aimed to explore how rice adapts to climate change by examining the response of nitrogen absorption and nitrogen use efficiency in rice under elevated levels of carbon dioxide and temperature, utilizing the SPAR system for analysis. The temperature increased by +4.7 ℃ in comparison to the period from 2001 to 2010, while the carbon dioxide concentration was held steady at 800 ppm, aligning with South Korea's late 21st-century RCP8.5 scenario. Nitrogen was applied as fertilizer at rates of 0, 9, and 18 kg 10a^-1, respectively. Under conditions of climate change, there was an 81% increase in the number of panicles compared to the present situation. However, grain weight decreased by 38% as a result of reduction in the grain filling rate. BNUE, indicative of the nitrogen use efficiency in plant biomass, exhibited a high value under climate change conditions. However, both NUEg and ANUE, associated with grain production, experienced a notable and significant decrease. In comparison to the current conditions, nitrogen uptake in leaves and stems increased by 100% and 151%, respectively. However, there was a 25% decrease in nitrogen uptake in the panicle. Likewise, the nitrogen content and NDFF (Nitrogen Derived from Fertilizer) in the sink organs, namely leaves and roots, were elevated in comparison to current levels. Therefore, it is imperative to ensure resources by mitigating the decrease in ripening rates under climate change conditions. Moreover, there seems to be a requirement for follow-up research to enhance the flow of photosynthetic products under climate change conditions.

• Clean Technology
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• v.26 no.2
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• pp.145-150
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• 2020

Nitrous oxide (N₂O) is one of the six greenhouse gases, and it is essential to reduce N₂O by showing a global warming potential (GWP) equivalent to 310 times that of carbon dioxide (CO₂). Selective catalytic reduction (SCR) is a technology that converts ammonia into harmless N₂ and H₂O by using ammonia as a reducing agent to remove NOx, one of the air pollutants; the process also produces high denitrification efficiency. In this study, the Fe-BEA catalyst was steam-treated at 100 ℃ for 2 h before Fe ion exchange in the fixed bed reactor in order to investigate the effect of the steam-treated Fe-BEA catalyst on the NH₃-SCR reaction. NH₃-SCR reaction test of synthesized catalysts was performed at WHSV = 180 h^-1, 370 to 400 ℃ in the fixed bed reactor. The Fe-BEA(100) catalyst steam-treated at 100 ℃ showed a somewhat higher activity than the Fe-BEA catalyst at 370 to 390 ℃. The catalysts were characterized by BET, ICP, NH₃-TPD, H₂-TPR, and ²⁷Al MAS NMR in order to determine the cause affecting NH₃-SCR activity. The H₂-TPR result confirmed that the Fe-BEA(100) catalyst had a higher reduction of isolated Fe³⁺ than the Fe-BEA catalyst, and that the steam treatment increased the amount of isolated Fe³⁺ as an active species, thus increasing the activity.

• Clean Technology
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• v.28 no.2
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• pp.131-137
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• 2022

The semiconductor process currently emits various by-products and unused gases. Emissions containing pollutants are generally classified into categories such as organic, acid, alkali, thermal, and cabinet exhaust. They are discharged after treatment in an atmospheric prevention facility suitable for each exhaust type. The main components of organic exhaust are volatile organic compounds (VOC), which is a generic term for oxygen-containing hydrocarbons, sulfur-containing hydrocarbons, and volatile hydrocarbons, while the main components of alkali exhaust include ammonia and tetramethylammonium hydroxide. The purpose of this study was to determine the combustion characteristics and analyze the NO_X reduction rate by maintaining a direct combustion and temperature to process organic and alkaline exhaust gases simultaneously. Acetone, isopropyl alcohol (IPA), and propylene glycol methyl ether acetate (PGMEA) were used as VOCs and ammonia was used as an alkali exhaust material. Independent and VOC-ammonia mixture combustion tests were conducted for each material. The combustion tests for the VOCs confirmed that complete combustion occurred at an equivalence ratio of 1.4. In the ammonia combustion test, the NO_X concentration decreased at a lower equivalence ratio. In the co-combustion of VOC and ammonia, NO was dominant in the NO_X emission while NO₂ was detected at approximately 10 ppm. Overall, the concentration of nitrogen oxide decreased due to the activation of the oxidation reaction as the reaction temperature increased. On the other hand, the concentration of carbon dioxide increased. Flameless combustion with an electric heat source achieved successful combustion of VOC and ammonia. This technology is expected to have advantages in cost and compactness compared to existing organic and alkaline treatment systems applied separately.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.6
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• pp.356-370
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• 2017

The energy savings and $CO_2$ emission reductions obtainable from the situation that the Smart Grid system (SGs) is assumed to be applied in Korea up to 2030 is quantitatively analyzed with many reported data. For calculation, SGs is divided into five sectors such as Smart Transmission and Distribution (ST&D), Smart Consumer (SC), Smart Electricity Service (SES), Smart Renewable Energy (SRE) and Smart Transportation (ST). Total annual energy savings in 2030 is estimated to be approximately 103,121 GWh and this is 13.1% of total electricity consumption outlook. Based on this value, total amount of reducible $CO_2$ emissions is calculated to 55.38 million $tCO_2$, which is 17.6% of total nation's GHG reduction target. Although the contribution of energy saving due to SGs to total electricity consumption increases as years go by, that of $CO_2$ emission reduction gradually decreases. This might be because that coal fired based power generation is planned to be sharply increased and the rate of $CO_2$ emission reduction scheduled by nation is very fast. The contributable portion of five each sector to total $CO_2$ emission reductions in 2030 is estimated to be 44.37% for SC, 29.16% for SRE, 20.12% for SES, 5.11% for ST&D, and 1.24% for ST.

• Journal of the Korea Concrete Institute
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• v.29 no.4
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• pp.379-387
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• 2017

The objective of this study is to develop sustainable PVA fiber-reinforced cementitious composites (FRCCs) that could exhibit comparable strength level to normal PVA FRCCs with no recycled materials. To evaluate mechanical properties of the FRCCs, compressive, flexural and direct tensile tests were conducted. In addition to the test, to calculate amount of carbon dioxide ($CO_2$) emission at the stage of manufacturing the FRCCs, life cycle inventory data base (LCI DB) were referenced from domestic and Japan. From the test results, the mechanical properties such as compressive, flexural and direct tensile strengths were decreased as the replacement ratio of recycled materials increased. And it was determined that the amount of $CO_2$ emission was reduced for the specimens with higher water-binder ratio (W/B) and replacement ratios. It was also found that binder intensity ($B_i$) value was higher as replacement ratio of fly ash (FA) increased. This result means that larger amount of FA is need to deliver one unit of a given performance indicator (1 MPa of strength) of FRCCs compared to that of ordinary portland cement (OPC). As a result, it could be concluded that FRCCs with W/B 45% replaced by FA 25% and recycled sand (RS) 25% is desirable for both target performance and $CO_2$ emission.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.9
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• pp.542-549
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• 2015

The bioelectrochemical anaerobic digestion for sewage sludge was attempted at different applied voltages ranged from 0.2 V to 0.4 V. At 0.3 V of the applied voltage, pH and VFAs were at 7.32 and 760 mg COD/L, respectively, which were quite stable. The methane production rate was $1.32L\;CH_4/L.d$, and the methane content in biogas was 73.8%, indicating that the performance of the bioelectrochemical anaerobic digestion could be considerably improved by applying a low voltage. At 0.4 V of the applied voltage, however, the contents of the minor VFA components including formic acid and propionic acid were increased. The methane production rate was reduced to $1.24L\;CH_4/L.d$ and the biogas methane content was also reduced to 72.4%. At 0.2 V of the applied voltage, the pH was decreased to 6.3, and VFAs was accumulated to 5,684 mg COD/L. The contents of propionic acid and butyric acid in the VFAs were considerably increased, The performances in terms of the methane production rate and the biogas methane content were deteriorated. The poor performance of the bioelectrochemical reactor at 0.2 V of the applied voltage was ascribed to the thermodynamic potential lack for the driving of the carbon dioxide reduction into methane at cathode.

• Journal of the Korean Society for Marine Environment & Energy
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• v.8 no.3
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• pp.111-115
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• 2005

The concentration of atmosphere carbon dioxide ($CO_2$) which is one of the major greenhouse gas, continues to rise by the increase in fossil fuel consumption, forest destruction and decrease of biological diversity, etc. In order to weaken the global warming, a reduction of $CO_2$ discharge to the atmosphere is required. The $CO_2$ ocean sequestration technology utilizes the intrinsic oceanic capacity of $CO_2$ absorption, diluting and/or dispersing the liquefied $CO_2$ in the deep ocean (>2,000 m). This geo-engineering approach is regarded as one of the occasions to mitigate the $CO_2$ concentration in the atmosphere. Some developed centuries such as Japan, USA, Norway, etc. have intensively carried out the projects on the research and development of $CO_2$ ocean sequestration since 1990s. There have been several approaches to develop the relative technological system to mitigate the increasing $CO_2$, however, there was no systematic and practical R&D programme in the $CO_2$ ocean sequestration. This paper has described the state of the art on the three optional methods of $CO_2$ sequestration, and compared with them in the aspect of the applicable possibility.