• 제목/요약/키워드: Carbon density

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공기양극 미생물연료전지 시스템에서 전력발생특성에 미치는 전기전도도와 CNT 양극의 영향 (The effects of conductivity and CNT cathode on electricity generation in air-cathode microbial fuel cell)

  • 유규선;박현수;송영채;우정희;이채영;정재우
    • 상하수도학회지
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    • 제26권3호
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    • pp.355-360
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    • 2012
  • The characteristics of power generation were investigated by changing the electrical conductivity from 10 to 40mS/cm using air-cathode microbial fuel cell, which had graphite fiber fabric(GFF) anode. There were three kinds of cathode used: one was carbon cloth cathode coated with Pt, another was carbon nanotube(CNT) cathode with non-precious catalyst of Fe-Cu-Mn, and the other was carbon nanotube(CNT) cathode without any catalyst. When it was operated in batch mode, power density of 1369.5mW/$m^2$ was achieved at conductivity of 20mS/cm. Power density from MFC with CNT cathode coated with multi-catalyst of Fe-Cu-Mn was shown about 985.55mW/$m^2$, which was 75.1% compared the power density of carbon cloth coated with Pt. This meant that CNT cathode coated with multi-catalyst of Fe-Cu-Mn could be an alternative of carbon cloth cathode.

The Lithium Ion Battery Technology

  • Lee, Ki-Young
    • Carbon letters
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    • 제2권1호
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    • pp.72-75
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    • 2001
  • The performance of Li-ion system based on $LiCoO_2$ and Graphite is well optimized for the 3C applications. The charge-discharge mode, the manufacturing process, the cell performance and the thermal reactions affecting safety has been explained in the engineering point of view. The energy density of the current LIB system is in the range of 300~400 Wh/l. In order to achieve the energy density higher than 500 Wh/l, the active materials should be modified or changed. Adopting new high capacity anode materials would be effective to improve energy density.

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나노다이아몬드가 첨가된 탄소블록의 열전도도 특성 (The Thermal Conductivity Characteristics of Carbon Block with Nano-Diamond)

  • 이준숭;문지훈;주성욱;이승욱;김민일
    • 공업화학
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    • 제34권6호
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    • pp.608-612
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    • 2023
  • 탄소블록의 열전도도를 증가시키기 위하여 탄소블록 제조 공정 중 nano-diamond (ND)를 첨가하였다. 첨가된 ND는 탄화 과정에서 바인더 피치의 휘발로 인하여 생성된 탄소블록의 기공을 제어하였다. ND의 첨가는 코크스 및 바인더 피치의 혼련 공정에 추가하였으며, 성형, 탄화를 거쳐 탄소블록을 제조하였다. 첨가된 ND의 양이 증가할수록 탄소블록의 ND 비율이 증가하였다. 첨가된 ND는 탄화 과정에서 바인더 피치의 휘발로 인하여 발생하는 가스의 이동 통로 역할을 하여 탄소블록의 밀도를 높이고, 기공률을 감소시켰다. ND의 첨가를 통하여 높아진 밀도, 낮아진 기공률, ND의 높은 열전도도를 통하여 탄소블록의 열전도도를 향상시킬 수 있었다.

A Comparative Study of Carbon Absorption Measurement Using Hyperspectral Image and High Density LiDAR Data in Geojedo

  • Choi, Byoung Gil;Na, Young Woo;Shin, Young Seob
    • 한국측량학회지
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    • 제35권4호
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    • pp.231-240
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    • 2017
  • This paper aims to study a method to estimate precise carbon absorption by quantification of forest information that uses accurate LiDAR data, hyperspectral image. To estimate precise carbon absorption value by using spatial data, a problem was found out of carbon absorption value estimation method with statistical method, which is already existed method, and then offered optimized carbon absorption estimation method with spatial information by analyzing with methods of compare digital aerial photogrammetry and LiDAR data. It turned out possible Precise classification and quantification in case of using LiDAR and hyperspectral image. Various classification of tree species was possible with use of LiDAR and hyperspectral image. Classification of hyperspectral image was matched in general with field survey and Mahalanobis distance classification method. Precise forest resources could be extracted using high density LiDAR data. Compared with existing method, 19.7% in forest area, 19.2% in total carbon absorption, 0.9% in absorption per unit area of difference created, and improvement was found out to be estimated precisely in international code.

메조페이스 핏치계 탄소/탄소 복합재료의 제조 및 마찰 마모특성 (Friction-wear Characterization and Fabrication of Carbon/Carbon Composite via Mesophase Pitch)

  • 박종규;이진용;하헌승;임연수;이승구
    • 한국세라믹학회지
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    • 제35권9호
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    • pp.974-980
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    • 1998
  • This study is concerned with the production of carbon fiber reinforced carbon(C/C) with polyaromatic mesophase pitch as matrix precursor and with the investigation of friction-wear characteristics in ambient air using a constant speed type of friction tester. The main problem in using the polyaromatic mesophase as the matrix precursor is the high viscosity which may limit the complete impregnation of the fiber preform in the vacuum. To solve these problems two dimensional carbon fiber fabrics were infiltrated with meso-phase pitch in the pitch impregnator. After the impregnation and the heat treatment process. C/C com-posites were characterized by density porosity to monitor the influence of high pressure and temperature. It showed that the bulk density was increased and the apparent porosity and the density increasing rate was reduced as repeating the impregnation the carbonization and the heat treatment. The friction-wear charac-teristics of C/C composites were investigated by measuring the average friction coefficient and the specific wear rate as functions friction speed and friction pressure using a constant speed type of friction tester. C/C composite4s showed the average friction coefficient to be reduced as increasing the friction speed and the friction pressure.

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Influence of Carbon Content on Superconductivity of $Bi_{2}Sr_{2}CaCu_{2}O_{x}$ HTS

  • Jeon, Yong-Woo;Soh, Dea-Wha;Fan, Zhanguo
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.276-279
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    • 2002
  • $Bi_{2}Sr_{2}CaCu_{2}O_{x}$ was prepared by the conventional method of solid state reaction and SHS method. The samples were annealed in different atmosphere in order to examine the influence of atmospheres on the carbon contents in the $Bi_{2}Sr_{2}CaCu_{2}O_{x}$ compound. The lowest carbon content in $Bi_{2}Sr_{2}CaCu_{2}O_{x}$ could be attended when the sample was annealed in $O_{2}$ at $800^{\circ}C$ for 100 hours. The $CO_{2}$ in air pollute the samples and increase the carbon content in the sintering process. The critical current density of the $Bi_{2}Sr_{2}CaCu_{2}O_{x}$ samples will decrease with the increasing carbon contents in the samples. The impurity carbon will deposit in the grain boundary, which makes critical current density lower.

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$H_{2}/N_{2}$ 혼합가스 혼합가스 소결분위기 변화가 사출성형한 Fe-Ni 혼합분말의 탄소량과 기계적 성질에 미치는 영향 (Effect of $H_{2}/N_{2}$ Sintering Atmosphere on the Carbon Content and Mechanical Properties in the Metal Injection Molding of Fe-Ni Mixed Powder)

  • 구광덕
    • 한국분말재료학회지
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    • 제3권1호
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    • pp.49-56
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    • 1996
  • The effect of$H_{2}/N_{2}$gas sintering atmosphere on the carbon content and mechanical properties during the metal injection molding process of carbonyl iron-nickel powder was studied. The carbon content of the specimen after debinding in the pure$N_{2}$atmosphere appeared 0.78 wt%. After showing the maximum value of 1.48 wt.% in the debinding atmosphere of 10%$H_{2}/N_{2}$gas mixture, the carbon content of the debinded specimen decreased gradually with increasing the$H_2$content in the$H_{2}/N_{2}$gas mixture. The carbon contents of the sintered specimen were 0.46~0.63wt% in Na gas atmosphere, while they appeared extremely low above 40%$H_{2}/N_{2}$gas atmosphere. The relative sintered density increased abruptly from 88~90% to 93~96% with the addition of Ni, while the density nearly unchanged above 2% Ni addition. The sintered density increased with increasing the fraction of$H_{2} in H_{2}/N_{2}$gas mixture. Tensile strength and hardness increased, and elongation decreased with increasing carbon and Ni content. In spite of high carbon content of 0.63 wt%, the superior elongation value of 10% was shown.

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비대칭 마그네트론 스퍼터링으로 합성된 비정질 탄소박막의 물리적, 구조적 특성에서 타겟 파워 밀도의 영향 (The effect of target power density on physical and structural properties of amorphous carbon films prepared by CFUBM sputtering)

  • 이재희;박용섭;박재욱;홍병유
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.366-366
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    • 2008
  • Amorphous carbon (a-C) is an interesting materials and its characteristics can be varied by tuning it $sp^3$ fractions. The $sp^3$ fraction in a-C films depends on the kinetic energy of the deposited carbon ions. In this work, a-C films was synthesized on Si(100) and glass substrates at room temperature by closed-field unbalanced magnetron (CFUBM) sputtering with the increase of graphite target power density. The structural and physical properties of films were investigated by using Raman spectroscopy, X-ray photoelectron spectrometer (XPS), nano- indentation, atomic force microscope (AFM) and contact-angle measurement. We obtained the good tribological properties, such as high hardness up to 26 GPa., friction coefficient lower than 0.1 and the smooth surface (rms roughness: 0.12 nm). The increase of the physical properties with the increase of target power density are related to the increase of nano-clusters in the carbon network. Also, these results might be due to the increase of the subplantation and resputtering by the increase of ions density in the plasma.

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Influence of defective sites in Pt/C catalysts on the anode of direct methanol fuel cell and their role in CO poisoning: a first-principles study

  • Kwon, Soonchul;Lee, Seung Geol
    • Carbon letters
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    • 제16권3호
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    • pp.198-202
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    • 2015
  • Carbon-supported Pt catalyst systems containing defect adsorption sites on the anode of direct methanol fuel cells were investigated, to elucidate the mechanisms of H2 dissociation and carbon monoxide (CO) poisoning. Density functional theory calculations were carried out to determine the effect of defect sites located neighboring to or distant from the Pt catalyst on H2 and CO adsorption properties, based on electronic properties such as adsorption energy and electronic band gap. Interestingly, the presence of neighboring defect sites led to a reduction of H2 dissociation and CO poisoning due to atomic Pt filling the defect sites. At distant sites, H2 dissociation was active on Pt, but CO filled the defect sites to form carbon π-π bonds, thus enhancing the oxidation of the carbon surface. It should be noted that defect sites can cause CO poisoning, thereby deactivating the anode gradually.

나노탄소섬유와 나노카바이드섬유를 이용한 복합재의 제조와 활용에 관한 연구 (Preparation and Application of Fiber Composites made of Carbon Nanofibers and Carbide Nanofibers)

  • 임연수;김기덕;이재춘;김명수;김성수
    • 한국세라믹학회지
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    • 제37권6호
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    • pp.569-575
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    • 2000
  • Fabrication of carbon fiber reinforced composites was carried out by hand lay-up method. Carbon nanofibers and SiC nanofibers were used as filler in the composites fabrication. Carbon nanofibers, one of the new carbon materials, have 5∼500 nm in diameter and 5-10 nm in length. SiC nanofibers were modified by silicon monoxide vapor with carbon nanofibers. The composites were carbonized at 1000$^{\circ}C$ in a nitrogen atmosphere, and then densified by molten pitches impregnated in vacuum. Multiple cycles of liquid pitch impregnation and carbonization were carried out to obtain a desired density. The composites were characterized by density, microstructure. The inter-laminar shear strength (ILSS) test was performed for mechanical properties. For the new application, the microwave reflective proeprty of composites was investigated. Dielectric constant and permeability spectrum were measured in 12∼18 GHz frequency ranges. On the basis of the wave propagation theory in a lossy media, the reflection loss from the composite inter-layer was predict as a function of frequency.

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