• Title/Summary/Keyword: Carbon cycle

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An Experimental Study on the Performance of $CO_2$ Air-conditioning Cycle Equipped with an Ejector

  • Kim, Mo-Se;Lee, Jae-Seung;Kim, Min-Soo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.17 no.3
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    • pp.100-106
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    • 2009
  • As an effort to prevent environmental problems caused by ozone depletion and global warming, alternative refrigerants are being developed, and one of the candidates is carbon dioxide. To overcome slightly low efficiency of $CO_2$ refrigeration system, air-conditioning cycle using an ejector was suggested. Ejector compensates throttling loss in an expansion device by reducing compression work. In this study, the ejector refrigeration cycle using $CO_2$ as a refrigerant is investigated to understand the effect of the mixing section diameter and refrigerant charge amount on the performance. If mixing section diameter is too large or too small, either cases show low performance. The optimum refrigerant charge amount which gives the best performance is found for standard operating conditions. The air-conditioning cycle was analyzed for several operating conditions.

Design and Exergy Analysis for a Combined Cycle using LNG Cold/Hot Energy (액화천연가스 냉온열을 이용한 복합사이클의 설계 및 엑서지 해석)

  • Lee Geun Sik
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.4
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    • pp.285-296
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    • 2005
  • In order to reduce the compression power and to use the overall energy contained in LNG effectively, a combined cycle is devised and simulated. The combined cycle is composed of two cycles; one is an open cycle of liquid/solid carbon dioxide production cycle utilizing LNG cold energy in $CO_2$ condenser and the other is a closed cycle gas turbine which supplies power to the $CO_2$ cycle, utilizes LNG cold energy for lowering the compressor inlet temperature, and uses the heating value of LNG at the burner. The power consumed for the $CO_2$ cycle is investigated in terms of a production ratio of solid $CO_2$. The present study shows that much reduction in both $CO_2$ compression power (only $35\%$ of power used in conventional dry ice production cycle) and $CO_2$ condenser pressure could be achieved by utilizing LNG cold energy and that high cycle efficiency ($55.3\%$ at maximum power condition) in the gas turbine could be accomplished with the adoption of compressor inlet cooling and regenerator. Exergy analysis shows that irreversibility in the combined cycle increases linearly as a production ratio of solid $CO_2$ increases and most of the irreversibility occurs in the condenser and the heat exchanger for compressor inlet cooling. Hence, incoming LNG cold energy to the above components should be used more effectively.

The Responses of a Small Lake Watershed to an Inorganic Carbon Cycle (무기탄소 순환에 대한 소규모 호수 유역의 반응)

  • Cho, Youngil
    • Journal of Korean Society on Water Environment
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    • v.29 no.5
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    • pp.610-617
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    • 2013
  • Investigating the budgets of alkalinity and dissolved inorganic carbon (DIC) in lake water systems is significant for the examination of the behavior of a lake as a sink or a source with respect to the circulation of inorganic carbon chemistry. Budgets of total alkalinity ($Alk_T$) and DIC in Onondaga Lake, which was polluted by chronic calcium (Ca) loading in spite of the closure of soda ash ($Na_2CO_3$) facility, were determined by the analyses of inorganic carbon chemistry in tributary stream channels linked to the lake. AlkT and DIC fluxes of Onondaga Creek and Ninemile Creek occupied 65% and 54%, respectively, as larger tributary streams in comparison with other tributaries as well as different input sources. Budget calculations indicate that 18% of AlkT and 11% of DIC inputs to Onondaga Lake, respectively, remained immobilized in the Lake. This suggests that Ca chronically leached had been precipitated with inorganic carbon or remineralized by secondary mineral formation during the experimental period. In this study, the assumed mass balance calculation in Onondaga Lake with tributary streams resulted in exhibiting that the lake played a role of the sink for the inorganic carbon cycle.

Effect of Carbon Matrix on Electrochemical Performance of Si/C Composites for Use in Anodes of Lithium Secondary Batteries

  • Lee, Eun Hee;Jeong, Bo Ock;Jeong, Seong Hun;Kim, Tae Jeong;Kim, Yong Shin;Jung, Yongju
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1435-1440
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    • 2013
  • To investigate the influence of the carbon matrix on the electrochemical performance of Si/C composites, four types of Si/C composites were prepared using graphite, petroleum coke, pitch and sucrose as carbon precursors. A ball mill was used to prepare Si/C blends from graphite and petroleum coke, whereas a dispersion technique was used to fabricate Si/C composites where Si was embedded in disordered carbon matrix derived from pitch or sucrose. The Si/pitch-based carbon composite showed superior Si utilization (96% in the first cycle) and excellent cycle retention (70% after 40 cycles), which was attributed to the effective encapsulation of Si and the buffering effect of the surrounding carbon matrix on the silicon particles.

An Extension of Product Data Model for Calculating Product-level Carbon Footprint (제품수준 탄소배출이력 계산을 위한 제품자료모델 확장)

  • Do, Nam-Chui
    • Korean Journal of Computational Design and Engineering
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    • v.16 no.4
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    • pp.268-276
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    • 2011
  • The product-level carbon footprint (PCF) is a comprehensive and widely accepted metric for sustainable product development. However, since a full PCF study in general is time and cost intensive, it is not feasible for the product development team to synchronize the activity to the main product development process. In addition, the current dedicated life cycle assessment (LCA) tools for calculating PCF, separated from the main product data management systems, have limitations to provide timely PCF information for design decision makings and collaborations between design and environment engineers. This paper examines the possibility of the extension of the current product data model that can support the PCF calculation with PDM (Product Data Management) databases. The product data model can represent not only the content of products but also context or system information of the products. The product data model can be implemented as a PDM database that can satisfy the needs for handy and timely PCF calculations from the consistent product data for dynamic design decision makings and engineering collaborations.

A study for multi thermal cycle effect on mechanical property change in carbon epoxy composite (탄소섬유 복합재료의 열사이클에 의한 물성치 변화에 관한 연구)

  • 최순권;박세만;박명균
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.43-48
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    • 2000
  • Composite materials have been increasingly used in automotive and aircraft industries, naturally leading to active researches on the materials. The carbon-epoxy composite is selected to study its thermal characteristics. During multiple thermal cycles composed of repeated cooling and heating variations of elastic constants are investigated to understand thermal effects on the carbon-epoxy composite. In this investigation longitudinal resonance method and flexural resonance method was used to characterize. The values of $E_1$ show small amount of increases depending on number of cycles of the thermal fatigue processes whereas values of $G_13$ do not indicate noticeable changes. Also, in cases of $E_2$ and $G_23$ their values decrease to a certain extend in initial stages after applications of thermal fatigue processes. However, the number of cycles of the applied thermal fatigue processes does not seem to affect their values.

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The prediction of emission concentrations in spark ignition engine using methanol as a fuel (Methanol을 연료로 한 전기점화 기관의 배출물 농도예측에 관한 연구)

  • 김응서;김상호
    • Journal of the korean Society of Automotive Engineers
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    • v.5 no.1
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    • pp.79-88
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    • 1983
  • A prediction of emission concentrations was made by calculating chemical equilibrium on the basis of an indicated pressure diagram in spark ignition engine using methanol as a fuel. A prediction according to Otto cycle was also made and for carbon dioxide, carbon monoxide and nitric oxide, emission test was performed using a conventional SI engine that was modified a little considering fuel characteristics. An investigation was made for those three cases-results from an indicated pressure diagram, Otto cycle and emission test. A good agreement between the measured values and the predicted ones existed for carbon dioxide and carbon monoxide, but not for nitric oxide. And good results existed for the other emission concentrations.

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Effects of Isocitrate Lyase Inhibitors on Spore Germination and Appressorium Development in Magnaporthe grisea

  • Kim Seung-Young;Park Jin-Soo;Oh Ki-Bong
    • Journal of Microbiology and Biotechnology
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    • v.16 no.7
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    • pp.1158-1162
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    • 2006
  • The glyoxylate cycle can conserve carbons and adequately supply tricarboxylic acid (TCA) cycle intermediates for biosynthesis when microorganisms grow on $C_{2}$ carbon sources. It has been reported that isocitrate lyase (ICL1), a key enzyme of the glyoxylate cycle, is highly induced when Magnaporthe grisea, the causal agent of rice blast, infects its host. Therefore, the glyoxylate cycle is considered as a new target for antifungal agents. A 1.6-kb DNA fragment encoding the ICL1 from M. grisea KJ201 was amplified by PCR, cloned into a vector providing His-tag at the N-terminus, expressed in Escherichia coli, and purified using Ni-NTA affinity chromatography. The molecular mass of the purified ICL1 was approximately 60 kDa, as determined by SDS-PAGE. The ICL1 inhibitory effects of TCA cycle intermediates and their analogs were investigated. Among them, 3-nitropropionate was found to be the strongest inhibitor with an $IC_{50}$ value of $11.0{\mu}g/ml$. 3-Nitropropionate inhibited the appressorium development in M. grisea at the ${\mu}M$ level, whereas conidia germination remained unaffected. This compound also inhibited the mycelial growth of the fungus on minimal medium containing acetate as a $C_{2}$ carbon source. These results suggest that ICL1 plays a crucial role in appressorium formation of M. grisea and is a new target for the control of phytopathogenic fungal infection.

The liquefaction system of the exhaust gas using cold energy in underwater engine (수중기관에서 냉열을 이용한 배기가스 액화시스템 해석)

  • Lee, Geun-Sik;Jang, Yeong-Su;No, Seung-Tak
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.5
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    • pp.1591-1602
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    • 1996
  • In operating the underwater engines such as encountered in exploring submarines, the dumping of the exhaust gas out of the engine requires a large portion of the total power, frequently amounting to 25-30% of the power generated. This unfavorable circumstance can be cured by liquefying the exhaust gas and storing it. In the present study, two liquefaction systems were simulated to enhance the overall efficiency; one is a closed cycle diesel engine and the other is a closed cycle LNG engine. The liquefied natural gas (LNG) is chosen as a fuel, not only because its use is economical but also because its cold energy can be utilized within the liquefaction system. Since a mixture of oxygen and carbon dioxide is used as an oxidizer, liquefying carbon dioxide is of major concern in this study. For further improving this system, the intercooling of the compressor is devised. The necessary power consumed for the liquefying system is examined in terms of the related properties such as pressure and temperature of the carbon dioxide vessel as a function of the amount of the exhaust gas which enters the compressor. The present study was successful to show that much gain in the power and reduction of the vessel pressure could be achieved in the case of the closed cycle LNG engine. The compression power of exhaust gas were observed remarkably lower, typically only 6.3% for the closed cycle diesel engine and 3.4% for the closed cycle LNG engine respectively, out of net engine power. For practicality, a design -purpose map of the operating parameters of the liquefaction systems was also presented.

Global Increases in Dissolved Organic Carbon in Rivers and Their Implications

  • Kang, Ho-Jeong;Jang, In-Young;Freeman, Chris
    • Korean Journal of Ecology and Environment
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    • v.43 no.4
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    • pp.453-458
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    • 2010
  • DOC (Dissolved Organic Carbon) is an operational terminology for organic carbon molecules dissolved in natural waters. DOC has been studied by ecologists extensively, because it plays a key role in various ecological functions such as substrates for secondary production and the carbon cycle. DOC also represents a substrate for microbial growth within potable water distribution systems, and can react with disinfectants (e.g., chloride) to form harmful disinfection by-products. In addition, residual DOC may carry with it organically bound toxic heavy metals. DOC in aquatic ecosystems may ultimately be transported to the oceans, or released back to the atmosphere by heterotrophic respiration, which can accelerate global climate change. There is evidence that DOC concentrations in aquatic ecosystems are increasing in many regions of the world including Europe, North America, and even in Korea. Land use changes, elevated temperature, elevated $CO_2$, recovery from acidification, and nitrogen deposition have been proposed as mechanisms for the trend. However, the key driving mechanism is yet to be conclusively determined. We propose that more extensive and longer-term observations, research of chemical properties of DOC, impacts of elevated DOC on environmental issues and interdisciplinary approaches are warranted as future studies to fill the gaps in our knowledge about DOC dynamics.