• Title/Summary/Keyword: Carbon contamination

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Geochemical Characteristics of Bottom Sediments of the Anyang River and the Influence on the Stream Water Contamination (안양천 바닥 퇴적물의 지구화학적 특성에 따른 하천수 오염영향)

  • 문지원
    • Economic and Environmental Geology
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    • v.33 no.3
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    • pp.205-215
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    • 2000
  • The Anyang River runs through highly industrialized area and joins the lower part of the Han River. loading out large amounts of potential pollutants. Attempts were made to understand geochemical behavior of trace elements in the stream sedimens collected from the bottom of the river and the stream water. Bottom sediments, suspended solids and stream waters were collected and analysed for the chemical and mineralogical composition. Heavy metals including Cr, Zn, Ni, and Co in the sediments were enriched appeared to reflect anthropogenic input. Pb, Cu, As were also enriched between several to 10 times , compared to background levels. Although some heavy metals were derived from anthropogeic input, geochemical associations seem to implyh much of the elements are originated from natural sources as well, mainly from granitic rocks . This is also supported by the mineralogical composition of the suspended solids, which are mainly composed of quartz, feldspar and mica. Most of the elements are associated with total carbon and clay sized fractions, with high values of correlation coefficient. Most of the elements are associated with total carbon and clay sized fractions , with high values of correlation coefficient. It was noteworthy that Hg was detected between 2 and 4 ppb in the stream water.

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Suppressing Effect of Hydrogen Evolution by Oxygen Functional Groups on CNT/ Graphite Felt Electrode for Vanadium Redox Flow Battery (탄소나노튜브/흑연펠트 전극의 산소작용기를 활용한 바나듐 레독스 흐름 전지의 수소발생 억제 효과)

  • Kim, Minseong;Ko, Minseong
    • Journal of the Korean institute of surface engineering
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    • v.54 no.4
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    • pp.164-170
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    • 2021
  • Vanadium redox flow batteries (VRFB) have emerged as large-scale energy storage systems (ESS) due to their advantages such as low cross-contamination, long life, and flexible design. However, Hydrogen evolution reaction (HER) in the negative half-cell causes a harmful influence on the performance of the VRFB by consuming current. Moreover, HER hinders V2+/V3+ redox reaction between electrode and electrolyte by forming a bubble. To address the HER problem, carbon nanotube/graphite felt electrode (CNT/GF) with oxygen functional groups was synthesized through the hydrothermal method in the H2SO4 + HNO3 (3:1) mixed acid solution. These oxygen functional groups on the CNT/GF succeed in suppressing the HER and improving charge transfer for V2+/V3+ redox reaction. As a result, the oxygen functional group applied electrode exhibited a low overpotential of 0.395 V for V2+/V3+ redox reaction. Hence, this work could offer a new strategy to design and synthesize effective electrodes for HER suppression and improving the energy density of VRFB.

Preprocess of GaAs Epitaxial Layer Growth by MBE (MBE에 의한 GaAs 에피층 성장을 위한 사진처리 과정)

  • Kang, Tae Won;Lee, Jae Jin;Hong, Chi You;Kim, Jin Whang;Chung, Kwan Soo
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.23 no.2
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    • pp.243-248
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    • 1986
  • The impurities in As and Ga sources and the contamination of the GaAs substrate prior to growing of MBE GaAs epitaxial layer have been investigated using RHEED, AES and RGA methods. The as source was contaminated by H2O, CO, CO2 and AsO, and the Ga source was contaminated by H2, H2O, CO and CO2. These contaminants could easily be removed by prebaking the source. On the other hand, GaAs substrate was contaminated principally carbon and oxygen. The oxygen could easily be removed by heating the substrate above 480\ulcorner, and the carbon could also be reduced by sputtering the substrate with 1ke V Ar+. The chemically etched substrate surface prior to growing the layer was rough, but it was made to be smooth and clean by heating it above 530 \ulcorner.

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Monte Carlo Simulation of the Carbon Beam Nozzle for the Biomedical Research Facility in RAON (한국형 중이온 가속기 RAON의 의생물 연구시설 탄소 빔 노즐에 대한 Monte Carlo 시뮬레이션)

  • Bae, Jae-Beom;Cho, Byung-Cheol;Kwak, Jung-Won;Park, Woo-Yoon;Lim, Young-Kyung;Chung, Hyun-Tai
    • Progress in Medical Physics
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    • v.26 no.1
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    • pp.12-17
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    • 2015
  • The purpose of the Monte Carlo simulation study was to provide the optimized nozzle design to satisfy the beam conditions for biomedical researches in the Korean heavy-ion accelerator, RAON. The nozzle design was required to produce $C^{12}$ beam satisfying the three conditions; the maximum field size, the dose uniformity and the beam contamination. We employed the GEANT4 toolkit in Monte Carlo simulation to optimize the nozzle design. The beams for biomedical researches were required that the maximum field size should be more than $15{\times}15cm^2$, the dose uniformity was to be less than 3% and the level of beam contamination due to the scattered radiation from collimation systems was less than 5% of total dose. For the field size, we optimized the tilting angle of the circularly rotating beam controlled by a pair of dipole magnets at the most upstream of the user beam line unit and the thickness of the scatter plate located downstream of the dipole magnets. The values of beam scanning angle and the thickness of the scatter plate could be successfully optimized to be $0.5^{\circ}$ and 0.05 cm via this Monte Carlo simulation analysis. For the dose uniformity and the beam contamination, we introduced the new beam configuration technique by the combination of scanning and static beams. With the combination of a central static beam and a circularly rotating beam with the tilting angle of $0.5^{\circ}$ to beam axis, the dose uniformity could be established to be 1.1% in $15{\times}15cm^2$ sized maximum field. For the beam contamination, it was determined by the ratio of the absorbed doses delivered by $C^{12}$ ion and other particles. The level of the beam contamination could be achieved to be less than 2.5% of total dose in the region from 5 cm to 17 cm water equivalent depth in the combined beam configuration. Based on the results, we could establish the optimized nozzle design satisfying the beam conditions which were required for biomedical researches.

Assesment of Indoor Air Quality within Public Transport Vehicles operating in specified locations throughout Seoul (서울 일부 지역 교통수단의 실내 공기질 평가)

  • Sohn Jong-Ryeul;Choi Dal-Woong;Choi Jung-Sook;Woo Wan-Gi
    • Journal of environmental and Sanitary engineering
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    • v.21 no.1 s.59
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    • pp.12-20
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    • 2006
  • This paper was conducted concerning the degree of indoor air quality in public transport vehicles such as taxicabs, buses and subway trains, as sampled through the active participation of drivers and passengers in Seoul between 13th August 2005 and 2nd November 2005. The results were summarized as follows: 1. Among the measured substances especially respirable particulate matters ($PM_{10}$), total bacteria counts (TBC) and carbon dioxide ($CO_2$) exceeded the standard level of $150{\mu}g/m^3,\;800CFU/m^3$ and 1000ppm. 2. The concentration of carbon dioxide ($CO_2$) in taxi recorded 2491ppm, which is more than the standard amount of 1000ppm. This level was comparatively higher than all other public transportation methods. Total bacteria counts (TBC) in bus and subway recorded $1082CFU/m^3\;and\;1856CFU/m^3$, respectively. 3. The drivers who regularly work long hours showed the higher concern about contamination of the air inside the public transport vehicles and they considered it to be worse than the air outside. In contrast, the general public showed less concern about the air quality inside the public transport vehicles. However, they too acknowledged that the quality of the air inside the public transport vehicles was poor. In regards to the degree of indoor air quality in the public transport vehicles, a counterplan must be implemented urgently to effectively combat the excessive levels of $PM_{10}$, microorganism and $CO_2$. We need to gather more conclusive evidence pertaining to other possible contaminants and influencing factors.

The Effect of Fillers on Rubber Characteristics for Gasket to Lithium Ion Battery (리튬이온 전지용 가스켓 고무의 특성에 미치는 충전제의 영향)

  • Seo, Kwan-Ho;Cho, Kwang-Soo;Yun, In-Sub;Choi, Woo-Hyuk;Hur, Byung-Ki;Kang, Dong-Gug
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.430-433
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    • 2010
  • The gasket materials of for the lithium ion battery requires chemical resistance to electrolyte, electrical insulating, compression set, anti-contamination and low temperature property. To check the special characteristics of fillers which are applied to rubber for gasket, compound of EPDM, NBR and FKM (fluoro elastomer) were made by adjusting weights of carbon black and silica additive. Using these compounds, we had done tests of long-term stability against electrolyte, compression set and low-temperature property with considering operating condition of the lithium ion battery. From this test, we investigated the physical and chemical characteristics of rubber with using of carbon black and silica additive in each.

MOCVD Deposition of AlN Thin Film for Packaging Materials

  • Chang-Kyu, Ahna;Seung-Chul Choi;Seong-Hoon Cho;Sung-Hwan Han;Je-Hong Kyoung
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2000.04a
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    • pp.118-118
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    • 2000
  • New single-source precursor, [AlCI3:NH2tBu] was synthesized for AlN thin f film processing with AICI3 (Aluminum Chloride) and tBuNH2 (tert-butylamine). AlN thin films for packaging aspplication were deposited on sapphire substrate by a atmosph하ie-pressure MOCVD. In most of other study methyl-based AI precursors w were used for source, But herein Aluminum Chloride was used for as AI source i in order to prevent the carbon contamination in the films and stabilize the p precursor. New precursor showed the very high gas vapor pressure so it allowed to m make the film under atmospheric-pressure and get the high purified film. High q quality AlN thin film was obtained at 700 to $900^{\circ}C$. The new precursor was p purified by a sublimation technique and help to fabricate high purity film. It s showed high vapor pressure, which is able to a critieal factor for the high purity a and atmospheric CVD of AlN. High Quality AIN thin film was obtained at $700-900^{\circ}C$. The AIN film was characterized by RBS

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A Mathematical Model Development for Microbial Arsenic Transformation and Transport

  • Lim, Mi-Sun;Yeo, In-Wook;Lee, Kang-Kun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.318-322
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    • 2004
  • Arsenic is a toxic and carcinogenic metalloid, whose sources in nature include mineral dissolution and volcanic eruption. Abandoned mines and hazardous waste disposal sites are another major source of arsenic contamination of soil and aquatic systems. To predict concentrations of the toxic inorganic arsenic in aqueous phase. the biogeochemical redox processes and transport behavior need to be studied together and be coupled in a reactive transport model. A new reaction module describing the fate and transport of inorganic arsenic species (As(II)), dissolved oxygen, nitrate, ferrous iron, sulfate, and dissolved organic carbon are developed and incorporated into the RT3D code.

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Mineral Water Investigation on 10 Area in Seoul (서울시내(市內) 10개(個) 약수(藥水)의 수질오염(水質汚染)에 관(關)한 연구(硏究))

  • Kim, Hyung-Suk;Koo, Do-Suh;Park, Yang-Won
    • Journal of Preventive Medicine and Public Health
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    • v.10 no.1
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    • pp.59-61
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    • 1977
  • We are calling the erupting ground water as drugwater or mineral water in Korea and thinking those water is good for health from ancient. But most of them were used by mountainer as drinking water and food making water. Authors tried to investigate the evidence of contamination by user on the 10 erupting ground water and gained following results: 1. All of the mineral, waters on 10 area in Seoul were unfitable to drinking water standard. 2. In the view of the bacteriology 80% were contaminated by coliform group. 3. The highest value of the free carbon dioxide contents were 652.96 ppm at Sam Sun Mineral Water.

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Study on the Accumulative Distribution of Malation and itns Determination form the Human Tissue. (사체중 MaIathion의 각 장기조직별 분석 및 정량에 관한 연구)

  • 이완구;박성우
    • Journal of Environmental Health Sciences
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    • v.5 no.1
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    • pp.18-20
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    • 1978
  • An experimental study was conducted to determine the quantity of contamination of organophosphrous pesticides accumulated in each human tissues. The samples used for this experiment were spleen, lung, heart, liver and kindney and those tissues were homogenized by a blender. The homogenized materials was extracted with mixed solvent, acetone/benzene (1:1) and cleaned up on a activated carbon column and determined by gas chromatography using AFID supported on 5% QF-1. The average recovery rate was 94% and the results obtained are summarized as follows. 1) The quantities of Malathin accumulated in each tissues were 0.53 ppm in spleen, 0.42 ppm in lung, 0.34 ppm in kidney, 0.19 ppm in heart and 0.19 ppm in liver. 2) Residues of pesticides in chronic or acute intoxicated tissues were highest in the spleen, decreasing in order of the lung, kidney, heart, and liver. 3) According to the above resuk we can conclude that the most proper material in detecting the pesticide is the spleen.

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