• 제목/요약/키워드: Carbon contamination

검색결과 217건 처리시간 0.025초

Preliminary Study on the Total Dissolved Organics Measurement and Their Contribution to Conductivities at Elevated Temperature

  • Kim, Kwang-Rag;Kang, Hee-Suk;Park, Seung-Woo;Lee, Sung-Ho;Ahn, Do-Hee;Lee, Han-Soo;Hongsuk Chung;Sung, Ki-Woung
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1996년도 추계학술발표회논문집(1)
    • /
    • pp.127-132
    • /
    • 1996
  • Total organic carbon (TOC) derived from organics is one of tile possible contamination in the reactor water system and causes of pH change and high conductivity levels. Measurements of total dissolved oxidizable carbon were carried out and its contribution to conductivities at elevated temperature was studied by using tile thermodynamic equilibrium analysis in carbonic acid system. The calculated conductivities were in good agreement with tile levels observed for tile formation of carbonic acid from salicylic acid solution.

  • PDF

윤활성 및 압연기 청정성을 겸비한 냉간 압연유의 개발 (Development of a Cold Rolling Oil with Lubricity and Mill Cleanness Property)

  • 한석영;송교봉;이준정
    • Tribology and Lubricants
    • /
    • 제13권2호
    • /
    • pp.74-81
    • /
    • 1997
  • The purpose of this study is to develop a cold rolling oil with lubricity and mill cleanness property under the rolling conditions of high reduction ratio and high rolling speed. Six kinds of oil samples were blended. Evaluation of lubricity and anti-seizuro property of the samples were carried out with a laboratory scale rolling mill, where the contact conditions between work roll and strip are very close to actual cold rolling mill. Laboratory evaluation for dispersion, contamination, anti-oil stain property and residual carbon, etc. were carried out with several testers such as longterm circulation tester, Coulter counter and Conradson tester. A new high speed cold rolling oil with good lubricity and mill cleanness property was developed compared with the previously developed rolling oil.

공간 측정에 의한 도로변 발생 다환방향족탄화수소 연구 (Analysis of Poly Aromatic Hydrocarbon (PAH) Pollutants Originated from Local Road Dust by Spacial Measurements)

  • 박다정;조인환;이광열;박기홍;이영재;안준영;배민석
    • 한국대기환경학회지
    • /
    • 제32권3호
    • /
    • pp.272-279
    • /
    • 2016
  • Understanding sources and contributions of $PM_{2.5}$ mass and particulate PAHs from traffic-related pollution can provide valuable information for alleviating air contamination from car emissions in urban areas. Two sampling sites at the Gwangju Institute of Science and Technology (GIST, $35.228^{\circ}N$, $126.843^{\circ}E$) and National institute of environmental research NamBu Supersite (NNBS, $35.226^{\circ}N$, $126.848^{\circ}E$) were selected for comprehensive road-oriented-PM investigations. Continuous measurements from optical particle sizer (OPS) and optical particle counter (OPC) with 24 hr integrated filter based samplers for organic carbon, water soluble organic carbon, and Poly Aromatic Hydrocarbons (PAHs) were conducted during Nov. 3 through 22 in 2014. As a result, $PM_{2.5}$ mass concentrations using OPC and OPS in NNBS presented about twice higher than in GIST due to road dust impacts based on wind direction analysis. In addition, ratios of elemental carbon (EC) to organic carbon (OC) and water insoluble organic carbon (WIOC) to organic carbon (OC) supported an additional evidence of the primary pollutant contributions oriented from road dust. PAHs related to 5 rings such as benzo(e&a)pyrene indicates higher associations.

Determination of Chromium Content in Carbon Steel Pipe of NPP using ICP-AES

  • Choi, Kwang-Soon;Lee, Chang-Heon;Han, Sun-Ho;Park, Yong-Joon;Song, Kyu-Seok
    • Bulletin of the Korean Chemical Society
    • /
    • 제32권12호
    • /
    • pp.4270-4274
    • /
    • 2011
  • A method is proposed for determining chromium content in the carbon steel pipes of a nuclear power plant (NPP) to evaluate wall thinning caused by flow-accelerated corrosion (FAC). A flat file was used to obtain filings samples. To assess sampling quality, a disk form of SRM 1227 was ground with the flat file, and the amount of Cr in the filings was determined by ICP-AES. The content of chromium in the filings of SRM 1227 was estimated as six times higher than the certified value due to the contamination of chromium in the file. To eliminate chromium contamination from the file, it was coated with WC-12Co using high-velocity oxygen-fuel (HVOF) spraying systems. After obtaining filings samples using the coated file, Cr content in four types of disk-form SRMs was determined by ICP-AES. The recoveries of Cr in the disk-form SRMs were in the range of 95.4-102.6%, with relative standard deviations from 0.43 to 3.0%. The Cr contents in the filings collected from the used outlet headers of the nuclear power plants using the flat file coated were in the range of 0.11-0.19%.

Nano Electrocatalysis for Fuel Cells

  • Sung, Yung-Eun
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
    • /
    • pp.133-133
    • /
    • 2013
  • For both oxygen reduction (ORR) and hydrogen oxidation reactions (HOR) of proton electrolyte membrane fuel cells (PEMFCs), alloying Pt with another transition metal usually results in a higher activity relative to pure Pt, mainly due to electronic modification of Pt and bifunctional behaviour of alloy surface for ORR and HOR, respectively. However, activity and stability are closely related to the preparation of alloy nanoparticles. Preparation conditions of alloy nanoparticles have strong influence on surface composition, oxidation state, nanoparticle size, shape, and contamination, which result from a large difference in redox priority of metal precursors, intrinsic properties of metals, increasedreactivity of nanocrystallites, and interactions with constituents for the synthesis such as solvent, stabilizer, and reducing agent, etc. Carbon-supported Pt-Ni alloy nanoparticles were prepared by the borohydride reduction method in anhydrous solvent. Pt-Ru alloy nanoparticles supported on carbon black were also prepared by the similar synthetic method to that of Pt-Ni. Since electrocatalytic reactions are strongly dependent on the surface structure of metal catalysts, the atom-leveled design of the surface structure plays a significant role in a high catalytic activity and the utilization of electrocatalysts. Therefore, surface-modified electrocatalysts have attracted much attention due to their unique structure and new electronic and electrocatalytic properties. The carbon-supported Au and Pd nanoparticles were adapted as the substrate and the successive reduction process was used for depositing Pt and PtM (M=Ru, Pd, and Rh) bimetallic elements on the surface of Au and Pd nanoparticles. Distinct features of the overlayers for electrocatalytic activities including methanol oxidation, formic acid oxidation, and oxygen reduction were investigated.

  • PDF

활성탄 주입을 통한 퇴적물 내 소수성 유기오염물질 원위치 안정화 기술: 작동 원리 (In-situ Stabilization of Hydrophobic Organic Contaminants in Sediment by Activated Carbon Amendment: Working Principles)

  • 이현민;정지현;최용주
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제27권1호
    • /
    • pp.1-16
    • /
    • 2022
  • In-situ activated carbon (AC) amendment is a promising remediation technique for the treatment of sediment impacted by hydrophobic organic contaminants (HOCs). Since its first proposal in the early 2000s, the remediation technique has quickly gained acceptance as a feasible alternative among the scientific and engineering communities in the United States and northern Europe. This review paper aims to provide an overview on in-situ AC amendment for the treatment of HOC-impacted sediment with a major focus on its working principles. We began with an introduction on the practical and scientific background that led to the proposal of this remediation technique. Then, we described how the remediation technique works in a mechanistic sense, along with discussion on two modes of implementation, mechanical mixing and thin-layer capping, that are distinct from each other. We also discussed key considerations involved in establishing a remedial goal and performing post-implementation monitoring when this technique is field-applied. We concluded with future works necessary to adopt and further develop this innovative sediment remediation technique to ongoing and future sediment contamination concerns in Korea.

Improvement of Graphene's Electrical Properties by ICP Cleaning

  • 강사랑;라창호;유원종
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
    • /
    • pp.629-629
    • /
    • 2013
  • Graphene is a carbon based material and it has intriguing features, such as phenomenally strong, thin, flexible, transparent and conductive, those make it attractive for a broad range of applications.Unfortunately, graphene is extremely sensitive to contamination. When we fabricate graphene devices, electrical properties of graphene are altered [1], and the charge carrier mobility drops accordingly by orders of magnitude. This significant impact on electron mobility occurs because any surrounding medium could act as a dominant source of extrinsic scattering, which effectively reduces the mean free path of carriers [2,3]. The dominant contaminant is generated through fabrication stage by polymethyl methacrylate (PMMA) [4], or photo resist (PR). Surface contamination by these residues has long been a critical problem in probing graphene's intrinsic properties. If we clearly solve this problem, we can get highly performed graphene devices. Here, we will report on graphene cleaning process by Induced Coupled Plasma (ICP). We demonstrated how much decomposition of residue impact on improving electrical properties of graphene.

  • PDF

Degradation of Phenanthrene by Bacterial Strains Isolated from Soil in Oil Refinery Fields in Korea

  • KIM JEONG DONG;SHIM SU HYEUN;LEE CHOUL GYUN
    • Journal of Microbiology and Biotechnology
    • /
    • 제15권2호
    • /
    • pp.337-345
    • /
    • 2005
  • The degradation of phenanthrene, a model PAH compound, by microorganisms either in the mixed culture or individual strain, isolated from oil-contaminated soil in oil refmery vicinity sites, was examined. The effects of pH, temperature, initial concentration of phenanthrene, and the addition of carbon sources on biodegradation potential were also investigated. Results showed that soil samples collected from four oil refinery sites in Korea had different degrees of PAH contamination and different indigenous phenanthrene-degrading microorganisms. The optimal conditions for phenanthrene biodegradation were determined to be 30$^{circ}C$ and pH 7.0. A significantly positive relationship was observed between the microbial growth and the rate of phenanthrene degradation. However, the phenanthrene biodegradation capability of the mixed culture was not related to the degree of PAH contamination in soil. In low phenanthrene concentration, the growth and biodegradation rates of the mixed cultures did not increase over those of the individual strain, especially IC10. High concentration of phenanthrene inhibited the growth of microbial strains and biodegradation of phenanthrene, but was less inhibitory on the mixed culture. Finally, when non-ionic surfactants such as Brij 30 and Brij 35 were present at the level above critical micelle concentrations (CMCs), phenanthrene degradation was completely inhibited and delayed by the addition of Triton X100 and Triton N101.

Terabit-per-square-inch Phase-change Recording on Ge-Sb-Te Media with Protective Overcoatings

  • Shin Jin-Koog;Lee Churl Seung;Suh Moon-Suk;Lee Kyoung-Il
    • 정보저장시스템학회:학술대회논문집
    • /
    • 정보저장시스템학회 2005년도 추계학술대회 논문집
    • /
    • pp.185-189
    • /
    • 2005
  • We reported here nano-scale electrical phase-change recording in amorphous $Ge_2Sb_2Te_5$ media using an atomic force microscope (AFM) having conducting probes. In recording process, a pulse voltage is applied to the conductive probe that touches the media surface to change locally the electrical resistivity of a film. However, in contact operation, tip/media wear and contamination could major obstacles, which degraded SNR, reproducibility, and lifetime. In order to overcome tip/media wear and contamination in contact mode operation, we adopted the W incorporated diamond-like carbon (W-DLC) films as a protective layer. Optimized mutilayer media were prepared by a hybrid deposition system of PECVD and RF magnetron sputtering. When suitable electrical pulses were applied to media through the conducting probe, it was observed that data bits as small as 25 nm in diameter have been written and read with good reproducibility, which corresponds to a data density of $1 Tbit/inch^2$. We concluded that stable electrical phase-change recording was possible mainly due to W-DLC layer, which played a role not only capping layer but also resistive layer.

  • PDF

Energy Efficiency & Sustainability the Cleanliness Management Role of Components and System in Automotive and Hydraulics

  • 홍정희;마이크데이
    • 드라이브 ㆍ 컨트롤
    • /
    • 제9권4호
    • /
    • pp.19-25
    • /
    • 2012
  • This paper explains how eliminating contamination from the manufacturing processes will lead to better product quality and hence the need for reworking, a trouble free commissioning period and greatly improved production efficiency. All of these will reduce costs and energy usage. It will also ensure that the product is delivered to the customer in a condition that will ensure improved reliability and longer life, again reducing both energy and other operating costs. Correctly designing the contamination control measures will achieve and maintain the level of fluid cleanliness that is required by the end user. The filter is critical to cleanliness management and should be selected with the same degree of thought and consideration as for other major components. This paper explains the role that Cleanliness Management plays in the reducing the carbon footprint of systems and processes by making them perform more efficiently for longer periods. It also examines two differing ways of selecting filters to incorporate the features of newer designs, and shows how significant savings in the costs of ownership can be achieved using these approaches.