• Title/Summary/Keyword: Carbon contamination

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Structural Studies of Thin Film Boron Nitride by X-ray Photoelectron Spectroscopy

  • Kim, Jong-Seong
    • Journal of Sensor Science and Technology
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    • v.5 no.1
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    • pp.51-56
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    • 1996
  • Structural properties of rf sputtered boron nitride films were studied as a function of deposition parameters such as nitrogen pressure, substrate temperature and substrate bias using X-ray photoelectron spectroscopy and Auger electron spectroscopy. Composition and information on chemical bonding of resultant films was determined by XPS. XPS core level spectra showed that ratio of boron to nitrogen varied from 3.11 to 1.45 with respect to partial nitrogen pressure. Curve fitting of XPS spectra revealed three kinds of bonding mechanism of boron in the films. XPS peak positions of both B 1s and N 1s shifted to higher energy with higher nitrogen pressure as well as increase in substrate bias voltage. AES was used to see possible contamination of films by carbon or oxygen as well.

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The Trend and Prospect of Advanced Water Treatment Process using Ozonizer (오존발생기를 이용한 고도정수처리기술 동향 및 전망)

  • 조국희;김영배;서길수;이형호;이광식;송현직;이상근
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 1998.11a
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    • pp.242-244
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    • 1998
  • Over the years manufactures have become increasingly aware of the importance of water purity and its effect on the quality of the final product. One of the largest problems that confronts pure water system operators is bacterial recontamination shortly after the water purification equipment. There are several recommended methods of either preventing or recommended methods of either preventing or removing such contamination but most have inherent disadvantages. Drinking water has required new treatment techniques such as ozonation and granular activated carbon(GAC) filtration. Ozone is known to be a powerful oxidant and disinfectant. Therefore it has been found to be necessary for the treatment of taste, odor and color as an oxidant of inorganic and organic compounds.

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Auger Study of LPE Grown In Ga As P/In P Heterostructure (Auger 전자현미경을 이용한 LPE에 의해서 성장된 InGaAsP/InP 이종접합계면에 대한 연구)

  • 김정호;권오대;박효현;남은수
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.25 no.12
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    • pp.1656-1662
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    • 1988
  • Auger depth profiles of various In Ga As P/In P heterojunctions grown by liquid phase epitaxial techniques under different growth conditions such as diffusion temperature, diffusion time and dopants, have been obtained. The surface contaminations of In Ga As have been investigated. We found that the samples with Zn diffusion exhibit significant interface grading phenomena including In depletion, Ga richness and P richness at the In Ga As P/In P interface, and In outdiffusion at the surface. The main surface contamination was found to be due to carbon and oxygen species. It can be suggested that Zn gettering takes a major role in such phenomena as interface grading, in depletion, and Ga and P richness at the interface.

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Strength Characteristic according to the Curing Method of the Ternary System Inorganic Binder (3성분계 무기결합재의 양생방법에 따른 강도특성)

  • Lee, Jin-Woo;Lee, Yun-Seong;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.05a
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    • pp.33-34
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    • 2013
  • Recently, as the policy of state that it is the low carbon green growth is promoted, the effort for reducing the CO2 gas generation ejected from the construction industry in the cement production is continued. That is, the method using the mineral admixtures including the silica fume and red mud, silica fume and etc. it is the industrial byproduct with the method solving the exhaustion problem of the environmental contamination settlement and natural resources, the great quantity as the cement substitute material is examined. Accordingly, in this research, the strength characteristic of the curing body differentiating the curing method of the ternary system inorganic binder using the blast furnace slag and red mud, silica fume and etc. as the cement substitute material tried to be examined.

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Comparative study on the specimen thickness measurement using EELS and CBED methods

  • Yoon-Uk Heo
    • Applied Microscopy
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    • v.50
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    • pp.8.1-8.7
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    • 2020
  • Two thickness measurement methods using an electron energy loss spectroscopy (EELS) and 10a convergent beam electron diffraction (CBED) were compared in an Fe-18Mn-0.7C alloy. The thin foil specimen was firstly tilted to satisfy 10a two-beam condition. Low loss spectra of EELS and CBED patterns were acquired in scanning transmission electron microscopy (STEM) and TEM-CBED modes under the two-beam condition. The log-ratio method was used for measuring the thin foil thickness. Kossel-Möllenstedt (K-M) fringe of the $13{\ba{1}}$ diffracted disk of austenite was analyzed to evaluate the thickness. The results prove the good coherency between both methods in the thickness range of 72 ~ 113 nm with a difference of less than 5%.

Evaluation of metal contamination and phytoremediation potential of aquatic macrophytes of East Kolkata Wetlands, India

  • Khatun, Amina;Pal, Sandipan;Mukherjee, Aloke Kumar;Samanta, Palas;Mondal, Subinoy;Kole, Debraj;Chandra, Priyanka;Ghosh, Apurba Ratan
    • Environmental Analysis Health and Toxicology
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    • v.31
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    • pp.21.1-21.7
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    • 2016
  • Objectives The present study analyzes metal contamination in sediment of the East Kolkata Wetlands, a Ramsar site, which is receiving a huge amount of domestic and industrial wastewater from surrounding areas. The subsequent uptake and accumulation of metals in different macrophytes are also examined in regard to their phytoremediation potential. Methods Metals like cadmium (Cd), copper (Cu), manganese (Mn), and lead (Pb) were estimated in sediment, water and different parts of the macrophytes Colocasia esculenta and Scirpus articulatus. Results The concentration of metals in sediment were, from highest to lowest, Mn ($205.0{\pm}65.5mg/kg$)>Cu ($29.9{\pm}10.2mg/kg$)>Pb ($22.7{\pm}10.3mg/kg$)>Cd ($3.7{\pm}2.2mg/kg$). The phytoaccumulation tendency of these metals showed similar trends in both native aquatic macrophyte species. The rate of accumulation of metals in roots was higher than in shoots. There were strong positive correlations (p <0.001) between soil organic carbon (OC) percentage and Mn (r =0.771), and sediment OC percentage and Pb (r=0.832). Cation exchange capacity (CEC) also showed a positive correlation (p <0.001) with Cu (r=0.721), Mn (r=0.713), and Pb (r=0.788), while correlations between sediment OC percentage and Cu (r=0.628), sediment OC percentage and Cd (r=0.559), and CEC and Cd (r=0.625) were significant at the p <0.05 level. Conclusions Bioaccumulation factor and translocation factors of these two plants revealed that S. articulatus was comparatively more efficient for phytoremediation, whereas phytostabilization potential was higher in C. esculenta.

Geochemical Characteristics and Contamination of Surface Sediments in Upper Yeongsan River System (상류수계 영산강 하상퇴적물의 지화학적 특성과 오염)

  • Oh, Kang-Ho;Kim, Joo-Yong;Koh, Yeong-Koo;Youn, Seok-Tai;Seo, Goo-Won;Park, Bae-Young;Shin, Sang-Eun;Kim, Hai-Gyoung
    • Journal of Korean Society on Water Environment
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    • v.21 no.5
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    • pp.520-527
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    • 2005
  • In order to investigate the geochemical characteristics of surface sediments in streams of upper Yeongsan River drainage system, sediment samples from the main stream of Yeongsan river, Hwangryong river, Gwangju and Jiseok streams were collected and analyzed for grain size and metal and organic carbon contents. The metal contents in the sediments are mainly dependent on organic matter contents in the domestic sewage, grain size of the sediments and geology around the streams. Enrichment factor (EF) and index of geoaccumulation (Igeo) representing the degree of metal contamination in the sediments are relatively low in the main stream of Yeongsan river main stream, Hwangryong river and Jiseok stream. However, those of Gwangju stream show the EF maximum values of P=8.30, Cu=5.55, Zn=14.29 and Pb=7.45 and the Igeo maximum values of P=3.58, Cu=4.43, Zn=3.22 and Pb=1.59.

Distribution of Methyl Mercury in Sediments from Kyeonggi Bay, Namyang Bay, Chinhae Bay, and Lake Shihwa, Korea

  • Lee, Kyu-Tae;Kannan, Kurunthachalam;Shim, Won-Joon;Koh, Chul-Hwan
    • Journal of the korean society of oceanography
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    • v.33 no.4
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    • pp.178-184
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    • 1998
  • To elucidate contamination levels and distribution of methyl mercury (Me-Hg) in Korean coastal areas, 126 sediment samples were collected from Kyeonggi Bay, Namyang Bay, Chinhae Bay, and Lake Shihwa during 1995-1996, and the Me-Hg concentrations were determined by cold vapor atomic fluorescence spectrometry (CVAFS). Contamination levels of Me-Hg in sediments from Kyeonggi Bay, Namyang Bay, Chinhae Bay, and Lake Shihwa were 274 ${\pm}$ 990, 108 ${\pm}$ 24, 294 ${\pm}$ 342, and 1080 ${\pm}$ 760 pg/g, respectively. Concentrations of Me-Hg in sediments were significantly correlated with total organic carbon and sulfur contents, but were independent of mud contents and mean grain size. The highest concentration of Me-Hg (7100 pg/g) was observed at Incheon North Harbor (Site Kl9) in Kyeonggi Bay. This Me-Hg concentration was one or two orders of magnitude higher than those in other Kyeonggi Bay sediments were. The average concentration of Me-Hg in sediments from Lake Shihwa was higher than in those from other study areas. The three peaks of Me-Hg concentrations were observed on three sites (55, 56,and 510) in Lake Shihwa and gradually decreased in distance-dependent manner around these sites. High concentrations of Me-Hg at surface and 10-cm sediment depth in Chinhae Bay maybe due to higher rates of methylation process by active sulfate-reducing bacteria or higher concentrations of total mercury available to sulfate-reducing bacteria.

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SiC Contaminations in Polycrystalline-Silicon Wafer Directly Grown from Si Melt for Photovoltaic Applications (실리콘 용탕으로부터 직접 제조된 태양광용 다결정 실리콘의 SiC 오염 연구)

  • Lee, Ye-Neung;Jang, Bo-Yun;Lee, Jin-Seok;Kim, Joon-Soo;Ahn, Young-Soo;Yoon, Woo-Young
    • Journal of Korea Foundry Society
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    • v.33 no.2
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    • pp.69-74
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    • 2013
  • Silicon (Si) wafer was grown by using direct growth from Si melt and contaminations of wafer during the process were investigated. In our process, BN was coated inside of all graphite parts including crucible in system to prevent carbon contamination. In addition, coated BN layer enhance the wettability, which ensures the favorable shape of grown wafer by proper flow of Si melt in casting mold. As a result, polycrystalline silicon wafer with dimension of $156{\times}156$ mm and thickness of $300{\pm}20$ um was successively obtained. There were, however, severe contaminations such as BN and SiC on surface of the as-grown wafer. While BN powders were easily removed by brushing surface, SiC could not be eliminated. As a result of BN analysis, C source for SiC was from binder contained in BN slurry. Therefore, to eliminate those C sources, additional flushing process was carried out before Si was melted. By adding 3-times flushing processes, SiC was not detected on the surface of as-grown Si wafer. Polycrystalline Si wafer directly grown from Si melt in this study can be applied for the cost-effective Si solar cells.

Method development and initial results of testing for perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) in waterproof sunscreens

  • Keawmanee, Sasipin;Boontanon, Suwanna Kitpati;Boontanon, Narin
    • Environmental Engineering Research
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    • v.20 no.2
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    • pp.127-132
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    • 2015
  • Perfluorooctane sulfonate (PFOS) and Perfluorooctanoic acid (PFOA) are persistent environmental pollutants, extremely stable, and possibly adversely affect human health. They are widely used in many industries and consumer goods, including sunscreen products. These substances are stable chemicals made of long carbon chains, having both lipid- and water-repellent qualities. The research objectives are (1) to find the most effective method for the preparation of semi-liquid samples by comparing solid phase extraction (SPE) and centrifugation after Pressurized liquid extraction (PLE), and (2) to determine the contamination levels of PFOS and PFOA in waterproof sunscreen samples. All sunscreen samples were analyzed by liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). Sunscreen samples were purchased from domestic and international brands sold in Thailand. Special chemical properties were considered for the selection of samples, e.g., those found in waterproof, sweat resistant, water resistant, and non-stick products. Considering the factors of physical properties, e.g., operation time, chemical consumption, and recovery percentage for selecting methods to develop, the centrifugation method using 2 mL of extracted sample with the conditions of 12,000 rpm and $5^{\circ}C$ for 1 hour after PLE was chosen. The highest concentrations of PFOS and PFOA were detected at 0.0671 ng/g and 21.0644 ng/g, respectively. Even though present concentrations are found at ng/g levels, the daily use of sunscreen products is normally several grams. Therefore, a risk assessment of PFOS and PFOA contamination in sunscreen products is an important concern, and more attention needs to be paid to the long-term effects on human health.