• Nuclear Engineering and Technology
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• 제52권10호
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• pp.2394-2401
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• 2020

Octadecylamine is an effective film-forming amine that protects carbon steel from corrosion. In the present study, the effect of octadecylamine concentration on adsorption on a carbon steel surface was investigated in anaerobic alkaline solution by using SEM/EDS, TEM and the Materials Studio simulation techniques. TEM morphology observation and EDS elemental detection determine the thicknesses of octadecylamine film on a carbon steel surface, which are confirmed by the in-situ electrochemical impedance spectroscopy measurement and resistance calculation. The Materials Studio simulation reveals the number of octadecylamine film layers at different concentrations. Results obtained in this study indicate that adsorption of octadecylamine film on carbon steel proceeds with the multi-layer adsorption mechanism.

• Corrosion Science and Technology
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• 제21권6호
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• pp.423-433
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• 2022

The objective of this study was to determine whether Cymbopogon citratus extract as a corrosion inhibitor from natural tropical resources could prevent corrosion of carbon steel in sulfuric acid solution. Inhibitory action of this extract was investigated using electrochemical methods such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Those methods revealed corrosion rate, efficiency of inhibition, and adsorptions isotherm values when the extract was added to the sulfuric acid solution at concentration up to 500 ppm with various immersion time at ambient temperature. Results revealed that higher concentration of the extract and longer immersion time decreased the corrosion rate of carbon steel whereas the inhibition efficiency of the extract was increased up to 97.25%. The value of charge transfer resistance was increased significantly by adding the extract at concentration up to 500 ppm with an immersion time of 60 minutes. The type of the extract was a mixed inhibitor. It could inhibit the corrosion process in both anodic and cathodic sides electrochemically. Results of this study suggest that the mechanism of adsorption on the surface of carbon steel is related to Langmuir adsorption isotherm.

• 한국제4기학회지
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• 제18권2호통권23호
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• pp.23-31
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• 2004

Temperature variations, and carbon dioxide and methane concentrations are summarized during the past 400,000 years. Atmospheric temperature varied approximately within $10^{\circ}C$ during the past 400,000 years. Most of the time during the past 400,000 years, temperature was lower than today except 410000, 320000, 250000, and 125000 years ago. Temperature was slightly higher or at least similar to today during the time period of 410000. 320000, 250000, and 125000 years ago. The carbon dioxide concentration varied between 180 and 300 ppm, and the methane concentration varied between 40 and 700ppb. The present atmospheric concentration of carbon dioxide is 375 ppm and methane is 1750 ppb. Temperature was 5-$7^{\circ}C$ lower than today during the Last Glacial Maximum(18,000 years ago) and the Younger Dryas(10,000 years ago). Temprature was varied within $1^{\circ}C$ during the past 10,000 years. Especially Middle Holocene Climatic Optimum(6,000 years ago), Medieval Warm Period (500-1,000 years ago), and Little Ice Age(100-500 year ago) were global climatic events. In general, mechanism for the Middle Holocene Climatic Optimum, Medical Warm Period, and Little Ice Age can be explained by the solar insulation, however their exact mechnism is not well known. Carbon dioxide concentration during the past 400,000 years never reached the current value of 375 ppm. Furthermore, the current methane concentration never reached during the past 20Ma. However, current temperature value has happened several times during the past 400,000 years. The implication of this is unsolved question so far. This should be challenged in the near future.

• 한국대기환경학회지
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• 제25권6호
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• pp.571-578
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• 2009

$PM_{2.5}$ black carbon (BC) concentrations were measured to investigate the filter spot loading effect in raw BC data at 5-minute time-based resolution using a single-wavelength aethalometer at a Gwangju site. Also the elemental carbon (EC) concentrations from 24-hr integrated filter-based measurements of $PM_{2.5}$ particles were determined to compare with the loading compensated BC values. Close examination of the time-series BC data showed clearly the "gaps" when the filter tape advances, suggesting the correction of raw BC data. Therefore, we calculated the average BC concentration in each range of attenuation (ATN) to decide if there was (or was not) an effect on the aethalometer data according to the loading of the filter spot. A consistent decrease of average BC concentration was found with increasing ATN values for every month, suggesting there was a consistent "spot loading effect" in the raw BC data. The loading compensated BC concentration according to a simple compensation model with loading effect was 1.01~1.15 times greater than the raw BC data. The 24-hr average concentration of EC observed during summer sampling period was about 3% higher than the original 24-hr average BC value and 2% lower than the loading compensated BC concentration.

• Journal of Forest and Environmental Science
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• 제34권1호
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• pp.53-56
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• 2018

Elemental carbon (EC) and organic carbon (OC) mass concentrations in PM2.5 were measured from March through October 2015 in Taehwa Research Forest (TRF). The concentration of carbon in the TRF was $3.4{\mu}g/m^3$ and the concentration of EC was $1.4{\mu}g/m^3$. Also the concentration of $OC_{sec}$ was the highest at $2.84{\mu}g/m^3$ in the summer and the lowest at 1.66 in the spring. The ratio of the secondary generation OC in the total OC was the highest at 62% in the summer. Monthly OC concentration was the lowest at $2.38{\mu}g/m^3$ in April and the highest at $6.60{\mu}g/m^3$ in July. In case of EC concentration was the lowest in April ($0.98{\mu}g/m^3$) and the highest in July ($3.41{\mu}g/m^3$). The OC/EC ratio showed the lowest ratio in March and the highest rate in September. It is suggested that the secondary generation reaction of OC component was active due to sufficient irradiation amount in summer.

• 현장농수산연구지
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• 제21권1호
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• pp.115-122
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• 2019

상추 양액 재배 시 탄산수 엽면시비는 탄산수의 이산화탄소 농도가 높을수록 광합성률, 기공전도도가 높았으며, 내서성이 향상되었다. 상추 생육은 탄산수의 이산화탄소 농도가 높을수록 좋았으나, 이산화탄소 농도가 700 ppm, 500 ppm 에서는 tip-burn 발생률이 높아 수량은 300 ppm, 대조구가 700 ppm, 500 ppm 보다 많았다. 본 연구 조건하에서 탄산수 엽면시비에 의한 고온 한계 시점을 분석하기 위하여 기온 처리별 F_O를 조사한 결과 무처리구에는 32℃, 300 ppm은 33℃, 500 ppm은 34℃, 700 ppm은 36℃이었다. 이 결과를 보면 탄산수 엽면시비는 작물의 고온 한계 온도를 최고 약 4 ℃정도 높이므로 내서성이 향상된 것으로 판단되었다. 또한 탄산수의 이산화탄소 농도가 높을수록 항산효소 SOD(superoxide dismutase) 활성이 높았다.

• 한국태양에너지학회 논문집
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• 제26권1호
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• pp.65-71
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• 2006

This study describes to analyze variation of carbon dioxide gas concentration by experimental and theoretical method according to the using patterns of ventilation system in a model classroom. Concentration of $CO_2$ gas varied by the occupancy and the ventilation systems are operating or not. More than 850 CMH ventilation system can maintain $CO_2$ gas concentration lower than 1,000 ppm along the class time and can be adopted the government guideline. Theoretical modeling of the concentration was performed at well-mixed ideal condition. Delays of concentration decay were shown at each case compared to actual.

• 한국환경보건학회지
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• 제41권6호
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• pp.389-396
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• 2015

Objectives: A hospital is a complex building that serves many different purposes. It has a major impact on patient's well-being as well as on the work efficiency of the hospital staff. Thermal comfort is one of the major factors in indoor comfort. The purpose of this study was to determine thermal comfort in various locations in a hospital. Methods: Various indoor environmental conditions in a general hospital were measured in February 2014. The predicted mean vote (PMV) and carbon dioxide ($CO_2$) concentration were measured simultaneously in the lobby, office, restaurant, and ward. Results: The ward was the most thermally comfortable location (PMV=0.44) and the lobby was the most uncomfortable (PMV = -1.39). However, the $CO_2$ concentration was the highest in the ward (896 ppm) and the lowest in the lobby (572 ppm). The average PMV value was the most comfortable in the ward and the lowest in the lobby. In contrast, for concentration of carbon dioxide, the highest average was in the ward and the lowest in the lobby. Due to air conditioner operation, during operating hours the PMV showed values close to 0 compared to the non-operating time. Correlation between PMV and $CO_2$ differed by location. Conclusion: The PMV and concentration of carbon dioxide of the hospital lobby, office, restaurant and ward varied. The relationship between PMV and carbon dioxide differed by location. Consideration of how to apply PMV and carbon dioxide is needed when evaluating indoor comfort.

• 한국가스학회지
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• 제15권3호
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• pp.26-30
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• 2011

개방형 순간 가스온수기는 설치와 관리가 적절히 되지 않아 일산화탄소 중독과 질식과 같은 인명사고를 발생시킬 수 있다. 연소기에 공기가 충분히 공급되지 않거나 배기구가 막히면 배기가스 중의 일산화탄소(CO)의 농도가 증가하는 특성을 보인다. 본 연구는 가정집에서 사용 중인 개방형 가스온수기를 회수하여 연소기 주변 공기 중산소농도 및 배기가스 중 CO농도의 변화를 확인하였다. 환기구 면적에 따른 산소농도 측정 실험에서 환기구의 면적이 바닥면적의 3.5%에서 산소농도가 약 17.7%로 나타났고, 배기구를 폐쇄한 상태에서 CO농도를 측정한 결과 4,000ppm이상이 측정되었다. 따라서 정기적으로 배기구를 점검하는 것이 환기구 크기보다 일산화탄소 중독사고를 예방하기 위하여 중요하다.

• Journal of Microbiology and Biotechnology
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• 제14권3호
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• pp.532-539
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• 2004

For efficient lincomycin production from Streptomyces lincolnensis L1245, various vegetable oils, natural nitrogen sources, and surfactants were investigated at the pilot-scale level in the flask. Olive oil as the sole carbon source was the most suitable one for producing lincomycin. When 20 g/lof olive oil was used, the lincomycin concentration and lipase activity reached 1.01 g/land 182 U/ml, respectively, after 5 days of culture. Among the various unsaturated fatty acids, when linolenic acid was used, the cell growth and lincomycin production were markedly decreased. On the other hand, when 0.2 g/l of oleic acid was added to the culture broth, the maximum lincomycin concentration was 1.0 g/l, which was about 1.7-fold higher than that obtained without the addition of oleic acid. Among the various natural nitrogen sources, pharmamedia or soybean meal was the most suitable nitrogen source. In particular, in the case of a mixture of 10 g/l of pharmamedia and soybean meal, 1.5 g/l of lincomycin concentration and 220 U/ml of lipase activity were obtained. When Span 180 was used as the surfactant, lincomycin production, lipase activity, and oil consumption increased. The correlation between the consumption rates of oil and lincomycin production in a culture using olive oil as the sole carbon source was also investigated. The lincomycin production depended on the consumption rate of olive oil. Using these results, fed-batch cultures for comparing the use of olive oil and starch as a conventional carbon source were carried out in a 5-1 fermentor. When olive oil was used as the sole carbon source, 34 g/l of olive oil was consumed after 7 days of culture. The maximum lincomycin concentration was 3.0 g/l, which was about 2.0-fold higher than that of starch medium after 7 days of culture. The product yield was 0.09 gig of consumed carbon source, which was about 3.0-fold higher than that of starch medium after 7 days of culture.