• Title/Summary/Keyword: Carbon cage

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Design and Simulation Tools for Moored Underwater Flexible Structures (계류된 수중 유연구조물의 설계 및 시뮬레이션 도구 개발)

  • Lee, Chun-Woo;Lee, Ji-Hoon;Choe, Moo-Youl;Lee, Gun-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.43 no.2
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    • pp.159-168
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    • 2010
  • This paper presents a mathematical model and simulation method for investigating the performance of set net systems and fish cage systems influenced by currents and waves. Both systems consist of netting, mooring ropes, a floating collar and sinkers. The netting and ropes were considered flexible structures and the floating collar was considered an elastic structure. Both were modeled on a mass-spring model. The structures were divided into finite elements and mass points were placed at the mid-point of each element, and the mass points were connected by mass-less springs. Each mass point was subjected to external and internal forces and the total force was calculated at every integration step. An implicit integration scheme was used to solve the nonlinear dynamic system. The computation method was applied to dynamic simulation of actual systems simultaneously influenced by currents and waves in order to evaluate their practicality. The simulation results improved our understanding of the behavior of the structure and provided valuable information concerning the optimized design of set net and fish cage systems exposed to an open ocean environment.

Clinical and Radiologic Assessment for Anterior Cervical Interbody Fusion with Synthetic Cages

  • Shin, Seung-Ho;Lee, Woo-Jong;Eun, Jong-Pil;Choi, Ha-Young;Lee, Jung-Chung
    • Journal of Korean Neurosurgical Society
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    • v.41 no.2
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    • pp.105-110
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    • 2007
  • Objective : This purpose of this study was to determine the clinical efficiency and applicability, and to analyze the radiologic findings of the anterior cervical approach using two synthetic cages for interbody fusion. Methods : A total of 41 patients with cervical diseases underwent anterior discectomy and interbody fusion with the PEEK $Solis^{TM}$ cage in 21 patients and the carbon composite $Osta-Pek^{TM}$ cage in 20 patients. Outcome assessment was done using Odom's criteria. Radiological assessment was performed with respect to subsidence, bony fusion and lordosis. The mean follow-up period was 13 months. Results : There were 34 [92.9%] successful cases. The average height of the disc space 12 months after surgery compared the height just after surgery was decreased over 3mm in 4 cases, indicating severe subsidence. The use of these synthetic cages have provided the increase in postoperative cervical lordosis. Conclusion : There were no significant differences between the $Solis^{TM}$ and $Osta-Pek^{TM}$ cages on clinical and radiologic outcomes. Both $Solis^{TM}$ and $Osta-Pek^{TM}$ cages showed low subsidences and complications associated with hardware with good clinical outcomes, high fusion rates, restored disc heights, and restored cervical lordosis.

Uptake Effects of Two Electrons for Relative Stability and Atomic Structures of Carbon Cluster Isomers of C20: ab initio Methods

  • Lee, Wang-Ro;Lee, Chang-Hoon;Kang, Jin-Hee;Park, Sung-Soo;Hwang, Yong-Gyoo;Lee, Kee-Hag
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.445-448
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    • 2009
  • This study examined the effect of the uptake of one and two electrons on the atomic structure of three isomers of $C_{20}$ clusters, namely the ring, bowl (corannulene like), and cage (the smallest fullerene). Geometry optimizations were performed using the hybrid density functional (B3LYP) methods for neutral, singly and doubly charged $C_{20},\;{C_{20}}^-,and\;{C_{20}}^{2-}$. These results show that the symmetry of the lowest energies for ring and bowl isomers were not changed, whereas the increasing order of energy for the cage (the smallest fullerene) isomers was changed from $D_{2h}\;<\;C_{2h}\;{\leq}\;C_2\;of\;C_{20}\;through\;Ci\;<\;C_{2h}\;<\;C_2\;<\;D_{2h}\;of\;{C_{20}}^-\;to\;Ci\;<\;C_2\;<\;D_{2h}\;<\;C_{2h}\;of\;{C_{20}}^{2-}$. The reduced symmetry isomers of the cage have comparative energy and the ground state symmetry of the neutral and single and double charged $C_{20}$ decreased with increasing number of electrons taken up in the point of energetics. Interestingly, the difference in energy between the ground state and the next higher energy state of ${C_{20}}^{2-}$ was 3.5kcal/mol, which is the largest energy gap of the neutral, single anion and double anion of the cage isomers examined.

Synthesis and Characterization of Three-dimensional Polymer Produced by Mutual Condensation of Ethylenediamine and $C_{60}$

  • Vovk, O.;Lee, Joong-Kee
    • Carbon letters
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    • v.5 no.2
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    • pp.68-74
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    • 2004
  • The polymer with contents of $C_{60}$ up to 57 wt.% was produced by mutual condensation of fullerene $C_{60}$ and ethylenediamine. The investigations of this polymer as well as pristine fullerene to comparison were carried out by FT-IR and UV-Vis spectroscopy, ToF-SIMS, TGA, and elemental analysis. At least three kinds of components was revealed as building blocks of polymer. The fullerene cage underwent only distortion but didn't destroy during formation of polymer. The pure fullerene was found as an intermediate of the thermal decomposition of polymer. The conclusion that this polymer could serve as precursor to produce carbon nanomaterial with high concentration curved graphene sheets and can be used for gas adsorption and electrochemical application was made.

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Effect of the Egg Yolks from Laying Hens Intubated Astaxanthin on the Macrophage Activity, Hemagglutinin-titer and Hemolysin-titer (Astaxanthin처리 산란계로부터 생산된 난황이 Mouse의 마크로파지 활성과 응집소가 및 용혈소가에 미치는 영향)

  • 김홍출;박숙자;김정곤;김영림;박원석;조용운;조현종;김정환;하영래
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.6
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    • pp.1283-1286
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    • 2001
  • Effect of the egg yolks from laying hens intubated, p.o., astaxanthin (designated AEY) on mouse humoral immunity was investigated using male ICR mouse (6~7 weeks of age). Mice were adapted in a temperature- and humidity- controlled house for one week and randomly divided into 5 treatment groups (9 mice/cage/treatment). Mice were intubated p.o., AEY (100, 250 and 500$\mu\textrm{g}$) or control egg yolks (CEY, 250$\mu\textrm{g}$), dissolved in 0.1 mL DMSO, for consecutive 4 days. At day 5, carbon suspension (pilot drawing ink 3 mL+3% gelatine 3 mL) was injected 3 $\mu$L Per 1 g body weight through tail vein. Carbon clearance time was measured at 5 and 35 minutes Post the injection of carbon suspension. Another two experiments were conducted to determine the hemagglultinin-titer (HGT) and hemolysin-titer (HLT) with male ICR mouse (8 mice/cage/treatment). Mice treated with AEY were induced immune activity with SRBC. HGT and HLT were measured from the blood at day 1 and 3 after treatment of SRBC. AEY treatment reduced the carbon clearance time. Especially the carbon clearance time by 500 $\mu\textrm{g}$ AEY treatment was 5.00 minutes, which was very short time compared with 9.42 minutes by control and 9.01 minutes by CEY. AEY group showed slights higher values of HGT and HLT than CEY group and control. At day 1, HGT in control, 250$\mu\textrm{g}$ CEY and 250$\mu\textrm{g}$ AEY groups was 5.50, 5.63, and 6.00, respectively. Similiarly, HLT in control, 250$\mu\textrm{g}$ CEY and 250$\mu\textrm{g}$ AEY groups was 4.75, 5.38, and 5.50, respectively, at day 1. These results suggest that AEY exhibited immunity-enhancing effect.

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육체운동이 사염화탄소의 간독성에 미치는 영향

  • 김민경;김영철
    • Toxicological Research
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    • v.7 no.2
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    • pp.165-171
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    • 1991
  • Effects of forced physical exercise on the CCl4 hepatotoxicity were examined in adult female rats. Rats were treated with CCl4 (2 mmol/kg, ip) and introduced into a cylindrical cage rotating at 9 rpm for 20 min/hr for 6 hr. Eighteen hr following the termination of exercise serum sorbitol dehydrogenase (SDH), glutamic oxaloacetic transaminase (GOT), glutamic pyruvic transaminase (GPT) activities and glucose-6-phosphatase activity were determined as parameters for hepatotoxicity. Physical exercise inhibited the $CCI_{4-}$induced increases in SDH, GOT, GPT activity, and glucose-6-phosphatase activity were determined as parameters for hepatotoxicity.

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Environmental Management of Marine Cage Fish Farms using Numerical Modelling (수치모델을 이용한 해상어류가두리양식장의 환경관리 방안)

  • Kwon, Jung-No;Jung, Rae-Hong;Kang, Yang-Soon;An, Kyoung-Ho;Lee, Won-Chan
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.10 no.4
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    • pp.181-195
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    • 2005
  • To study the effects of aquaculture activity of marine cage fish farms on marine environment, field researches including hydrography, sediment, benthos and trap experiment at the marine cage fish farms(Site A) around estuaries of Tongyeong city were carried out during June $26\~27$, 2003. A simulation using numerical model-DEPOMOD was conducted to predict the solid deposition from fish cage and to assess the probable solid deposition, and the efficiency of environmental management of marine cage fish farms was studied. The marine cage fish farms cultured mainly common sea bass (Lateolabrax japonicus), red seabream (Pagrus major), striped breakperch (Oplegnathus fasciatus) and black rockfish(Sebastes schlegeli), and total amount of cultured fish of the Site A were 23.1MT. The amount of husbandry fish by unit area(and volume) of the fish cage was $43.0kg\;m^{-2}(6.1kg\;m^{-3})$. The daily mean amounts of food fed by unit biomass and cage area were $30.8g\;kg^{-1}day^{-1},\;1.32kg\;m^{-2}day^{-1},$ respectively, at the Site A. The concentration of ORP of the sediment below the center at the Site A was -334.6 mV and the concentrations of AVS, COD, Carbon and Nitrogen were $0.43mg\;g^{-1}dry,\;17.75mg\;g^{-1}dry,\;10.19mg\;g^{-1}dry\;and\;3.49mg\;g^{-1}dry$, respectively. Capitella capitata was dominant benthic species which occupied $57.8\%$ of total species, and the Infaunal Trophical Index(ITI) was marked below 20 within 20 m distance from the edge of the Site A. The result of trap experiment, the solid deposition from the Site A was $34,485g\;m^{-2}yr^{-1}$ at 0 m from the center of the cage and $18,915g\;m^{-2}yr^{-1}$ at 42 m. From a model simulation, it was estimated that using a model simulation, the proportion of unfed food was $40\%$ at the Site A and the annual total amount of solid deposition was 63,401 accounting for $24.4\%$ of the annual total food fed at the Site A. The area solid deposition settled was estimated to be $8,450m^2$, which was about 16 times of the total area of fish cage at the Site A. And concerning ITI and abundance of benthos, the model predicted that sustainable solid flux at the Site A was below $10,000gm^{-2}yr^{-1}$. The percentage of food wasted was main element of solid deposition at the marine cage fish farms, and for minimizing solid deposition it is necessary to increase the efficiency of the food uptake. Based on the result of the model simulation, if the percentage of food wasted decreases to $10\%$ from the current $40\%$, then the solid deposition could decrease to a half. In addition, it was predicted that if farmers use EP pellets as food fed instead of MP and fish trash, solid deposition could decrease by $57\%$. Also this study proposes that the cage facility ratio of the licensed area be decreased to less than $5\%$ to minimize the sediment pollution.

Health Assessment of the Fish-cage Farms using BHI(Benthic Health Index) (저서동물지수를 활용한 어류가두리 양식장의 건강도 평가)

  • Park, Sohyun;Kim, Sunyoung;Park, Se-jin;Jung, Rae-Hong;Yoon, Sang-Pil
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.5
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    • pp.735-745
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    • 2022
  • In this study, a health assessment was conducted using the Benthic Health Index (BHI) to assess fish cage farms, where a fishery environment assessment was also performed. A total of 43 farms were evaluated located in the East Sea, West Sea, and South Sea in Korea. The results of the BHI health evaluation included 8 grade 1 farms, 4 grade 2, 12 grade 3, and 19 grade 4. The grade 1 farms included sandy sediment farms and those with low intensity aquaculture, while the grade 2 farms included those located in areas with active seawater circulation. The fish cage farms belonging to grade 3 and 4 included the majority of farms with high-intensity aquaculture activities. There was no significant difference in total organic carbon between grade 3 and 4 farms, but the results of polychaete community analysis show that organic matter concentration was significantly higher in grade 4 farms.

Mass Balance of Finfish Cage Farm in South Korea (어류가두리 양식장의 물질수지 산정)

  • Bo-Ram Sim;Hyung Chul Kim;Sang-Pil Yoon;SokJin Hong;Woosung Jung;Sungchan Kang
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.4
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    • pp.473-483
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    • 2023
  • This study was conducted to better understand the impact of marine fish farming by estimating mass balances of carbon and nitrogen. According to the results, 94.55% of carbon and 95.66% of nitrogen inputs were from the feed supplied in the farm. Of the total carbon emissions in the farm, 47.28% was due to fish respiration, which was subsequently released into seawater. Advection and diffusion in the farm contributed to 30.29% of the carbon released. In the case of nitrogen, 50.70% of the nitrogen released into the seawater was produced by fish excreta, and 31.37% was advected and diffused into the system. The sedimentary environment received 3.82% and 3.10% of the carbon and nitrogen released from the farm, respectively. The fish feed used for healthy growth contained 11.64% carbon and 9.17% nitrogen. Since the feed type was floating pellets, the load released into the sedimentary environment was relatively lower than that released into the marine environment. These findings suggest that the identification of an optimal fish feed that respects fish physiology and preserves a healthy ecology is critical for the future of aquaculture. Furthermore, ecosystem-based aquaculture systems that decrease environmental burden, while endeavoring to improve environmental health, are required.

Structural and Bonding Trends among the B7C11-,B6C2, and B5C31+

  • Park, Sung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.26 no.1
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    • pp.63-71
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    • 2005
  • Equilibrium geometries, electronic structures, and energies of borocarbon clusters (binary compounds of carbon and boron), an unexplored class of molecules with highly unusual characteristics and potential for further development, have been investigated by means of B3LYP/6-311+G$^*$ density functional theory computations. A large number of B$_7$C${_1}^{1-}$, B$_6C_2$, and B$_5C_{3}\,^{1+}$ clusters with planar and non-planar monocyclic and polycyclic rings, as well as cage structures, have been systematically studied. Unexpectedly, planar forms are predicted not only to be the most stable structures, but also, in many cases, to have unprecedented planar heptacoordinate boron (p-heptaB) and planar heptacoordinate carbon (p-heptaC) arrangements. All these pheptaB and p-heptaC have 6π electrons and are aromatic according to the nucleus independent chemical shift (NICS). This novel bonding pattern is analyzed in terms of natural bond orbital (NBO) analysis. For virtually all possible B$_7$C${_1}^{1-}$, B$_6C_2$, and B$_5C_{3}\,^{1+}$ combinations, the p-heptaB arrangements are the more stable than other type structures.