• Title/Summary/Keyword: Carbon bonding

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Influence of Allylamine Plasma Treatment Time on the Mechanical Properties of VGCF/Epoxy

  • Khuyen, Nguyen Quang;Kim, Jin-Bong;Kim, Byung-Sun;Lee, Soo
    • Advanced Composite Materials
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    • v.18 no.3
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    • pp.221-232
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    • 2009
  • The allylamine plasma treatment is used to modify the surface properties of vapor grown carbon fibers (VGCF). It is to improve the interfacial bonding between the VGCF and epoxy matrix. The allylamine plasma process was performed by batch process in a vacuum chamber, using gas injection followed by plasma discharge for the durations of 20, 40 and 60 min. The interdependence of mechanical properties on the VGCF contents, treatment time and interfacial bonding between VGCF/ep was investigated. The interfacial bonding between VGCF and epoxy matrix was observed by scanning electron microscopy (SEM) micrographs of nanocomposites fracture surfaces. The changes in the mechanical properties of VGCF/ep, such as the tensile modulus and strength were discussed. The mechanical properties of allylamine plasma treated (AAPT) VGCF/ep were compared with those of raw VGCF/ep. The tensile strength and modulus of allyamine plasma treated VGCF40 (40 min treatment)/ep demonstrated a higher value than those of other samples. The mechanical properties were increased with the allyamine plasma treatment due to the improved adhesion at VGCF/ep interface. The modification of the carbon nanofibers surface was observed by transmission electron microscopy (TEM). SEM micrographs showed an excellent dispersion of VGCF in epoxy matrix by ultrasonic method.

Study on Friction Characteristic of Sintered Friction Component for Synchronizer-Ring of Diesel Vehicle (디젤차량 싱크로나이저링을 위한 소결마찰재 개발 및 접합특성 평가)

  • Song, Joon Hyuk;Kim, Eun Sung;Kim, Kyung-Jae;Oh, Je-Ha;Yang, Sung Mo;Kang, Shin Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.3
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    • pp.373-378
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    • 2013
  • The speed change performance of transmissions has become a serious issue because of the increase in the inertia moment that has accompanied increases in engine output and transmission size. Therefore, it is necessary to develop better wear resistant friction materials. In this study, an appropriate sintered friction component for the synchronizer ring of a diesel manual transmission was developed, and its bonding characteristics were analyzed. That is, a process for bonding an Fe-based base material and Cu-based sintered friction material was developed. BSE and EDX analyses of this bonding layer were conducted, along with a shear strength test, to determine the bonding characteristics.

Modeling of CNTs and CNT-Matrix Interfaces in Continuum-Based Simulations for Composite Design

  • Lee, Sang-Hun;Shin, Kee-Sam;Lee, Woong
    • Korean Journal of Materials Research
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    • v.20 no.9
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    • pp.478-482
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    • 2010
  • A series of molecular dynamic (MD), finite element (FE) and ab initio simulations are carried out to establish suitable modeling schemes for the continuum-based analysis of aluminum matrix nanocomposites reinforced with carbon nanotubes (CNTs). From a comparison of the MD with FE models and inferences based on bond structures and electron distributions, we propose that the effective thickness of a CNT wall for its continuum representation should be related to the graphitic inter-planar spacing of 3.4${\AA}$. We also show that shell element representation of a CNT structure in the FE models properly simulated the carbon-carbon covalent bonding and long-range interactions in terms of the load-displacement behaviors. Estimation of the effective interfacial elastic properties by ab initio simulations showed that the in-plane interfacial bond strength is negligibly weaker than the normal counterpart due to the nature of the weak secondary bonding at the CNT-Al interface. Therefore, we suggest that a third-phase solid element representation of the CNT-Al interface in nanocomposites is not physically meaningful and that spring or bar element representation of the weak interfacial bonding would be more appropriate as in the cases of polymer matrix counterparts. The possibility of treating the interface as a simply contacted phase boundary is also discussed.

A Study on Mechanical Strength in AI7075/CFRP Hybrid Composite (AI7075/CFRP 하이브리드 복합재료의 기계적강도 평가에 관한 연구)

  • 유재환
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.57-62
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    • 1997
  • The combined structure of hybrid composite made through the bonding process of materials of different properties greatly defines its mechanical characteristics, as the results of the experiments on materials of different properties show much dissimilarity. When carbon/epoxy materials are applied to hybrid composite, the carbon materials helps to improve the mechanical properties of the hybrid composite, and the epoxy reduces its fracture strain and impact resistance. Carbon fiber which is now in general commercialization is classified as high modulus or high strength system, and its manufacturing methods are various. The study of the materials having combined structure is focused on the numerical analysis of the layers of bonding surface in materials with difference modulus. The hybrid composite made through the multilayered bonding of reinforced aluminium sheets with aramid fiber now faces the marketing phase, and especially its excellent fatigue resistance and mechanical properties promote active researches on the similar products of hybrid composite. This study aims to investigate the effects of CFRP volume ratio and fiber's orientation over the properties of mechanical strength and fatigue life of the hybrid composite, AI7075/CFRP. To carry out this study, static tensile and fatigue tests were given to some of the panels which, made through the co-cure processing in an autoclave, have different CFRP volume ratio and carbon fiber orientations.

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Carbon/Epoxy Grid Structure with Near Zero CTE in 3-D Direction (3차원 방향으로 극소 열팽창계수를 갖는 탄소/에폭시 복합재료 격자 구조물)

  • 이형주;김창근;윤광준;박훈철
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.272-276
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    • 1999
  • The present paper proposes design and manufacturing methods of the carbon/epoxy square grid structure with near zero-CTE in three geometrical principal directions. Bonding strength of the grid structure is examined for different bonding methods. Numerical examples show that maximum displacement of the composite grid structure is almost zero comparing with that of aluminum grid structure with same dimension under thermal loading.

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Evaluation of Electromagnetic Pulse Shielding Effectiveness and Bonding Performance of Inorganic Paint based on Carbon Material (탄소재료 기반 무기계 도료의 전자파 차폐성능 및 부착성능 평가)

  • Jang, Kyong-Pil;Kim, Sang-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.1
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    • pp.801-807
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    • 2021
  • In various industrial fields and infrastructure based on electronic components, such as communication equipment, transportation, computer networks, and military equipment, the need for electromagnetic pulse shielding has increased. Two methods for applying electromagnetic pulse shielding are effective. The first is construction using shielding materials, such as shielding concrete, shielding doors, and shielding windows. The other is coating shielding paints on non-shielding structures. Electromagnetic pulse shielding paints are made using conductive materials, such as carbon nanotubes, graphite, carbon black, and carbon fiber. In this paint, electromagnetic pulse shielding performance is added to the commonly used water-based paint. In this study, the shielding effectiveness and bonding performance of paints using conductive graphite and carbon black as shielding materials were evaluated to develop electromagnetic pulse shielding inorganic paints. The shielding effectiveness and bonding performance were evaluated by applying six mixtures composed of different kinds and amounts of shielding material. The mixture of conductive graphite and carbon black at a weight ratio of 1:0.2 was the most effective in shielding as 33.6 dB. Furthermore, the mixture produced using conductive graphite only showed the highest bonding performance of 1.06 MPa.

Wireless Graphene Oxide-CNT Bilayer Actuator Controlled with Electromagnetic Wave (전자기웨이브에 의해 제어되는 무선형 그래핀-카본나노튜브 액츄에이터)

  • Xu, Liang;Oh, Il-Kwon
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2011.04a
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    • pp.282-284
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    • 2011
  • Based on graphene oxide and multi-walled carbon nanotube layers, a wireless bi-layer actuator that can be remotely controlled with an electromagnetic induction system has been developed. The graphene-based bi-layer actuator exhibits a large one-way bending deformation under eddy current stimuli due to asymmetrical responses originating from the temperature difference of the two different carbon layers. In order to validate one-way bending actuation, the coefficients of thermal expansion of carbon nanotube and graphene oxide are mathematically formulated in this study based on the atomic bonding energy related to the bonding length. The newly designed graphene-based bi-layer actuator is highly sensitive to electromagnetic wave irradiation thus it can trigger a new actuation mode for the realization of remotely controllable actuators and is expected to have potential applications in various wireless systems.

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Atomic bonding structure in the a-C:H thin films prepared by ECR-PECVD (ECR-PECVD 방법으로 제조한 a-C:H 박막의 결합구조)

  • 손영호;정우철;정재인;박노길;김인수;배인호
    • Journal of the Korean Vacuum Society
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    • v.9 no.4
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    • pp.382-388
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    • 2000
  • Hydrogenated amorphous carbon (a-C:H) films were fabricated by electron cyclotron resonance plasma-enhanced chemical vapor deposition. The bonding structure of carbon and hydrogen in the a-C:H films has been investigated by varying the deposition conditions such as ECR power, gas composition of methane and hydrogen, deposition time, and negative DC self bias voltage. The bonding characteristics of the a-C:H thin film were analyzed using FTIR spectroscopy. The IR absorption peaks of the film were observed in the range of $2800\sim3000 \textrm{cm}^{-1}$. The atomic bonding structure of a-C:H film consisted of $sp^3$ and $sp^2$ bonding, most of which is composed of $sp^3$ bonding. The structure of the a-C:H films changed from $CH_3$ bonding to $CH_2$ or CH bonding as deposition time increased. We also found that the amount of dehydrogenation in a-C:H films was increased as the bias voltage increased.

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Experimental and numerical study of the behavior of fiber reinforced concrete beams with nano-graphene oxide and strengthening CFRP sheets

  • Mohammad Reza Halvaeyfar;Ehsanollah Zeighami;S. Mohammad Mirhosseini;Ali Hassani Joshaghani
    • Structural Engineering and Mechanics
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    • v.87 no.4
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    • pp.375-389
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    • 2023
  • In many fiber concrete beams with Carbon Fiber Reinforced Polymer (CFRP), debonding occurs between the carbon sheets and the concrete due to the low strength of the bonding resin. A total of 42 fiber concrete beams with a cross-section of 10×10 cm with a span length of 50 cm are fabricated and retrofitted with CFRP and subjected to a 4-point bending test. Graphene Oxide (GO) at 1, 2, and 3 wt% of the resin is used to improve the mechanical properties of the bonding resins, and the effect of length, width, and the number of layers of CFRP and resin material are investigated. The crack pattern, failure mode, and stress-strain curve are analyzed and compared in each case. The results showed that adding GO to polyamine resin could improve the bonding between the resin and the fiber concrete beam. Furthermore, the optimum amount of nanomaterials is equal to 2% by the weight of the resin. Using 2% nanomaterials showed that by increasing the length, width, and number of layers, the bearing and stiffness of fiber concrete beams increased significantly.