• Title/Summary/Keyword: Carbon Migration

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Migration of Antidegradants to the Surface in NR Vulcanizates: Influence of Content of Carbon Black

  • 최성신
    • Bulletin of the Korean Chemical Society
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    • v.19 no.2
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    • pp.170-174
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    • 1998
  • Migration properties of antidegradants to the surface in NR vulcanizates containing carbon black of 30, 50, and 70 phr were studied using the migration-generating equipment with a vacuum technique. The migration was carried out at 60, 80, and 100 ℃ for 20 h. BHT, IPPD, HPPD, and wax were used as migrants. IPPD migrates faster than the other migrants. Amounts of BHT, IPPD, and HPPD that migrated at 60 and 80 ℃ decrease as the content of carbon black in the vulcanizate increases. Migrations of antidegradants in the NR vulcanizate containing carbon black of 50 phr are faster than those containing carbon black of 30 and 70 phr at 100 ℃. Although n-C23H48 is heavier than HPPD, it migrates faster than HPPD and even faster than BHT at 100 ℃. Influencing factors of carbon black on the migrations are its porous structure and polar functional groups on the surface.

The Study on the Migration of Carbon in T23/T91 Dissimilar Metal Welds for Boiler (보일러용 T23/T91 이종용접부의 탄소이동에 관한 연구)

  • Park, Ki-Duck;Jung, Byong-Ho;Kang, Chang-Yong
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.6
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    • pp.288-294
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    • 2014
  • The study on the migration of carbon in T23/T91 dissimilar metal welds for the boiler was conducted at $600^{\circ}C$ with an increase of aging time from 1 to 100 hrs. Following results were obtained. The heavily etched dark band tended to increase from a molten boundary owing to an increase of aging time, which leads to form hard (T91) and soft (T23) zones with different hardness. It was found that carbon was migrated from T23 area to T91 area due to different carbon activities. In addition, soft and hard zones were formed in regional area mainly resulted from carbide dissolutions and precipitates.

The Study of Corrosion Induced Co migration and Its Effect on Thermal Asperity Phenomenon (부식작용으로 인하여 디스크면으로 이동된 코발트가 Thermal Asperity 현상에 미치는 영향)

  • 좌성훈
    • Tribology and Lubricants
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    • v.15 no.4
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    • pp.335-342
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    • 1999
  • Corrosion of the disk has been an ongoing concern for the manufacturers of hard disk drives. With the advent of magnetoresistive (MR) head, very low levels of corrosion and contamination become more critical since the raised defects and corrosion products on the disk surface-anything that heats the MR sensor due to the contact-can distort the output signal of the head. This phenomenon is called as thermal asperity. In this paper, the effect of corrosion as a form of Co migration on the occurrence of thermal asperity in MR drives was investigated. The corrosion test at high temperature (60$^{\circ}C$) and high relative humidity (80%) was emphasized in this study and the testing results at ambient condition were compared. The corrosion on the disks was characterized as the amount of Co ion migration using an ion chromatography (IC) and a time-of-flight secondary ion mass spectroscopy (TOF-SIMS). It is proved that corrosion on the disk surface after storage testing is closely correlated to the amount of Co ions migration from the magnetic layer to disk surfaces and higher Co migration causes more thermal asperities in the drive. In order to reduce Co migration, several methods such as burnishing process and structure of the carbon overcoat were investigated. It is found that the hydrogenated carbon overcoat shows the least Co migration among different types of overcoat layer. However, the most effective way to reduce Co migration is the application of Cr layer between the overcoat and the magnetic alloy layer.

Equifield line simulation and ion migration prediction for concrete under 2-D electric field

  • Liu, Chih-Chien;Kuo, Wen-Ten;Huang, Chun-Yao
    • Computers and Concrete
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    • v.12 no.4
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    • pp.431-442
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    • 2013
  • This study attempted to find a proper method applicable to simulating practical equifield lines of two-dimensional Accelerate Lithium Migration Technique (ALMT), and evaluate the feasibility of using the theoretical ion migration model of one-dimensional ALMT to predict the ion migration behavior of two-dimensional ALMT. The result showed that the electrolyte or carbon plate can be used as matrix to draw equifield line graph similar to that by using mortar as matrix. Using electrolyte electrode module for simulation has advantages of simple production, easy measurement, rapidness, and economy. The electrolyte module can be used to simulate the equifield line distribution diagram in practical two-dimensional electrode configuration firstly. Then, several equifield line zones were marked, and several subzones under one-dimensional ALMT were separated from various equifield line zones. The theoretical free content distribution of alkali in concrete under two-dimensional electric field effect could be obtained from duration analysis.

Effect of heat treatment on mechanical properties of overlay welds (육성 용접부의 기계적 성질에 미치는 열처리조건의 영향)

  • 이기호;김기철;윤의박
    • Journal of Welding and Joining
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    • v.7 no.4
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    • pp.30-37
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    • 1989
  • Effect of heat treatment on mechanical properties of an overlay weldment was investigated. Over welding was carried out on the structural C-Mn mild steel substrate to take required test specimens. Shielded metal arc welding process with 13Cr-0.2Ni stick electrode was applied. The heat treatment temperatures and holding times were $450{\circ}C., 550{\circ}C., 650{\circ}C., 750{\circ}C., 850{\circ}C.$ and 0.5hr, 2hr, 10hr, respectively. Mechanical tests and microscopic inspection were also carried out to investigate welds soundness. Test results indicated that carbon migration was dominant near bonded zone. At temperature of around 650.deg. C, carburized layer and decarburized layer were formed remarkably along overlay welds region and C-Mn mild steel region, respectively. The wideth of these layers became wider with increasing heat treatment temperature and/or holding time at the elevated temperature, and this relationship agreed with Larson-Miller parameter. Side bending test results demonstrated that the crack free region of overlay welds could be deduced from the relationship between temperature and holding time.

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Studies on the Analysis of DOA in PVC Wrap Film and its Migration into Foodstuffs (염화비닐 랩 필름의 DOA 분석 및 식품에의 이행에 관한 연구)

  • Lee, Keun-Taik;Gyoung, Young-Soo;Park, Tae-Kyu
    • Korean Journal of Food Science and Technology
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    • v.22 no.2
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    • pp.145-149
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    • 1990
  • Extraction and analysis conditions of di-(2-ethylhexyl) adipate (DOA) and its migration contents into foods wrapped with plasticized polyvinyl chloride (PVC) film during storage and cooking with microwave were examined using gas chromatography. Experiments on the extraction solvent and method showed that the method of reflux using carbon tetrachloride for longer than one hour allowed the highest extraction of DOA. Analysis of four PVC wrap films from different factories in domestic market showed the DOA contents of 18.9% for home-use and 24.6% for retail-use on the average. The highest migration during storage was observed in pork belly, which were 21% and 26% after one and three days respectively. During microwave cooking; smaller than 5.5% of DOA were migrated into foods when the film was not contacted with foods, whereas about 49% migration was observed in pork belly contacted with film directly.

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Landuse and Landcover Change and the Impacts on Soil Carbon Storage on the Bagmati Basin of Nepal

  • Bastola, Shiksha;Lim, Kyuong Jae;Yang, Jae Eui;Shin, Yongchul;Jung, Younghun
    • Journal of the Korean GEO-environmental Society
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    • v.20 no.12
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    • pp.33-39
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    • 2019
  • The upsurge of population, internal migration, economic activities and developmental works has brought significant land use and land cover (LULC) change over the period of 1990 and 2010 in the Bagmati basin of Nepal. Along with alteration on various other ecosystem services like water yield, water quality, soil loss etc. carbon sequestration is also altered. This study thus primary deals with evaluation of LULC change and its impact on the soil carbon storage for the period 1990 to 2010. For the evaluation, InVEST (Integrated Valuation of Ecosystem Services and Tradeoffs) Carbon model is used. Residential and several other infrastructural development activities were prevalent on the study period and as a result in 2010 major soil carbon reserve like forest area is decreased by 7.17% of its original coverage in 1990. This decrement has brought about a subsequent decrement of 1.39 million tons of carbon in the basin. Conversion from barren land, water bodies and built up areas to higher carbon reserve like forest and agriculture land has slightly increased soil carbon storage but still, net reduction is higher. Thus, the spatial output of the model in the form of maps is expected to help in decision making for future land use planning and for restoration policies.

스테인레스강 Overlay 용접부의 Disbonding에 관한 연구 1

  • 이영호;윤의박
    • Journal of Welding and Joining
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    • v.1 no.2
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    • pp.45-52
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    • 1983
  • Many pressure vessels for the hot H$\sub$2//H$\sub$2/S service are made of 2+1/4Cr-1Mo steel with austenitic stainless steel overlay to combat agressive corrosion due to hydrogen sulfide. Hydrogen dissolves in to materials during operation, and sometimes gives rise to unfore-seeable damages. Appropriate precautions must, therefore, be taken to avoid the hydrogen induced damages in the design, fabrication and operation stage of such reactor vessels. Recently, hydrogeninduced cracking (or Disbonding) was found at the interface between base metal and stainless weld overlay of a desulfurizing reactor. Since the stainless steel overlay weld metal is subjected to thermal and internal-pressure loads in reactor operation, it is desirable for the overlay weld metal to have high strength and ductility from the stand point of structural safety. In section III of ASME Boiler and Pressure Vessel Code, Post-Weld Heat Treatment(PWHT) of more than one hour per inch at over 1100.deg. F(593.deg. C) is required for the weld joints of low alloy pressure vessel steels. This heat treatment to relieve stresses in the welded joint during construction of the pressure vessel is considered to cause sensitization of the overlay weld metal. The present study was carried out to make clear the diffusion of carbon migration by PWHT in dissimilar metal welded joint. The main conclusion reached from this study are as follows: 1) The theoretical analysis for diffusion of carbon in stainless steel overlay weld metal does not agree with Fick's 2nd law but the general law of molecular diffusion phenomenon by thermodynamic chemical potential. 2) In the stainless steel overlay welded joint, the PWHT at 720.deg. C for 10 hours causes a diffusion of carbon atoms from ferritic steel into austenitic steel according to the theoretical analysis for carbon migration and its experiment. 3) In case of PWHT at 720.deg. C for 10 hours, the micro-hardness of stainless steel weld metal in bonded zone increase very highly in the carburized layer with remarkable hardening than that of weld metal.

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Effects of Strain Annealing Grain Size on the Magnetic Properties of Extra-Low Carbon Steel (극저탄소강판의 자성에 미치는 변형소둔 결정립도의 영향)

  • An, S.K.;Jeong, W.S.;Park, J.U.
    • Journal of the Korean Society for Heat Treatment
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    • v.19 no.4
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    • pp.208-218
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    • 2006
  • The effects of the grain size on the magnetic properties in extra-low carbon steel after strain annealing were investigated. Two kinds of sample were prepared. One is the annealed sheet, which was annealed at $670^{\circ}C$ and $850^{\circ}C$ for various time periods after cold rolling. The other is the strain annealed sheet, which was temper rolled by 0.4% and subsequently strain annealed at the temperature ranging between $670^{\circ}C$ and $850^{\circ}C$ for various time periods. The grains after strain annealing became more coarse than those after primary annealing. The grains were coarsened due to the strain induced grain boundary migration (SIGM). It was found that the permeability tended to be increased and coercivity tended to be decreased with the increase of grain size. The optimum magnetic properties was achieved after strain annealing at $850^{\circ}C$ for 30 minites. Under this condition, the coercivity was measured to be 0.6 and the permeability was measured up to be 13000.