• 한국가스학회지
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• 제15권1호
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• pp.35-39
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• 2011

본 논문에서는 FEV 차량용 복합소재 연료탱크의 탄소섬유 적층두께에 따라 달라지는 강도안전성에 미치는 기여율의 영향을 해석하고자 한다. 기여율에 의한 영향을 FEM 모델링으로 고찰하기 위해, 복합소재 연료탱크의 알루미늄 라이너와 탄소섬유 적층에 작용하는 von Mises 등가응력을 후프방향과 헤리컬방향에 대하여 각각 계산 하였다. FEM 해석결과에 따르면, 알루미늄 라이너에 작용하는 등가응력 기여율은 후프방향으로는 77.5%, $70^{\circ}C$ 경사진 헤리컬방향으로는 18.11%, $12^{\circ}C$ 경사진 헤리컬방향으로는 4.39%로 각각 작용하는 것으로 나타났다. $12^{\circ}C$ 경사진 탄소섬유의 적층 두께비가 후프방향 적층 두께비의 42% 정도로 높게 유지됨에도 불구하고 알루미늄 라이너 소재에서 보여준 기여율 경향은 탄소섬유 적층의 강도안전성에 대해서도 유사한 것으로 나타났다. 결과적으로, 탄소섬유 연료탱크의 강도안전성은 탄소섬유 적층의 두께보다 와인딩 각도에 의해 더 많은 영향을 받는다는 계산결과를 보여주고 있다.

• Advanced Composite Materials
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• 제18권1호
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• pp.77-93
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• 2009

This paper investigated the damage transition mechanism between the fiber-breaking mode and the fiber-avoiding crack mode when the fiber-length is reduced in the unidirectional discontinuous carbon fiber-reinforced-plastics (CFRP) composites. The critical fiber-length for the transition is a key parameter for the manufacturing of flexible and high-strength CFRP composites with thermoset resin, because below this limit, we cannot take full advantage of the superior strength properties of fibers. For this discussion, we presented a numerical model for the microscopic damage and fracture of unidirectional discontinuous fiber-reinforced plastics. The model addressed the microscopic damage generated in these composites; the matrix crack with continuum damage mechanics model and the fiber breakage with the Weibull model for fiber strengths. With this numerical model, the damage transition behavior was discussed when the fiber length was varied. The comparison revealed that the length of discontinuous fibers in composites influences the formation and growth of the cluster of fiber-end damage, which causes the damage mode transition. Since the composite strength is significantly reduced below the critical fiber-length for the transition to fiber-avoiding crack mode, we should understand the damage mode transition appropriately with the analysis on the cluster growth of fiber-end damage.

• Composites Research
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• 제29권5호
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• pp.269-275
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• 2016

Multiscale hybrid composites, which consist of polymeric resins, microscale fibers and nanoscale reinforcements, have drawn significant attention in the field of advanced, high-performance materials. Despite their advantages, multiscale hybrid composites show challenges associated with nanomaterial dispersion, viscosity, interfacial bonding and load transfer, and orientation control. In this paper, carbon nanotube(CNT)/carbon fiber(CF)/polycarbonate(PC) multiscale hybrid composite were fabricated by a solution process to overcome the difficulties associated with controlling the melt viscosity of thermoplastic resins. The dependence of CNT loading was studied by varying the method to add CNTs, i.e., impregnation of CF with CNT/PC/solvent solution and impregnation of CNT-coated CF with PC/solvent solution. In addition, hybrid composites were fabricated through surfactant-aided CNT dispersion followed by vacuum filtration. The morphologies of the surfaces of hybrid composites, as analyzed by scanning electron microscopy, revealed the quality of PC impregnation depends on the processing method. Dynamic mechanical analysis was performed to evaluate their mechanical performance. It was analyzed that if the position of the value of tan ${\delta}$ is closer to the ideal line, the adhesion between polymer and carbon fiber is stronger. The effect of mechanical interlocking has a great influence on the dynamic mechanical properties of the composites with CNT-coated CF, which indicates that coating CF with CNTs is a suitable method to fabricate CNT/CF/PC hybrid composites.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.855-859
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• 2005

Carbon fiber polymeric composites have been widely used in bearing materials under high pressure without oil-lubrication due to their self-lubricating characteristics. However, the severe wear of carbon composite surface occurs due to the generation of wear debris when the pressure applied on the composite surface is higher than the critical value of composite surface. In this work, in order to remove wear debris continuously during sliding operation, composite specimens with many micro-grooves on their sliding surfaces were devised. To investigate the effect of wear debris on the tribological behavior of carbon/epoxy composites, dry sliding tests were performed with respect to applied pressure using the composite specimens with and without micro-grooves. From the measurement of friction coefficients and wear rates, a model for the effect of wear debris on the friction and wear of composites was proposed.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2005년도 추계학술발표대회 논문집
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• pp.149-152
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• 2005

In order to extend the life time of building and civil infra-structure, nowadays, patch type carbon sheets are widely used as repairing meterials. Repaired concrete columns and beams with carbon sheets gain their stiffness and strength, but they lose toughness and show brittle failure behaviors. Usually, the cracks of concrete structures are visible with naked eyes and the status of the structure in the life cycle is estimated with visible inspection. After repairing of the structure, crack visibility is blocked by repaired carbon sheets. Therefore, structural monitoring after repairing is indispensible and self diagnosis method with optical fiber sensor is very useful. In this paper, peel-out effects is detected with optical fiber sensors and the strain difference between main structure and repaired carbon sheets when they separate each other.

• Composites Research
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• 제31권6호
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• pp.299-303
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• 2018

탄소섬유 강화 PA6 복합재료의 탄소섬유-메트릭스간 계면결합력과 반응중합도 향상을 위해서 기존 탄소섬유의 에폭시 사이징제를 디사이징처리하여 에폭시를 제거한 후 우레탄계, 나일론계, 페녹시계 사이징제로 재처리해주었으며, 리사이징처리된탄소섬유의표면을관찰하였다. 리사이징처리된탄소섬유의계면결합력은 IFSS(Interfacial shear strength)를 통해서 확인하였으며, 계면 결합 강도 측정 후 파단면은 주사전자현미경을 통해서 관찰하였다. 나일론계와 페녹시계 사이징제로 처리된 탄소섬유가 우레탄계 사이징에 비해 계면 결합력이 상승한 것을 확인하였다. 우레탄계 리사이징 처리된 탄소섬유는 기존 에폭시 사이징 탄소섬유보다 계면 결합력이 감소한 것으로 확인되었다. 이 결과는 기존 탄소섬유의 저활성과 평활성을 제거하여 탄소섬유와 나일론6 사이의 계면 결합력이 향상된 것으로 판단된다.

• Carbon letters
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• 제14권2호
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• pp.94-98
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• 2013

Isotropic pitch fibers were stabilized and carbonized for preparing carbon fibers. To optimize the duration and temperature during the stabilization process, a thermogravimetric analysis was conducted. Stabilized fibers were carbonized at 1000, 1500, and $2000^{\circ}C$ in a furnace under a nitrogen atmosphere. An elemental analysis confirmed that the carbon content increased with an increase in the carbonization temperature. Although short graphitic-like layers were observed with carbon fibers heat-treated at 1500 and $2000^{\circ}C$, Raman spectroscopy and X-ray diffraction revealed no significant effect of the carbonization temperature on the crystalline structure of the carbon fibers, indicating the limit of developing an ordered structure of isotropic pitch-based carbon fibers. The electrical conductivity of the carbonized fiber reached $3.9{\times}10^4$ S/m with the carbonization temperature increasing to $2000^{\circ}C$ using a four-point method.

• Composites Research
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• 제37권3호
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• pp.186-189
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• 2024

본 연구는 나노필러가 혼합된 열가소성 탄소섬유강화 복합재료(Carbon fiber reinforced thermoplastic polymer, CFRTP)의 물성을 비교 평가하였다. Polyamide 6 (PA6) 수지에 Multi-wall carbon nano tube (MWCNT), Silicon oxide, Core shell rubber, Aramid nano fiber 등의 다양한 나노필러를 혼합한 후, 이를 기지재(Matrix)로 탄소섬유강화복합 재료(CFRP)를 제조하여 그 물성을 측정하였다. 나노필러의 종류와 혼합비율에 따라, 인장강도, 층간계면결합력 (Inter-laminar shear strength), Izod 충격 강도 등이 측정되었다. 인장 강도와 충격 강도의 경우 Core shell rubber를 혼합한 경우 가장 높은 물성을 가졌으나, 계면결합력은 silicon oxide를 1 wt.% 이하 혼합하였을 때 최적값을 가졌다.

• Carbon letters
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• 제15권4호
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• pp.268-276
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• 2014

Recently, methods that usea carbon-based filler, a conductive nanomaterial, have been investigated to develop composite fillers containing dielectric materials. In this study, we added geometric changes to a carbon fiber, a typical carbon-based filler material, by differentiating the orientation angle and the number of plies of the fiber. We also studied the electrical and electromagnetic shield characteristics. Based on the orientation angle of $0^{\circ}$, the orientation angle of the carbon fiber was changed between 0, 15, 30, 45, and $90^{\circ}$, and 2, 4, and 6 plies were stacked for each orientation angle. The maximum effect was found when the orientation angle was $90^{\circ}$, which was perpendicular to the electromagnetic wave flow, as compared to $0^{\circ}$, in which case the electrical resistance was small. Therefore, it is verified that the orientation angle has more of an effect on the electromagnetic interference shield performance than the number of plies.

• 한국염색가공학회지
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• 제9권4호
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• pp.47-53
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• 1997

To improve the interfacial bonding of carbon fiber-nylon 6 composite, carbon fiber(CF) were oxidized by nitric acid treatment, and two types of graft polymer(GP) of nylon 6-g-polyacrylamide (PAAm) -water dispersable GP(WDGP) and m-cresol solu ble GP(CSGP) were treated as coupling agents. Introduction of polar groups such as -COOH, -OH, etc, on the surface of the oxidized CF was confirmed by IR spectra. The stem polymer of nylon 6 in the coupling agent (GP) could be compatible with'matrix nylon 5, and the grafted branch of PAAm on GP could react to the polar groups on the oxidized CF in composite. The interfacial strength was measured by the transverse tensile test to the fiber direction for single CF embedded nylon 6 film especially prepared and by the pull-out test method. The interfacial strength of the composite reinforced with oxidized CF is greater than that reinforced with unoxidized CF. The interfacial strength of the composite was increased by treatment of coupling agents(GPs) considerably, and the increasing tendency by the WDGP is greater than that by the CSGP. The optimum conditions of coupling agent treatment are as follows: the concentration, adsorption tlme of GP, and curing temperature are 2%, 20 minutes, and $170^{\circ}$, respectively.