• Title/Summary/Keyword: Carbon Equivalent

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Does High-Speed Rail Have Superiority over Motorway in Terms of CO2 Emission? (고속철도는 고속도로에 비하여 저탄소 친환경적인가?)

  • Kang, Taeseok;Chang, Hyunho
    • International Journal of Highway Engineering
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    • v.18 no.5
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    • pp.83-93
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    • 2016
  • PURPOSES : The aim of this article is to compare and identify eco-friendly competitiveness between (regional) motorway and high-speed rail(HSR) from the perspective of $CO_2$ emission in the Republic of Korea. METHODS : In order for an analysis of low-carbon competitiveness between the two modes, $CO_2e$ emission, $CO_2eppk$ (equivalent $CO_2$ gram per passenger kilometer), is employed as a comparison index. As for HSR, the index is calculated based on the passenger transport data and the gross of $CO_2e$ produced by Kyungbu high-speed line in 2013. Additionally, the gross of $CO_2e$ is computed by the greenhouse gas emission factors of domestic electricity generation mix. Regarding the index of motorway, it is directly calculated using both the official $CO_2e$ emission factor and the passenger-car occupancy of motorway. RESULTS : The results revealed, in the case of inter-regional transport, that the $CO_2e$ emission of displacement-based cars is 54.9% less than that of HSR, as the domestic electric power systems heavily relies on the thermal power plants over 66%. Note that internal combustion engines commonly used for vehicles are more energy-efficient than steam-driven turbines usually utilized for thermal power generation. CONCLUSIONS : It can be seen, at the very least in our study, that HSR has no superiority over motorway in the case of $CO_2e$ emission under the situations of domestic electricity generation mix. In addition, advanced eco-friendly vehicles have strong advantages over HSR. Therefore, all-out efforts should be made to develop and harvest renewable energy sources in order to achieve low-carbon HSR, sparing fossil fuels.

Filter-based Correction for Positive Sampling Artifacts in the Determination of Ambient Organic Carbon (여과지를 이용한 유기탄소의 측정 오차 보정)

  • Kang, Byung-Wook;Yeon, Ik-Jun;Cho, Byung-Yeol;Park, Sang-Chan;Lee, Hak-Sung;Jeon, Jun-Min;Na, Kwang-Sam
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.1
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    • pp.63-72
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    • 2011
  • This study describes the impact of positive sampling artifact caused by a filter-based sampling in the determination of ambient organic carbon (OC). Three different sampling media combinations were employed for this investigation: (1) Quartz filter-alone (Q-alone), (2) quartz filter behind quartz-fiber filter (QBQ), and (3) quartz filter and quartz filter behind Teflon filter (Q-QBT). The measurement of ambient OC was carried out at a semi-urban site near oceanside at the end of November of 2008. It was found that Q-alone sampling configuration resulted in a higher OC than QBQ and Q-QBT by 14% and 28%, respectively due to no correction for positive artifact caused by adsorption of gas-phase OC onto the filter. A lower quantity of OC was collected from the backup quartz filter on QBQ than that from Q-QBT. A possible explanation is that the front quartz filter of QBQ was not fully saturated with gas-phase OC during the sampling period, allowing smaller amount of gas-phase OC to reach the backup quartz filter. The contribution of positive artifact to $PM_{2.5}$ mass was approximately 2.15 ${\mu}g/m^3$ which is equivalent to 6% in terms of Q-QBT sampling configuration. The positive artifact was found to be more dominated during summer than during winter, showing temperature dependence. It was concluded that Q-QBT sampling configuration offers less impact of positive artifact on ambient OC sampling than QBQ in quantification of OC.

A Study on Effect of Thermal Decomposition Products of Coal on Anodic Reactions in Direct Carbon Fuel Cell (석탄 열분해 생성물이 직접탄소연료전지에서 애노드 반응에 미치는 영향에 대한 연구)

  • Rhie, Young Hoon;Eom, Seong Yong;Ahn, Seong Yool;Choi, Gyung Min;Kim, Duck Jool
    • Journal of Hydrogen and New Energy
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    • v.24 no.5
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    • pp.413-420
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    • 2013
  • Effect of inherent volatile matters in fuels on electrochemical reactions of anode was investigated for a single direct carbon fuel cell (DCFC). Raw coals used as power source in the DCFC release light gases into the atmosphere under the operating temperature of DCFC ($700^{\circ}C$) by thermal decomposition and only char remained. These exhausted gases change the gas composition around anode and affect the electrochemical oxidation reaction of system. To investigate the effect of produced gases, comparative study was conducted between Indonesian sub-bituminous coal and its char obtained through thermal treatment, carbonizing. Maximum power density of raw coal ($52mW/cm^2$) was appeared higher than that of char ($37mW/cm^2$) because the gases produced from the raw coal during thermal decomposition gave additional positive results to electrochemical reaction of the system. The produced gases from coals were analyzed using TGA and FT-IR. The influence of volatile matters on anodic electrolyteelectrode interface was observed by the equivalent circuit induced from fitting of impedance spectroscopy data.

Investigation of the Central Carbon Metabolism of Sorangium cellulosum: Metabolic Network Reconstruction and Quantification of Pathway Fluxes

  • Bolten, Christoph J.;Heinzle, Elmar;Muller, Rolf;Wittmann, Christoph
    • Journal of Microbiology and Biotechnology
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    • v.19 no.1
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    • pp.23-36
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    • 2009
  • In the present work, the metabolic network of primary metabolism of the slow-growing myxobacterium Sorangium cellulosum was reconstructed from the annotated genome sequence of the type strain So ce56. During growth on glucose as the carbon source and asparagine as the nitrogen source, So ce56 showed a very low growth rate of $0.23\;d^{-1}$, equivalent to a doubling time of 3 days. Based on a complete stoichiometric and isotopomer model of the central metabolism, $^{13}C$ metabolic flux analysis was carried out for growth with glucose as carbon and asparagine as nitrogen sources. Normalized to the uptake flux for glucose (100%), cells recruited glycolysis (51%) and the pentose phosphate pathway (48%) as major catabolic pathways. The Entner-Doudoroff pathway and glyoxylate shunt were not active. A high flux through the TCA cycle (118%) enabled a strong formation of ATP, but cells revealed a rather low yield for biomass. Inspection of fluxes linked to energy metabolism revealed that S. cellulosum utilized only 10% of the ATP formed for growth, whereas 90% is required for maintenance. This explains the apparent discrepancy between the relatively low biomass yield and the high flux through the energy-delivering TCA cycle. The total flux of NADPH supply (216%) was higher than the demand for anabolism (156%), indicating additional reactions for balancing of NADPH. The cells further exhibited a highly active metabolic cycle, interconverting $C_3$ and $C_4$ metabolites of glycolysis and the TCA cycle. The present work provides the first insight into fluxes of the primary metabolism of myxobacteria, especially for future investigation on the supply of cofactors, building blocks, and energy in myxobacteria, producing natural compounds of biotechnological interest.

Microstructural Evolution with Annealing of Ultralow Carbon IF Steel Severely Deformed by Six-Layer Stack ARB Process (6층겹침ARB공정에 의해 강소성가공된 극저탄소IF강의 어닐링에 따른 미세조직 변화)

  • Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.22 no.8
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    • pp.403-408
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    • 2012
  • A sample of ultra low carbon IF steel was processed by six-layer stack accumulative roll-bonding (ARB) and annealed. The ARB was conducted at ambient temperature after deforming the as-received material to a thickness of 0.5 mm by 50% cold rolling. The ARB was performed for a six-layer stacked, i.e. a 3 mm thick sheet, up to 3 cycles (an equivalent strain of ~7.0). In each ARB cycle, the stacked sheets were, first, deformed to 1.5 mm thickness by 50% rolling and then reduced to 0.5 mm thickness, as the starting thickness, by multi-pass rolling without lubrication. The specimen after 3 cycles was then annealed for 0.5 h at various temperatures ranging from 673 to 973 K. The microstructural evolution with the annealing temperature for the 3-cycle ARB processed IF steel was investigated in detail by transmission electron microscopy observation. The ARB processed IF steel exhibited mainly a dislocation cell lamella structure with relatively high dislocation density in which the subgrains were partially observed. The selected area diffraction (SAD) patterns suggested that the misorientation between neighboring cells or subgrains was very small. The thickness of the grains increased in a gradual way up to 873 K, but above 898 K it increased drastically. As a result, the grains came to have an equiaxed morphology at 898 K, in which the width and the thickness of the grains were almost identical. The grain growth occurred actively at temperatures above 923 K.

A Property of Crack Propagation at the Specimen of CFRP with Layer Angle (적층각도를 지닌 CFRP 시험편에서의 크랙전파 특성)

  • Hwang, Gue Wan;Cho, Jae Ung;Cho, Chong Du
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.12
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    • pp.1013-1019
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    • 2016
  • CFRP is the composite material manufactured by the hybrid resin on the basis of carbon fiber. As this material has the high specific strength and the light weight, it has been widely used at various fields. Particularly, the unidirectional carbon fiber can be applied with the layer angle. CFRP made with layer angle has the strength higher than with no layer angle. In this paper, the property of crack growth due to each layer angle was investigated on the crack propagation and fracture behavior of the CFRP compact tension specimen due to the change of layer angle. The value of maximum stress is shown to be decreased and the crack propagation is slowed down as the layer angle is increased. But the limit according to the layer angle is shown as the stress is increased again from the base point of the layer angle of $60^{\circ}$. This study result is thought to be utilized with the data which verify the probability of fatigue fracture when the defect inside the structure at using CFRP of mechanical structure happens.

Synthesis of SiC from the Wire Cutting Slurry of Silicon Wafer and Graphite Rod of Spent Zinc-Carbon Battery (폐 반도체 슬러리 및 폐 망간전지 흑연봉으로부터 탄화규소 합성)

  • Sohn Yong-Un;Chung In-Wha;Sohn Jeong-Soo;Kim Byoung-Gyu
    • Resources Recycling
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    • v.12 no.3
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    • pp.25-30
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    • 2003
  • The synthesis of SiC used for the parts of the gas turbine and the heat exchanger, was carried out. In this study, wire cutting slurry of silicon wafer and the graphite rod of spent zinc-carbon battery were applied to the starting materials for the synthesis. The powders of Si or Si+SiC were obtained from the waste material by filtration, gravity separation and magnetic separation. Graphite powder was produced by dismantling, grinding and gravity separation from spent zinc-carbon battery. The synthesis of SiC could be completed from the mixture powders of Si and C or Si+SiC and C at the condition of equivalent ratio of Si and C, atmosphere of Ar or vacuum, temperature of above 1$600^{\circ}C$ and 2 hours reactions. The purity of synthesized Si-C was above 99%.

Chemical Fluxes at the Sediment-Water Interface Below Marine Fish Cages on the Coastal Waters off Tong-Young, South Coast of Korea (남해안 통영지역 가두리양식장 해수-퇴적물 경계면에서의 chemical fluxes)

  • Shim, Jeong-Hee;Kang, Young-Chul;Choi, Jin-Woo
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.2 no.2
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    • pp.151-159
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    • 1997
  • Benthic respiration and chemical fluxes were measured at the sediment-water interface underlying the marine fish cages floating on the open coastal waters off Tong-Young, the South Coast of Korea. The effects of cage farming on coastal benthic environment and on mass balance of organic carbon in the benthic boundary layer under the marine fish cages are addressed. In a growing season of caged fishes of June, 1995, benthic chambers and sediment traps were deployed on the sediment-water interfaces of the two sites chosen for this study: 1) Cage Site, directly underlying the fish cages of the farm at 18 m water depth, and 2) Control Site, about 100 m away from the farm at 32 m water depth. Benthic respiration rates and chemical fluxes were calculated from the evolution of dissolved oxygen and chemicals in the chamber water, and mass balance of organic carbon in the benthic boundary layer was constructed based on the vertical flux of particulate organic matter (POM) and chemical fluxes out of the sediment. High organic dumping (6400 mg C $m^{-2}d^{-1}$) and high benthic respiration (230 mmol $O_2\;m^{-2}d^{-1}$) were observed at the Cage Site. Equivalent to 40% of vertical flux of organic carbon into the Cage Site seemed to be decomposed concurrently and released back to overlying waters (2400 mg C $m^{-2}d^{-1}$). Consequently, up to 4000 mg C $m^{-2}d^{-1}$ of organic carbon could be buried into the farm sediment (equivalent to 60% of organic carbon flux into the Cage Site). At the Control Site, relatively less input of organic carbon (4000 mg C $m^{-2}d^{-1}$) and low benthic respiration rate (75 mmol $O_2\;m^{-2}d^{-1}$) were observed despite short distance away from the cages. The influence of cage farming on benthic chemical fluxes might be restricted and concentrated in the sea bottom just below the fish cages in spite of massive organic dumping and high current regime around the fish cage farm.

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The Effects of Eco-friendly Design of Dishwashing Detergent on Product's Carbon Emission Reduction (친환경 설계로 제조된 주방세제의 탄소배출량 감축 효과)

  • Kim, Jong Seok;Kim, Won Chan;Lee, Yong Ju;Kim, Heung Sik;Park, Heon Young;Yang, Bong Sig;Kim, Wan Soo;Park, Pil Ju;Hong, Eun Ah
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.2
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    • pp.87-91
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    • 2015
  • As negative effects of climate change have been visualized and its direct damages to economy have been realized, the global efforts to respond to climate change by reducing greenhouse gas emission were accelerated. Korea's Carbon Footprint Labeling gets a lot of attention as one of the effective methods to contribute to national GHG reduction goal, and for enterprises to show customers how much effort the company put into global warming prevention. Consumers' interest on low-carbon products has been increasing. This study uses Life Cycle Assessment method to calculate the amount of carbon emission of dishwashing detergent, LG Household & Healthcare, which reduced carbon emissions by using raw materials that has relatively lower environment load. Life Cycle Assessment Method is based on guidelines of Carbon Footprint Labeling, Ministry of Environment, and pre-manufacturing, manufacturing, and disposal phase are included while use phase of the product is excluded from assessment. In order to understand the effects of eco-design on carbon emissions, the dishwashing detergent's carbon emissions are compared before and after the change of main raw materials. The result shows the improvement from $0.47kgCO_2eq/kg$ to $0.38kgCO_2eq/kg$ per product, and this means the main raw materials' carbon emissions could be reduced by around 9.4%, which is equivalent to 916tons of GHG emissions per year.

Vibration Characterization of Cross-ply Laminates Beam with Fatigue Damage (피로 손상을 입은 직교 복합재료 적층보의 진동 특성)

  • 문태철;김형윤;황운봉;전시문;김동원;김현진
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.1-4
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    • 2001
  • A new non-destructive fatigue prediction model of the composite laminates is developed. The natural frequencies of fatigue-damaged laminates under extensional loading are related to the fatigue lift of the laminates by establishing the equivalent flexural stiffness reduction as a function of the elastic properties of sublaminates. The flexural stiffness is derived by relating the $90^{\circ}$-ply elastic modulus reduction, and using the laminate plate theory to the degraded elastic modulus and the intact elastic modulus of other laminate. The natural frequency reduction model, in which the dominant fatigue mode can be identified from the sensitivity scale factors of sublaminate elastic properties, provides natural frequency vs. fatigue cycle curves for the composite laminates. Vibration tests were also conducted on $[\textrm{90}_{2}\textrm{0}_{2}]_s$ carbon/epoxy laminates to verify the natural frequency reduction model. Correlations between the predictions of the model and experimental results are good.

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