• 한국환경보건학회지
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• 제27권1호
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• pp.36-43
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• 2001

Chitosans were prepared from red crab chitin under various alkali treatment conditions(different alkali concentrations, reaction times and temperatures) and theirphysicochemical properties were investigated. The nitrogen content and deacetylation degree of red crab chitin were 6.15% and 22.17A%, respectively. By the IR spectra, red crab and reference chitin showed the sharp bands at 1650 $cm^{-1}$ / and 1550 $cm^{-1}$ /, which are characteristic of chitin. The nitrogen contents of prepared chitosans ranged from 6.19~7.48%. Thedeacetylation degree was increased from 63~76% and 48~78% with increasing reaction time and temperature, whereas viscosity was decreased. The nitrogen content and yield of red crab chitosan perpared from chitin with 50% NaOH, 1:25(w/v) for 3.0 hr at 120$cm^{-1}$ / were 7.26% and 85.0%, respectively. and viscosity, deacetylation degree and molecular weight, 67.0 mPa.s, 75.0% and 6.5$\times$10$^{5}$ Dalton, respectively. From the IR spectra, the amide absorption bands of red crab and reference chitosan became very weak, similarly. And at solid state $^{13}$ C-NMR spectra, C=O(carbonyl carbon) signals absent, whereas $CH_3$(methyl carbon) was residues. Chemical shift of $^{13}$ C-NMR spectra of red crab and reference chitosans were in good agreement with slight experimental deviation.

• 대기
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• 제20권4호
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• pp.519-530
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• 2010

In this paper we review current research on Atmospheric Brown Clouds (ABCs) with lightweight Unmanned Aerial Vehicles (UAVs) and miniaturized instruments. The UAV technology for in-situ measurements, including aerosol concentration, aerosol size distribution, aerosol absorption, cloud drop size distribution, solar radiation fluxes (visible and broadband), and spectral radiative fluxes, is a leading-edge technology for cost-effective atmospheric sounding, which can fill the gap between the ground measurement and satellite observation. The first experimental observation with UAVs in Korea, Cheju ABC Plume Monsoon Experiment (CAPMEX), conducted during summer 2008 revealed that the Beijing plumes exerted a strong positive influence on the net warming and fossil-fuel-dominated black-carbon plumes were approximately 100% more efficient warming agents than biomass-burning-dominated plumes. Long-term sustainable routine UAV measurements will eventually provide truly three-dimensional data of ABCs, which is necessary for the better understanding of their climate impacts and for the improvement of numerical models for air pollution, weather forecast and climate change.

• 한국가스학회지
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• 제14권3호
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• pp.35-40
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• 2010

이 연구는 근로자 및 인체에 유해한 휘발성유기화합물질인 benzene, toluene, p-xylene을 흡착제거할 수 있는 흡착제를 개발하고자 하였다. 따라서 그 것을 위하여 기존 상업용 흡착효율을 높이고자 KOH/ACF(activated carbon fibers)를 몰비 1:1로 ACF를 재활성 시켜 기존 ACF와 재 활성 시킨 ACF와의 흡착효율을 비교 검토하고자 하였다. 그 결과 각 물질에 대한 흡착시간에 따른 흡착파과효율(%)는 농도가 클수록 커져 빠른 파과속도를 보였고 또한 농도를 125PPM으로 고정시키고 유량을 0.5$\ell$/min에서 탈착실험을 통한 흡착효과의 재현성은 toluene과 p-xylene의 경우 유사한 경향을 보였다. 그러나 benzene의 경우 재활성한 ACF가 재활성 되지 않은 상업용 ACF보다 오히려 탈착효과가 낮은 것으로 관찰되었다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.525-528
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• 2006

Transparent conducting films were fabricated on polyethylene terephthalate substrate by a spray method using double-walled carbon nanotubes dispersed in organic solvent and water-based solution. We analyzed the films by absorption spectra, sheet resistance, and scanning electron microscopy. Transparent conducting films with high uniformity and high transparency were fabricated by the spray method. We found that the dispersion particularly nanodispersion of CNTs was of crucial importance to improve the film performance.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1989년도 하계종합학술대회 논문집
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• pp.390-393
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• 1989

Diamond is synthesized from the gaseous mixture of carbon monoxide and hydrogen by microwave PECVD. $10{\times}10mm^2$ silicon wafers are used as the substrate,and it can be raised more than $900^{\circ}C$ by microwave absorption, radiation by plasma and bombardment of ions. The changes of the morphology and the growth rates of the deposits with the experimental conditions are examined by Scanning Electron Microscopy. The d values of all the deposited films concide with those of powder diffraction data in XRD. In Raman spectra, the peak of the deposit coincides with that of the natural diamond which has a value of 1332.5 $cm^{-1}$, and the broad peak from 1360 $cm^{-1}$to 1600 $cm^{-1}$which represents the amorphous graphite was observed in the higher concentration of carbon monoxide.

• Advanced Composite Materials
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• 제16권1호
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• pp.1-10
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• 2007

Composite materials consisting of crushed carbon fiber reinforced plastics (CFRP) pieces and acrylonitrile-butadiene-styrene (ABS) resin were prepared by an injection mold method to solve the problem of recycling of CFRP. The electrical properties, such as electrical resistivity, alternating current impedance and electromagnetic interference (EMI) shielding effect, were measured for the composites. The electrical resistivity of the composites showed a percolation type of conduction behavior and no difference between parallel and perpendicular to the injection direction was observed for CFRP content higher than the critical value. Measurement of alternating current impedance revealed that the conduction mechanism is attributed to the direct conductive paths generated by distributed carbon fibers; however, strong frequency dependence of the impedance was observed for the CFRP content near the critical one. The frequency dependence of the impedance is caused by the inter-fiber connection and can be expressed as a simple equivalent circuit. The absorption component of shielding effect (SE) was smaller than the expected value estimated from its resistivity. The decline of SE is thought to be caused by the decrease in effective thickness due to fiber orientation.

• 한국해양공학회지
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• 제10권4호
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• pp.75-83
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• 1996

Polymeric composites can be subjected to a wide variety of environmemtal conditions in practical use. One of most important conditions to be considered in the stuctural design using such materials is the miisture envirnment. Thus the moisture effect on interlaminar fracture toughness $G_IC$ and $G_IIC$ of CFRP(carbon fiber reinforced plastic) composed of carbon fibers and epoxy resin is studied in this paper. Specimens were first processed in 25, 50, $80^{\circ}C$ flesh water and $25^{\circ}C$ sea water for various periods of time. After that, the water absorption and fracture toughness tests were performed under laboratory atmosphere. As result, the specimen processed in $80^{\circ}C$ flesh water indicates the highest misture absorbing capability, the second in $50^{\circ}C$ flesh water, the third in $25^{\circ}C$ sea water, and the specimen in $25^{\circ}C$ flesh water does the lowest. The interlaminar fracture toughness $G_IC$ increases, approaches to the maximum, and decreases as the immersion time increases. In case of interlaminar $G_IIC$, the value of the specimen processed in $80^{\circ}C$ flesh water turns out to be higher than others. In addition, the scanning electron micrographs(SEM) of fracture surfaces were also examined in order to explain the mechanism of fracture.

• 한국세라믹학회지
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• 제51권3호
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• pp.139-144
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• 2014

Activated carbon fiber (ACF) was modified with MnS nanoparticles to prepare MnS-ACF, and it was employed for preparation of MnS-$ACF/TiO_2$ composites with titanium (IV) n-butoxide (TNB). The properties of MnS-$ACF/TiO_2$ composites were characterized by XRD, SEM, and EDX. EDX results showed the presence of C, O, and Ti as major elements and traces of the metal elements Mn and S. The photocatlytic activity was evaluated by degradation of methyl blue (MB) and methyl orange (MO) dye. The results demonstrated that as-prepared samples could effectively photodegrade MB and MO under UV irradiation. Subsequently, the decomposition of MB solution showed the combined effects of adsorptions by ACF and enhanced photocatalytic effect by $TiO_2$. Finally, the photocatalytic effect increased due to photo-induced-electron absorption effect by ACF and electron trap effect by comodified MnS nanoparticles.

• 한국공작기계학회논문집
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• 제17권3호
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• pp.34-39
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• 2008

In this study, CFRP(Carbon Fiber Reinforced Plastics) that has high specific strength and elastic modulus and low thermal strain was used as a material for the lightweight structural member. CFRP is a fiber material as anisotropic material. The anisotropic material is characterized by the change of its mechanical properties according to stacking orientation angle. CFRP orientation angle was oriented in [A/B]s in order to examine the effect of CFRP orientation angle on the characteristics of energy absorption. CFRP is very weak to the impact from the outside. So, when impact is applied to CFRP, its strength is rapidly lowered. The hybrid material was manufactured by combining CFRP to aluminum which is lightweight and widely used for structural members of the automobile. The hybrid member was shaped as a side member that could support the automobile engine and mount and absorb a large amount of impact energy at the front-end in case of automobile collision. The bending test device was manufactured in accordance with ASTM standard, and mounted to UTM for bending test. For comparing bending characteristics of the hybrid member with those of Aluminum and CFRP member, tests were performed for aluminum, CFRP and hybrid member, respectively.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2003년도 춘계학술논문발표회논문집
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• pp.164-170
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• 2003

In this paper, we studied on the firing characteristics and electrical fire analysis of power cord deteriorated by thermal stress. The cross section of PVC insulating cord deteriorated by indirect flame decreased through heat convection. PVC insulating cord deteriorated by direct flame was bumpy shape. The exothermic peak of normal cord was shown at ($526.7^{\circ}C$), but the peaks or on(heat treatment temperature) ($150^{\circ}C$) cord was shown at ($299.6^{\circ}C$) and [$502.2^{\circ}C$]. The exothermic peaks according to high temperature were similar to those of amorphous carbon. In the FT-IR analysis, the absorption peak of normal cord indicated double bond of oxygen and carbon in benzene ring at 1720.0$cm^{1}$. As the HTT was high, the height of characteristic peak decreased and the peak of carbonyl group was shown at about 1625.7$cm^{-1}$. The characteristic peak of single bond(O-H) was shown at about 3479.2$cm^{-1}$. In case of the internal part of wire covering deteriorated by over current, the characteristic peak were shown at about 3417.3$cm^{-1}$ and 1600.2$cm^{-1}$. The above results show that we can distinguish the differences according to the fire pattern through the internalㆍexternal analysis of wire covering deteriorated by heat.