• Journal of Environmental Health Sciences
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• v.27 no.1
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• pp.36-43
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• 2001

Chitosans were prepared from red crab chitin under various alkali treatment conditions(different alkali concentrations, reaction times and temperatures) and theirphysicochemical properties were investigated. The nitrogen content and deacetylation degree of red crab chitin were 6.15% and 22.17A%, respectively. By the IR spectra, red crab and reference chitin showed the sharp bands at 1650 $cm^{-1}$ / and 1550 $cm^{-1}$ /, which are characteristic of chitin. The nitrogen contents of prepared chitosans ranged from 6.19~7.48%. Thedeacetylation degree was increased from 63~76% and 48~78% with increasing reaction time and temperature, whereas viscosity was decreased. The nitrogen content and yield of red crab chitosan perpared from chitin with 50% NaOH, 1:25(w/v) for 3.0 hr at 120$cm^{-1}$ / were 7.26% and 85.0%, respectively. and viscosity, deacetylation degree and molecular weight, 67.0 mPa.s, 75.0% and 6.5$\times$10$^{5}$ Dalton, respectively. From the IR spectra, the amide absorption bands of red crab and reference chitosan became very weak, similarly. And at solid state $^{13}$ C-NMR spectra, C=O(carbonyl carbon) signals absent, whereas $CH_3$(methyl carbon) was residues. Chemical shift of $^{13}$ C-NMR spectra of red crab and reference chitosans were in good agreement with slight experimental deviation.

• Atmosphere
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• v.20 no.4
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• pp.519-530
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• 2010

In this paper we review current research on Atmospheric Brown Clouds (ABCs) with lightweight Unmanned Aerial Vehicles (UAVs) and miniaturized instruments. The UAV technology for in-situ measurements, including aerosol concentration, aerosol size distribution, aerosol absorption, cloud drop size distribution, solar radiation fluxes (visible and broadband), and spectral radiative fluxes, is a leading-edge technology for cost-effective atmospheric sounding, which can fill the gap between the ground measurement and satellite observation. The first experimental observation with UAVs in Korea, Cheju ABC Plume Monsoon Experiment (CAPMEX), conducted during summer 2008 revealed that the Beijing plumes exerted a strong positive influence on the net warming and fossil-fuel-dominated black-carbon plumes were approximately 100% more efficient warming agents than biomass-burning-dominated plumes. Long-term sustainable routine UAV measurements will eventually provide truly three-dimensional data of ABCs, which is necessary for the better understanding of their climate impacts and for the improvement of numerical models for air pollution, weather forecast and climate change.

• Journal of the Korean Institute of Gas
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• v.14 no.3
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• pp.35-40
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• 2010

This study is to develop of an adsorbent for the removing of human body harmful benzene, toluene, and p-xylene as VOCs. Thus, this study researched the adsorption efficiency of the commercial ACF and the reactivated ACF by KOH/ACF to molar 1: 1. As the results, the effects have shown to enlarge with the increasing of VOCs concentration for adsorptive breakthrough time and breakthrough percentage on each substance. Also, the study have investigated as a similar tendency in case of desorption efficiency for toluene and p-xylene at constant concentration as 125PPM and 0.5$\ell$/min volume flow rate. But in case of benzene, it has been investigated to have rather lower desorption efficiency re-activation ACF than commercial ACF.

• 한국정보디스플레이학회:학술대회논문집
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• 2006.08a
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• pp.525-528
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• 2006

Transparent conducting films were fabricated on polyethylene terephthalate substrate by a spray method using double-walled carbon nanotubes dispersed in organic solvent and water-based solution. We analyzed the films by absorption spectra, sheet resistance, and scanning electron microscopy. Transparent conducting films with high uniformity and high transparency were fabricated by the spray method. We found that the dispersion particularly nanodispersion of CNTs was of crucial importance to improve the film performance.

• Proceedings of the KIEE Conference
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• 1989.07a
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• pp.390-393
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• 1989

Diamond is synthesized from the gaseous mixture of carbon monoxide and hydrogen by microwave PECVD. $10{\times}10mm^2$ silicon wafers are used as the substrate,and it can be raised more than $900^{\circ}C$ by microwave absorption, radiation by plasma and bombardment of ions. The changes of the morphology and the growth rates of the deposits with the experimental conditions are examined by Scanning Electron Microscopy. The d values of all the deposited films concide with those of powder diffraction data in XRD. In Raman spectra, the peak of the deposit coincides with that of the natural diamond which has a value of 1332.5 $cm^{-1}$, and the broad peak from 1360 $cm^{-1}$to 1600 $cm^{-1}$which represents the amorphous graphite was observed in the higher concentration of carbon monoxide.

• Advanced Composite Materials
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• v.16 no.1
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• pp.1-10
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• 2007

Composite materials consisting of crushed carbon fiber reinforced plastics (CFRP) pieces and acrylonitrile-butadiene-styrene (ABS) resin were prepared by an injection mold method to solve the problem of recycling of CFRP. The electrical properties, such as electrical resistivity, alternating current impedance and electromagnetic interference (EMI) shielding effect, were measured for the composites. The electrical resistivity of the composites showed a percolation type of conduction behavior and no difference between parallel and perpendicular to the injection direction was observed for CFRP content higher than the critical value. Measurement of alternating current impedance revealed that the conduction mechanism is attributed to the direct conductive paths generated by distributed carbon fibers; however, strong frequency dependence of the impedance was observed for the CFRP content near the critical one. The frequency dependence of the impedance is caused by the inter-fiber connection and can be expressed as a simple equivalent circuit. The absorption component of shielding effect (SE) was smaller than the expected value estimated from its resistivity. The decline of SE is thought to be caused by the decrease in effective thickness due to fiber orientation.

• Journal of Ocean Engineering and Technology
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• v.10 no.4
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• pp.75-83
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• 1996

Polymeric composites can be subjected to a wide variety of environmemtal conditions in practical use. One of most important conditions to be considered in the stuctural design using such materials is the miisture envirnment. Thus the moisture effect on interlaminar fracture toughness $G_IC$ and $G_IIC$ of CFRP(carbon fiber reinforced plastic) composed of carbon fibers and epoxy resin is studied in this paper. Specimens were first processed in 25, 50, $80^{\circ}C$ flesh water and $25^{\circ}C$ sea water for various periods of time. After that, the water absorption and fracture toughness tests were performed under laboratory atmosphere. As result, the specimen processed in $80^{\circ}C$ flesh water indicates the highest misture absorbing capability, the second in $50^{\circ}C$ flesh water, the third in $25^{\circ}C$ sea water, and the specimen in $25^{\circ}C$ flesh water does the lowest. The interlaminar fracture toughness $G_IC$ increases, approaches to the maximum, and decreases as the immersion time increases. In case of interlaminar $G_IIC$, the value of the specimen processed in $80^{\circ}C$ flesh water turns out to be higher than others. In addition, the scanning electron micrographs(SEM) of fracture surfaces were also examined in order to explain the mechanism of fracture.

• Journal of the Korean Ceramic Society
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• v.51 no.3
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• pp.139-144
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• 2014

Activated carbon fiber (ACF) was modified with MnS nanoparticles to prepare MnS-ACF, and it was employed for preparation of MnS-$ACF/TiO_2$ composites with titanium (IV) n-butoxide (TNB). The properties of MnS-$ACF/TiO_2$ composites were characterized by XRD, SEM, and EDX. EDX results showed the presence of C, O, and Ti as major elements and traces of the metal elements Mn and S. The photocatlytic activity was evaluated by degradation of methyl blue (MB) and methyl orange (MO) dye. The results demonstrated that as-prepared samples could effectively photodegrade MB and MO under UV irradiation. Subsequently, the decomposition of MB solution showed the combined effects of adsorptions by ACF and enhanced photocatalytic effect by $TiO_2$. Finally, the photocatalytic effect increased due to photo-induced-electron absorption effect by ACF and electron trap effect by comodified MnS nanoparticles.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.17 no.3
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• pp.34-39
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• 2008

In this study, CFRP(Carbon Fiber Reinforced Plastics) that has high specific strength and elastic modulus and low thermal strain was used as a material for the lightweight structural member. CFRP is a fiber material as anisotropic material. The anisotropic material is characterized by the change of its mechanical properties according to stacking orientation angle. CFRP orientation angle was oriented in [A/B]s in order to examine the effect of CFRP orientation angle on the characteristics of energy absorption. CFRP is very weak to the impact from the outside. So, when impact is applied to CFRP, its strength is rapidly lowered. The hybrid material was manufactured by combining CFRP to aluminum which is lightweight and widely used for structural members of the automobile. The hybrid member was shaped as a side member that could support the automobile engine and mount and absorb a large amount of impact energy at the front-end in case of automobile collision. The bending test device was manufactured in accordance with ASTM standard, and mounted to UTM for bending test. For comparing bending characteristics of the hybrid member with those of Aluminum and CFRP member, tests were performed for aluminum, CFRP and hybrid member, respectively.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2003.04a
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• pp.164-170
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• 2003

In this paper, we studied on the firing characteristics and electrical fire analysis of power cord deteriorated by thermal stress. The cross section of PVC insulating cord deteriorated by indirect flame decreased through heat convection. PVC insulating cord deteriorated by direct flame was bumpy shape. The exothermic peak of normal cord was shown at ($526.7^{\circ}C$), but the peaks or on(heat treatment temperature) ($150^{\circ}C$) cord was shown at ($299.6^{\circ}C$) and [$502.2^{\circ}C$]. The exothermic peaks according to high temperature were similar to those of amorphous carbon. In the FT-IR analysis, the absorption peak of normal cord indicated double bond of oxygen and carbon in benzene ring at 1720.0$cm^{1}$. As the HTT was high, the height of characteristic peak decreased and the peak of carbonyl group was shown at about 1625.7$cm^{-1}$. The characteristic peak of single bond(O-H) was shown at about 3479.2$cm^{-1}$. In case of the internal part of wire covering deteriorated by over current, the characteristic peak were shown at about 3417.3$cm^{-1}$ and 1600.2$cm^{-1}$. The above results show that we can distinguish the differences according to the fire pattern through the internalㆍexternal analysis of wire covering deteriorated by heat.