• Title/Summary/Keyword: Carbide formation

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Effects of Ti on Mechanical Property and Damping Capacity in Hot-rolled Fe-17%Mn Alloy (열간압연한 Fe-17wt%Mn 합금의 기계적 성질과 진동감쇠능에 미치는 티타늄 첨가의 영향)

  • Kim, Tai-Hoon;Kim, Jung-Chul
    • Journal of Korea Foundry Society
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    • v.29 no.2
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    • pp.59-63
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    • 2009
  • Effects of Ti on damping capacity and mechanical properties are investigated in hot rolled Fe-17%Mn alloy. The existing damping alloy with Fe-Mn binary system was limited the use by high production cost, however in case of using scrap iron instead of pure iron although the content of carbon is higher it is possible to be applied wider field especially construction items because the production cost is lower. However, the excellent specific damping capacity is dropped due to the high content of carbon, we developed advanced type of damping alloy included Ti. TiC is formed with added Ti and it holds the specific damping capacity similar to existing damping alloy. The effect of Ti on damping capacity is found to be beneficial in carbon-containing alloy, which is attributed to the depletion of carbon solute due to the formation of TiC.

A Corrosion Resistance Evaluation of Welded AISI 304 Stainless Steel by Electrochemical Methods. (전기화학적 방법에 의한 AISI 304 스테인리스강 용접부의 내식성 평가)

  • 백신영;김관휴
    • Journal of Advanced Marine Engineering and Technology
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    • v.14 no.1
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    • pp.83-89
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    • 1990
  • Electrochemical methods have been proposed as non-destructive, rapid and quantitative means for determining the degree of sensitization associated with Chromium depleted zones surrounding precipitates of Cr carbide and formation of secondary phase in stainless steel. In this study, the specimen of AISI 304 stainless steel and its welded sections, which welded by TIG, MIG, $CO_2$ and ARC, were tested corrosion resistance by electrochemical methods in 0.5N HCl and 1N $H_2SO_4$ with or without 0.01N KSCN. The results were confirmed that electrochemical methods could be used as a test method of corrosion resistance evaluation for the welded AISI 304 stainless steel.

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Built-Up Edge Analysis of Orthogonal Cutting By Visco-Plastic Finite Element Method (점소성 유한요소법에 의한 이차원 절삭의 구성인선 해석)

  • 김동식
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1995.10a
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    • pp.60-63
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    • 1995
  • The behavior of the work materials in the chip-tool interface in extremely high strain rates and temperatures is more that of viscous liquids than that of normal solid metals. In these circumstances the principles of fluid mechanics can be invoked to describe the metal flow in the neighborhood of the cutting edge. In the present paper an Eulerian finite element model is presented that simulates metal flow in the vicinity of the cutting edge when machining a low carbon steel with carbide cutting tool. The work material is assumed to obey visco-plastic (Bingham solid) constitutive law and Von Mises criterion. Heat generation is included in the model, assuming adiabatic conditions within each element. the mechanical and thermal properties of the work material are accepted to vary with the temperature. The model is based on the virtual work-stream function formulation, emphasis is given on analyzing the formation of the stagnant metal zone ahead of the cutting edge. The model predicts flow field characteristics such as material velocity effective stress and strain-rate distributions as well as built-up layer configuration

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Synthesis of Ultrafine TaC Powders Using Tantalum Oxalate Solution (수산 탄탈륨 용액을 이용한 초미립 TaC 분말의 합성)

  • Kwon, Dae-Hwan;Hong, Seong-Hyeon;Kim, Byoung-Kee
    • Korean Journal of Materials Research
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    • v.13 no.12
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    • pp.806-811
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    • 2003
  • Ultrafine TaC powders were synthesised by spray drying using tantalum oxalate solution. The spray dried powders were spherical shape and less than 30 $\mu\textrm{m}$ in size. The powders calcined at 500 and X$700^{\circ}C$ showed amorphous structures and $Ta_2$$O_{5}$ phase was obtained by calcining at $700^{\circ}C$. The particle size and shape remains constant after calcination. The calcined spherical powders were composed of an agglomerate of primary particles under 50 nm in size. The complete formation of TaC could be achieved by heat treatment at $1050^{\circ}C$ for 6 hrs. The observed size of TaC powders by TEM was less than 200 nm.

The Influence of Carbide Formation after Pack-Chromizing Coating Including Hydrocarbon Gas (고탄소강의 Pack-chromizing공정에서 탄화수소계 가스 첨가에 의한 카바이드 형성 거동)

  • Kim, Sang-Gwon;Yeo, Guk-Hyeon;Lee, Jae-Hun;Sim, Jae-Gu;Kim, Yeong-Don;Gu, Hyo-Jin
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.188-189
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    • 2014
  • 코스트 저감과 연비 향상을 위한 부품 중 반복 하중과 내열성 부품의 적용이 증대하고 있다. 기존의 자동차 부품에서는 펄라이트가 석출되기 때문에 고탄소 철계 부품에 팩크로마이징 공정을 이용한 크롬탄화물을 형성하면서 탄화수소계 가스를 투입하므로서 기존의 불활성 분위기를 깨고 비평형상태로 분위기를 유지함으로 높은 경도의 $(Cr,Fe)_{23}C_6$$(Cr,Fe)_7C_3$ 복합 탄화물의 형성과 이에 의한 마찰계수 변화를 관찰하였다.

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Covalently-Bonded Solid Solution Formed by Combustion Synthesis

  • Ohyanagi, Manshi;Munir, Zuhair A.
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.250-257
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    • 2000
  • The feasibility of synthesizing SiC-AlN solid solution by field-activated combustion synthesis was demonstrated. At lower fields of 8-16.5V/cm, composites of AlN-rich and SiC-rich phases were synthesized, but at fields of 25-30 V/cm, the product was a 2H structure solid solution. Combustion synthesis of the solid solution by nitridation of aluminum with silicon carbide under a nitrogen gas pressure of 4-8 MPa was also investigated. The maximum combustion temperature and wave propagation velocity were found to be influenced by the electric field in the field-activated combustion synthesis, and by the green density and nitrogen pressure in the combustion nitridation. In both cases the formation of solid solutions is complete within seconds, considerably faster than in conventional methods which require hours.

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Sintering of Silicon Carbide by Reaction Bonding and its Characteristics (Effect of Addition of B4C and Y2O3 in Initial Sintering Precess) (반응소결에 의한 SiC의 소결과 그 특성에 관한 연구 (초기 소결과정에서의 B4C 및 Y2O3의 첨가 영향))

  • 백용혁
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.609-614
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    • 1988
  • This study was carried out to investigate the effects of B4C or Y2O3 additives on the tendency of sintering, $\beta$-SiC synthesis and mineral phase changes by reaction bonding of SiC at 145$0^{\circ}C$. At the sintering temperature of 145$0^{\circ}C$, the additives such as B4C or Y2O3 did not improved porosity and bending strength. Added more than 1.5% of Y2O3, 0.5-0.3% of B4C, the formation of $\beta$-SiC was increased. At higher temperature above 145$0^{\circ}C$, it seems that the bodies added B4C, contained 3C form of SiC were denser than that of Y2O3 added. Because the transition of 3Clongrightarrow4Hlongrightarrow6H promoted sintering.

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Synthesis of Ultrafine TaC-5%Co Composite Powders using Tantalum Oxalate Solution (수산 탄탈륨 용액을 이용한 초미립 TaC-5%Co 복합 분말의 합성)

  • 권대환;홍성현;김병기
    • Journal of Powder Materials
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    • v.10 no.4
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    • pp.255-261
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    • 2003
  • Ultrafine TaC-5%Co composite powders were synthesized by spray conversion process using tantalum oxalate solution and cobalt nitrate hexahydrate(Co($(NO_3)_2$ . 6$H_2O$). The phase of Ta-Co oxide powders had amorphous structures after calcination below 50$0^{\circ}C$ and changed $Ta_2O_5$, $TaO_2$ and $CoTa_2O_6$ phase by heating above $600^{\circ}C$. The calcined Ta-Co oxide powders were spherical agglomerates consisted of ultrafine primary particles <50 nm in size. By carbothermal reaction, the TaC phase began to form from 90$0^{\circ}C$. The complete formation of TaC could be achieved at 105$0^{\circ}C$ for 6 hours. The observed size of TaC-Co composite powders by TEM was smaller than 200 nm.

Thermal Fatigue and Wear Properties of High Speed Steel Roll for Hot Strip Mill (열간압연용 고속도공구강롤의 열피로 및 마모특성)

  • 류재화;박종일
    • Transactions of Materials Processing
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    • v.6 no.2
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    • pp.95-101
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    • 1997
  • The thermal fatigue and wear properties of high speed steel roll which was recently developed were investigated by observing microstructure, by measuring mechanical and physical properties, by conducting thermal fatigue testing, and by measuring the amount of wear in actual mill. High speed steel roll had better thermal fatigue testing, and by measuring the amount of wear in actual mill. High speed steel roll had better thermal fatigue life than high chromium iron roll, which was due to lower carbide content, higher strength, and higher thermal conductivity. The amount of wear of high speed steel roll was nearly the same as that of high chromium iron roll in the first finishing stand, which was due to the oxide formation on the roll surface. However, in the third finishing stand, the wear resistance of high speed steel roll was 2~3 times as good as that of high chromium iron roll because the former had higher hardness at high temperature.

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