• Design & Manufacturing
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• v.14 no.3
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• pp.31-36
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• 2020

In injection molding processes, the property of molten resin should be characterized accurately. Among several properties, the PvT state is the most important one, since it affects the shrinkage, warpage, molded weight, and the part density. Thus, the PvT data is crucial to the simulation of the injection molding process. This work shows how such a measurement can be performed for a semi-crystalline and amorphous polymers. The PvT measurement has been conducted using a capillary rheometer using a suitable accessory that blocks the capillary. The results have shown that the PvT data can be obtained using such a rheometer and then the PvT coefficients of the Tait equation can be reached.

• Journal of the Korean Ceramic Society
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• v.49 no.3
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• pp.231-235
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• 2012

Plasticity is the ability of clay to respond to pressure with a continuous and permanent change of shape in any direction without breaking apart, and hold that shape when released. In this work, the effect of water content and aging period on the plasticity of porcelain clay was evaluated using the capillary rheometer to measure the flow rate and the shear stress. The shear stress of porcelain clay was slightly increased with increasing the aging period, indicating that the plasticity of porcelain clay was influenced by an organic content. It was also observed that the water content in the porcelain clay had a great influence on the plasticity of porcelain clay. The shear stress with water content of 21 wt% was sharply increased with increasing shear rate, but the shear stresses with water contents of 24 and 27 wt% is gently incremented.

• Journal of the Korean Society of Visualization
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• v.21 no.1
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• pp.110-118
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• 2023

Characterizing the extensional rheological properties of non-Newtonian fluids is crucial in many industrial processes, such as inkjet printing, injection molding, and fiber engineering. However, educational institutions and research laboratories with budget constraints have limited access to an expensive commercial extensional rheometer. In this study, we developed a custom-made extensional rheometer using a CO₂ laser cutting machine and 3D printer. Furthermore, we utilized a smartphone with a low-cost microscopic lens for achieving a high spatial resolution of images. The aqueous polyethylene-oxide (PEO) solutions and a Boger fluid were prepared to characterize their extensional properties. A transition from a visco-capillary to an elasto-capillary regime was observed clearly through the developed rheometer. The extensional relaxation time and viscosity of the aqueous PEO solutions with a zero-shear viscosity of over 300 mPa·s could be quantified in the elasto-capillary regime. The extensional properties of the solutions with relatively small zero shear viscosity could be calculated using a smartphone's slow-motion feature with increasing temporal resolution of the images.

• Elastomers and Composites
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• v.22 no.3
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• pp.213-218
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• 1987

In this study, the rheological properties of a partially valcanized black filled EPDM were investigated as a function of degree of crosslinks using capillary rheometer. In order to obtain the samples having various degree of crosslinks between 0 and 6 percent, the vulcanization kinetics was also studied by Monsanto rheometer. The results showed that the die swell ana the pressure drop at the capillary entrance and exit increase nearly linearly with the increase in degree of crosslinks. However, melt fracture occurred at a lower shear rate for the samples of higher degree of crosslinks. These results were discussed in terms of the melt elasticity produced at the entrance region of capillary by the partial vulcanization. It is also interesting to note that the fluctuation of die swell during the practical extrusion or calendering process in the factories can be caused by the partial vulcanization occurred during the process.

• Elastomers and Composites
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• v.17 no.3
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• pp.191-203
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• 1982

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.495-496
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• 2006

The kneading process and formulations of feedstock obviously affect the quality of MIM products. In the present work, the rheological behaviour of the composite MIM feedstock, metal matrix (Cu) with few additions of ceramic powders $(Al_2O_3)$, was measured by a self-designed/manufactured simple capillary rheometer. Experimental results show that the distribution between powders and binder is more uniformly when blending time increased. Though high powder loading will increase the feedstock viscosity, the fluidity reveals relatively stable through the load curves of extrusion. Besides, the temperature-dependence of viscosity of the feedstock approximately follows an Arrehnius equation. Basing on Taguchi's method, the kneading optimization conditions and the rheological model of the feedstock were established, respectively.

• Journal of the Korean Society of Visualization
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• v.19 no.1
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• pp.81-87
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• 2021

Extensional flow of viscoelastic fluids is widely utilized in various industrial processes such as electrospinning, 3D printing and plastic injection molding. Extensional rheological properties, such as apparent viscosity and relaxation time, play an important role in the design and evaluation of the viscoelastic fluid-involved processes. In this work, we propose a lab-built capillary breakup extensional rheometer (CaBER) based on flow image processing to investigate the capillary breakup of polyethylene oxide (PEO) solution and its extensional rheological properties. We found that the apparent extensional viscosity and extensional relaxation time of the PEO solution are independent of the strike time. The proposed CaBER is expected to be applied to characterization of the extensional rheological properties of viscoelastic fluids at low cost with high precision.

• Polymer(Korea)
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• v.26 no.3
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• pp.316-325
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• 2002

The deformation and coalescence behaviors of immiscible LDPE/PS blends (86.5/13.5 vol%) prepared by internal mixer were studied using rheometer and scanning electron microscope. The fine droplets coagulated at initial stage of mixing, and deformed fiber at large strain. The critical capillary number was calculated according to the empirical equation of De Bruijn and it was 0.95, the local capillary number was 3.867. The polymer blends were annealed at $200^{\circ}C$ for various time to investigate morphological change of polymer blends. The maximum size of droplet after annealing at $200^{\circ}C$ was found at ${\gamma}$=1798, and there was destruction of the morphology at 15 minutes of annealing time. The viscosity of matrix was critical to determine a coalescence of droplet.

• Korea-Australia Rheology Journal
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• v.16 no.1
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• pp.47-54
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• 2004

Low Reynolds number, dilute, and surfactant-free bubble suspensions are prepared by mechanical mixing after introducing carbon dioxide bubbles into a Newtonian liquid, polyol. The apparent shear viscosity is measured with a wide-gap parallel plate rheometer by imposing a simple shear flow of capillary numbers(Ca) of the order of $10^{-2}$ ~ $10^{-1}$ and for various gas volume fractions ($\phi$). Effects of capillary numbers and gas volume fractions on the viscosity of polyol foam are investigated. At high capillary number, viscosity of the suspension increases as the gas volume fraction increases, while at low capillary number, the viscosity decreases as the gas volume fraction increases. An empirical constitutive equation that is similar to the Frankel and Acrivos equation is proposed by fitting experimental data. A numerical simulation for deformation of a single bubble suspended in a Newtonian fluid is conducted by using a newly developed two-dimensional numerical code using a finite volume method (FVM). Although the bubble is treated by a circular cylinder in the two dimensional analysis, numerical results are in good agreement with experimental results.

• Elastomers and Composites
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• v.44 no.3
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• pp.336-342
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• 2009

We measured shear viscosity of polystyrene (PS) and poly(butyl methacrylate) (PBMA) particles, with a capillary rheometer, prepared by suspension polymerization with 1.0 wt% hydrophobic silica as a stabilizer by varying the initiator concentration at $75^{\circ}C$. PS particles with weight average molecular weight of 66,500 g/mol displayed a Newtonian behaior at low shear rates at $190^{\circ}C$. With increasing molecular weight, PS particles showed shear thinning over the entire range of shear rates. For PBMA particles, steady shear measurement was carried out at $170^{\circ}C$. PBMA particles with weight average molecular weight of 156,700 g/mol showed a Newtonian behaior only at low shear rates. PBMA particles also showed shear thinning with an increase in molecular weight and its pattern similar to that of PS. When carbon black was incorporated into PS and PBMA polymers, steady shear measurement was conducted at $170^{\circ}C$. An increase in carbon black concentration in PS and PBMA composite particles exhibited a progressive increase in shear viscosity. The increase in shear viscosity, however, was less pronounced compared to an increase as a function of molecular weight. Preparing PS composites containing carbon black by internal mixing resulted in an increase in shear viscosity. Its increase, however, was found to be less than that shown in PS composite particles. We speculate that this is caused by an enhanced dispersion of carbon black particles with an internal mixer. Yield behavior was not observed in any of the samples we selected in this experiment.