• Journal of the Korean Crystal Growth and Crystal Technology
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• v.14 no.6
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• pp.267-271
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• 2004

Lithium cobalt oxide $(LiCoO_2)$ cathode powders for rechargeable battery have been successfully prepared using urea hydrolysis method. The obtained hydrolysis-derived precursors with different Li/Co molar ratio were calcined at various temperatures. Low temperature phase $(LT-LiCoO_2)$ and high temperature phase $(HT-LiCoO_2)$ were obtained after calcination at $500^{\circ}C$ for 2 hr, and phase transformation from $LT-LiCoO_2{\;}to{\;}HT-LiCoO_2$ was completely occurred over $700^{\circ}C$. The layered structure of $LiCoO_2$ was well developed with a rise in the calcination temperature. Charge-discharge test show that the lithium cobalt oxide with 1.2 molar ratio prepared at $800^{\circ}C$ has an initial discharge capacity as high as 152 mAh/g, and the relatively stable cycling characteristic with 9.2 % of capacity fading was obtained after 40th charge-discharge test.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.19 no.3
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• pp.514-522
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• 2015

In Microwave Radio Link, it is necessary to consider the radio fading to consistently assure the radio link of the high quality as the distance. If the fixed modulation is used for the microwave radio link, it is difficult to keep the high availability of link for the case of the long distance. Adaptive Modulation(AM) provide good quality on microwave link, but the application of the only-AM is not enough to provide the availability assurance due to the fluctuating characteristics of link capacity. Our previous study has proposed the improvement method of transmission in association with the distance, however the previous method needed to make up for the common application. There was no suggestion of a mathematical formula with a variable. In this paper, we propose an optimized Adaptive Transmission Techniques with calculating formula of the priority traffic transmission capacity based on AM in consideration of the fade margin for the availability assurance as the distance and the comparison of the channel bandwidth for Long-distance Radio Link.

• Journal of Communications and Networks
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• v.2 no.1
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• pp.76-84
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• 2000

Communication systems, including cell-based mobile communication systems, multiple satellite communication systems of multi-beam satellite systems, require reliable handoff methods between cell-to-cell, satellite-to-satellite of beam-to-team, respectively. Recent measurement of a CDMA cellular system indicates that the system is in handoff at about 35% to 70% of an average call period. Therefore, system reliability during handoff is one of the major system performance parameters and eventually becomes a factor in the overall system capacity. This paper presents novel and improved techniques for handoff in cellular communications, multi-beam and multi-satellite systems that require handoff during a session. this new handoff system combines the soft handoff mechanism currently implemented in the IS-95 CDMA with code and packet diversity combining techniques and an iterative decoding algorithm (Turbo Coding). the Turbo code introduced by Berrou et all. has been demonstrated its remarkable performance achieving the near Shannon channel capacity [1]. Recently. Turbo codes have been adapted as the coding scheme for the data transmission of the third generation international cellular communication standards : UTRA and CDMA 2000. Our proposed encoder and decoder schemes modified from the original Turbo code is suitable for the code and packet diversity combining techniques. this proposed system provides not only an unprecedented coding gain from the Turbo code and it iterative decoding, but also gain induced by the code and packet diversity combining technique which is similar to the hybrid Type II ARQ. We demonstrate performance improvements in AWGN channel and Rayleigh fading channel with perfect channel state information (CSI) through simulations for at low signal to noise ratio and analysis using exact upper bounding techniques for medium to high signal to noise ratio.

• Bulletin of the Korean Chemical Society
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• v.33 no.1
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• pp.65-68
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• 2012

Novel type $Li_{1.1}V_{0.9-2x}W_xMo_xO_2$ powders were prepared by a solid-state reaction of $Li_2CO_3$, $V_2O_3$, $WO_2$ and $MoO_2$ precursors in a nitrogen atmosphere containing 10 mol % hydrogen gas, and assessed as anode materials in lithium-ion batteries. The specific charge and discharge capacities of the $Li_{1.1}V_{0.9-2x}W_xMo_xO_2$ anodes were higher than those of the bare $Li_{1.1}V_{0.9}O_2$ anode. The cyclic efficiency of these anodes was approximately 73.3% at the first cycle, regardless of the presence of W and Mo doping. The composite anode, which was composed of $Li_{1.1}V_{0.75}W_{0.075}Mo_{0.075}O_2$ (20 wt %) and natural graphite (80 wt %), demonstrated reasonable specific capacity, high cyclic efficiency, and good cycling performance, even at high rates without capacity fading.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.45 no.2
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• pp.60-66
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• 2008

In this paper, a new subcarrier-based handover scheme which exploits different channel gains of subcarriers in downlink OFDMA cellular systems. In this handover scheme, mobile users can obtain diversity gain by subcarrier selection. Feedback for unselected subcarriers reduces interference. The capacity enhancement by the handover scheme is originated from the following two characteristics of OFDMA systems. One is that interference per subcarrier is proportional to the traffic load. The other is that every subcarrier has different channel gain ?? 새 the Rayleigh fading channel. Therefore, selecting subcarriers with stronger channel gains results in diversity gain. Simulation results confirm that the proposed handover scheme improves the capacity of the OFDMA systems by reducing 24 percentage of the outage probability.

• Clean Technology
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• v.28 no.2
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• pp.97-102
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• 2022

Lithium sulfur (Li-S) batteries have attracted considerable attention as a promising candidate for next-generation power sources due to their high theoretical energy density, low cost, and eco-friendliness. However, the poor electrical conductivity of sulfur and its insoluble discharging products (Li₂S₂/Li₂S), large volume changes, severe self-discharge, and dissolution of lithium polysulfide intermediates result in rapid capacity fading, low Coulombic efficiency, and safety risks, hindering Li-S battery commercial development. In this study, a three-dimensionally (3D) connected hierarchical porous carbon framework (HPCF) derived from waste sunflower seed shells was synthesized as a sulfur host for Li-S batteries via a chemical activation method. The natural 3D connected structure of the HPCF, originating from the raw material, can effectively enhance the conductivity and accessibility of the electrolyte, accelerating the Li⁺/electron transfer. Additionally, the generated micropores of the HPCF, originated from the chemical activation process, can prevent polysulfide dissolution due to the limited space, thereby improving the electrochemical performance and cycling stability. The HPCF/S cell shows a superior capacity retention of 540 mA h g^-1 after 70 cycles at 0.1 C, and an excellent cycling stability at 2 C for 700 cycles. This study provides a potential biomass-derived material for low-cost long-life Li-S batteries.

• The Journal of the Acoustical Society of Korea
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• v.26 no.7
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• pp.366-374
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• 2007

In underwater wireless communication, needs for long distance communication using the high frequency are surpassing ones of short range communication by ultrasonic wave, and demands for transmitting and receiving various data such as voice or high resolution image data are increasing as well. In this work, we studied the effects on the real underwater communication depending on the difference of digital modulation methods. Simulation shows that only the performance of GMSK among many other PSK based modulation schemes(BPSK, QPSK, MSK, GMSK) is significant. Test condition simulates the oceanographic conditions along the 207-survey line, 15Km south of Busan and SNR is maintained 35dB or below. Simulated tests are composed of both transmitting image data($3{\times}10^5$ pixel, 4 bit per pixel) and voice communication($10^{-2}$BER, channel capacity of 1Kbps). Test results show that there are gain of about 7 seconds in transmission time in image transmission case, where channel capacity for BPSK, QPSK, and MSK and for GMSK were 65 Kbps and 45 Kbps, respectively and gain of about 8Km in distances in voice communication case.

• Applied Chemistry for Engineering
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• v.35 no.3
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• pp.255-259
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• 2024

In this study, an aqueous-based redox flow battery (RFB) was constructed using tungstosilic acid (TSA), which is a kind of polyoxometalate, as the negative electrode active material and iron chloride (FeCl3) as the positive electrode active material in a sulfuric acid (H₂SO₄) supporting electrolyte. As a result of the cell's performance, it exhibited capacity fading and low energy efficiency. To address these issues, malic acid (MA), an organic additive, was introduced to the positive electrode active material and then tested for electrochemical properties and single cell performance. The malic acid in the iron chloride aqueous solution is working as a chelate agent, and two carboxyl groups are effectively coordinated with iron ions. It was found that MA reduced the electrolyte resistance of the positive electrode active material, leading to chemical stabilization and an increase in capacity and energy efficiency.

• Journal of the Korean Electrochemical Society
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• v.13 no.4
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• pp.246-250
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• 2010

In this study, nano-crystallized $Al_2O_3$ was coated on the surface of $LiFePO_4$ powders via a novel dry coating method. The influence of coated $LiFePO_4$ upon electrochemical behavior was discussed. Surface morphology characterization was achieved by transmission electron microscopy (TEM), clearly showing nano-crystallized $Al_2O_3$ on $LiFePO_4$ surfaces. Furthermore, it revealed that the $Al_2O_3$-coated $LiFePO_4$ cathode exhibited a distinct surface morphology. It was also found that the $Al_2O_3$ coating reduces capacity fading especially at high charge/discharge rates. Results from the cyclic voltammogram measurements (2.5-4.2 V) showed a significant decrease in both interfacial resistance and cathode polarization. This behavior implies that $Al_2O_3$ can prevent structural change of $LiFePO_4$ or reaction with the electrolyte on cycling. In addition, the $Al_2O_3$ coated $LiFePO_4$ compound showed highly improved area-specific impedance (ASI), an important measure of battery performance. From the correlation between these characteristics of bare and coated $LiFePO_4$, the role of $Al_2O_3$ coating played on the electrochemical performance of $LiFePO_4$ was probed.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.14 no.4
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• pp.45-50
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• 2014

In this paper, we proposed a method using the user mobile device to overcome the interference constraint without building a cooperative communication system. In addition, in order to mitigate interference, we apply the user mobile device selection method, and then exploit power allocation scheme in the user mobile device. The proposed protocol is analyzed in the Rayleigh fading environment, and the performance system is evaluated in terms of the bit error rate and the outage probability. The simulation results showed that when the proposed transmission algorithm is applied, the interference can be mitigated. Further, network overload problems can be solved in the weak channel interference. Therefore, we can increase the network capacity without additional relay.