• Title/Summary/Keyword: Calcium oxide

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Kinetic of High-Temperature Removal of $H_2S$ by Ca-based Sorbents (황화수소 제거를 위한 칼슘계 고온 탈황제의 황화반응속도)

  • 김영식;전지환;손병현;정종현;정덕영;오광중
    • Journal of Environmental Science International
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    • v.8 no.1
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    • pp.125-133
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    • 1999
  • Sorbents of calcined limestone and oyster particles having a diameter of about 0.63mm were exposed to simulated fuel gases containing 5000ppm $H_2S$ for temperatures ranging from 600 to 80$0^{\circ}C$ in a TGA (Thermalgravimetric analyzer). The reaction between CaO and $H_2S$ proceeds via an unreacted shrinking core mechanism. The sulfidation rate is likely to be controlled primarily by countercurrent diffusion through the product layer of calcium sulfide(CaS) formed. The kinetics of the sorption of $H_2S$ by CaO is sensitive to the reaction temperature and particle size, and the reaction rate of oyster was faster than the calcined limestone.

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AN EXPERIMENTAL STUDY ON MARGINAL LEAKAGE OF THE DENTAL PERMANENT CEMENTS AFFECTED BY THE TEMPORARY CEMENTS (치과용 임시합착 Cement가 영구합착 Cement의 변연누출에 미치는 영향에 관한 실험적 연구)

  • Lee, Hyeog;Lee, Ho-Yong
    • The Journal of the Korean dental association
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    • v.22 no.4 s.179
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    • pp.313-322
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    • 1984
  • This study was designed to observe the marginal leakage of three permanent cements affected by three temporary cements. The temporary cements used in this study were Zinc oxide-eugenol, Non-eugenol, and Calcium hydroxide cements and the permanent cements were Zinc phosphate, Polycarboxylate and Alumina reinforced EBA cements. To measure the dye penetration into permanently cemented zone, the experimental specimens were treated with the temporary cements for a week. An analysis of the data obtained from 120 specimens resulted in the following conclusions: 1. Regardless of the types of the permanent cements used, using Calcium hydroxide cement as temporary cement showed higher marginal leakage than other temporary cements. 2. Using Polycarboxylate cement as permanent cement showed less marginal leakage than other permanent cements. 3. The marginal leakage in zinc phosphate cement was similar to Alumina reinforced EBA cement regardless of the types of the temporary cements.

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Effect of Agitation and Additive on the Vaterite Contents of Precipitated Calcium Carbonate from Oyster Shell Waste (폐 굴껍질 이용 침강성 탄산칼슘 제조에서 교반속도와 첨가제가 Vaterite 함유량에 미치는 영향)

  • Young-Cheol Bak
    • Clean Technology
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    • v.29 no.2
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    • pp.95-101
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    • 2023
  • An experiment was conducted to produce vaterite-type precipitated calcium carbonate from waste oyster shells in order to use them as recyclable resources. Calcined oyster shells containing calcium oxide as their main component were prepared at a temperature of 800℃ for 24 h. The oyster shells were dissolved in nitric acid or hydrochloric acid solution to make 0.1 M calcium nitrate or calcium chloride aqueous solution, and a carbonation reaction was performed using a 0.1 M sodium carbonate aqueous solution under various experimental conditions, which included varying the amount of aspatic acid additive, the amount of NH4OH added, the reaction time, the reaction temperature, the stirring speed, and the type of dissolved acid. The XRD, SEM, and size distributions were analyzed and the vaterite content was calculated. Spherical precipitated calcium carbonate with a vaterite content of 95.9% was synthesized by adding 0.1 mol aspatic acid/1 mol CaO and 2 cm3 of NH4OH, and reacting for 1 h at 25℃ while stirring at 600 rpm. The average particle diameter was found to be 12.11 ㎛. Calcium carbonate contatining high vaterite is used as high value added calcium carbonate for medical, food, inke additiver, etc.

Cell characterization and Nitric Oxide Synthase in the Centeral Nervous System of the Rainbow Trout(Oncorhynchus mykiss) (무지개 송어(Oncorhynchus mykiss) 중추신경계(CNS)에 있어서 세포특징과 Nitric Oxide Synthase)

  • Jang, Seon-Il;Choi, Min-Soon;Kim, Young-Gill
    • Journal of fish pathology
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    • v.7 no.1
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    • pp.63-70
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    • 1994
  • Nitric oxide(NO) has recently been shown to play an important role on central nervous system(CNS) function in mammals. It is synthesized from L-arginine by the enzyme NO synthase. In this study, we examined this enzyme's existence in CNS of rainbow trout(Oncorhynchus mykiss) and described the forms of microglia. astrocytes. and oligodendrocytes. Two forms of microglia are distributed in CNS. one resembling their mammalian counterpart(large microglia : LM). and the other comprising small microglia(SM) with very little cytoplasm. CNS contained astrocytes of a distinct type which form reticular network, but lack connections to capillaries. The oligodendrocyte was generally a much denser cell than the astrocyte. We have detected NOS($1.04{\pm}0.12\;pg/min/mg$) from rainbow trout CNS. It could be inhibited reversibly or irreversibly by $N^{G}MMA$ and EGTA. These result suggest that the formation of NO from L-arginine in CNS is calcium-dependent and a pathway of early evolutionary orgin.

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Suggestion of Physicochemical Characteristics and Safety Management in the Waste Containing Nanomaterials from Engineered Nano-materials Manufacturing Plants and Waste Treatment Facilities (산업용제조시설과 폐기물처리시설에서 발생된 나노폐기물의 물리화학적 특성 및 안전관리방안 제시)

  • Kim, Woo-Il;Yeon, Jin-Mo;Cho, Na-Hyeon;Kim, Yong-Jun;Um, Nam-Il;Kim, Ki-Heon;Lee, Young-Kee
    • Journal of Korea Society of Waste Management
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    • v.35 no.7
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    • pp.670-682
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    • 2018
  • Engineered nanomaterials (ENMs) can be released to humans and the environment through the generation of waste containing engineered nanomaterials (WCNMs) and the use and disposal of nano-products. Nanoparticles can also be introduced intentionally or unintentionally into waste streams. This study examined WCNMs in domestic industries, and target nanomaterials, such as silicon dioxide, titanium oxide, zinc oxide, nano silver, and carbon nanotubes (CNTs), were selected. We tested 48 samples, such as dust, sludge, ash, and by-products from manufacturing facilities and waste treatment facilities. We analyzed leaching and content concentrations for heavy metals and hazardous constituents of the waste. Chemical compositions were also measured by XRD and XRF, and the unique properties of nano-waste were identified by using a particle size distribution analyzer and TEM. The dust and sludge generated from manufacturing facilities and the use of nanomaterials showed higher concentrations of metals such as lead, arsenic, chromium, barium, and zinc. Oiled cloths from facilities using nano silver revealed high concentrations of copper, and the leaching concentrations of copper and lead in fly ash were higher than those in bottom ash. In XRF measurements at the facilities, we detected compounds such as silicon dioxide, sulfur trioxide, calcium oxide, titanium dioxide, and zinc oxide. We found several chemicals such as calcium oxide and silicon dioxide in the bottom ash of waste incinerators.

Susceptibility of Foodborne Pathogens Isolated from Fresh-Cut Products and Organic Vegetable to Organic Acids and Sanitizers

  • Park, Kyung Min;Baek, Minwoo;Kim, Hyun Jung;Kim, Byeong Sam;Koo, Minseon
    • Journal of Food Hygiene and Safety
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    • v.28 no.3
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    • pp.227-233
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    • 2013
  • In this study, we evaluated the ability of various disinfectants to suppress the growth of microorganisms in fresh-cut products and organic vegetable. The growth of more than 50% of B. cereus isolates were suppressed by 50% ethanol, 0.1% hydrogen peroxide, 0.4% sodium hypochlorite or 1% calcium oxide. E. coli generally showed high susceptibility to concentration of 10% ethanol, 0.4% sodium hypochlorite and 1% calcium oxide. Eighty percent or more of S. aureus isolates exhibited resistance to ethanol, hydrogen peroxide and sodium hypochlorite, but the isolates were susceptible to concentrations of 1% calcium oxide. All isolates evaluated in this study were sensitive to benzalkonium chloride (BAC) and growth in the presence of $2.0{\mu}g/mL$ of BAC was completely inhibited. These pathogens showed widely different susceptibilities to different organic acids. Greater than 0.5% acetic acid and 2% and higher concentrations of malic acid and tartaric acid inhibited the growth of 60% of the isolates of B. cereus. Two percent acetic acid and tartaric acid inhibited 50% of the S. aureus isolates. Seventy percent of the E. coli isolates were resistant to malic acid and susceptible to 1% acetic acid and 10% tartaric acid. The antibacterial effects of the various sanitizers evaluated in this study were not only dependent on the type of disinfectant but also on the pathogen. Thus, it is important to select a sanitizer that is safe and effective at removing specific types of microorganisms.

Processing and Properties of Calcium Cobaltite Layer Structure Oxide Thermoelectrics (칼슘 코발트 층상 산화물계 열전반도체의 제조와 물성)

  • Kwak, Dong-Ha;Park, Jong-Won;Yoon, Sun-Ho;Choi, Jung-Chul;Choi, Seung-Chul
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.1
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    • pp.1-6
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    • 2008
  • Thermoelectric properties of calcium cobalt layer structure oxide system, $Ca_3Co_2O_6$ and $Ca_3Co_4O_9$ were investigated at the temperature range of 300 to 1000K for the application of thermoelectric generation. In the composition, the Ca site was partially substituted with Bi, Sr, La, K and the Co site was partially substituted with Mn, Fe, Ni, Cu, Zn. The thermoelectric properties of Bi substituted $Ca_3Co_4O_9$. $Ca_{2.7}Bi_{0.3}Co_4O_9$ for electrical conductivity, Seebeck coefficient and power factor were $85.4({\Omega}$cm)^{-l}, $176.2{\mu}V/K$ and $265.2{\mu}W/K^m$, respectively. The unit thermoelectric couple was fabricated with the p-type of $Ca_{2.7}Bi_{0.3}Co_4O_9$ and n-type ($Zn_{0.98}Al_{0.02}$)O thermoelectrics whose figure-of-merit(Z) were $0.87{\times}10^{-4}/K$ and $0.41{\times}10^4/K$, respectively. The generated thermoelectric power was about 30mV at the temperature difference of 120K in the unit thermoelectric couple.

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Kimchi cabbage (Brassica rapa L.) by-products treated with calcium oxide and alkaline hydrogen peroxide as feed ingredient for Holstein steers

  • Son, A-Rang;Kim, Seon-Ho;Valencia, Raniel A.;Jeong, Chang-Dae;Islam, Mahfuzul;Yang, Chul-Ju;Lee, Sang-Suk
    • Journal of Animal Science and Technology
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    • v.63 no.4
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    • pp.841-853
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    • 2021
  • This study aimed to investigate the effects of Kimchi cabbage by-products either treated or untreated with calcium oxide (CaO) and alkaline hydrogen peroxide (AHP) as substitutional ingredient of total mixed ration (TMR) on in vitro fermentation, in situ disappearance and growth performance of Holstein steers. Cannulated Holstein (600 ± 47 kg) was used for both the in vitro and in situ experiments. The treatments used were TMR only (CON), TMR + 30% Kimchi cabbage by-products fresh matter (FM) basis (TC), TMR + 30% Kimchi cabbage by-products FM basis + 5% CaO FM basis (TCC), and TMR + 30% Kimchi cabbage by-products FM basis + 5% CaO FM basis + 3.22% AHP FM basis (TCCA). For in vivo experiment, thirty-four Holstein steers (273 ± 45 kg) were subjected to a 150-day feeding trial, divided into two groups: CON and TC. In the in vitro experiment, pH of TCCA was greatest (p < 0.05) among other treatments at all incubation times. Ammonia nitrogen and volatile fatty acid concentrations were not significantly different for each treatment. However, butyrate was greater (p < 0.05) in TCC and CON than in both TC and TCCA. During in situ experiment, the dry matter (DM) disappearance was greatest (p < 0.05) in TCCA among other treatments. Also, disappearance of neutral detergent fiber (NDF) and acid detergent fiber (ADF) were observed greatest (p > 0.05) in TCCA treatment. In the in vivo experiment, average daily gain (ADG) did not differ between CON and TC. In blood profile analysis, alanine aminotransferase, aspartate aminotransferase, glucose, total cholesterol, high-density lipoprotein cholesterol, low-density lipoprotein cholesterol, and total protein concentration were not significantly different between treatments. But, creatinine concentration was greater (p < 0.05) in TC than in CON. Overall results suggest that Kimchi cabbage by-products either treated or untreated with CaO and AHP can be used as substitutional ingredient in TMR for Holstein steers.

Investigation on the Self-Healing Performance of Cement Mortar Incorporating Inorganic Expansive Additives (무기질계 팽창재가 포함된 시멘트 모르타르의 자기치유성능에 관한 연구)

  • Shin, Jin-Wook;Her, Sung-Wun;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.404-412
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    • 2020
  • Herein, the properties and self-healing performance of cement mortar incorporating calcium sulfoaluminate(CSA), crystalline admixture(CA), and magnesium oxide(MgO) were investigated. Mortar strength test and water permeability experiments were conducted to analyze self-healing performance of the mortar. Also, variation in crack width were measured via digital optical microscope observation. The hydration products formed in the crack via self-healing were analyzed using x-ray diffraction(XRD), thermogravimetry(TG), and digital optical microscope. The analysis revealed that compressive strength and tensile strength increased as CA substitutional ratio increased. However, in the case of MgO replacement, the compressive strength and tensile strength decreased as the CA substitution ratio increased. The products in the recovered cracks are found to be mostly Ca(OH)2, MgCO3, and CaCO3. CaCO3 was shown to be the main healing product and had a higher portion than Ca(OH)2 and MgCO3 in the recovery products. Moreover, the optimal mix derived via water permeability and crack width results was 8% CSA + 1% CA + 2.5% MgO.

Efficacy of antibacterial treatments of fresh ginseng (Panax ginseng C.A. Meyer) (항균제 처리에 따른 수삼의 미생물 저감화 효과)

  • Choi, Jun-Bong;Cho, Won-Il
    • Korean Journal of Food Science and Technology
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    • v.54 no.1
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    • pp.75-79
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    • 2022
  • Fresh, washed ginseng can be contaminated with microorganism loads as high as 6.5 log CFU/g for total bacteria and 4.3 log CFU/g for mold. The goal of this study was to test eight antibacterial agents on ginseng. Immersing fresh ginseng washed in 1% (w/w) sodium citrate, sodium diacetate, sodium acetate, citric acid, and sodium lactate solution for 1 h resulted in a bactericidal effect of 31.0-97.5% for total bacteria. Among the organic acids, sodium citrate had the best antibacterial effect, with total bacteria reduced from 6.5 log to 4.9 log CFU/g. A 1% (w/w) vitamin B1 lauryl sulfate solution with surfactant function by hydrophilic and hydrophobic sites can reduce 2.7 log CFU/g (99.8% inactivation) on total bacteria. In the 1% (w/w) calcium oxide solution, total bacteria were reduced by 3 log, showing an excellent inactivation effect of 99.9%. Calcium oxide is a highly useful material for inactivation of microorganisms in fresh ginseng.