• Title/Summary/Keyword: Calcium ion ($Ca^{2+}$)

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Effects of Long-Term Fertilization for Cassava Production on Soil Nutrient Availability as Measured by Ion Exchange Membrane Probe and by Corn and Canola Nutrient Uptake

  • Hung T. Nguyen;Anh T. Nguyen;Lee, B.W.;J. Schoenau
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.47 no.2
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    • pp.108-115
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    • 2002
  • The effects of long-term fertilization on soil properties and nutrient availability are not well documented for cassava cultivation in Vietnam. In 1990, a field research plots were established with 12 treatments to test the effect of different rates of nitrogen (N), phosphorus (P) and potassium (K) on soil properties in Acrisols at Thai Nguyen University in Northern Vietnam. In 1999, composite soil samples (0 to 20cm depth) were collected from eight selected plots for measurements of nutrient supply rates by ion exchange membrane probes and for growing corn and canola in a growth chamber with and without added lime. Generally, long-term nitrogen (N) fertilization increased available N supply rates but decreased available potassium (K) and magnesium (Mg). Long-term phosphorus(P) applications increased canola N, calcium (Ca) and Mg uptake. Canola P uptake increased with increased P rates only when lime was added. Long-term K applications increased canola N, K, Ca, Mg uptake but only significantly increased corn N uptake. Liming significantly increased uptake of N, P, K, Ca, Mg and S for both corn and canola. However, N $H_{4-}$N, K and Mg soil supply rates were reduced when lime was added, due to competition between Ca from the added lime and other nutrients.

Substitutions of coloring ions and their effects on wagnerite pigments for cetamic glazes (도자기 유약용 wagnerite의 합성 및 발색원소의 영향)

  • 정용선;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.160-168
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    • 1998
  • In order to investigate the color variation and the solubility limit in wagnerites by metal ion substitution, wagnerite ($A_2XO_4Z$) was synthesized and then, substituted by coloring metal ions, especially $CO^{2+},Ni^{2+}$ and $Cu^{2+}$ ions. When calcium was replaced with Mg, Co, Ni and Cu divalent ions, solid solutions were formed with a limited solubility. Single phase wagnerites were synthesized by the substitution of Ca with Mg and Co, and their colors were white and purple, respectively. Substitutions with $Li^+$ were succeeded in the specific composition and the substitution of vanadium for $X^{5+}$ were attempted, resulting in the wagnerites of dark purple, dark gold and light yellow colors. The substitution of chlorine was, also, attmepted for the fluorine site.

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Studies on the Production of Enzymes by Thermophilic Actinomycetes (PART II) Some Properties of $\alpha$-Amylase from Thermophilic Actinomycetes (고온성 방선균에 의한 순소생산에 관한 연구 (제2보) $\alpha$-Amylase의 효소학적 성질)

  • Yang, Han-Chul;Park, Yong-Jin;Cho, Hong-Yeon
    • Microbiology and Biotechnology Letters
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    • v.4 no.3
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    • pp.91-97
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    • 1976
  • During the course of studies on the production and utilization of thermostable ${\alpha}$-amylase from a thormophilic actinomycete species isolated from soil, partial characterization of the ${\alpha}$-amylase has been (arried out. The optimum pH for the dextrinogenic activity of the enzyme was found to be 6.5 and the maximum reaction rate was achieved at a temperature range of 55$^{\circ}$ to 65$^{\circ}C$. Calcium ion was recognized to have a slight effect in activating the enzyme, while heavy metal salts especially ferrous and cupric ions showed a remarkable inhibition effect. The enzyme was best protected iron thermal denaturation at pH 8.0 with tris-HCI buffer;inactivation was rapid at higher or lower pH values. Furthermore, its thermal stability was greatly increased by calcium ion, particulary at the final concentration of 1${\times}$10$\^$-2/ mole in the reaction mixture. The Km value for the ${\alpha}$-amylase was calculated to be 2.17${\times}$10$\^$-4/g per $m\ell$ and the energy of activation for the dextrinogenic reaction to be 12,000${\pm}$580 ㎈ per mole.

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Formation of Hydroxyapatite in Portland Cement Paste

  • Chung, Chul-Woo;Lee, Jae-Yong;Kim, Ji-Hyun
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.1
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    • pp.68-75
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    • 2014
  • In order to increase the integrity of the wellbore which is used to prevent the leakage of supercritical $CO_2$, it is necessary to develop a concrete that is strongly resistant to carbonation. In an environment where the concentration of $CO_2$ is exceptionally high, $Ca^{2+}$ ion concentration in pore solution of Portland cement concrete will drop significantly due to the rapid consumption of calcium hydroxide, which decreases the stability of the calcium silicate hydrate. In this research, calcium phosphates were used to modify Portland cement system in order to produce hydroxyapatite, a hydration product that is strongly resistant to carbonation under such an environment. According to the experimental results, calcium phosphates reacted with Portland cement to form hydroxyapatite. The formation of hydroxyapatite was verified using X-ray diffraction analyses with selective extraction techniques. When using dicalcium phosphate dihydrate and tricalcium phosphate, the 28-day compressive strength was lower than that of plain cement paste. However, the specimen with monocalcium phosphate monohydrate showed equivalent strength to that of plain cement paste.

Effect of trans-10, cis-12 Conjugated Linoleic Acid on Calcium-Dependent Reactive Oxygen Species and Nitric Oxide Production and Nuclear Factor-${\kappa}B$ Activation in Lipopolysaccharide-Stimulated RAW 264.7 Cells (LPS 자극 RAW 264.7 세포에 있어서 칼슘의존성 ROS와 NO 생산 및 NF-${\kappa}B$ 활성에 대한 CLA의 억제효과)

  • Choi, Tae-Won;Kang, Byeong-Teck;Kang, Ji-Houn;Yang, Mhan-Pyo
    • Journal of Veterinary Clinics
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    • v.32 no.2
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    • pp.135-140
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    • 2015
  • Trans-10, cis-12-conjugated linoleic acid (t10c12-CLA) has been shown to participate in the regulation of anti-inflammatory effects. The objectives of this study were to examine the effects of t10c12-CLA on reactive oxygen species (ROS) and nitric oxide (NO) production and nuclear factor-kappaB (NF-${\kappa}B$) activation in lipopolysaccharide (LPS)-stimulated RAW 264.7 cells and to determine whether these effects were associated with change of intracellular calcium ion ($Ca^{2+}$). ROS production was increased in LPS-stimulated RAW 264.7 cells, and this effect was suppressed by 1,2-bis-(o-aminophenoxy) ethane-N,N,N',N'-tetraacetic acid-acetoxymethyl ester (BAPTA/AM), a calcium chelator. t10c12-CLA suppressed ROS production in LPS-stimulated RAW 264.7 cells, which was further more decreased by treatment with BAPTA/AM. These indicated that t10c12-CLA decreases $Ca^{2+}$-dependent ROS production in LPS-stimulated RAW 264.7 cells. Similarly, NF-${\kappa}B$ p65 DNA binding activity and NO production were decreased by treatment with either t10c12-CLA, BAPTA/AM, or t10c12-CLA and BAPTA/AM combination. However, there were no differences between t10c12-CLA and BAPTA/AM treatment in NO production of LPS-stimulated RAW 264.7 cells. These data indicate that t10c12-CLA inhibits the increases in ROS and NO production and the NF-${\kappa}B$ activation in LPS-stimulated condition. These results suggested that CLA exerts potent anti-inflammatory effects by suppression of LPS-induced ROS and NO production, and NF-${\kappa}B$ activationn via $Ca^{2+}$-dependent pathway.

Classification of Forest Vegetation Type and Environmental Properties in Limestone Area of Korea (석회암지대 산림식생의 유형과 환경특성)

  • Yun, Chung-Weon;Moon, Hyun-Shik
    • Journal of agriculture & life science
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    • v.43 no.2
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    • pp.1-8
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    • 2009
  • The limestone area covers the narrow range of the Korean Peninsula, and it consists of a peculiar ecosystem and topography. Therefore, this study on limestone area was carried out classification of vegetation type, physicochemical properties of forest soils and correlation between environment factors and vegetation types in order to furnish fundamental data for the forest management of limestone area. Forest vegetation was classified into two community groups such as Quercus variabilis community group and Quercus mongolica community group, and it was classified into eight vegetation units. Soil texture of survey sites showed largely silt loam and soil pH indicated the value of mean 7.55 in the A layer of soil profile. Content of exchangeable cation such as calcium ion ($Ca^{2+}$) and magnesium ion ($Mg^{2+}$) showed $26.04cmol_{c}/kg$ and $2.93cmol_{c}/kg$, respectively, which was about ten times higher than average of other regions of Korea. According to corelation between environmental factors and vegetation units, Q. variabilis community group was positively correlated to soil pH, slope degree and the rate of bare rock, and content of calcium ion ($Ca^{2+}$), and then Q. mongolica community group was positively correlated to altitude, respectively.

Effect of Carboxylic Acid on the Hydration of Plaster of Paris under Alkalinity (알카리성 분위기에서 소석고의 수화에 미치는 카르복실산의 영향)

  • 이승헌
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1107-1114
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    • 1994
  • Although various theories have been presented on the mechanism of setting retardation of plaster in addition to organic admixtures. The purpose of this paper is that Hydration studies of plaster of paris in the presence of carboxylic acids under alkalinity are examined in the coordination chemistry. Setting of plaster of paris is retarded by the addition of carboxylic acids except oxalic acid. And setting of plaster of paris contained 5 wt% of Ca(OH)2 is also retarded by the addition of above-mentioned carboxylic acids. The degree of retarding effect under alkalinity is found to be a function of the number of the functional group and the length of carbon chain of carboxyl acids. These reasons are attributed to the soluble complex formation, that is calcium complex formation between calcium ion and carboxylic acids. The author's proposal was confirmed by the results of electrical conductivity measurement. The formation of calcium complex was surpported by IR spectra.

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The influence of Calcium, Magnesium, Sodium and Potassium Ion on the Adenosintriphosphatase activity of heart and skeletal microsomal fraction of rabbits. (가토심장(家兎心臟) 및 골격근(骨格筋)에서 분리(分離)한 Microsome 분획내(分劃內) ATPase 활성도(活性度)에 대(對)한 $Mg^{++}$, $Ca^{++}$, $Na^+$$K^+$의 영향(影響))

  • Choi, Sin-Jyoung;Hong, Ki-Whan;Kim, Gui-Tae
    • The Korean Journal of Pharmacology
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    • v.2 no.1 s.2
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    • pp.31-40
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    • 1966
  • The microsomal fraction is isolated from rabbit heart and skeletal muscle. The fraction is found to contain the $Na^+$-and $K^+$-activated ATPase. The maximal ATPase activity is obtained in $Na^+$ and $K^+$ concentration of 100 mM. Calcium itself stimulates the $Na^+$-and $K^+$-activated portion of ATPase in the presence of $Mg^{++}$. However, calcium does not stimulate ATPase in the absence of $Mg^{++}$.

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Influence of Salt Concentrations on the Stabilities and Properties of Sodium Caseinate Stabilized Oil-in-Water Emulsions

  • Surh, Jeong-Hee;McClements, David Julian
    • Food Science and Biotechnology
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    • v.17 no.1
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    • pp.8-14
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    • 2008
  • The influence of salt concentration on the stability of sodium caseinate (CAS)-stabilized emulsions (20 wt% corn oil, 3.2 wt% CAS, 5 mM imidazole/acetate buffer, pH 7) was examined. In the absence of salt, laser diffraction measurements and optical microscopy measurements indicated there were some large oil droplets ($d>10\;{\mu}m$) in the emulsions stabilized by 0.8 to 3.2 wt% of CAS. The droplet aggregation (mostly droplet coalescence) observed in the emulsions containing ${\leq}2.8\;wt%$ CAS tended to decrease as the CAS concentration increased, however, after which concentration (at 3.2 wt% CAS) depletion flocculation occurred. The addition of $CaCl_2$ (5-20 mM) into the emulsions stabilized by 3.2 wt% CAS prevented the depletion flocculation although there was a small fraction of relatively large individual droplets in the emulsions, which was attributed to electrostatic screening effect and bridging effect of calcium ion. This study has shown that calcium ion that has been reputed to promote droplet aggregation could improve emulsion stability against droplet aggregation in CAS-stabilized emulsions.

Divalent Cation-dependent Inactivation of N-type Calcium Channel in Rat Sympathetic Neurons (쥐 교감신경 뉴론 N형 칼슘통로의 2가 양이온의존성 비활성화)

  • Goo Yong-Sook
    • Progress in Medical Physics
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    • v.17 no.2
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    • pp.96-104
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    • 2006
  • Experiments from several groups Including ours have demonstrated that $Ca^{2+}$ can enhance the inactivation of N-type calcium channels. However, it is not clear if this effect can be ascribed to a 'classic' $Ca^{2+}$-dependent inactivation (CDI) mechanism. One method that has been used to demonstrate CDI of L-type calcium channels is to alter the intracellular and extracellular concentration of $Ca^{2+}$. In this paper we replaced the external divalent cation to monovalent ion ($MA^+$) to test CDI. In the previous paper, we could separate fast (${\tau}{\sim}150ms$) and slow (${\tau}{\sim}2,500ms$) components of inactivation in both $Ba^{2+}$ and $Ca^{2+}$ using 5-sec voltage step. Lowering the external divalent cation concentration to zero abolished fast inactivation with relatively little effect on slow inactivation. Slow inactivation ${\tau}$ correspond very well with provided the $MA^+$ data is shifted 10 mV hyperpolarized and slow inactivation ${\tau}$ decreases with depolarization voltage in both $MA^+\;and\;Ba^{2+}$, which consistent with a classical voltage dependent inactivation (VDI) mechanism. These results combined with those of our previous paper lead us to hypothesize that external divalent cations are required to produce fast N-channel inactivation and this divalent cation-dependent inactivation is a different mechanism from classic CDI or VDI.

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