• 제목/요약/키워드: Calcium agent

검색결과 322건 처리시간 0.026초

EVA 에멀젼의 내수성 및 기계적 특성에 미치는 금속 이온 가교제의 효과 (Effect of Metal Ionic Crosslinking Agents on the Water Resistance and Mechancial Properties of EVA Emulsion)

  • 이은경;최세영
    • 접착 및 계면
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    • 제9권2호
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    • pp.24-31
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    • 2008
  • 본 연구에서는 EVA 에멀젼에 내수성 및 기계적 특성을 향상시키기 위하여 금속 이온 가교제인 calcium hydroxide 및 magnesium carbonate를 사용하여 이온성 가교결합을 도입하였다. EVA 에멀젼 필름의 가교밀도, 열적특성, 표면자유에너지 그리고 인장강도, 파단신율 및 인열강도 특성을 고찰하였다. 금속 이온 가교제 양이 증가함에 따라 EVA 에멀젼의 가교밀도는 증가하였고, 이에 내수성과 $T_g$ 값도 증가하였다. 그러나 EVA 에멀젼 필름의 표면에너지 및 기계적 특성들은 다소 다른 거동을 보였다. Calcium hydroxide 0.4% 그리고 magnesium carbonate 0.5%를 첨가한 경우가 EVA 에멀젼에 강한 이온성 가교결합이 형성되어 가장 높은 표면 자유에너지 값과 인장강도 및 인열강도를 보였다. 그러므로 본 연구에서 calcium hydroxide 및 magnesium carbonate와 같은 금속 이온 가교제가 EVA 에멀젼의 내수성과 기계적 물성을 향상시킴을 확인하였다.

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Experimental study on chemical activation of recycled powder as a cementitious material in mine paste backfilling

  • Liu, Yin;Lu, Chang;Zhang, Haoqiang;Li, Jinping
    • Environmental Engineering Research
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    • 제21권4호
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    • pp.341-349
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    • 2016
  • To improve the utilization rate of construction waste as mine backfilling materials, this paper investigated the feasibility of using recycled powder as mine paste backfilling cementitious material, and studied the pozzolanic activity of recycled construction waste powder. In this study, alkali-calcium-sulfur served as the activation principle and an orthogonal test plan was performed to analyze the impact of the early strength agent, quick lime, and gypsum on the pozzolanic activity of the recycled powder. Our results indicated that in descending order, early strength agent > quick lime > gypsum affected the strength of the backfilling paste with recycled powder as a cementitious material during early phases. The strength during late phases was affected by, in descending order, quick lime > gypsum > early strength agent. Using setting time and early compressive strength as an analysis index as well as an extreme difference analysis, it was found that the optimal ratio of recycled powder cementitious material for mine paste backfilling was recycled powder:quick lime:gypsum:early strength agent at 78%:10%:8%:4%. X-ray diffraction analysis and scanning electron microscope were used to show that the hydration products of recycled powder cementitious material at the initial stages were mainly CH and ettringite. As hydration time increased, more and more recycled powder was activated. It mainly became calcium silicate hydrate, calcium aluminate hydrate, etc. In summary, recycled powder exhibited potential pozzolanic activities. When activated, it could replace cementitious materials to be used in mine backfill.

아세트산 처리 갑오징어갑 칼슘제의 기능적 특성 (Functional Properties of Calcium Powder of Cuttle Bone Treated with Acetic Acid)

  • 김진수;조문래;허민수
    • 한국수산과학회지
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    • 제36권2호
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    • pp.74-79
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    • 2003
  • The functional properties such as a firming maintenance capacity for fermented vegetables, protein coagulation capacity antibacterial activity, calcium and peroxide absorption capacity of calcium powder of cuttle bone treated with acetic acid (ATC) were examined. In the Korean pickled cucumbers (20 days), the calcium content of ethanol insoluble solids was 5,264.9 mg/100 g and this value was higher than that of control (2,036.4 mg/100 g). Protein coagulation capacity of ATC was $0.9\%$ and its calcium absorption capacity was $49.3\%.$ The peroxide absorption capacity of ATC was shown $0-1.1\%$ range. Antibacterial activity was detected above $0.2\%.$ The ATC was effective in a firming maintenance of fermented vegetables (cucumber), coagulation capacities for soybean milk and antibacterial activity. The ATC was not effective in clarifying wastewater. Peroxide absorption capacity toward linoleic acid could not be checked by ATC, but its calcium absorption ratio was high compared to that of commercial calcium powder.

고형화 슬러지의 공학적 특성 및 현장적용성 분석 (Engineering characteristics and field demonstrations of solidified sludges)

  • 고용국
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2003년도 봄 학술발표회 논문집
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    • pp.593-596
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    • 2003
  • The special amendment agent used in this study is mainly composed of inorganic metal salts such as sodium chloride, magnesium chloride, potassium chloride, calcium chloride, thus is friendly to the environment, and has a function of soil-cement-agent solidification. In this study, a series of laboratory and field experiments including unconfined compressive strength, permeability, pH test, constituent analysis, leaching test were carried out to analyse engineering and environmental characteristics of solidified sludge. The results of this research showed that the solidified sludge could be efficiently used in covering, filling, and planting materials.

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칼슘/비타민D 섭취와 택견운동이 노인 허약에 미치는 효과 (Effects of Calcium/Vitamin D Intake and Taekkyeon Exercise on the Elderly's Frailty)

  • 이광옥
    • Journal of Korean Biological Nursing Science
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    • 제18권3호
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    • pp.185-191
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    • 2016
  • Purpose: The purpose of this study is to understand the effect of taking calcium/vitamin D supplements and performing Taekkyeon exercises on the frailty of the elderly targeting a vulnerable senior social group. Methods: A total of 124 people aged 65 and older consisting of 60 persons in the experimental group, and 64 persons in the control group participated in this study, and this study is a non-equivalent control group pre/post-test design quasi-experimental study. This study analyzed the homogeneity between the experimental group and the control group using a chi-square test and t-test while analyzing the difference in the degree of frailty and bone density with the practice of Taekkyeon and a calcium agent using t-test and GEE. Results: The study results showed that the frailty and bone density of the experimental group significantly improved. Conclusion: Through this study, it was confirmed that calcium/vitamin D intake and Taekkyeon exercises were an effective intervention which strengthened the elderly's physical condition.

아스팔트 혼합물의 내수분손상 향상에 대한 박리방지제의 효과 (Effect of Antistripping Agent on the Enhancement of Resistance to Moisture Damage of Asphalt Mixture)

  • 이은경;최세영
    • 접착 및 계면
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    • 제10권4호
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    • pp.182-190
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    • 2009
  • 본 연구에서는 아스팔트 혼합물의 수분 손상을 감소시키기 위한 박리방지제 효과에 대하여 고찰하였다. 아스팔트 박리방지제는 tetraethylene pentamine (TEPA), Triethylenetetramine (TETA), 그리고 bis(hexamethylene)-triamine (BHMT) 각각과 포름알데히드의 축합반응에 의하여 합성하였다. 또한 스테아르산 또는 팔미트산과 금속 수산화물과의 반응을 통하여 금속계 박리방지제를 합성하였다. 박리방지제가 첨가된 아스팔트 혼합물의 기계적 특성은 마샬안정도, 수침잔류안정도 및 피막률에 대하여 분석하였다. 본 연구에서 합성된 박리방지제는 아스팔트 혼합물의 수분손상을 감소시켰다. 특히 BHMT계 및 C/S (Calcium stearate hydroxide) 박리방지제가 가장 높은 수침잔류 안정도 및 피막률을 보였다. 왜냐하면 각각 아민농도의 증가, 그리고 금속계면활성제의 효과적 역할로 인하여 BHMT 박리방지제와 C/S 박리방지제는 아스팔트와 골재 사이의 접착력을 향상시켜 주었기 때문이다.

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접착성(接着性) 레진이 가견치수조직(家犬齒髓組織)에 미치는 독성(毒性)에 관(關)한 실험적(實驗的) 연구(硏究) (TOXIC EFFECT OF ADHESIVE RESINS ON THE DOG'S PULP TISSUE)

  • 손호현
    • Restorative Dentistry and Endodontics
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    • 제10권1호
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    • pp.31-42
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    • 1984
  • The toxic effect of adhesive resins on the dog's pulp tissue was studied with 70 teeth from 5 dogs. The experimental materials were Clearfil, a mixture of Clearfil with calcium hydroxide powder, Panavia-EX, and a mixture of Panavia-EX with calcium hydroxide powder. As a control group, calcium hydroxide powder was used. Each material was placed on the pulpotomized tissue surface. After 3 days, 1, 2,4, and 6 weeks, the teeth and apical tissue were processed routinly and stained with hematoxylin and eosin. Pathological tissue changes due to the toxicity of adhesive resins were observed by light microscope, and the pH of Panavia-EX and the Bonding agent of Clearfil were measured. Following were the results; 1. In the group of calcium hydroxide powder, slight inflammatory change was observed in the pulpotomized surface and adjacent pulp tissue on 3 day. 1 week case showed incomplete dentin bridge. The remaining pulp tissue was normalized according to the days elapsed. 2. In the group of Clearfil, early inflammatory change revealed in the superificial portion of the remaining pulp tissue on 3 day. The inflammation spreaded over the total pulp tissue and partial necrosis was observed in 1 week and 2 week cases. Total necrosis of pulp tissue and moderate inflammatory change at the apical tissue was noticed in 4 week and 6 week cases. 3. In the group of Panavia-EX, moderate inflammatory change appeared in the superficial pulp tissue on 3 day, and severe inflammatory change over all pulp tissue found in 1 week case. Pulp necrosis was obvious in 2 week case. 4 week and 6 week cases were totally necrotized up to the periapical tissue. 4. In the groups of mixtures with calcium hydroxide powder, the pulp tissue destruction was retarded, compared with the groups of Clearfil and Panavia-EX. 5. Panavia-EX was more destructive than Clearfil. 6. The acidity of freshly mixed Bonding agent of Cleafil was pH 4.0, and that of Panavia-EX was pH 2.0.

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알루미늄 캔 스크랩의 고품위 재활용을 위한 발포금속의 제조 (Fabrication of Aluminum Foams for High Profit Recycling of Aluminum Can Scraps)

  • 하원;김세광;김영직
    • 한국주조공학회지
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    • 제25권5호
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    • pp.203-208
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    • 2005
  • The main emphasis of this study is to optimize the process variables for manufacturing aluminum foam materials by direct foaming of remelted aluminum scraps. Aluminum foams were fabricated from two different raw materials, pure aluminum and used beverage cans. For both cases, $TiH_{2}$ was used as a foaming agent. Calcium was added as a thickener for the foaming of pure aluminum and no thickener was added for that of used beverage Cans because the pre-existing oxides of the used beverage cans are used as a thickener. Calcium and $TiH_{2}$ content varies from 0.5wt.% to 2.0wt.% and from 0.5wt.% to 1.5wt.%, respectively. The processing conditions, such as the effect of calcium on the melt viscosity, foaming temperature, and the optimum amount of the foaming agent with regard to the melt viscosity were discussed.

굴 폐각을 적용한 슬러지 탈수 및 탈수효율 개선에 관한 연구 (A Study on the Improvement of Sludge Dewatering and Dewatering Efficiency by Using Oyster Shell)

  • 엄한기;이진헌;주현종
    • 한국물환경학회지
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    • 제32권5호
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    • pp.458-464
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    • 2016
  • This study evaluated the dewatering efficiency of inorganic dehydrating agents that contain oyster shells. A filter press dehydrator was used for this study. The experiments were performed by the single injection of calcium-based chemicals, the single injection of oyster shells, and the mixed injection of oyster shells and calcium-based chemicals. The moisture content of the dewatered cake generated after dehydration confirmed that the best dewatering efficiency was found at the mixing ratios of CaCO3 to sludge, oyster shell to sludge, and inorganic dehydrating agent to sludge of 3:1, 10:1, and 1.5:2.5:1, respectively. The moisture contents exhibited less than 58% when the injection mixing ratio of inorganic dehydrating agent to sludge was 1.5:2.5:1. From EPS, SEM, and EDX analysis, it was found that the calcium adsorbed on the sludge surface could reduce extracellular polymeric substances (EPSs) and enhanced the dewaterbility. Based on the above results, it is considered possible to apply inorganic dehydrating agents containing recycled oyster shells in sludge dewatering in order to reduce sludge.

Calcium Channel Blocker가 사염화탄소에 의한 간손상에 미치는 영향 및 조직학적 검경 (Effect and Histopatbologic Examination of Calcium Channel Blocker on Carbon Tetrachloride-induced Hepatotoxicity in Rats)

  • 전명애;정춘식;정기화
    • Biomolecules & Therapeutics
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    • 제6권3호
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    • pp.247-255
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    • 1998
  • Carbon tetrachloride (CCI$_4$) induces the hepatotoxicity due to the reactive free radicals generated by cytochrome P-450 (CYP-450) enzyme, which result in destabilization of cellular membrane. Diltiazem, a calcium channel blocking agent, has been known to suppress the CYP-450 enzyme activities. To study the effect of diltiazem in $CCl_4$-treated rats, we measured the activities of alanine aminotransferase (ALT), aspartate aminotransferase (AST) and glutathione S-transferase (GST), contents of bilirubin, albumin, total protein, cholesterol, triglyceride, blood urea nitrogen, creatinine malondialdehyde and calcium. Also we conducted liver histopathologic examinations. Diltiazem, when administered 1 hour prior to CCI$_4$ treaeent, significantly reduced the activities of ALT and AST, the contents of microsomal malondialdehyde and calcium in liver and microsome as compared with those of $CCl_4$-treated rats. In addition, histopathologic examination showed that diltiazem prevented the development of centrilobular necrosis induced by CCI$_4$ in liver tissue. Our results suggested that diltiazem could inhibit the formation of free radicals and the influx of calcium. Therefore diltiazem may be applied to suppress the liver damage caused by $CCl_4$.

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