• Korean Journal of Materials Research
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• v.6 no.6
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• pp.543-554
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• 1996

Bi-Sr-Ca-Cu-O 계에서 상형성에 관해 연구하였다. 임계온도가 80K인 초전도체는 Bi-Sr-Ca-Cu의 몰비율이 2:2:1:2의 성분으로부터 solid state synthesis의 방법으로 합성하였다. 이때 이상에 대한 x-ray diffraction pattern은 모두 색인하였다. 2:2:1를 기본으로한 solid solution의 형성을 Bi2Sr2-xCa1+yCu2O8+$\delta$으로 단일상(single phase)을 형성하고 있으며, 이때 x와 y의 범위는 0

• Electrical & Electronic Materials
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• v.9 no.7
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• pp.680-689
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• 1996

SrCaCuO와 BiPbCuO 화합물로 이루어진 이중층시료가 만들어 졌으며, 소결과정에서 나타나는 확산과 입자간의 상호작용으로 108K의 임계온도를 나타내었다. 이 시료는 820.deg. C에서 0-210 시간동안 소결되었다. 초전도체의 생성, 성장메카니즘과 임계온도의 관계가 연구되었으며, 최적조건은 820.deg. C에서 210시간 소결하고 SrCaCuO와 BiPbCuO의 도포비가 1:0.6인 시편에서 나타났다. 또한 이중층시료에서 가장 좋은 조성비는 S $r_{2}$C $a_{2}$C $u_{2}$ $O_{x}$와 B $i_{1.9}$P $b_{0.5}$C $u_{3}$ $O_{y}$ 이었다.다.

• Korean Journal of Materials Research
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• v.17 no.3
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• pp.147-151
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• 2007

Cu-free multi-component sol, of which final oxide composition becomes $Bi_{1.9}Pb{0.35}SrCaO,\;Bi_{1.8}Pb_{0.2}SrCaO\;and\;Bi_{1.5}SrCaO$, respectively, was prepared through sol-gel route and coated on a bare Cu substrate. Starting materials were metal-alkoxides as follows.; [$Bi(OC_{2}H_{5})_{3}\;Pb(O^{1}C_{3}H_{7})_{2},\;Sr(O^{i}C_{3}H_{7})_{2},\;Ca(OC_{2}H_{5})_{2}$] as a reagent grade. Transparent light yellowish sol was obtained in the case of $Bi_{1.9}Pb_{0.35}SrCaO\;and\;Bi_{1.8}Pb_{0.2}SrCaO$ composition and $Bi_{1.5}SrCaO$ composition's sol was light greenish. Each sol was repeatedly dip-coated on Cu substrate four times and pre-heated at $400^{\circ}C$ and finally heat-treated in the range of $740{\sim}900^{\circ}C$. In the results, crystalline phases confirmed by XRD were (2201) orthorhombic and monoclinic phases. However, only $Bi_{1.9}Pb_{0.35}SrCaO_{x}$ composition showed pseudo-superconductive behavior after heat-treatment at $900^{\circ}C$ for 12 seconds and then onset temperature was 77 K, even though it did not exhibit zero resistance below Tc.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.597-600
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• 2002

Electrical properties of $\{(Sr_xCa_{1-x})_{0.95-y-z}Bi_2Pb_{0.05+y}\})Ti_{1.02}O_3$ ceramic were studied as a function of Sr/Ca ratio and Bi, Pb contents. Dielectric properties of specimens with different x, y, z values were explained in terms of ionic polarizability with Molecular Additionally Rules and Clausius-Mosotti equation. For the composition of $\{(Sr_{0.62}Ca_{0.38})_{0.90}Bi_{0.01}Pb_{0.09}\})Ti_{1.02}O_3$ and $\{(Sr_{0.62}Ca_{0.38})_{0.905}Bi_{0.015}Pb_{0.08}\})Ti_{1.02}O_3$, dielectric constant$({\varepsilon}_r)$, quality factor(Q) and temperature coefficient(TC) were 389, 3048, -1490 and 394, 1869, -1340 at 1MHz, respectively.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.177-180
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• 2009

Here is presented the measurement on SrO- and SrCaO-PDP operated at lower voltage. SrO- and SrCaO-PDP attain high luminous efficacy at low voltage, where the breakdown voltage is 30 % lower than that of the ordinary MgO-PDP. A one-dimensional fluid model is applied for the simulation of PDP discharge. High VUV radiation efficiency is confirmed at high ${\gamma}_i$ and both low and high $V_s$ as in the experiment. Discharge analysis in simulation also shows that the high ${\gamma}_i$ protective layer leads to high plasma density especially near the cathode electrode, being responsible for high efficiency.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.43 no.5
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• pp.795-801
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• 1994

The BiPbSrCaCuO superconductor was fabricated by diffusion of The dual layer composed of SrS12TCaS11TCuS12TOS1xT in upper layer and BiS12TPbSI0.3TCuS12TOS1yT in lower layer, and varified growh-mechanism of BiPbSrCaCuO superconducting phase. And, we produced optimum conditions of spread volume and each stage of sintering time were upper layer:Lower layer=1:0.2, 1:0.4, 1:0.6 and 24hr., 120hr., 210hr. From the result, the optimum conditions are spread volume(Upper layer:Lower layer=1:0.6), sintering time(210hrs.) at 820$^{\circ}C$.The BiPbSrCaCuO superconductor, fabricated optimum condition, showed zero resistance at critical temperature of 70k.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.181-183
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• 2009

Comparative study of the dependence of the firing voltage of MgSrO and MgCaO protective layers on chemical composition was carried out. It was observed that the firing voltage increases when CaO/MgO or SrO/MgO ratio increases.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.11a
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• pp.500-502
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• 2000

BiPbSrCaCuO 계 초전도체에서 관측되는 자기부양효과에 대하여 연구를 수행하였다. BiPbSrCaCuO 계 초전도체에 산화은을 첨가한 시료와 첨가하지 않은 시료의 자기적 특성을 측정하여 자기부양효과의 메카니즘에 대하여 고찰하였다. toroidal자석에서 관측되는 자기부양 효과는 자석의 중심부분에서만 발생하며, 자석의 ring 부분에서는 관측되지 않았다. 이 결과는 본 연구의 자기 부양효과의 발생에는 자석의 형상 및 자속의 분포 형태와 밀접한 관련이 있음을 의미한다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.217-220
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• 1999

We investigated the effects of doping elements on the Bi-Sr-Ca-Cu-0 ceramics. The doping elements can be classified into groups depending on their supeconducting characteristics in the Bi -Sr-Ca-Cu -O structure. The first group of doping elements(Co, Fe, Ni and Zn) substitute into the copper site and can reduce the critical temperatures of the 2223 and 2212 phases. The second group of doping elements(Y and La) substitute into the Ca site and cause the disappearance of the 2223 phase and increase the critical temperatures in the 2212 phase.

• Korean Journal of Materials Research
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• v.6 no.11
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• pp.1121-1126
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• 1996

(Pb0.63Ca0.37)ZrO3 세라믹에 MgO와 SrO를 첨가하여 Ca를 Mg와 Sr 이온으로 치환하였을 때의 고주파 유전특성에 대해 연구하였다. Ca 이온의 일부를 Mg 이온으로 치환시킨 경우에는 A-O결합에 의한 분극의 증가로 인하여 유전상수는 직선적으로 증가하지만 품질계수는 감소한다. 또한 Ca 이온을 Sr 이온으로 치환시킨 경우에는 결합길이의 증가로 인해 분극이 감소되어 유전상수와 품질계수가 감소한다. 고주파용 유전재료의 설계에 있어서 관용인자와 이온결합성의 평가가 중요하다.