• Korean Journal of Environmental Agriculture
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• v.29 no.4
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• pp.343-347
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• 2010

Heavy application of fertilizer and manure in excess from the optimum requirement for crop growth can increase phosphorus (P) accumulation and P release potential in soils. In this study, the relationship between soil test P and 0.01M $CaCl_2$ extractable P was analysed to evaluate the P release potential of agricultural soils under different land-use. The paddy, upland, plastic film house(PFH) soils were sampled from Tongyoung and Changnyeong, and Daegok areas in Gyeongnam province, respectively. With respect to the P accumulation, available P contents in upland and PFH soils were 619 and 796 mg $P_2O_5$/kg, respectively indicating that different land-use types can greatly impact soil P accumulation. As soil available P was increased in the paddy soil, the content of 0.01M $CaCl_2$ extractable P also linearly increased without change point. Comparatively, P threshold were detected at 520 mg $P_2O_5$/kg in both upland and PFH soils, indicating that P release potential were higher in these land-use systems. For reducing P release from agricultural soils, management of optimum P content is needed in soils possessing high P release potential. Further, the change point value, if it is to be used as an environmental indicator, requires more detailed investigation to cover a wide range of soil characteristics.

• Korean Journal of Soil Science and Fertilizer
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• v.29 no.4
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• pp.385-388
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• 1996

Accumulation of soil chemical components in plastic-house is serious problem in Korea. This study was carried out to solve the problem by comparing the contents of soil chemical properties in plastic-house with that of upland field. The content of organic matter and available $P_2O_5($ in plastic-house soil were higher than that of upland field. Particularly, organic matter content in plastic-house soil (43g/kg) was 1.7times higher than that of upland soil (26g/kg), and content of available $P_2O_5($ (893mg/kg) in plastic-house: soil was 4.9 times higher than that of upland soil(183mg/kg). The content of exchangeable K, Ca and Mg in plastic-house soil were 0.5, 6.8 and 1.6cmol/kg and that of upland field soil were 0.5, 2.3 and 2.5cmol/kg, respectively.

• Journal of Conservation Science
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• v.33 no.4
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• pp.297-312
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• 2017

In the ancient iron-making process, a slag former was often added so that iron and other minerals in the ore could be smoothly separated. However, there are insufficient data for judging whether a slag former was added. Thus, in this study, we conducted a smelting experiment to understand the material characteristics of a steel structure that differed depending on the addition of a slag former. It was found that the steel structure produced in the first experiment had a total Fe content of 39.45-52.94 wt%, which decreased to 34.89-38.92 wt% in the second and third experiments. CaO compounds such as calcite, gehlenite, and hercynite appeared, in addition to iron oxides, after the addition of a slag former. As a result of an assessment of whether a slag former was added by comparing the ratio between the components, it was found that the ratio of $CaO/SiO_2$ was 0.42. From a comparative analysis of $Al_2O_3/SiO_2$ and $CaO/SiO_2$, it was judged that the ratio of $Al_2O_3$ and $SiO_2$ can be utilized as an index to judge similar systems of smelting process (ore, furnace wall, and fuel).

• Journal of Korea Soil Environment Society
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• v.3 no.3
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• pp.93-107
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• 1998

Because of its stable quantity and quality, groundwater has long been a reliable source of drinking water for domestic users. Rapid economic growth and rising standards of living have in recent years put severe demands on drinking water supplies in Korea. Groundwaters that are currently being used for natural mineral water were hydrochemically evaluated and investigated in order to maintain their quality to satisfy strict health standards. There exist 15 natural mineral water plants in the Okcheon metamorphic belt. Characteristics of groundwaters are different from those of other areas in that electrical conductivity, hardness, contents of Ca, Mg and $HCO_3$are relatively high. The content of major cations is in the order of Ca>Mg, Na>K, whereas that of major anions shows the order of $HCO_3$>$SO_4$>Cl>F. The fact that the Ca-Mg-HCO$_3$type is mostly predominant among water types reflects that dissolution of carbonates that are abundantly present in the metamorphic rocks plays an important part in groundwater chemistry. Representative correlation coefficients between chemical species show Mg-$HCO_3$(0.92), Ca-$HCO_3$(0.88), Ca-Mg(0.80), Ca-Cl(0.78), Mg-$SO_4$(0.78), Ca-$SO_4$(0.71), possibly due to the effect by dissolution of carbonates, gypsum or anhydrite. Determinative coefficients between some chemical species represent a good relationship, especially for EC-(K+Na+Ca), Ca-$HCO_3$, Ca-Mg, indiacting that they are similar in chemical behaviors. According to saturation index, most chemical species are undersaturated with respect to major minerals, except for some silica phases. Groundwater is slightly undersaturated with respect to calcite and dolomite, whereas it is still greatly undersaturated with respect to gypsum, anhydrite and fluorite, Based on the Phase equilibrium in the systems $NA_2$O-$Al_2$$O_3$-$SiO_2$-$H_2$O and $K_2$O-$Al_2$$O_3$-$SiO_2$-$H_2$O, it is clear that groundwater is in equilibrium with kaolinite, evolved from the stability area of gibbsite during water-rock interaction. It is expected that chemical evolution of groundwater continue to proceed with increasing pH by reaction of feldspars, with calcite much less reactive.

• Korean Journal of Soil Science and Fertilizer
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• v.27 no.4
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• pp.275-283
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• 1994

The effects of anthracite and bituminous fly ash application on rice yield were investigated and the available silicate in paddy soil with ash application was analyzed. The obtained results are as follow : The yield of rice gradually decreased as the amount of anthracite ash increased. On the contrary, the rice yield gradually increased as the amount of bituminous ash increased. At harvesting stage the chemical properties in soil such as pH, organic content, and inorganic content($P_2O_5$, K. Ca, Mg and available $SiO_2$) were higher in bituminous ash treated soil than in anthracite treated soil. The amount of inorganic components in rice plant such as T-N, $P_2O_5$, $K_2O$, CaO, and MgO gradually decreased with the growing stage of rice. However, the amount of available silicate increased with the growing stage of rice. The silicate content in soil was determined by two different methods ; 1N-NaOAc extracted method and submerging setting method. In bituminous ash treated soil, the correlation between the silicate content in plant and in soil was found when the silicate content in soil was determined by the soil submerging method. In anthracite ash treated soil, however no correlation was found between the silicate content in plant and in soil determined by either method.

• Korean Journal of Food Science and Technology
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• v.32 no.3
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• pp.668-673
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• 2000

The influence of storage atmosphere on ethylene production, quality attributes and storage injury of 'Tsugaru' apples was investigated. Apples were stored in 1% $O_2+1%\;CO_2,\;1%\;O_2+3%\;CO_2,\;3%\;O_2+1%\;CO_2,\;3%\;O_2+3%\;CO_2$ and air at $0^{\circ}C$ for 5 months. Ethylene production was more suppressed by 1% $O_2$ than 3% $O_2$ atmospheres regardless $CO_2$ levels. The loss of flesh firmness and the decrease of titratable acidity were not significantly different among the storage atmospheres until 3 months of storage but more retarded by 1% $O_2$ than 3% $O_2$ atmospheres thereafter. Soluble solid content was unaffected by the storage atmosphere, but the content tended to be increased until 2 months of storage and then not varied. Ethanol content increased up to a peak level followed by a gradual loss during storage in CA but increased continuously in air. In the sensory evaluation after storage for 5 months, hardness, tartness and overall acceptability of apples stored in 1% $O_2$ atmospheres were significantly higher than those stored in the others. There was no fruit injury or off-flavor production resulting from the 1% $O_2$ atmospheres. The incidence of bitter pit was reduced as storage $O_2$ level decreased. The results show that the optimum conditions of CA storage for 'Tsugaru' apples are $0^{\circ}C$ and 1% $O_2+1{\sim}3%\;CO_2$.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.5
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• pp.210-213
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• 2011

Glass-ceramics composed of $5Na_2O-36CaO-10TiO_2-xP_2O_5$ could be obtained with $P_2O_5$ content as following procedure: 1) leaching out $Ca_3(PO_4)_2$ crystals between $Ca_3(PO_4)_2$ and $NaTi_2(PO_4)_3$ selectively in 1 N HCl solution for 2 days, and 2) exchanging $Na^+$ ion to $Ag^+$ ion in Ag($NO_3$) solution for 1 day. Scanning electron microscope (SEM) and X-rat diffractometer (XRD) were measured to verify the proper synthesis of glass-ceramics. And anti-bacteria test was accomplished using Staphylococus aureus bacteria. In the results of anti-bacteria test, the bacteria were died perfectly after 3 hours.

• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.267-275
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• 2007

Melting slag generated from municipal-incinerator ash contains lots of impurities which have adverse effects on zeolite synthesis. These impurities are detrimental to zeolite synthesis, and the yield and purity of zeolite was decreased. And thus its performance is lowered. In melting slag, there are lots of components such as $Fe_2O_3$, FeO and CaO. To remove these impurities, we treated the melting slag with hydrochloric acid at initial pH 1, 3, 5, and 7. After the treatment, the $SiO_2,\;Fe_2O_3,\;and\;TiO_2$ ratios increased, but the $Al_2O_3,\;FeO,\;CaO,\;Na_2O$ and MgO ratios decreased. We reacted these treated slag in a NaOH solution under hydrothermal conditions at $80^{\circ}C$. The hydrothermal products from the slag and the slag treated at pH 7 and pH 5 were determined to be tobermorite, whereas those at pH 3 and pH 1, Na-P1 and Na-X zoelite respectively. CaO was found to inhibit the synthesis of zeolite.

• Journal of the Mineralogical Society of Korea
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• v.19 no.4 s.50
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• pp.347-353
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• 2006

The atomic-nano scale structures of multi-component aluminosilicate glasses have not been well understood in spite of its implications fur dynamics and generation of magma in the natural system due to lack of suitable spectroscopic and scattering experiments. Here, we report O-17 MAS and isotropic projection of 3QMAS NMR spectra for quaternary Na-Ca silicate glasses $[(CaO)_x(Na_2O)_{1-x}]\;(A1_2O_3)_{0.5}(SiO_2)_6,\;CNAS)$ at 14.1 Tesla where atomic configurations around bridging oxygen (Si-O-Si, Si-O-Al) and non bridging oxygen (Na-O-Si, Ca-O-Si, (Na, Ca)-O-Si) are partially resolved. With increasing Na content, the fraction of Na-O-Si increases while those for bridging oxygens remain constant. The Na/Ca ratio apparently affects the peak widths of bridging oxygen peaks (e.g., Si-O-Si)) and thus the topological entropy as well as chemical shifts of the bridging oxygen peaks, implying that both BOs and NBOs are strongly interacting with network modifying cations The effect of cation field strength on the degree of Al-avoidance was also discussed.

• Journal of Sensor Science and Technology
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• v.11 no.4
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• pp.218-223
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• 2002

NASICON sensors that the NASICON electrolytes with various CaO amounts were sintered at low temperature($900^{\circ}C$), were fabricated to improve $CO_2$ sensitivity and stability in sensing behaviors. The manufactured device was shown good sensing characteristics and stability of output electromotive force at $250^{\circ}C$, comparatively low operating temperature.