• Title/Summary/Keyword: CaO 함량

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Dissolution Properties of K2O-CaO-MgO-SiO2-P2O5 Glasses (K2O-CaO-MgO-SiO2-P2O5계 유리의 제조 및 용출특성)

  • 이용수;윤태민;강원호
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1132-1137
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    • 2003
  • For the application of environment conscious glass-fertilizer, dissolution characteristics of phosphate glass was investigated. In 0.1K₂O-0.1SiO₂-0.6P₂O/sub 5/ glass system, the compositions were designed according to variation of CaO & MgO contents, and glass formation region was confirmed. From the glass composition, the confirmed glasses were investigated to figure out thermal and dissolution properties. It was detected that glass transition & softening temperature of the glasses increased with increasing MgO contents. The dissolution properties of the glasses was affected by CaO and MgO content ratio.

Studies on Chemical Constituents of Barley in Korea II. Relationship between protein content and P, K, Ca, or Mg among barley varieties (한국산(韓國産) 보리의 화학조성(化學組成)에 관(關)한 연구(硏究) II. 대맥품종별(大麥品種別) P, K, Ca, Mg 함량(含量)과 단백질함량(蛋白質含量)과의 관계(關係))

  • Park, Hoon;Lee, Dong-Suk
    • Korean Journal of Food Science and Technology
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    • v.7 no.2
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    • pp.82-84
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    • 1975
  • In polished barley of 22 varieties protein content was correlated significantly with MgO of $P_2O_5$ content (at p=0. 01), $K_2O$ (at p=0. 05), but it was not related to CaO. Dye binding capacity was correlated significantly (at p=0. 01) with MgO or $P_2O_5$. Thus MgO could be used for mass screening of protein content. Carbohydrate content showed insignificant negative correlation coefficients with above four minerals. There were significant positive correlation (at p=0. 01) among $P_2O_5$, $K_2O$ and MgO. The mean contents of $K_2O$, $P_2O_5$, MgO and CaO were 0. 03, 0. 29, 0. 084 and 0. 043%, respectively.

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Effect of Carbonation Curing on the Hydration Properties of Circulating Fluidized Bed Boiler Ash (탄산화 양생이 순환유동층 보일러 애시의 수화특성에 미치는 영향)

  • Soo-Won Cha;Shi-Eun Lee;Won-Jun Lee;Young-Cheol Choi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.324-331
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    • 2023
  • In this study, the hydration and carbonation properties of circulating fluidized bed boiler (CFBC) ash with different free-CaO contents were investigated. In addition, the possibility of utilizing CFBC ash with a high free-CaO content as a cementitious material was investigated by carbonation curing as a pretreatment. The CFBC ash with high free-CaO content exhibited rapid setting behavior and low early compressive strength when mixed with cement. For CFBC ash with high free-CaO content, carbon dioxide capture increased with the duration of carbonization curing. In addition, the free-CaO value decreased together, indicating that the free-CaO reacted with carbon dioxide. When the CFBC ash with high free-CaO content was pretreated by carbonation, no fresh set appeared, and the initial compressive strength was improved. From the results of this study, it is confirmed that CFBC ash with high free-CaO content has a high potential to be utilized as a cementitious material through proper carbonation curing.

Burnability and Mineral Properties of Clinker Added Chlorine (염소 함유 클링커의 소성성 및 광물특성에 관한 연구)

  • Kim, Tae-Yeon;Kim, Nam-Il;Chu, Yong-Sik
    • Resources Recycling
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    • v.29 no.6
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    • pp.48-56
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    • 2020
  • In this study, raw mix was mixed with CaCl2 for analyzing characteristics of clinker added chlorine and chlorine was added by 2,000ppm at high concentration condition. The raw mix added chlorine was burned at 1250℃~1350℃ and maintained during 10minutes at each maximum temperature. Clinker target modulus was LSF 92, SM 2.5 and IM 1.6 in this study. The burnability of clinker added chlorine was identified by free-CaO content. Free-CaO content decreased as chlorine content increased and free-CaO content of 1350℃-2000ppm clinker decreased by 1.5%. Optical microscope and XRD Analyses were used for identify mineral properties of clinker added chlorine. The mineral of clinker could not be observed at 1250℃ and the size of alite grew larger as chlorine content increased at 1350℃. It showed a good crystallizability as chlorine content increased. As chlorine content of clinker increased, clinker showed a good burnability and mineral property.

Studies on the Ouality of Boxthorn in Korea(Lycium chinense Miller) (한국 구기 품종의 품질에 관한 연구)

  • 이상래
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.28 no.2
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    • pp.267-271
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    • 1983
  • The southern parts varieties have shown higher content of Oleic acid, Linoleic acid, Vitamin A, Alcaloid, Ca, P and Fe than northern parts Varieties. The $N.\;P_2O_5\;and\;K_2O content of narrow leaf were higher than wide leaf, on the other hand the Ca, Mg, Fe and $SiO_2$ content of wide leaf were higher than narrow leaf. The content of $N, \;P_2O_5, \;K_2O$ have shown higher in first yellow leaf date, the content of Ca has shown higher in first falling leaf date and the content of Mn and Cu content have shown higher in second new leaf date.

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Effect of Low-grade Limestone on Raw Mill Grinding and Cement Clinker Sintering (저품위 석회석이 원료밀의 분쇄성과 시멘트 클링커 소성성에 미치는 영향)

  • Yoo, Dong-Woo;Park, Tae-Gyun;Choi, Sang-Min;Lee, Chang-Hyun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.20-25
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    • 2021
  • The cement clinker, the main raw material of cement, is manufactured using limestone as the main material. Depending on the quality of limestone, the use of subsidiary materials changes, and has a great influence on the production of cement clinkers. In this study, the effect of CaO content of limestone, a cement clinker material, on Raw Mill grinding and sintering of cement clinker was investigated. The grinding time of the union materials changed in the content of limestone CaO was measured to identify the grinding properties. The raw material combination was cleaned within a range of 1,350-1,500℃. The sintering performance of cement clinker by Burnability index calculation was identified. The lower the grade of limestone, the lower the grinding quality of the raw material combination. The lower the CaO content of limestone, the greater the variation in F-CaO for sintering temperature. The lower the class of limestone, the higher B. I. value was calculated, indicating the lower cement clinker sintering. In addition, the mineral analysis results of cement clinker showed that if the F-CaO value was low due to the increase in sintering temperature, the Belite content decreased and the Alite content increased. In the case of Alite, the ratio of R-type decreased and that of M-type increased as the content of limestone CaO increased.

A study of sintering behavior of spray coating in CaO-Al2O3-SiO2 glasses on Al2O3 substrate (CaO-Al2O3-SiO2 계 유리 스프레이 코팅막의 소성 거동에 대한 연구)

  • Na, Hyein;Park, Jewon;Park, Jae-Hyuk;Kim, Dae-Gun;Choi, Sung-Churl;Kim, Hyeong-Jun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.298-307
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    • 2019
  • Two types of CaO-Al2O3-SiO2 (CAS) glass powder applied spray coating on the surface of sintered Al2O3 were researched for sintering behavior; (1) Si-rich, glass containing high content SiO2, (2) Ca-rich, containing high content CaO. Foaming of bubbles remaining inside the Ca-rich glass was produced at a viscosity of approximately 107~109 poise, resulting in decreasing shrinkage (interfering with sintering) and increasing surface roughness. In case of Si-rich glass, there was no serious foaming bubbles phenomenon like Ca-rich below 1000℃, however cristobalite crystals with low density occurred at 1200℃ and then produced re-foaming of bubbles, resulting in abnormal sintering behavior. These phenomenon is considered to be a decrease in viscosity due to an increase in the Ca content of the glass according to the formation of low-density cristobalite crystals. Therefore, in case of CAS glass, it is necessary to consider the increase of surface roughness and the sintering interference because of foaming bubbles phenomenon at low temperature sintering. Especially, when containing high SiO2 content, abnormal foaming phenomenon due to crystallization at high temperature should be predicted.

Study on the Free CaO Analysis of Coal Ash in the Domestic Circulating Fluidized Bed Combustion using ethylene glycol method (에틸렌글리콜법을 활용한 국내 순환유동층보일러 석탄회의 Free CaO 평가 연구)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Kim, Young-Jin;Choi, Moon-Kwan;Cho, Kye-Hong;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.26 no.1
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    • pp.1-8
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    • 2017
  • This study was carried out to physicochemical properties and free CaO contents of coal ash in domestic circulating fludized bed combustion power plant using ethylene glycol method. Results of physicochemical properties, there are many differences in CaO contents for the region position in CFBC plant. The reason, It is considered to be reflected that regulation of exhaust concentration for oxides of sulfur and other operation characteristics of region position in CFBC plant. Free CaO contents are 1.96 ~ 10.78% of fly ash and 0.07~4.24 % of bottom ash, fly ash is higher than in the bottom ash. besides CaO contents of raw materials, particle distribution have a lot of influence Free CaO contents.

Anti-bacterial properties of $Na_2O-CaO-TiO_2-P_2O_5$ glass added in Ag (Ag를 첨가에 따른 $Na_2O-CaO-TiO_2-P_2O_5$계 글라스의 항균특성)

  • Yoo, Eun-Sung;Kang, Won-Ho
    • Proceedings of the KAIS Fall Conference
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    • 2008.11a
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    • pp.90-92
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    • 2008
  • 본 논문에서는$xAg_2O$-(5-x)$Na_2O$-36CaO-$10TiO_2$-$19.5P_2O_5$ (mol ratio)의 유리조성으로부터 $Ag_2O$의 함량을 변화시켜 유리의 제조 및 특성평가를 하였다. 제조된 유리는 TG-DSC를 통하여 열적특성을 관찰하였으며, 항균특성은 staphylococcus aureus균주에 대하여 항균특성을 평가하였다. 평가결과 열적특성은 $Ag_2O$함량이 증가할수록 결정화온도가 낮아짐이 관찰되었고, 항균특성 역시 $Ag_2O$성분의 함량이 증가 할수록 항균특성이 증가하는 것으로 관찰되었다.

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A Study on Tungsten Paste for Metallization and Cofiring of an Alumina Green Sheet (Alumina Green Sheet의 동시소성용 텅스텐 페이스트 제조 및 금속 접합에 관한 연구)

  • 박경리
    • Journal of the Microelectronics and Packaging Society
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    • v.3 no.2
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    • pp.39-50
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    • 1996
  • 본 연구에선 주어진 조성의 알루미나 green sheet에 대하여 텅스텐의 입경 및 산화 물의 조성을 변화시키므로써 수축률을 제어하여 camber를최소화하여 결합강도를 최대로 하 는 텅스텐 페스트조성을 찾아내는 것을 목적으로 하였다. 본 실험에서 사용한 텅스텐 분말 의 입경은 0.35$\mu$m, 0.6$\mu$m, 0.72$\mu$m, $1.5\mu$m, 1.9$\mu$m, 3.2$\mu$m이며 frit는 Al2O3, MgO, SiO2 와 Al2O3, CaO, SiO2를 사용하여 각각의 조성에 따라 함량을 변화시키며 실험하였다. 소성 은 154$0^{\circ}C$로 습윤 수소분위기에서 시행하였으며 사용된 알루미나 green sheet의 알루미나 중심 입경은 2.8$\mu$m이었다. 분석은 주사전자 현미경으로 미세구조를 관찰하였고 EPMA Line Profile로 원소 분석을 하였으며 잔류응력을 측정하기 위하여 XRD분석을 하였다. Frit 을 함유하지 않은 경우 텅스텐 분말의 입경이 1.9$\mu$mdlfEo 최대 접합 강도를 나타내었다. Frit을 함유한 경우 Mgo계 frit조성에서는 MgO/Al2O3/SiO3=1/1/1일 때 CaO계 frot 조성에 서는 CaO/Al2O3/SiO2=1/2/1일 때 최대 접합 강도를 나타내었다. Frit 함량을 변화시킨 경우 MgO계는 10wt%함유하였을 때 CaO 계는 5wt%함유하였을 때 최대 접합강도를 나타내었 다. Frit 함량을 변화시킨 경우 MgO계는 10wt%함유하였을 때, CaOr계는 5wt%함유하였을 때 최대 접합강도를 나타내었다.