• Title/Summary/Keyword: Ca-ion concentration

Search Result 476, Processing Time 0.025 seconds

The Corrosion Control Using CCPP(Calcium Carbonate Precipitation Potential )Index in Metallic Coupons ($CaCO_3$침전능 조절에 의한 금속시편에서의 부식방지)

  • 이재인;임진경;서상훈;김동윤;신춘환
    • Journal of Environmental Science International
    • /
    • v.9 no.6
    • /
    • pp.505-509
    • /
    • 2000
  • The purpose of this study was to evaluate the effects of $Ca(OH)_2$ and $CO_2$ additions on the corrosion of metal coupons(ductile iron, galvanized steel, copper and stainless steel). Corrosion rate and released metal ion concentration of ductile iron and galvanized steel decreased by adjusting alkalinity, calcium hardness and pH with $Ca(OH)_2$ & $CO_2$ additions on copper and stainless steel were less than those on ductile iron and galvanized steel. When ductile iron coupon was exposed to water treated with Ca(OH)$_2$&$CO_2$, additions, the main components of corrosion product formed on its surface were $CaCO_3$ and $Fe_2 O_3 or Fe_2 O_4$ which often reduce the corrosion rate by prohibiting oxygen transport to the metal surface.

  • PDF

[ $Ce^{4+}$ ]-Stimulated Ion Fluxes Are Responsible for Apoptosis and Taxol Biosynthesis in Suspension Cultures of Taxus Cells

  • Li Jing-Chuan;Ge Zhi-Qiang;Yuan Ying-Jin
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • v.10 no.2
    • /
    • pp.109-114
    • /
    • 2005
  • Ion fluxes across the plasma membrane activated by 1 mM $Ce^{4+}$, cell apoptosis and taxol biosynthesis in suspension cultures of Taxus cusp/data were studied. The extracellular pH sharply decreased upon the addition of 1 mM $Ce^{4+}$, then increased gradually and exceeded the initial pH value over a time period of 12 h. The extracellular $Ca^{2+}$ concentration decreased within the first 3 h after the addition of $Ce^{4+}$, then gradually decreased to one third of initial value in control at about 72 h and remained unchanged afterwards. Experiments with an ion channel blocker and a $Ca^{2+}$-channel blocker indicated that the dynamic changes in extracellular pH and the $Ca^{2+}$ concentration resulted from the $Ce^{4+}$-induced activation of W uptake and $Ca^{2+}$ influx across the plasma membrane via ion channels. A pretreatment of the ion channel blocker initiated $Ce^{4+}$-treated cells to undergo necrosis, and the prior addition of the $Ca^{2+}$-channel blocker inhibited $Ce^{4+}$-induced taxol biosynthesis and apoptosis. It is thus inferred that W uptake is necessary for cells to survive a $Ce^{4+}$-caused acidic environment and is one of the mechanisms of $Ce^{4+}$-induced apoptosis. Furthermore, the $Ca^{2+}$ influx across the plasma membrane mediated both the $Ce^{4+}$-induced apoptosis and taxol biosynthesis.

The effect of calcium ion concentrations in the medium and the treatment of caffeine and Ca-ionophore A23187 on in vitro capacitation of bull spermatozoa (배양액중의 calcium 이온 농도 및 caffeine과 Ca-ionophore A23187 처리가 소정자의 수정능획득에 미치는 영향)

  • Kim, Kye-Seung;Jo, Choong-Ho;Hwang, Woo-Seok
    • Korean Journal of Veterinary Research
    • /
    • v.31 no.1
    • /
    • pp.123-130
    • /
    • 1991
  • The present study was performed to investigate the effect of Ca ion concentration on sperm viability and acrosome reaction rate and to evaluate the effect of treatments using caffeine and Ca-ionophore A23187 on acrosome reaction rate in frozen-thawed bull spermatozoa. Viabilities of in vitro capacitated bull spermatozoa at 0, 2.25 and 4.5 mM Ca ion concenrations were 21.00, 26.00 and 22.59%, respectively and significantly higher in Ca ion 2.25mM added group than Ca ion free group (p<0.05) and acrosome reaction rates of in vitro capacitated bull spermatozoa were 17.09, 52.15 and 47.92%, respectively and significantly high in Ca ion added groups(p<0.05). Viabilities in vitro capacitation by caffeine and Ca-ionophore A23187 in control, caffeine treated group, Ca-ionophore A23187 treated group and caffeine+Ca-ionophore A23187 treated group were 37.91, 27.67, 22.33 and 25.59%, respectively and significantly higher in control than treated groups(p<0.05), there were no significant differences among the treated groups, and acrosome reaction rates were 10.33, 37.92, 48.09 and 57.17%, respectively and there were significant differences among the groups(p<0.05), especially higher in caffeine+Ca-ionophore A23187 treated group than others.

  • PDF

Development of a Solid State Ion Sensor Module for Analysis of Hydroponic Nutrients (수경재배용 배양액의 이온성분 분석을 위한 고체형 센서 모듈 개발)

  • Kim, G.;Lee, S.B.;Chang, Y.C.
    • Journal of Biosystems Engineering
    • /
    • v.32 no.5
    • /
    • pp.348-353
    • /
    • 2007
  • A solid state ion sensor module has been developed and evaluated for hydroponic nutrients analysis. The sensor module consisted of five ion-selective electrodes (ISE) fabricated by screen-printing technology. The electrochemical responses of ion sensors for nitrate, ammonium, potassium, calcium, and pH were measured with specially designed 7-channel low voltage signal transducers. The analytical characteristics of the sensors were comparable with those of conventional ISE sensors. The solid state ion sensors exhibit linear relationships over five concentration decades. Detection limit of the sensors were $5.6{\times}10^{-5}{\sim}1.6{\times}10^{-7}M$ depends on ions. Performance test results showed that relative errors of measured ion concentrations were less than 5% for $NO_3{^-},\;K^+,\;Ca^{2+}$ ion, and pH. The concentration of $NO_3{^-},\;NH_4{^+},\;K^+,\;Ca^{2+}$, and pH ion in standard solution and nutrient solutions could be determined by direct potentiometric measurements without any conditioning before measurements.

The Effect of High Concentration Cation Matrix on the Analysis of the Low Anion Concentration in Suppressed Ion Chromatography (Suppressed 이온 크로마토그래피에서 과량의 양이온이 낮은 농도의 음이온 분석에 미치는 영향)

  • Kang, Mi-Jeong;Lee, Sueg-Geun
    • Analytical Science and Technology
    • /
    • v.11 no.6
    • /
    • pp.495-498
    • /
    • 1998
  • The effect of high concentration ion matrix on the analysis of low anion concentration in the suppressed ion chromatography was studied. The anions studied were $Br^-$, $NO_3{^-}$, $HPO_4^{2-}$, $SO_4^{2-}$, and $C_2O_4^{2-}$ in the presence of excess NaCl and $CaCl_2$. In this study we suggested that the erroneous results in the suppressed ion chromatographic determination of small concentration of anions were not caused by the interaction of large amount of cation in the suppressor, but by the interaction of cation with concerned anion in the original solution. The error in the analysis of such anion can not be eliminated just by dilution. Therefore, we suggested that standard addition method might be adequate for analyses of those samples.

  • PDF

금속 이온을 이용한 Bacillus Stearothermophilus 호열성 단백질 분해효소의 역가 향상 및 호열 ${\cdot}$ 호기성 소화공정에의 응용

  • Kim, Yeong-Gi;Bae, Jin-Hye;Lee, Won-Hong;Choe, Jeong-U
    • 한국생물공학회:학술대회논문집
    • /
    • 2000.11a
    • /
    • pp.167-170
    • /
    • 2000
  • Proteolytic hydrolysis is one of the main enzymatic reaction of waste activated sludge (WAS) digestion. Pretense excreted from Bacillus stearothermophilus (ATCC 31197) showed optimum temperature of $75^{\circ}C$ for maxium heat stable proteolytic activity against azo casein. The dependency of $Ca^{2+}$, $Zn^{2+}$ on heat stability of proteolytic enzymes were measured with various concentrations. It was shown that $Ca^{2+}$ ion enhanced heat stability of these enzymes. Then thermophilic aerobic digestion (TAD) was performed using B. sterothermophilus with the addition of divalent ions. Performance of TAD process with ATCC 31197 activated by $Ca^{2+}$, $Zn^{2+}$ions in terms of dissolved organic carbon (DOC) concentration, extracellular protein concentration, and scanning electrion microscopy (SEM) analysis. The best result of protein reduction concentration in digestion test was obtained with the addition of 2 mM $Ca^{2+}$ ion.

  • PDF

Effect of Na, K, Ca and Mg ions on the Action Potential of the Sinoatrial Node in the Rabbit (토끼 동방결절 활동전압에 대한 Na, K, Ca 및 Mg 이온의 영향)

  • Lee, Jeong-Ryeol;Eom, Yung-Ui
    • Journal of Chest Surgery
    • /
    • v.18 no.1
    • /
    • pp.1-6
    • /
    • 1985
  • Isolated sinus node cells of the rabbit were used to assess the effects of extracellular Na, K, Ca and Mg concentrations on cardiac pacemaker activity. With intracellular glass micro-electrodes spontaneous action potentials of SA node were recorded and the effects of various ions and their blockers were analyzed in terms of the cycle length, the amplitude and the duration of action potentials, the results obtained were as follows. 1. Sodium reduction [up to 30%] decreased the amplitude of action potential and lengthened the cycle length. TTX, specific blocker of Na channel slightly lengthened the cycle length. 2. Increasing potassium ion concentration, the duration of action potential decreased and the frequency increased in 6mM, however, spontaneous action potential was stopped in 24 mM. Barium ion known to be decreasing K conductance increased the duration of action potential but no significant change in the cycle length was noticed. 3. Calcium ion has shortening effect on the duration and the cycle length of action potential but not with dose-dependent manner. Cadmium ion .[0.02mM] lengthened cycle length and the duration of action potential. 4. Increasing the concentration of magnesium ion the cycle length was lengthened, significantly.

  • PDF

Preparation of Calcium Alginate Fiber by Ion Exchange (이온교환에 의한 칼슘알지네이트 섬유의 제조)

  • Son, Tae-Won;Lee, Min-Gyeong;Han, Song-Jeong
    • Textile Coloration and Finishing
    • /
    • v.23 no.1
    • /
    • pp.51-59
    • /
    • 2011
  • Calcium alginate fiber were prepared by wet spinning of various conditions, including different concentrations of sodium alginate solution and $CaCl_2$ concentrations for coagulating the fiber through an absorption of calcium ion. The absorption of calcium ion during the coagulating step lead to solidify the fibers by the replacement of sodium ion with calcium ion to produce some crosslinking. The concentration of calcium ion in the calcium alginate fiber seems to be well related to the mechanical and physical property of the fiber, such as fiber strength moisture regain, and degree of swelling. The tensile strength of calcium alginate fiber was increased along with the increasing amount of sodium alginate solution. According to EDS analysis, 7 wt% $CaCl_2$ coagulation bath resulted in more calcium ion in the fiber compared to 3 wt% $CaCl_2$ coagulation bath. The decomposition temperature of calcium alginate fiber was $199^{\circ}C$, which $14^{\circ}C$ higher than that of sodium alginate.

Calcium Ion Effect on the Sugar-H+ -Cotransport System in Chlorella vulgaris (Chlorella vulgaris의 당류 능동수송계에 미치는 칼슘 이온의 영향)

  • 조봉희
    • Journal of Plant Biology
    • /
    • v.36 no.4
    • /
    • pp.321-326
    • /
    • 1993
  • Sugar uptake is accompanied with H+-substrate-symport generally. Both H+/sugar-and H+/K+ stoichiometries during the sugar-uptake have been reported to be exactly 1 : 1. This paper reports that the stoichiometries were enhanced dramatically by the addition of CaCl2 into the medium and by the high cell density of 200 $\mu$L pc/mL. The concentration of free Ca2+ ions in the cells increased significantly with cell density. It is suggested that the free Ca2+ ions are responsible for the change of stoichiometry of sugar transport system by regulation of H+ ion level of biomembrane.

  • PDF

A Study on the Chemical Characteristics of Acid Rain in Taejon City (대전지역 산성강우의 화학적 특성에 관한 연구)

  • 구자공;박경렬
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.9 no.2
    • /
    • pp.147-153
    • /
    • 1993
  • From March 1990 to August 1991, every each 5mm bulk precipitation samples were collected at one residental area in Taejon City to investigate chemical characteristics of acid rain. Major ion concentrations of rain samples $(pH, SO_4^{2-}, NO_3^-, CL^-, NH_4^+, Na^+, K^+, Ca^{2+}, Mg^{2+})$ were analysed and compared with the concentration of air pollutants (T. S. P, $SO_2, NO_x$) that were measured by Ministry of Environment. The results of statistical analysis are as followings. Rain pH was relatively high on October and January and relatively low on August, November and February. Major anion is sulfate, and it's concentration is 2.36 times higher than nitrate's, and major cations are ammonium, sodium and calcium ion. Monthly variation of sulfate and calcium concentrations are higher than the others. Ion concentration and rain pH were correlated negatively with rainfall amount. Major ions in rain samples were $SO_4^{2-}, NO_3^-, NH_4^+, Ca^{2+}$ and regression equations are proposed by multiple regression of measured data. Also, regression equation between air pollutants(T. S. P, $SO_2$) and $SO_4^{2-}, Na^+, K^+, Ca^{2+}, Mg^{2+} ions in rain samples were made. From this wer can predict rain pH.

  • PDF