• Journal of the Korean Crystal Growth and Crystal Technology
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• v.18 no.5
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• pp.184-190
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• 2008

$CaMoO_4$ crystals with ellipsoid, peanut, dumbbell, and notched sphere shapes were synthesized using a simple precipitation reaction. The morphology of $CaMoO_4$ crystals evolved from ellipsoids, through peanut-like structures and dumbbells, to notched spheres with increasing the concentration of $Ca^{2+}$ and $MoO_4^{2-}$ ions. This morphology evolution of $CaMoO_4$ crystals is attributed to a fractal mechanism. Branched crystal growth started at both ends of the ellipsoids. The peanut-like and dumbbell morphologies were formed by the first and second fractal growths, respectively. Finally, the notched spheres were formed by further fractal growth of dumbbells.

• Polymer(Korea)
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• v.39 no.3
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• pp.382-387
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• 2015

The dispersion of calcium carbonate ($CaCO_3$) in polypropylene (PP) and the effect of $CaCO_3$ size on the crystallinity of PP were studied. Polymer composite usually suffers from the brittleness when reinforced with inorganic fillers. The problem is generally related to the size and dispersion of fillers. First, the dispersion was studied for the nanosize $CaCO_3$ with 15~40 nm average diameter. To enhance the dispersibility in PP, the surface of the $CaCO_3$ was treated with sodium lignosulfonate (SLS). $CaCO_3$/PP composites were prepared via melt compounding. The $CaCO_3$ coated with more than 3 wt% SLS was uniformly distributed within the PP matrix, while the uncoated $CaCO_3$ formed aggregated structures in the PP. Even with 30 wt%, the SLS-$CaCO_3$ was well dispersed in the PP matrix. Also, the transition enthalpy of $CaCO_3$/PP increased and the full-width of half maximum of the crystallization peak decreased regardless of SLS coating and size of $CaCO_3$. However, the crystallinity of PP was more influenced by nano $CaCO_3$. These results imply that the nano $CaCO_3$ coated with SLS may reduce the brittleness of polymer composites.

• Journal of the Mineralogical Society of Korea
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• v.17 no.4
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• pp.339-355
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• 2004

Locality of domestic high-Ca limestones can be divided into three districts, i.e., (1) the Jecheon-Danyang area, (2) the Samcheok-Taebaek-Jungsun area, and (3) the Uljin-Andong area, in accordance with their geologic background and type of the deposits. Except for some crystalline limestones from the Jecheon-Danyang area, domestic high-Ca limestones were mostly recrystallized and Ca-enriched by the effects of hydrothermal alteration and/or thermal metamorphism. The lime-stones can be also divided into crystalline limestone type, marble type, micro- and mega-crystalline calcite types on the basis of their composition, crystallinity, and mineral facies. An applied-mineralogical characterization of the high-Ca limestones was done through the systematic analyses and tests for the limestones. The high-Ca limestones from the area (1), which are megascopic ally close to the original limestone in lithology, display lower whiteness, higher contents of CaO (51 ～ 54 wt.%), low crystallinity, and fine-grained texture. Two typical hydrothermal types of the high-Ca limestones from the area (2), i.e., micro- (mostly 0.2～0.3 mm) and mega-crystalline (2～15 em) calcite types, have comparatively higher whiteness and rather variable CaO contents (50～55 wt.%) with exhibiting quite different crystallinity each other. The micro-crystalline calcite type is especially dominant in this area, and has comparatively uniform crystallinity and homogeneous composition. Compared to these limestones, the high-Ca limestones from the area (3) show remarkable differences in grade and quality according to their types of deposit and occurrence. Based on these mineral characters and chemical composition, a possible scheme for industrial uses of the domestic high-Ca limestones was suggested.

• Korean Journal of Materials Research
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• v.9 no.6
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• pp.547-550
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• 1999

Optical and electrical properties of MgO-CaO films as a protective layer for AC plasma display panel were studied. When the [(CaO/(MgO+CaO)] ratio of evaporation starting materials was optimum composition, 0.1, firing voltage and memory margin of the film were 176V and 0.5, respectively. When [CaO/(CaO+MgO)] was 0, 0.1 and 0.2, memory margin was 0.39, 0.5 and 0.41, respectively, and surface roughness of films was $27.7\AA$, $21.1\AA$ and $40.3\AA$, respectively. It was thought that memory margin had a reverse-relation with surface roughness. The density of film was calculated by measuring the refractive index of film. The density of MgO film was 3.21g/㎤ and the density of film, when [CaO/(CaO+MgO)] was 0.1, was 3.632g/㎤. The mixture of MgO-CaO films showed a good transmittance property in the visual range.

• Journal of Soil and Groundwater Environment
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• v.12 no.4
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• pp.35-53
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• 2007

Geochemical and isotope studies on the groundwater system of the Youngcheon area were carried out. Most groundwaters belong to Ca-$HCO_3$ and Ca-$SO_4$ types and some groundwaters belong to Na-$HCO_3$ type. Geochemical characteristics of these groundwaters were mainly affected by their basement rocks around the boreholes. High $SO_4$ content of groundwater is the result of reaction with sulfate or sulfide minerals in the host rock. Ca was originated from the carbonate minerals in the sedimentary rock. After the groundwater was saturated with calcite, the Na-$HCO_3$ type groundwaters were evolved by the reaction with plagioclase for a relatively long residence time. This explanation was supported by low tritium contents of Na-$HCO_3$ type groundwaters. ${\delt}a^{18}O$ and ${\delta}D$ data indicate that the groundwaters are of meteoric water origin and there was no difference between the various types of waters. Grondwaters from the boreholes BH-1, BH-9 and BH-12 showed the geochemical and isotopic characteristics of deep groundwater. Most borehole groundwaters except them did not show the systematic geochemical variations with sampling depth indicating that the shallow and deep groundwaters were mixed with each other throughout the study area. The results of water quality analysis indicate that the study area is highly contaminated by the introduction of agricultural sewage.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.12 no.6
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• pp.329-334
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• 2002

The $CaTio_3$powder with perovskite structure was synthesized by mixing anatase $TiO_2$and $Ca(OH)_2$powders as starting materials, and KOH or NaOH as mineralizer, followed by hydrothermal method. The change of crystal structure, particle shape and size of the synthesized $CaTiO_3$powder was investigated with kind and concentration of mineralizer. It was found that the spherical particles of 0.7 $\mu$m were obtained when using 1N KOH and the hexahedrons particles of 3$\mu$m were obtained for the case of using 10 N KOH. With increasing KOH concentration, the particle shape was changed from sphere to hexahedrons and its size also increased. When using 1 N NaOH, the powder was consisted of 0.5~1 $\mu$m particle in size, whereas hexahedrons of 1~4 $\mu$m and whiskers more than 10$\mu$m in size was obtained for the 10 N NaOH solution. With increasing NaOH concentration, the particle shape was varied from hexahedrons to whiskers, showing the similar result with the KOH case. It was confirmed from EDS analysis that Na element, which was detected in hexahedrones was not contained in the whiskers.

• Journal of the Mineralogical Society of Korea
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• v.17 no.1
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• pp.61-73
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• 2004

The purposes of this study are to investigate the occurrence, the hydrochemical characteristics and the origin of the $CO_2$-rich springs from the Kangwon Province, and to reanalyze the previous studied results of other researchers. The $CO_2$-rich water samples were collected at 13 locations in the Kangwon Province. The $CO_2$-rich water shows a high $CO_2$ concentration ($P_{CO2}$ 0.787 to 4.78 atm), weak acidic pHs, electrical conductivity values ranging from 422 to 2,280 $\mu$S/cm, and high Fe and F contents. The chemical compositions of $CO_2$-rich water from this study area are classified into three types; $Ca-HCO_3$, Ca(Na)-$HCO_3$, $Na-HCO_3$ types. The chemical data of $CO_2$-rich waters and their host rocks indicate that $Na-HCO_3$ type water are mainly influenced by biotite, K-feldspar granite, and Ca(Na)-HC $O_3$, type water is chiefly influenced by gneiss and carbonate minerals in granite. F and Fe contents of $CO_2$-rich waters are abundant in $Na-HCO_3$, and $Ca-HCO_3$ types, respectively. The results of this study suggest that the chemical composition $CO_2$-rich water is mainly controlled by the mineralogical composition of aquifer host rocks. Oxygen and deuterium isotope data indicate that $CO_2$-rich water is meteoric origin. The $\delta^{13}$C values (-0.3$\textperthousand$ to -6.2$\textperthousand$ PDB) suggest that dissolved carbonates are mainly derived from a deep-seated $CO_2$ and partly from carbonate minerals.

• KIISE Transactions on Computing Practices
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• v.22 no.8
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• pp.393-398
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• 2016

Collective Adaptive System is an adaptive multi-agent system which accomplishes its goal by collaborating various agents. Because the collective property of the Collective Adaptive System is accomplished by the goal of the system being based on collaboration, testing the goal accomplishment and their interactions among heterogeneous agents is important. This paper presents a feasibility study of applying a model-based testing approach using task-based test model to a Collective Adaptive System. This paper describes additional information to be applied for Collective Adaptive System for future studies. To analyze our approach, we applied the proposed approach to a smart home system as a case study; our results indicated that we can systematically derive test cases to check whether the Collective Adaptive System successfully achieved its goals by modifying and extending the existing task model.

• Journal of Conservation Science
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• v.23
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• pp.11-24
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• 2008

A physical characteristics and chemical compositions change by weathering on the granite were examined for the conservation treatment of the Mireuksaji temple stone pagoda. The natural weathered granite was collected from the Mt. Mireuk, and divided into the classification standards based on weathering degrees and strength measured by rock-test hammer. The results from comparison of the strength measured by undestructive rock-test hammer and the strength values converted from ultrasonic velocity showed that each strength measurement value was proportionate. The water absorption of the sample was 1.68 to 0.20%. The F-type of fresh rock was not naturally saturated and the WW-type was naturally saturated but took quite a long time. The water absorption was increased gradually in order of SW-type, the MW-type and the HW-type according to weathering condition. The CW-type samples showed the highest water absorption among the weathered classification samples. Through dyeing test, it was found out that only the feldspar was dyed out of the F-type and the WW-type. The SW-type and the MW-type were distinguished by the fact that plagioclase being dyed. And dyed area was expanded to quartz crack in HW-type and CW-type. Physical change by weathering of the rock-forming minerals could be classified with 3 grades. Through the XRD analysis, albite among the rock-forming mineral showed remarkable decrease. SEM-EDX analysis of the component change in the rock-forming minerals such as biotite, plagioclase, and orthoclase, showed that in case of highly-weathered grade samples compared with fresh samples, contents of the $Al_2O_3$, $K_2O$, $Na_2O$ increase and CaO, MgO decrease in the biotite, the CaO, $K_2O$ increase and $Na_2O$ decrease in the plagioclase, the $Al_2O_3$ a little increase and $K_2O$, $Na_2O$ decrease in the orthoclase. The results of extracted cation analysis using the powder samples of each weathering grade, the CaO, $Na_2O$, $K_2O$ and MgO are highly chemical variations in rock forming minerals and positive variation show high in the weathering grade of the WW-type and CW-type. This research will be used as an importance data to establish a plan for conservation treatment of composed stone in the Mireuksaji temple stone pagoda.

• Journal of the Korean Society of Groundwater Environment
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• v.6 no.3
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• pp.140-151
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• 1999

Groundwater samples from the southern area composed of andesitic rocks and the northwestern area composed of granite in Pusan city, have been collected and analyzed. According to the Piper diagram. groundwater in the southern area belongs to Ca$\^$2＋/－HCO$_3$$\^$－/ and Ca$\^$2＋/－(Cl$\^$－/＋SO$_4$$\^$2－/) types, and that in the northwestern area mostly belongs to Ca$\^$2＋/－HCO$_3$$\^$－/ type and partly Na$\^$＋/－HCO$_3$$\^$－/ type. Two factors (factor 1 and factor 2) were obtained from the result of the factor analysis in the southern area. Factor 1, consisting of Mg$\^$2＋/, Ca$\^$2＋/, Cl$\^$－/, SO$_4$$\^$2－/, NH$_4$$\^$＋/, EC and NO$_3$$\^$－/ is represented by the dissolution of Ca-plagioclase and calcite, and the influence of anthropogenic sources. Factor 2, consisting of K$\^$＋/, Na$\^$＋/. SiO$_2$, SO$_4$$\^$2－/, and HCO$_3$$\^$－/ is mainly represented by the dissolution of feldspar. Three factors were obtained from the result of the factor analysis in the northwestern area Factor 1, consisting of Na$\^$＋/, K$\^$＋/, NH$_4$$\^$＋/, Cl$\^$－/, SO$_4$$\^$2－/ and NO$_3$$\^$－/ explains dissolution of plagioclase and mica, the influence of anthropogenic sources and salt water. Factor 2, consisting of Ca$\^$2＋/ and HCO$_3$$\^$－/ explains the dissolution of Ca-plagioclase. Factor 3, consisting of Mg$\^$2＋/ and SiO$_2$, explains the dissolution of silicate minces. and contaminants. Based on the phase stability diagrams, groundwater both in the southern and in the northwestern area is mostly in equilibrium with kaolinite. Cl$\^$－/ with respect to Na$\^$＋/, Ca$\^$2＋/, Mg$\^$2＋/, K$\^$＋/, SO$_4$$\^$2－/ and HCO$_3$$\^$－/ indicates that both the northwestern area and the southern area are influenced by the salt water.