• Title/Summary/Keyword: Ca-형

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Occurrence and Chemical Composition of Carbonate Mineral from Wallrock Alteration Zone of Janggun Pb-Zn Deposit (장군 연-아연 광상의 모암변질대내 탄산염 광물의 산상 및 화학조성)

  • Bong Chul Yoo
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.3
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    • pp.167-183
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    • 2023
  • The Janggun Pb-Zn deposit consists of Mn orebody, Pb-Zn orebody and Fe orebody. The Mn orebody composed of manganese carbonate orebody and manganese oxide orebody on the basis of their mineralogy and genesis. The geology of this deposit consists of Precambrian Weonnam formation, Yulri group, Paleozoic Jangsan formation, Dueumri formation, Janggum limestone formation, Dongsugok formation, Jaesan formation and Mesozoic Dongwhachi formation and Chungyang granite. This manganese carbonate orebody is hydrothermal replacement orebody formed by reaction of lead and zinc-bearing hydrothermal fluid and Paleozoic Janggum limestone formation. The wallrock alteration that is remarkably recognized with Pb-Zn mineralization at this hydrothermal replacement orebody consists of mainly rhodochrositization with minor of dolomitization, pyritization, sericitization and chloritization. Carbonates formed during wallrock alteration on the basis of paragenetic sequence are as followed : Ca-dolomite (Co type, wallrock) → ankerite and Ferroan ankerite (C1 type, early stage) → ankerite (C2 type) → sideroplesite (C3 type) → sideroplesite and pistomesite (C4 type, late stage). This means that Fe and Mn elements were enriched during evolution of hydrothermal fluid. Therefore, The substitution of elements during wallrock alteration beween dolomitic marble (Mg, Ca) and lead and zinc-bearing hydrothermal fluid (Fe, Mn) with paragenetic sequence is as followed : 1)Fe ↔ Mn and Mn ↔ Mg, Ca, Fe elements substitution (ankerite and Ferroan ankerite, C1 type, early stage), 2)Fe ↔ Mn, Mn ↔ Mg, Ca and Mg ↔ Ca elements substitution (ankerite, C2 type), 3)Fe ↔ Mn, Fe ↔ Ca and Mn ↔ Mg, Ca elements substitution (sideroplesite, C3 type), and 4)Fe ↔ Mg, Fe ↔ Mn and Mn ↔ Mg, Ca elements substitution (sideroplesite and pistomesite, C4 type, late stage)

Preparation of Electrolyte Membranes for Thin Manganese Batteries and Its Electrochemical Characteristics (박형 망간전지용 전해질막의 제조 및 전기화학적 특성)

  • Jeong, Soon-Ki
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.6
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    • pp.1292-1295
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    • 2006
  • Three kinds of electrolyte membranes were prepared by impregnating filter papers with one of the electrolyte solutions fur primary manganese battery ($NH_4Cl$, $ZnCl_2$, and alkaline types) and hygroscopic agent ($CaBr_2$ or $CaCl_2$), respectively. The thickness of them was $250{\sim}300{\mu}m$, and they were very flexible. The electrochemical characteristics greatly depended on the hygroscopic agent to supply water to the cell. The electrolyte membrane containing $CaCl_2$ showed the highest ionic conductivity and the largest discharge capacity.

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Occurrences and Physicochemical Properties of Japanese Bentonite Deposits (일본 벤토나이트 광상의 부존특성 및 광석의 물리화학적 특성)

  • Song Min-Sub;Koh Sang-Mo;Takagi Tetsuichi
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.3
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    • pp.245-265
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    • 2004
  • This study was to compare the geological occurrences and geneses of the Myogi, Tsukinuno, Dobuyama and Kawasaki bentonite deposits distributed in the Tertiary sedimentary basins of NE Japan, and to compare the mineralogical and physicochemical properties of their bentonites. The Japanese bentonite deposits are mainly distributed in the Green-tuff region which was formed in Neogene. The shape of ore body of the Myogi, Tsukinuno and Kawasaki deposits formed by the diagenesis are layered and stratiform. In contrast to this, the Dobuyama deposit formed by hydrothermal alteration shows the cone shape. The mineralization age of four deposits are 1.8 ~ 21 Ha from Early Miocene to Pliocene. The Dobuyama bentonite with the highest montmorillonite content shows the highest surface area, CEC, MB adsorption, and strengths. The Tsukinuno bentonite with a little high montmorillonite content is characterized by strong alkalinity, high viscosity and swelling. The Kawasaki bentonite, the Na-Ca mixed type, shows higher viscosity and swelling than the Ca-type Dobuyama bentonite. The Myogi bentonite with the lowest montmorillonite content shows the properties of low viscosity, In adsorption, strengths and a little high CEC and surface area. The high CEC and surface area of this deposit is due to the sufficient occurrence of zeolite. A strong dispersion in the Na-type bentonite and a strong flocculation in the Ca-type bentonite took place, and both the types show a slow flocculation with time. The physicochemical properties of the bentonite are mainly controlled by the montmorillonite content, interlayer cations, and impurity minerals such as zeolite. But bentonites inconsistent to this factors are sometimes occurred. This is maybe due to the crystal chemistry such as layer charge of montmorillonite and crystal morphology of montmorillonite such as aspect ratio.

Evaluation of pH and Compressive Strength Development of Alpha-Calcium Sulfate Hemihydrate-based Binder (알파형 반수석고 기반 결합재의 pH 및 강도발현 평가)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.1
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    • pp.59-65
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    • 2016
  • This study examined the compressive strength development and pH values of alpha-calcium sulfate hemihydrate(${\alpha}-CH$)-based binders developed for vegetation concrete with neutral pH between 6~7. Considering cost down and strength enhancement of the prepared binders, the ${\alpha}-CH$ was partially replaced by ground granulated blast furnace slag(GGBS), fly ash(FA), or ordinary Portland cement(OPC) by 25% and 50%. The compressive strength of mortars using 100% ${\alpha}-CH$ was 50% lower than that of 100% OPC mortars. With the increase of the replacement level of GGBS or FA, the compressive strength of ${\alpha}-CH$-based mortars tended to decrease, whereas the pH values were maintained to be 6.5~7.5. The main hydration products of ${\alpha}-CH$-based binders with GGBS or FA were a gypsum($CaSO_4$), whereas portlandite($Ca(OH)_2$) was not observed in such binders. Meanwhile, the pH values of ${\alpha}-CH$-based binders with OPC exceeded 11.5 due to the formation of $Ca(OH)_2$ phase as a hydration product. From the thermogravimetric analysis, the amount of $Ca(OH)_2$ in ${\alpha}-CH$-based binders with OPC was evaluated to be approximately 10% of the cement content.

Fabrication of Solid Electrolyte Oxygen Sensors Using $CaF_{2}$ and their Characteristics ($CaF_{2}$를 이용한 고체전해질 산소센서의 제조및 그 특성)

  • Lee, Jae-Hyun;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.3 no.2
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    • pp.40-49
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    • 1994
  • Potentiometric cell oxygen sensors using $CaF_{2}$ were fabricated for monitering the oxygen partial pressure in the low temperature range ($300^{\circ}C{\sim}$500^{\circ}C). The disk type oxygen sensors consist of a reference electrode: Air($O_{2}:21%$)|Pt, a solid electrolyte $CaF_{2}$, and a sensing metel Pt electrode. And the change in open circuit emf of the disk type cell was about 45mV for the oxygen concentration range, $0.1%{\sim}10%$, at the cell temperature of $400^{\circ}C$. Also, the reference electrode incorporated type sensor showed the change of 40mV for 0.1% to 10% oxygen partial pressure range.

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Pre-concentration of Apple Juice with Different Reverse Osmosis Membranes (역삼투막을 이용한 사과쥬스의 예비농축)

  • Kim, Kil-Hwan;Park, Hyun-Jin;Kim, Dong-Man
    • Korean Journal of Food Science and Technology
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    • v.20 no.3
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    • pp.419-425
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    • 1988
  • The clarified apple juice was pre-concentrated by reverse osmosis system as a trial for reduction of heat treating time and quality drop in concentration of the juice. The permeate fluxes through CA 865 and CA 960 membranes were higher than those of HR 95 and HR 98 membranes even at the low operating pressure. In the concentration limit depended on the membranes used, HR membranes operated at 60 bar showed $29.0^{\circ}$Brix, and the time required to reach the limit was 86 min for HR 95 and 71 min for HR 98. In cases of CA membranes run at 30 bar, the juice concentration was linearly increased without the limit, and longer time to reach the same concentration was required in comparison with HR membranes. As the juice concentration was increased, the loss of soluble solids was increased, and the average contents of soluble solids in the permeate passed through HR 95, HR 98, CA 865 and CA 960 were 1.3, 0.5, 7.5 and $2.3^{\circ}$ Brix, respectively, in the juice concentration range of 20.0 -$25.0^{\circ}$ Brix. The lower amounts of sugars, total acid and flavor volatiles were involved in the permeate through HR membranes, especially HR 98 than in the permeate through CA membranes.

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탄산수와 탄산침전물 및 침전잔류물에서의 희토류원소(REEs)의 분배 및 거동 특성

  • 최현수;고용권;윤성택;배대석
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.384-387
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    • 2004
  • 강원도 지역 탄산수에 대해 혼합에 의한 용존 희유원소의 거동특성 및 탄산염 침전물 형성에 따른 REE 분별작용을 살펴보았다. 탄산수들은 화학적으로 $Na-HCO_3형,\; Ca-Na-HCO_3형\; 및\; Ca-HCO_3$형으로 구분되며, 동위원소조성도 유형에 따라 명확히 구분되는 특징을 보인다. 지화학 및 동위원소 자료의 해석 결과, $Na-HCO_$형 탄산수는 지하심부에서 심부 기원 $CO_2$의 공급에 의해 형성된 반면, 다른 두 유형의 탄산수들은 $Na-HCO_$ 형 탄산수와 천부지하수 간의 혼합에 의해 생성되었음을 지시하였다. 탄산수 내 용존 REE 함량은 물 유형에 따라 변화하지만, ∑REE 함량은 TDS, pH, alkalinity, $\delta^{18}O$$\delta^{18}O$ 및 tritium 함량과 좋은 상관성을 보여주어, 천부 지하수와의 혼합된 특징을 나타내었다. Na-HCO$_3$형 탄산수의 용존 REE 패턴은 강한 HREE 부화를 보여주어 이른바 'S-shape'을 나타내는 반면, $Na-HCO_$ 형은 분산되어 있으며 LREE 부화를 보여주었다. $Ca-Na-HCO_3$형은 약한 HREE 분화 패턴을 보여주었다. 탄산수로부터 침전된 침전물과 침전물을 제거한 잔류물의 REE 패턴은 원 탄산수와 거의 유사한 형태를 보여주어, 탄산염 침전물과 잔류물 간의 REE 분별작용은 일어나지 않았음을 나타낸다.지 않았음을 나타낸다.

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MOnCa2: High-Level Context Reasoning Framework based on User Travel Behavior Recognition and Route Prediction for Intelligent Smartphone Applications (MOnCa2: 지능형 스마트폰 어플리케이션을 위한 사용자 이동 행위 인지와 경로 예측 기반의 고수준 콘텍스트 추론 프레임워크)

  • Kim, Je-Min;Park, Young-Tack
    • Journal of KIISE
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    • v.42 no.3
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    • pp.295-306
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    • 2015
  • MOnCa2 is a framework for building intelligent smartphone applications based on smartphone sensors and ontology reasoning. In previous studies, MOnCa determined and inferred user situations based on sensor values represented by ontology instances. When this approach is applied, recognizing user space information or objects in user surroundings is possible, whereas determining the user's physical context (travel behavior, travel destination) is impossible. In this paper, MOnCa2 is used to build recognition models for travel behavior and routes using smartphone sensors to analyze the user's physical context, infer basic context regarding the user's travel behavior and routes by adapting these models, and generate high-level context by applying ontology reasoning to the basic context for creating intelligent applications. This paper is focused on approaches that are able to recognize the user's travel behavior using smartphone accelerometers, predict personal routes and destinations using GPS signals, and infer high-level context by applying realization.