• Title/Summary/Keyword: Ca-형

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Hydrogeochemical, Stable and Noble Gas Isotopic Studies of Hot Spring Waters and Cold Groundwaters in the Seokmodo Hot Spring Area of the Ganghwa Province, South Korea (강화 석모도 지역 온천수와 지하수의 수리지구화학 및 동위원소 연구)

  • Kim, Kyu-Han;Jeong, Yun-Jeong;Jeong, Chan-Ho;Keisuke, Nagao
    • Economic and Environmental Geology
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    • v.41 no.1
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    • pp.15-32
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    • 2008
  • The hydrochemical and isotopic (stable isotopes and noble gas isotopes) analyses for hot spring waters, cold groundwaters and surface water samples from the Seokmodo hot spring area of the Ganghwa province were carried out to characterize the hydrogeochemical characteristics of thermal waters and to interpret the source of thermal water and noble gases and the geochemical evolution of hot spring waters in the Seokmodo geothermal system. The hot spring waters and groundwaters show a weakly acidic condition with the pH values ranging from 6.42 to 6.77 and 6.01 to 7.71 respectively. The outflow temperature of the Seokmodo hot spring waters ranges from $43.3^{\circ}C\;to\;68.6^{\circ}C$. Relatively high values of the electrical conductivities which fall between 60,200 and $84,300{\mu}S/cm$ indicate that the hot spring waters were mixed with seawater in the subsurface geothermal system. The chemical compositions of the Seokmodo hot spring waters are characterized by Na-Ca-Cl water type. On the other hand, cold groundwaters and surface waters can be grouped into three types such as the Na(Ca)-$HCO_3$, Na(Ca)-$SO_4$ and Ca-$HCO_3$ types. The ${\delta}^{18}O\;and\;{\delta}D$ values of hot spring waters vary from -4.41 to -4.47%o and -32.0 to -33.5%o, respectively. Cold groundwaters range from -7.07 to -8.55%o in ${\delta}^{18}O$ and from -50.24 to -59.6%o in ${\delta}D$. The oxygen and hydrogen isotopic data indicate that the hot spring waters were originated from the local meteoric water source. The enrichments of heavy isotopes ($^{18}O\;and\;^2H$) in the Seokmodo hot spring waters imply that the thermal water was derived from the diffusion Bone between fresh and salt waters. The ${\delta}^{34}S$ values ranging from 23.1 to 23.5%o of dissolved sulfate are very close to the value of sea water sulfate of ${\delta}^{34}$S=20.2%o in this area, indicating the origin of sulfate in hot springs from sea water. The $^3H/^4He$ ratio of hot spring waters varies from $1.243{\times}10^{-6}\;to\;1.299{\times}10^{-6}cm^3STP/g$, which suggests that He gas in hot spring waters was partly originated from a mantle source. Argon isotopic ratio $(^{40}Ar/^{36}Ar=298{\times}10^{-6}cm^3STP/g)$ in hot spring waters corresponds to the atmospheric value.

The vacuolar processing enzyme (VPE) mutation suppresses an HR-like cell death induced by the double knockout mutant of vacuolar Ca2+-ATPases in Arabidopsis (애기장대에서 두 액포막 칼슘펌프 돌연변이에 의하여 유도되는 세포사멸 표현형의 액포수식효소(VPE) 돌연변이에 의한 억제)

  • Park, Hyeong-Cheol;Lee, Sang-Min;Kim, Ho-Soo;Chung, Woo-Sik
    • Journal of Plant Biotechnology
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    • v.38 no.2
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    • pp.169-175
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    • 2011
  • Calcium ($Ca^{2+}$) signals have been implicated in regulating plant development and responses to the environmental stresses including a programmed cell death pathway. In animals and plants, cytosolic $Ca^{2+}$ signals have been involved in the activation of programmed cell death (PCD). Recently, we reported that disruption of Arabidopsis vacuolar $\b{A}$utoinhibited $\underline{C}a^{2+}$-$\b{A}$TPases (ACAs), ACA4 and ACA11, resulted in the activation of a salicylic acid-dependent programmed cell death pathway. Although extensive studies have revealed various components of a PCD in plants, executors to directly induce PCD are well unknown. Here, we provide that the vacuolar processing enzymes (VPEs) are involved in a PCD induced by the double knockout mutant of vacuolar $Ca^{2+}$-ATPases in Arabidopsis. The gene expression of VPE was rapidly up-regulated and the enzyme activity of VPE was increased in the double mutant plants. We also generated aca4/aca11/avpe, aca4/aca11/${\gamma}$vpe and aca4/aca11/avpe/${\gamma}$vpe mutant plants. Although cell death phenotype of the double mutant plants was not completely disappeared in the triple and quadruple mutant plants, the triple and quadruple mutant plants showed to significantly delay cell death phenotype of the double mutant plants. These results suggest that the VPE is involved in the HR-like cell death in the double mutant of vacuolar $Ca^{2+}$-ATPases in Arabidopsis.

The Properties of Underwater-Hardening Epoxy Mortar Used the Rapidly Cooled Steel Slag (RCSS) (급냉 제강슬래그를 사용한 수중 경화형 에폭시 모르타르의 특성)

  • Kim, Jin-Man;Kwak, Eun-Gu;Bae, Kee-Sun
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.549-555
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    • 2007
  • Although blast furnace slag has been widely used in concrete as a cementitious admixture or aggregate for many years, the slowly cooled steel slag is not used in concrete but mainly in road. Its use in concrete operates problem such as the lack of volume stability due to high free CaO content, which can be potentially hazardous in concrete. However, the rapidly cooled steel slag by atomization has a low free CaO content, a high density, and a spherical shape, so it is expected to use in concrete so much. This paper is to understand the probability that the rapid cooled steel slag can replace the silica sand used as aggregate in the epoxy mortar. We did the experimental study on the properties of the epoxy mortar having various replacement proportion of rapidly cooled steel slag. This study shown that increasing content of the rapidly cooled steel slag in epoxy mortar lead to increase largely the passing time of nozzle by O-lot, compressive strength and flexural strength. However except the flow is almost same level. So we understand that the rapidly cooled steel slag has positive effect on increasing of properties in epoxy mortar.

Hydration Properties of Low Carbon type Low Heat Blended Cement (무기질 자극제를 사용한 탄소배출 저감형 저발열형 혼합시멘트의 수화특성에 관한 연구)

  • Choi, Sung-Woo;Ryu, Deuk-Hyun;Kim, Hun-Sang;Kim, Gyu-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.3
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    • pp.218-226
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    • 2013
  • Of construction materials, cement and steel are the representative material that carbon dioxide. to reduce carbon emissions in the use of these materials The purpose of this study is low heat type blended cement, which is manufactured using a amount of cement than ordinary low heat blended cement. Low heat blended cement, mixing ratio of 10%, was investigated hydration properties and adiabatic temperature of concrete. The study in order to activate the reaction mineral admixture, a separate source of CaO and $SO_3$ areneeded. gypsum and lime, it expected amount of cement, low-carbon low-heat blended cement could reduce the hydration heat concrete than currentlyused low heat blended cement.

Performance Enhancement of Attitude Estimation using Adaptive Fuzzy-Kalman Filter (적응형 퍼지-칼만 필터를 이용한 자세추정 성능향상)

  • Kim, Su-Dae;Baek, Gyeong-Dong;Kim, Tae-Rim;Kim, Sung-Shin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.12
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    • pp.2511-2520
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    • 2011
  • This paper describes the parameter adjustment method of fuzzy membership function to improve the performance of multi-sensor fusion system using adaptive fuzzy-Kalman filter and cross-validation. The adaptive fuzzy-Kanlman filter has two input parameters, variation of accelerometer measurements and residual error of Kalman filter. The filter estimates system noise R and measurement noise Q, then changes the Kalman gain. To evaluate proposed adaptive fuzzy-Kalman filter, we make the two-axis AHRS(Attitude Heading Reference System) using fusion of an accelerometer and a gyro sensor. Then we verified its performance by comparing to NAV420CA-100 to be used in various fields of airborne, marine and land applications.

Characterization of Shrinkage Reducing Type Cement Carbon Dioxide-reducible CSA Synthesis (이산화탄소 저감형 CSA합성을 통한 수축저감형 시멘트의 특성 평가)

  • Cho, Yong-Kwang;Nam, Seong-Young;Kim, Chun-Sik;Cho, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.28 no.1
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    • pp.17-21
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    • 2019
  • Calcium sulfaluminate (CSA) was synthesized to improve the shrinkage of OPC. In this study, the setting time, the compressive strength and the length change ratio were confirmed by replacing the synthesized CSA with OPC by 10% and 13% by 16%. In the case of shrinkage-reducing type cement, formation of Ca-Al-$H_2$-based hydrate was activated. Therefore, the setting time was shortened. The compressive strength of the shrinkage - reducing type cement is comparable to that of OPC after 7 days' strength. However, shrinkage reducing type cement showed improved initial strength compared to OPC. The length change ratio was found to be improved by drying shrinkage from -0.075% to -0.047% on the 28th day.

Role of $^{18}F$-fluorodeoxyglucose PET/CT in Recurrent Ovary Cancer (재발 난소암의 진단에서의 $^{18}F$-fluorodeoxyglucose PET/CT의 유용성: Enhanced CT와 Tumor Marker CA 125와의 비교)

  • O, Joo-Hyun;Yoo, Ie-Ryung;Choi, Woo-Hee;Lee, Won-Hyoung;Kim, Sung-Hoon;Chung, Soo-Kyo
    • Nuclear Medicine and Molecular Imaging
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    • v.42 no.3
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    • pp.209-217
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    • 2008
  • Purpose: To date, anatomical imaging modalities of the pelvis and tumor markers have been the mainstay of surveillance for recurrent ovary cancer. This study aimed to assess the role of $^{18}F$-FDG PET/CT in evaluation of ovary cancer recurrences, especially in comparison with enhanced a and tumor marker CA 125. Materials and methods: 73 patients who had PET/CT scan for restaging of confirmed ovary cancer, and additional imaging with enhanced a of the pelvis within one month were included. CA 125 level was available in all patients. From the PET/CT images, maximum standard uptake values (SUVmax) of suspected recurrence sites were recorded. Confirmation was available through re-operation or biopsy in 26 cases, and clinical assessment with series of follow-up images in 47. Results: PET/CT had 93% sensitivity and 88% specificity for detecting recurrent ovary cancer. Enhanced a of pelvis had sensitivity and specificity of 83% and 88%, and CA 125 50% and 95%. Conclusion: PET/CT has higher sensitivity for detecting recurrent ovary cancer compared to enhanced a though the differences were not significant. PET/CT has significantly higher sensitivity than CA 125. However, the three tests all agreed in only 43% of the recurrence cases, and recurrence should be suspected when any of the tests, especially PET/CT, show positive findings.

Study on Phase Relation and Synthesis of Pyrochlore in the System of Ca-Ce-Zr-Ti-O (Ca-Ce-Zr-Ti-O System에서의 파이로클로어 합성 및 상관계에 대한 연구)

  • Chae Soo-Chun;Bae In-Kook;Jang Young-Nam;Yudintsev S.V.
    • Economic and Environmental Geology
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    • v.37 no.6 s.169
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    • pp.603-612
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    • 2004
  • Pyrochlore is known as one of the most promising materials for the immobilization of radionuclide in high level waste. This study included the synthesis, phase relation and characteristics of $pyrochlore(CaCeZr_xTi_{2-x}O_{7,\;x=0.2\~2.0)$ in the system of Ca-Ce-Zr-Ti-O. Using the CPS(Cold pressing and sintering) method, the mixtures of $CaCO3_,\;CeO_2,\;ZrO_2\;and\;TiO_2$ oxides were pressed, and sintered at $1100\~1600^{\circ}C$ for 20 hours. The optimal synthetic conditions at various compositions were differed from 1300 to $1600^{\circ}C$ Even in the optimal temperatures, pyrochlore or fluorite coexisted with minor amount of perovskite, $CeO_2\;or\;Ce_{0.75}Zr_{0.25}O_2$. It was confirmed that pyrochlore and fluorite structures were stable at $x\leq0.6\;and\;x\geq1.0$, respectively. Especially, the compositions of pyrochlore or fluorite showed non-stoichiometric compositions in that contents of Ca and Ti were more deficient and those of Zr and Ce were more excess than batch compositions with the increase of x value. These characteristics stemmed from the behavior of elements occupied at eight- and six-coordinated site, and then caused the coexistence of perovskite, $CeO_2\;or\;Ce_{0.75}Zr_{0.25}O_2$ along with pyrochlore or fluorite.

Behavior of Synthetic Layered Double Hydroxides in Soils (인공합성된 Layered Double Hydroxides의 토양중 행동)

  • Choi, Choong-Lyeal;Seo, Yong-Jin;Lee, Dong-Hoon;Kim, Jun-Hyeong;Yeou, Sang-Gak;Choi, Jyung;Park, Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.5
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    • pp.412-417
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    • 2007
  • This study was to elucidate the effects of layered double hydroxides(LDHs) application on the chemical properties of the soils along with the fate of the applied LDHs. The effects of LDHs application were compared with those of calcium carbonate widely used for the neutralization of acidic soils. Incorporation of LDHs into the soil resulted in higher pH value and $Mg^{2+}$ content in soil leachate than that of $CaCO_3$ treatment. There was no significant difference in water-soluble P content in both the treatments. However, $Al^{3+}$ and $Si^{4+}$ contents were decreased by LDHs and $CaCO_3$ treatment, even though a large amount of $Al^{3+}$ was released into soil solution with the disintegration of LDHs framework. LDHs structure in soil was gradually disintegrated from the its original layered structure under acidic condition of soil. Therefore, this study suggests that LDHs could be utilized as a carrier of functional substances to enhance the efficiency of various ago-chemicals without any ill effects on the soil environments.

A Study on Aadjustment of the Patterns, and the Correlation between the Diagnostic Tool for Climacteric and Postmenopausal Syndrome Pattern Identification (CaPSP) and Korean Medicine Doctors' Diagnosis (갱년기장애 및 폐경기 후 증후군 변증진단 도구의 변증분류 조정과 진단의 간의 진단일치도 연구)

  • Lee, In-Seon;Kim, Jong-Won;Jeon, Soo-Hyung;Chi, Gyoo-Yong;Kang, Chang-Wan
    • The Journal of Korean Obstetrics and Gynecology
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    • v.34 no.1
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    • pp.1-14
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    • 2021
  • Objectives: We studied for the adjustment of the patterns of 'The Diagnostic Tool for Climacteric and Postmenopausal Syndrome Pattern Identification (hereinafter CaPSPI)' (studyI) and the correlation between CaPSPI and Korean medicine doctors' diagnosis which was carried out without knowing the results of CaPSPI (studyII). Methods: The studyI followed the previous study method in 2018 (2018-3). The studyII was conducted from June 1, 2019 to July 10, 2020 with ◯◯ University Korean Medicine Hospital IRB's approval (2019-4). Doctors' diagnosis was conducted face-to-face with the subjects. Doctors' diagnosis was carried out based on the Kupperman's questionnaire, 'Diagnosis System of Oriental Medicine (hereinafter DSOM)' and four examinations (四診) records. The diagnosis was marked with 0 for 'no', 1 for 'somewhat', 2 for 'yes' and 3 for 'very yes'. The correlation between CaPSPI and the mean of doctors diagnostic scores were investigated statistically. Results: The studyI showed that heart-heat (心火) pattern was added. The Factor loading coefficient for heart-heat was 0.551 to 0.789, and the Cronbach's coefficient was 0.896. The studyII showed that the diagnosis (Kappa statistic) of two doctors showed statistically significant concordance (all eight patterns), with correlation of them were 0.3 or higher. And the correlation between the CaPSPI score and the mean of doctors' diagnostic score showed a statistically significant correlation, with liver qi depression (肝鬱) being the highest at 0.552 and dual deficiency of the heart-spleen (心脾兩虛) being the lowest at 0.301. Conclusions: Since the diagnosis results of CaPSPI showed a significant correlation with the diagnosis of Korean traditional medicine experts, it was believed that the CaPSPI results can be trusted and used for clinical purposes.