• 한국세라믹학회지
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• 제40권3호
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• pp.234-240
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• 2003

보통 포틀랜드 시멘트에 CSA계 팽창재를 l0 wt% 혼합한 시멘트 경화체를 MgS $O_4$. 7$H_2O$ l0 wt%로 제조된 용액에 침지시켜 물성을 측정하였다. 재령의 경과에 따라서 압축강도, 수화생성물 및 미세구조변화를 관찰한 결과 천연원료로 제조된 CSA계 팽창재［No. 6(C/(equation omitted) : 2.29, A/(equation omitted) : 0.16)]는 초기에 미세한 에트링자이트 생성 및 후기에는 $\beta$-C$_2$S의 수화 반응으로 경화체가 치밀화되어 OPC 보다 $Mg^{2＋}$, S $O_4$$^{2－}$ 이온의 확산에 대한 저항성이 증가되었다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2002년도 학술논문발표회
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• pp.7-12
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• 2002

The purpose of this study is to design and to apply the self-compaction concrete mixture to field, having not only high strength but also compensation for shrinkage without thermal crack under 4 sides outer restraint of the member. In the experimental mix, replacement ratio of limestone Powder, CSA expansive additives, and unit water were selected as parameters, using portland blast-furnace slag cement. And, bleeding test, expansibility test, hydration heat analysis were performed. As a results, when Cement is replaced with 35% limestone Powder, 6% CSA expansive additives at unit water 175kg/$m^3$, demanded performances of fresh and hardened self-compaction concrete are accomplished in the field application.

• 한국건축시공학회지
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• 제3권4호
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• pp.135-138
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• 2003

The purpose of this study was to design the self-compaction concrete mixture, having not only high strength but also compensation of shrinkage without thermal crack under 4 sides outer restraint of the member. In the experimental mix, replacement ratio of limestone Powder, CSA expansive additives, and unit water were selected as parameters, using portland blast-furnace slag cement. And, bleeding test, expansibility test, hydration heat analysis were performed. As a results, when 35% of limestone Powder, 6% CSA expansive additives are replaced at unit water 175kg/$\textrm{m}^3$, demanded performances of fresh and hardened self-compaction concrete are accomplished.

• 한국건축시공학회지
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• 제4권1호
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• pp.85-88
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• 2004

The purpose of this study was to design the self-compaction concrete mixture, having not only high strength but also compensation of shrinkage without thermal crack under 4 sides outer restraint of the member. In the experimental mix, replacement ratio of limestone Powder, CSA expansive additives, and unit water were selected as parameters, using portland blast-furnace slag cement. And, bleeding test, expansibility test. hydration heat analysis were performed. As a results, when 35% of limestone Powder, 6% CSA expansive additives are replaced at unit water 175kg/$\textrm{m}^3$, demanded performances of fresh and hardened self-compaction concrete are accomplished.

• 콘크리트학회논문집
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• 제16권3호
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• pp.369-374
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• 2004

$C_4A_3S$ 합성은 천연원료인 석회석과 산업폐기물 및 부산물인 수산화알루미늄, 이수석고를 일정혼합비로 균일하게 혼합하여 20, 400, 600, $1200^{\circ}C$에서 1시간 소성 후 급냉하여 $C_4A_3S$ 클링커를 합성하였다. 합성한 클링커를 보통 포틀랜드 시멘트에 10 wt%치환하여 수중 양생하에서 수화반응 및 물성특성을 조사하였다. $1200^{\circ}C$에서 $C_4A_3S$ 클링커가 합성됨을 X-Ray diffraction pattern으로 관찰할 수 있었다 $1200^{\circ}C$에서 소성된 시료는 급결성을 띠었으며, 압축강도는 보통 포틀랜드 시멘트보다 20~30% 정도 높게 나타났다. 주요 수화생성물은 ettringite, 수산화 칼슘이며, ettringite의 팽창으로 인하여 모르타르의 건조수축이 보통 포틀랜드 시멘트보다는 낮게 나타났다.

• 콘크리트학회논문집
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• 제12권1호
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• pp.79-88
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• 2000

Usually, the expansive additives is used to prevent the occurrence of drying shrinkage in concrete. However it may sometimes be over-added in field due to the insufficient cognition of constructor's, which may cause the serious problems in concrete structures. In this study the experiments are performed to present the expansion properties of concrete by varying the water to binder ratios, unit contents of expansive additives and curing conditions. By the results, the strength showed an increase with the addition of expansion additives from 30kg/㎥ up to 50kg/㎥, and a great decrease by contraries if the larger amount are added. Also the more the expansion additives were used, the more length change occurred in concrete. In view of the curing conditions, the concrete by air cured appeared a little expansion even the unit expansion additives increased, which showed an opposite inclination of that with standard curing. This could be explained by the less occurrence of hydration in air condition which also lead to the little expansion of concrete. Hence the expansion concrete to be cured in water or moisture condition became an especial important thing. concrete using expansive additives showed that high expansion was taken place with the rise of temperature.

• 한국세라믹학회지
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• 제42권7호
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• pp.483-489
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• 2005

For the raw materials of 3CaO$\cdot$3Al$_{2}$O$_{3}$ $\cdot$CaSO$_{4}$(CSA) clinker manufacturing, the applications of industrial wastes such as waste shell, spent oil-refining catalyst and desulfurized gypsum were examined. The c1inkerbility of the raw mix and the behaviour of formation of clinker minerals were studied and then some hydraulic properties of cements containing the clinker were also investigated. By virtue of the high reactivity of thermally decomposed raw materials, CSA clinkers were obtained at relatively low temperature of 1250$^{\circ}C$ and thus oil-refining catalysts were more desirable than aluminium hydroxide as an aluminous raw material. The expansive cement samples showed somewhat lower flow value than that of OPC, but their compressive strengths were developed earlier and higher than that of OPC due to formation of ettringite in the early hydration time, which indicated the possibility of practical use of low-cost CSA clinker using industrial wastes only.

• 한국건설순환자원학회논문집
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• 제8권4호
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• pp.404-412
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• 2020

본 연구는 무기질 재료인 Calcium sulfoaluminate(CSA), Crystalline admixture(CA) 그리고 Magnesium oxide(MgO)가 포함된 시멘트 모르타르의 물성 및 자기치유성능을 조사하였다. 자기치유성능을 분석하기 위해 모르타르 강도시험, 물투과성 실험을 실시하였으며, 다양한 균열폭 변화는 디지털 광학현미경을 사용하여 측정하였다. 자기치유를 통해 생성된 수화물에 대해서는 X-ray powder diffraction, Thermogravimetry를 통한 성분분석을 실시하였다. 분석결과 CA치환량이 증가 할수록 압축 및 휨 강도는 증가하였다. 하지만 MgO치환 시에는 오히려 CA치환량이 증가 할수록 압축 및 휨 강도는 감소하였다. 회복된 균열부에 생성된 치유물질은 Ca(OH)2, MgCO3, CaCO3으로 확인되었다. CaCO3은 균열부에 생성된 주요 치유 성분으로 나타났으며, Ca(OH)2, MgCO3보다 높은비율을 차지하고 있는 것으로 확인 되었다. 또한, 물 투과성과 균열폭 결과를 통한 최적의 배합은 CSA 8% + CA 1% + MgO 2.5%으로 나타났다.