• 한국수소및신에너지학회논문집
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• 제16권1호
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• pp.58-65
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• 2005

The $LaCrO_3$-dispersed Cr alloys for metallic interconnect of solid oxide fuel cell were prepared as a function of $LaCrO_3$ content in the range of 5 to 25 vol.% and were sintered at 1500$^{\circ}C$ under an Ar atmosphere with 5 vol.% $H_2$. The sintering and oxidation behaviors of these alloys were examined. The alloys indicated a good sinterability above 95% relative density at a given sintering condition, and their sintering densities is independent on $LaCrO_3$ content. The $LaCrO_3$ particles of the sintered alloys were concentrated on interfaces of Cr particles, and the size of the Cr particles increased with decreasing $LaCrO_3$ content, which is caused by inhibited grain growth of Cr particle by $LaCrO_3$ particle. The oxidation test showed all $LaCrO_3$-dispersed Cr alloys have good oxidation resistance as compared with pure Cr, which is attributed to presence of $LaCrO_3$ at the interface at which the oxidation reaction occurs rapidly. The Cr alloys with about 15 vol.% $LaCrO_3$ are very resistant to oxidation.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권8호
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• pp.570-576
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• 1999

$LaCrO_3$-dispersed Cr alloys for metallic interconnector of solid oxide fuel cell have been studied as function of $LaCrO_3$ content in the range of 5 to 25 vol.% in order to examine the electric conductivity, the oxidation property and the thermal expansion behavior of these alloys. The $LaCrO_3$-dispersed Cr alloys showed high electrical conductivities of $3~5\times10^4$ S/cm at room temperature, and as the $LaCrO_3$content increased the conductivity decreased slightly. During the cyclic oxidation test at $1100^{\circ}C$, the weight change of the Cr alloys decreased with increasing number of oxidation cycle except first cycle, which is attributed to the vaporization of the oxide scale. More addition of the $LaCrO_3$ content reduced also the weight change of the Cr alloys. These mean that the oxide scale formed at the surface of the Cr alloy becomes stable with increasing number of oxidation cycle and$LaCrO_3$ content. The measured thermal expansion of the Cr alloy was well fitted to that of 8 mol% $Y_2O_3$-stabilized $ZrO_2$ electrolyte. These results demonstrate that $LaCrO_3$-dispersed Cr alloy is a useful material for metallic interconnector of solid oxide fuel cell.

• 한국통신학회논문지
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• 제32권9C호
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• pp.826-833
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• 2007

본 논문에서는 CR (Cognitive Radio) 시스템의 무선 적응전송에 대한 연구 기반을 마련하기 위해 CR 시스템 환경 및 시나리오 모델을 제시하고, 제시된 시스템 환경 모델에서 CR 시스템을 위한 간섭온도 인지 기반의 적응 전송 기법을 제안한다. 제안된 CR 적응전송 기법은 CR-APC (CR-Adaptive Power Control)를 사용하여 주 사용자에게 간섭 영향을 미치지 않는 범위 내에서 CR 사용자에게 최대 전송전력을 제공하고, CR-AMC (CR-Adaptive Modulation and Coding)를 적용하여 주어진 채널 상태에서 CR 사용자에게 최적의 전송률을 보장할 수 있는 방식이다. 모의실험 결과, 제안된 CR 적응전송 기법을 사용한 경우 주 사용자에게는 간섭 영향을 거의 미치지 않아 비트오율 성능 열화가 거의 없었으며, CR 사용자에게는 주어진 채널 상태에서 최적의 전송률을 보장할 수 있음을 확인할 수 있다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 D
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• pp.1303-1305
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• 1998

In order to reduce or avoid oxidation problem at operation the interconnects in SOFCs have so far mostly been made of ceramic material. It has high chemical stability both under cathode and anode condition, relatively thermal expansion coefficient that matchs that of electrolyte material YSZ. But this material shown rather weak in the low oxygen atmosphere and thermal shock, and it has lower mechanical strength than alloys. To avoid these problems one may consider to use metals or alloys as materials for interconnects. Metallic interconnects are advantageous because of their high thermal and electronic conductivities. But it has some problems, Those are high thermal expansion and oxidation at high temperature in air. To solve these problems in the interconnection material in this study, $LaCrO_3$-dispersed Cr alloys for metallic interconnector of SOFC have been investigated as a fuction of $LaCrO_3$ content in the range of 5 to 25 vol.%. The Cr alloy were prepared by mixing Cr and $LaCrO_3$ powders in high-energy ball mill for 48h and by sintering under Ar atmosphere with 5vol.% $H_2$ for 10h at $1500^{\circ}C$. The alloys had a relative density of 95% and above. The Cr alloys in composed of two kind of small $LaCrO_3$ and large Cr particles. As the $LaCrO_3$ content increased, the Cr particle size decreased but the $LaCrO_3$ particle size remained contant. Also the oxidation tests show that the $LaCrO_3$-dispersed Cr is very resistant to oxidation in air. These results means that $LaCrO_3$-dispersed Cr is a useful material for metallic interconnect of planar SOFC.

• 한국자기학회지
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• 제9권4호
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• pp.210-216
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• 1999

본 연구에서는 e-beam evaporator를 사용하여 제조한 CoCrTa/CrNi 박막시편의 자성층 두께에 따른 부식특성과 열처리에 따른 부식특성의 변화를 알아보았다. Potentiodynamic scan을 이용하여 알아본 결과, 자성층 두께가 증가함에 따라 부식전위가 낮아지고, 부동태 전류밀도가 감소함을 알 수 있었다. XRD를 이용한 분석결과에 따르면, 이것은 자성층 두께가 증가함에 따라 (100)면보다 수소과전압이 큰 (0002)면으로 우선 성장했기 때문이다. 열처리에 따른 CoCrTa(400$\AA$) 자성박막의 부식특성 변화를 potentiodynamic scan과 accelerated corrosion chamber test를 이용하여 알아본 결과, 열처리후 박막시편의 내부식성이 우수해짐을 알 수 있었다. 이것은 열처리에 의해 자성층위에 Cr 산화물층이 형성되고, 이 산화물층이 자성층의 보호막으로 작용했기 때문이다.

• Nuclear Engineering and Technology
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• 제31권6호
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• pp.561-571
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• 1999

Microstructure and mechanical properties of five Cr-Mo steels for nuclear industry applications have been investigated. Transmission electron microscopy, energy dispersive spectrometer, differential scanning calorimeter, hardness, tensile, and impact test were used to evaluate the Cr and W effect on the microstructure and mechanical properties. Microstructures of Cr-Mo steels after tempering are classified into three types : bainitic 2.25Cr-lMo steel, martensitic Mod.9Cr-lMo, HT9M, and HT9W steels, and dual phase HT9 steel. The majority of the precipitates were found to be M$_{23}$C$_{6}$ carbides. As minor phases, fine needle-like V(C,N), spherical NbC, fine needle-like Cr-rich Cr$_2$N, and Cr-rich M$_{7}$C$_3$were also found. Addition of 2wt.% W in Cr-Mo steels retarded the formation of subgrain and dissolution of Cr$_2$N precipitates. Hardness and ultimate tensile strength increased with increasing Cr content. Though Cr content of HT9W steel was lower than that of HT9 steel, the hardness of HT9W was higher due to the higher W content. W added HT9W steel had the highest ultimate tensile strength above $600^{\circ}C$. But impact toughness of W added steel (HT9W) and high Cr steel (HT9) was low.w.w.

• 한국표면공학회지
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• 제29권6호
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• pp.847-850
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• 1996

The bi-layered films composed of Co-Cr-Ta layers and paramagnetic $Co_{67}Cr_{33}$ underlayer were deposited by suing Facing Targets Sputtering(FTS). The effects of $Co_{67}Cr_{33}$ underlayer on the crystallographic and magnetic characteristics of the Co-Cr-Ta layer deposited on the underlayer was investigated. The diffraction intensity $I_{p(002)}$ of Co-Cr-Ta layers on the $Co_{67}Cr_{33}$ layer was stronger than that of single layer and Co-Cr-Ta/Ti double layer. Therefore, the crystallinity of Co-Cr-Ta layer was imporved by the $Co_{67}Cr_{33}$ underlayer rather than Ti ones. However, te coercivity H$_{c\bot}$ of Co-Cr-Ta layers deposited on $Co_{67}Cr_{33}$ underlayer was as low as 250 Oe even at substrate temperature of $220^{\circ}C$. This H$_{c\bot}$ decrease seems to be attributed to the effect of the $Co_{67}Cr_{33}$ underlayer as well as interval time between deposition of the underlayer and the Co-Cr-Ta layer.

• 대한치과기공학회지
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• 제35권2호
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• pp.105-112
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• 2013

Purpose: This study was to analyze the castability, surface oxide characteristic of Co-Cr alloy for porcelain fused to metal crown and the bonding strength of porcelain fused to metal crown. Co-Cr and Ni-Cr alloy for porcelain fused to metal crown was used for tests of the castability and surface oxide state and shear bonding strength by various porcelain. The aim of this study was to suggest the differences of result according to Co-Cr and Ni-Cr alloy. Methods: The kinds of alloy as test specimen was Co-Cr and Ni-Cr alloy. The castability index on the alloy specimens. The surfaces of two alloys were analyzed by SEM and EDX in order to observe oxide characteristic. And the shear test was performed by MTS. Results: The castability index of Co-Cr alloy was 96.8% and Ni-Cr alloy was 94.4%. The strongest bonding strength of Co-Cr alloy was shown 67.37 MPa. Conclusion: The shear bonding strength between Co-Cr alloy and EX3 porcelain was the strongest comparing with others. And all of each alloy was indicated as same level about the castability.

• 한국주조공학회지
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• 제7권2호
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• pp.108-113
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• 1987

Al-Cr alloy with composition in the range from 1.5 wt% to 10 wt% Cr were rapidly solidified from the melt by the single roller method. The supersaturated solid solution was obtained up to 6 wt% Cr in Al-Cr alloy for $20{\mu}m$ thickness. Lattice parameter decreased with increasing Cr content at the rate of 0.00456A per wt% Cr up to 6 wt% Cr. Microhardness increased with increasing Cr content at the rate of $10\;Kg/mm^2$ per wt% Cr up to 6 wt% Cr. Microhardness measurements on the Al-6 wt% Cr supersaturated solid solution annealed isothermally showed no sign of age hardening. Decomposition temperature, determined by lattice parameter changes and microhardness changes, was $470^{\circ}C$ for Al-6 wt% Cr supersaturated solid solution. Transmission electron microscopy showed that decomposition within one hour below $400^{\circ}C$ occurred at grain boundaries only, and also the additional decomposition within grains being evident at $450^{\circ}C$ The coarse precipitate structure showed at $500^{\circ}C$ and $550^{\circ}C$, respectively. The coarse precipitate structure is considered $Al_7Cr$.

• Nuclear Engineering and Technology
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• 제55권10호
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• pp.3535-3542
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• 2023

Eutectic reactions of five kinds of Cr-coated Zr alloy cladding with different base materials (Zr-Nb-Sn alloy or Zr-Nb alloy), different coating thicknesses (6~22.5 mm), and different coating materials (Cr single layer or Cr/CrN bilayer) were studied using Differential Scanning Calorimetry (DSC). The DSC experiments demonstrated that the onset temperatures of the Cr single layer coated specimens were almost identical to ~1308 ℃, regardless of base materials or coating thicknesses. This study demonstrated that the Cr/CrN bilayer coated Zr-Nb-Sn alloy has a slightly (~10 ℃) higher eutectic onset temperature compared to the single Cr-coated specimen. The eutectic region characterized by post-eutectic microstructure proportionally increases with coating thickness. The post-eutectic characterization with different holding times at high temperature (1310-1330 ℃) reveals that progression of Zr-Cr eutectic requires time, and it dramatically changed with exposure time and temperature. The practical value of the time gain in non-instantaneous eutectic formation in terms of safety margin, however, seems to be limited.