• Journal of Environmental Impact Assessment
• /
• v.23 no.4
• /
• pp.285-295
• /
• 2014

In this study, we analyzed probability distribution of EMCs (Event Mean Concentration) of COD, TOC, T-N, T-P and SS from rice paddy fields and compared the mean values of observed EMCs and the median values of estimated EMCs ($EMC_{50}$) through probability distribution. The field monitoring was conducted during a period of four crop-years (from May 1, 2008, to September 30. 2011) in a rice cultivation area located in Emda-myun, Hampyeong gun, Jeollanam-do, Korea. Four probability distributions such as Normal, Log-normal, Gamma, and Weibull distribution were used to fit values of EMCs from rice paddy fields. Our results showed that the applicable probability distributions were Normal, Log-normal, and Gamma distribution for COD, and Normal, Log- Normal, Gamma and Weibull distribution for T-N, and Log-normal, Gamma and Weibull distribution for T-P and TOC, and Log-normal and Gamma distribution for SS. Log-normal and Gamma distributions were acceptable for EMCs of all water quality constituents(COD, TOC, T-N, T-P and SS). Meanwhile, mean value of observed COD was similar to median value estimated by the gamma distribution, and TOC, T-N, T-P, and SS were similar to median value estimated by log-normal distribution, respectively.

• Journal of Korean Society on Water Environment
• /
• v.29 no.5
• /
• pp.618-624
• /
• 2013

This study was conducted to suggest the concentration distribution of organic matters in 348 tributaries of Nakdong River, and to review the validity of the conversion of organic matter indexes. The average concentration of organic matters in the tributaries was TOC 2.4 mgC/L, DOC 2.1 mgC/L, COD 1.0 mgC/L, respectively. DOC ratio to TOC is 87% and COD ratio is 44%. First tributaries shows higher organic pollution than second tributaries. The correlation between TOC and COD was relatively high as 0.796 (p < 0.01, n = 670). Based upon these results, a regression analysis was conducted. The results showed that TOC concentration was 2.5 times higher than COD concentration. In conclusion, it is appropriate to use TOC for the management of all organic matters. Furthermore, there is a need to build organic matter-related Databases for more rivers so as to establish TOC standards and manage the water quality.

• Journal of the Korean Ceramic Society
• /
• v.33 no.5
• /
• pp.602-615
• /
• 1996

The purpose of the present study is to investigate the microstructural effect on the R-curve behavior in three aluminas with different grain size distributions by analyzing the bridging stress distribution. The crack opening displacement (COD) according to the distance behind the stationary crack tip was measured using an in situ SEM fracture method. The measured COD values in the fine-grained alumina agreed well with Wiederhorn's sollution while they deviated from Wiederhorn's solution in the two coarse-grained aluminas because of the increase of the crack closure due to the grain interface bridging in the crack wake. A numerical fitting procedure was conducted by the introduction of the power-law relation and the current theoretical model together with the measured COD's in order to obtain the bridging stress distribution. The results indicated that the bridging stress function and the R-curve computed by the current model were consistent with those computed by the power-law relation providing a reliable evidence for the bridging stress analysis of the current model. The strain-softening exponent in the power-law relation n, was calculated to be in the range from 2 to 3 and was closely related to the grain size distribution. Thus it was concluded from the current theoretical model that the grain size distribution affected greatly the bridging stress distribution thereby resulting in the quantitative analysis of microfracture of polycrystalline aluminas through correlating the local-fracture-cont-rolling microstructure.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.26 no.2
• /
• pp.82-95
• /
• 2021

We investigated the temporal and spatial distribution characteristics of chemical oxygen demand (COD) and total organic carbon (TOC) in all 13 locations of Masan Bay from February to November in 2015. The COD and TOC contents were high during the June-August period when the pollution load increased. In particular, the concentrations of COD and TOC were about twice as high in the surface water as in the bottom water. In spatial distribution, the COD and TOC concentrations at the inner bay were about twice as high as those of the outer bay in Masan Bay. As a result of estimating the oxidation efficiency of COD from the surface layer of Masan Bay in 2015 based on the theoretical oxygen demand (TOD), it was at the level of about 23%. Due to the low oxidation efficiency of COD, there is a risk that the organic matter in Masan Bay will be somewhat underestimated. Therefore, for quantitative analysis of organic matter, COD and TOC analyses need to be combined.

• Journal of Environmental Science International
• /
• v.16 no.12
• /
• pp.1369-1382
• /
• 2007

To find proper water quality management strategy for oxygen consumption organic matters in Jinhae bay, the physical process and net supply/decomposition in terms of COD was estimated by three-dimensional eco-hydrodynamic modeling. The estimation results of physical process in terms of COD showed that transportation of COD was dominant in loading area from land to sea, while accumulation of COD was dominant in $middle{\sim}bottom$ level. In case of surface level, the net supply rate of COD was $0{\sim}60\;mg/m^2/day$. The net decomposition rate of COD was $0{\sim}-0.05\;mg/m^2/day$($-5{\sim}-10$ m, in depth) to 2 level, and $-0.05{\sim}-0.20\;mg/m^2/day(10m{\sim})$ to bottom level. These results indicate that the biological decomposition and physical accumulation of COD are occurred for the most part of Jinhae Bay bottom. The variation of net supply or net decomposition rate of COD as reducing land based input loading is also remarkable. Therefore, it is important to consider both allochthonous and autochthonous oxygen demanding organic matters to improve the water quality of Jinhae Bay.

• Journal of Environmental Science International
• /
• v.14 no.9
• /
• pp.835-842
• /
• 2005

The three-dimensional eco-hydrodynamic model was applied to estimate the physical process in terms of COD (chemical oxygen demand) and net supply(or decomposition) rate of COD in Kamak Bay to find proper management plan for oxygen demanding organic matters. The estimation results of the physical process in terms of COD showed that transportation of COD is dominant in surface level while accumulation of COD is dominant in bottom level. In the case of surface level, the net supply rate of COD was 0 -0.50 mg/m2/day. The net decomposition rate of COD was 0 -0.04 mg/m2/day in middle level(3 -6m) and 0.05 -0.1 5 mg/m2/day in bottom level(6m -bottom). These results indicates that the biological decomposition and physical accumulation of COD are occurred predominantly at the northern part of bottom level. Therefore, it is important to consider both allochthonous and autochthonous oxygen demanding organic matters in the region.

• Membrane and Water Treatment
• /
• v.6 no.4
• /
• pp.263-276
• /
• 2015

This paper deals with the influence of chemical oxygen demand to nitrogen ratio ((COD/N) ratio) on the performance of an membrane bioreactor. We aim at establishing relations between COD/N ratio, organisms' distribution and sludge properties (specific resistance to filtration (SRF) and membrane fouling). It is also essential to define new criteria to characterize the autotrophic microorganisms, as the measurements of apparent removal rates of ammonium seem irrelevant to characterize their specific activity. Two experiments (A and B) have been carried on a 30 L lab scale membrane bioreactor with low COD/N ratio (2.3 and 1.5). The obtained results clearly indicate the role of the COD/N ratio on the biomass distribution and performance of the membrane bioreactor. New specific criteria for characterising the autotrophic microorganisms activity, is also defined as the ratio of maximum ammonium rate to the specific oxygen uptake rate in the endogenous state for autotrophic bacteria which seem to be constant whatever the operating conditions are. They are about 24.5 to 23.8 $gN-NH_4{^+}/gO_2$, for run A and B, respectively. Moreover, the filterability of the biological suspension appear significantly lower, specific resistance to filtration and membrane fouling rate are less than $10^{14}m^{-2}$ and $0.07\;10^{12}m^{-1}.d^{-1}$ respectively, than in conventional MBR confirming the adv < antage of the membrane bioreactor functioning under low COD/N ratio.

• Journal of environmental and Sanitary engineering
• /
• v.13 no.2
• /
• pp.106-114
• /
• 1998

This study was carried out for the purpose of industrial reuse of effluent released from activated sludge unit by $\gamma $-ray irradiation technique. The dissolved organic carbon in the effluent of an activated sludge unit is mostly refractory or inert material which are difficult to be degraded by micro organism. The effluent generated from activated sludge unit was irradiated with Co$^{60}$ $\gamma $-ray under condition of air bubbling. The effects of irradiation on the pH, COD, TOC, color, molecular weight distribution were investigated by membrane filtration and u.v.-spectrum analysis. With increasing dose, the TOC was decreased smoothly. The COD was increased at lower dose, while the COD was decreased at higher dose. The TOC and COD, however, were decreased smoothly when TiO$_{2}$ was added to the solution. It was thought that the differential decreasing trend of COD and TOC in according to the absence or presence of TiO$_{2}$ was due to the molecular weight distribution shifted from group of higher molecular weight to group of lower one which are more easy to be decomposed. The removal efficiency of color was 71.5% and it was increased to 85.7% when TiO$_{2}$ was added to the solution. The $\gamma $-ray irradiation was effective on the production of chlorine.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.51 no.2
• /
• pp.171-178
• /
• 2015

Selectivity and by-catch are the main features used to define fish catch for fisheries management or to determine fishing gear efficiency. A fish girth distribution analysis was carried out to determine the retention rate of juveniles discarded and to establish common selectivity for a multispecies catch. Total body length, body weight, and girth of juvenile fish retained in the cod-end and cover net separately were collected using an 18-mm mesh cover net during 12 fishing trials with a 41-mm cod-end beam trawl. The by-catch weight ratio in the cod-end was twice that of the by-catch ratio in number. The 50% selectivity of body length and 50% girth of redfin velvet fish were not significantly different between the cod-end and cover net, whereas those of other fish species were significantly different between the cod-end and cover net. The difference in 50% selectivity girth of other fish between the cod-end and cover net was similar between cod-end mesh size and cover net mesh size. Furthermore, the difference in 50% body length selectivity of other fish between the cod-end and cover net was almost double the difference in girth. Girth selectivity in a multispecies catch using towed fishing gear was effectively used to determine fish and net mesh size.

• Journal of Environmental Science International
• /
• v.12 no.3
• /
• pp.307-317
• /
• 2003

In this study, the material cycle model was applied to suggest alternative management of water quality for Jeju Harbor. The distribution of COD, DIN (dissolved inorganic nitrogen) and DIP (dissolved inorganic phosphorus) concentrations was reasonably reproduced by simulations on the model area of the Jeju Harbor using a material cycle model. The simulations of COD, DIN and DIP concentrations were performed under the conditions of 20∼100% pollution loadings reductions from pollution sources. In case of the 100% reduction of the input loads from Sanzi river, concentrations of COD, DM and DIP were reduced to 39%, 78% and 52%, respectively at Jeju harbor. In contrast, in case of the pollutant loadings reductions from sediment, the effect of DIN and DIP reduction relatively seemed to increase around the center of study area. The 95% reduction of the pollutant loadings from river and sediment is required to meet the COD and nutrients concentration of second grade of ocean water quality criteria.