• Proceedings of the Korea Water Resources Association Conference
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• 2008.05a
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• pp.505-509
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• 2008

우리나라의 최근에 개발된 신도시나 신시가지를 제외한 대부분이 합류식 하수관망으로 구성되어 있다. 이에 따른 초기강우시 도시 인접하천으로 유입되는 유출수가 수질오염을 가중시키고 있다. 분류식 하수관이 설치된 지역이라도 강우에 의해 도시지역 노면에서 우수관을 통해 하천으로 배출되며 유출수 자체도 오염물질 농도가 높고 유해물질까지 함유하고 있는 경우가 많다. 그러므로 도시하천에 대한 종합적인 수질관리를 위해서는 점오염원뿐만 아니라 초기강우시 도시 유출수의 수질 및 오탁부하량 등 비점오염원에 대한 기초조사 및 해석이 선행되어야 한다고 판단된다. 따라서, 이 연구에서는 도시하천의 초기강우에 의한 유출수의 수질특성을 분석하기 위하여 홍제천, 중랑천, 남가좌배수구역 및 군자배수구역 등 4개 도시유역에서 직접 시료를 채취하여 각 수질항목에 대하여 분석하였다. 수질분석은 환경오염공정시험법이나 표준시험법에 준하였고, 현장에서 실측이 가능한 항목들은 현장에서 측정하였으며, 나머지 항목은 시료를 즉시 실험실로 운반하여 분석하였다. 홍제천은 1996년 8월부터 1997년 9월까지 5개 강우사상의 자료를 분석하였고, 중랑천은 2001년 5월부터 2005년 4월까지 7개 강우사상, 남가좌배수구역은 1995년 7월에서 1997년 9월까지 5개 강우사상, 그리고 군자배수구역은 2005년 4월부터 2007년 9월까지 11개 강우사상에 걸쳐 수질분석을 실시하였다. 분석된 수질자료를 이용하여 도시지역의 초기강우에 의한 초기유출수와 수질의 관계를 분석 비교 하였으며, 또한, 초기유출수에 따른 비점오염원별 상관성을 분석하여 유량 측정을 통하여 보다 손쉽게 총 오염부하량을 산출 할 수 있도록 비유량과 SS, $BOD_5$, COD 등의 수질성분간의 상관계수와 회귀식을 도출하여 이들 상관식으로부터 유량변화에 따른 수질성분의 예측에 활용토록 하였다. 그러나, 외삽구간의 유량에 대한 수질 예측 결과에는 큰 오차가 있을 수 있으므로, 보다 다양한 유량에 대한 수질관측자료로 보완된 상관식의 개발로 극복되어질 수 있을 것으로 판단된다. 이 연구의 성과는 도시유출에서 수질과의 상관성과 도시하천의 유량 수질관리에 유용한 자료로 활용될 수 있을 것으로 판단된다.

• Korean Journal of Ecology and Environment
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• v.39 no.1 s.115
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• pp.73-84
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• 2006

The objective of this study was to analyze long-term temporal trends of water chemistry and spatial heterogeneity for 10 sampling sites of the Yeongsan River watershed using water quality dataset during 1995 to 2004 (obtained from the Ministry of Environment, Korea). The water quality, based on multi-parameters of biological oxygen demand (BOD), chemical oxygen demand (COD), conductivity, dissolved oxygen (Do), total phosphorus (TP), total nitrogen (TN) and total suspended solids (TSS), largely varied depending on the sampling sites, seasons and years. Largest seasonal variabilities in most parameters occurred during the two months of July to August and these were closely associated with large spate of summmer monsoon rain. Conductivity, used as a key indicator for a ionic dilution during rainy season, and nutrients of TN and TP had an inverse function of precipitation (absolute r values> 0.32, P< 0.01, n= 119), whereas BOD and COD had no significant relations(P> 0.05, n= 119) with rainfall. Minimum values in conductivity, TN, and TP were observed during the summer monsoon, indicating an ionic and nutrient dilution of river water by the rainwater. In contrast, major inputs of total suspended solids (TSS) occurred during the period of summer monsoon. BOD values varied with seasons and the values was closely associated (r=0.592: P< 0.01) with COD, while variations of TN were had high correlations (r=0.529 : P< 0.01) with TP. Seasonal fluctuations of DO showed that maximum values were in the cold winter season and minimum values were in the summer seasons, indicating an inverse relation with water temperature. The spatial trend analyses of TP, TN, BOD, COD and TSS, except for conductivity, showed that the values were greater in the mid-river reach than in the headwater and down-river reaches. Conductivity was greater in the down-river sites than any other sites. Overall data of BOD, COD, and nutrients (TN, TP) showed that water quality was worst in the Site 4, compared to those of others sites. This was due to continuous effluents from the wastewater treatment plants within the urban area of Gwangju city. Based on the overall dataset, efficient water quality management is required in the urban area for better water quality.

• Journal of Korean Society on Water Environment
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• v.20 no.6
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• pp.631-640
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• 2004

This research was conducted to understand the magnitude and nature of the stormwater emissions with the goal of quantifying stormwater pollutant concentrations and mass emission rates of pollutants. Eight highway sites in Southern California area were monitored for three years with collecting of grab and flow-weighted composite samples, rainfall and runoff flow. Generally the EMCs cannot be determined by simple statistical averaging of measured pollutant concentrations because of random characteristics of runoff quality and quantity. Therefore, this manuscripts will show a new EMC determination method. The EMC ranges of 95% confidence intervals are 102.78-216.37mg/L for TSS, 104.53-251.79mg/L for COD, 5.42-10.58mg/L for oil & grease and 2.42-10.18mg/L for TKN. The ranges of washed-off mass loading are determined to $0.06g/m^2-17.27g/m^2$ for TSS and $0.1-3.23g/m^2$for COD.

• Journal of Animal Science and Technology
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• v.49 no.1
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• pp.137-146
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• 2007

This study was conducted to determine fertilizer nutrient and pollutant production of Holstein dairy cattle by estimating manure characteristics. The moisture content of feces was 83.9% and 95.1% for urine. The pH of feces and urine were in the ranges of 7.0～7.4 and 7.5～7.8, respectively. The average BOD5, COD, SS, T-N, T-P concentrations of the dairy feces were 18,294, 52,765, 102,889, 2,575, and 457mg/ℓ, respectively. Dairy urine showed lower levels of BOD5(5,455mg/ℓ), COD(8,089mg/ℓ), SS(593mg/ℓ), T-N(3,401mg/l), and T-P(13mg/ℓ) than feces. The total daily produced pollutant amounts of a dairy cow were 924.1g(Milking cow), 538.8g(Dry cow), 284.4g(Heifer) of BOD5, 2,336.5g (Milking cow), 1,651.8g(Dry cow), 734.1g(Heifer) of COD and 4,210.1g(Milking cow), 2,417.1g(Dry cow), 1,629.1g(Heifer) of SS and 194.8g(Milking cow), 96.4g(Dry cow), 58.3g(Heifer) of T-N and 24.0g(Milking cow), 10.2g(Dry cow), 6.1g(Heifer) of T-P. The calculated amount of pollutants produced by a 450kg dairy cow for one year were 181.3kg of BOD5, 492.5kg of COD, 899.9kg of SS, 36.0kg of T-N and 4.1kg of T-P. The total yearly estimated pollutant production from all head(497,261) of dairy cattle in Korea is 90,149 tons of BOD5, 244,890 tons of COD, 447,491 tons of SS, 17,898 tons of T-N and 2,008 tons of T-P. The fertilizer nutrient concentrations of dairy feces was 0.26% N, 0.1% P2O5 and 0.14% K2O. Urine was found to contain 0.34% N, 0.003% of P2O5 and 0.31% K2O. The total daily fertilizer nutrients produced by dairy cattle were 197.4g (Milking cow), 97.4g(Dry cow), and 57.9g(Heifer) of Nitrogen, 54.2g(Milking cow), 22.2g(Dry cow), and 14.2g(Heifer) of P2O5 and 110.8g(Milking cow), 80.4g (Dry cow), and 39.5g(Heifer) of K2O. The total yearly estimated fertilizer nutrient produced by a 450kg dairy animal is 36.2kg of N, 8.8kg of P2O5, 24.6kg of K2O. The estimated yearly fertilizer nutrient production from all dairy cattle in Korea is 18,000 tons of N, 4,397 tons of P2O5, 12,206 tons of K2O. Dairy manure contains useful trace minerals for crops, such as CaO and MgO, which are contained in similar levels to commercial compost being sold in the domestic market. Concentrations of harmful trace minerals, such as As, Cd, Hg, Pb, Cr, Cu, Ni, Zn, met the Korea compost standard regulations, with some of these minerals being in undetected amounts.

• Journal of the Korean Society for Marine Environment & Energy
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• v.14 no.1
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• pp.40-50
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• 2011

We study the characteristic and total flux of non-point pollutants such as total suspended solids (TSS), chemical oxygen demand (COD), dissolved nutrients, total phosphorus (TP) and total nitrogen (TN) in the storm water runoff from urban streams and sewer outlets of Banweol Industrial Complex around Shihwa Lake. The concentrations of non-point pollutants were generally increased with increasing of the duration and intensity of rainfall. Mean TSS concentration of Ansan stream was higher than that of sewer outlets but mean concentrations of COD, TP and TN were approximately 2~5 times higher of sewer outlet than of urban stream. TSS showed statistically positive relationships with COD and TP but it had negative correlation with dissolved nutrients. There was a significant correlation between total flux of non-point pollutants in the storm water runoff and total basin area of each sewer outlet, showing that the highest runoff flux was observed at 3rd sewer outlet which represents the largest basin area from Banweol industrial complex. Total runoff fluxes for TSS, COD, TP and TN in this study were 187,536 kg, 17,118 kg, 922 kg, 13,519 kg, respectively. Given the basin area of sewer outlet in Banweol industrial complex which corresponds only 3% from total catchment area around Shihwa Lake, enormous amount of non-point pollutants will be entered into Shihwa Lake without any treatment. It is necessary to manage and reduce of various non-point sources and pollutants because the runoff of nonpoint pollutants during storm events should be deteriorating the water quality of Shihwa Lake. Our results provides useful informations on the development of best managements practices (BMPs) for effective implementation of total pollution loads management system of Shihwa Lake.

• Journal of Wetlands Research
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• v.11 no.3
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• pp.145-151
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• 2009

Recently the water quality management policy has been changed from managing the point source to controlling the nonpoint sources (NPSs) because of TMDL program. Most NPSs are accumulated on the surface during dry periods. These accumulated pollutants are washed-off during a storm event and highly impairing the water quality of the receiving water bodies. Usually NPS has high uncertainty and is hard to control because of the variability of the rainfall and watershed characteristics. Also, NPS is derived from various land uses. The Ministry of Environment (MOE) is studying and monitoring the pollutant loads from each land use since 2007 to determine the unit pollutant loads. This research was a part of long-term monitoring program conducted to characterize the washoff and provide the mean EMC of artificial grassland. The average EMCs result of BOD, COD, DOC, SS, TN, NH4-N, NO3-N, TP, and PO4-P of the artificial grassland were deterined to 8.2, 17.5, 11.3, 110.1, 3.07, 0.20, 0.75, 0.86 and 0.08 mg/L, respectively. The results of statistical analysis conducted showed a low correlation to the contaminants.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.457-457
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• 2021

인공습지는 자연이 가진 정화기작을 인위적으로 증가시키기 위하여 조성한 자연기반해법에 해당한다. 인공습지는 습지 내 식물, 미생물, 토양 등의 상호기작에 의하여 오염물질이 제거된다. 인공습지의 오염물질저감효율은 시설의 규모와 유량, 유입물질의 부하량 수리학적 부하량, 체류시간 등의 영향을 받게 된다. 일반적으로 인공습지 적정 규모는 유역 및 기상인자의 특성과 조성목적에 고려하여 산정된다. 본 연구는 전국 35개 지역에 설치된 54개 인공습지를 선정하여 모니터링을 수행하였으며, 2011년부터 2018년에 설치된 시설이다. 54개 시설 중 도심지역에 13개, 농업지역 25개, 공업지역 3개, 상업지역 3개, 축산 10개가 설치되어있다. 습지형태는 Cell형 자유수면형 인공습지(Free Water Surface, Cell-FWS), 유로형(Flow) 자유수면형 인공습지(Cell-FWS), Cell과 Flow형이 결합된 Hybrid-FWS, 수직흐름형 인공습지(vertical flow constructed wetland)와 수평지하흐름형 인공습지(vertical flow constructed wetland)가 결합된 HYBIRD 형 습지로 구분된다. 연구결과, 일반적으로 SA/CA 비율이 클수록 오염물질의 저감효율은 증가하는 것으로 나타났다. 오염 물질별 인공습지 규모를 비교할 경우 저감효율 60%에서 인공습지의 규모는 유기물>영양염류>입자상물질 순으로 나타났다. 목표 제거효율 60%에서 SA/CA 비는 BOD에서 약 3.2%, COD에서 2.5%, SS에서 1.9%, TN 2.5%, TP 2.3%로 나타났다. 입자상물질인 SS는 유기물 및 영양염류에 비하여 유역면적 대비 시설면적이 가장 적게 나타났으며, 유기물질 제거에 큰 시설규모가 필요한 것으로 나타났다. 따라서 인공습지 설계시 유역 토지이용 및 강우특성을 고려하여 적정한 수질과 유량모니터링이 필요하며, 이를 토대로 목표 오염물질 선정이 중요한 것으로 나타났다. 또한, 농업지역의 최적화된 인공습지 위치는 임야가 20~30%, 밭이 20% 이하, 논이 10~50%를 포함하는 곳이 적정한 것으로 평가되었다. 도시지역 인공습지는 도시면적이 증가할수록 효율이 크게 변하지 않기에 가용위치가 적정한 위치로 평가된다. 인공습지의 효율은 유역의 세부 토지이용에 크게 의존하는 것으로 평가되었다. 따라서 인공습지 설계시 농업지역에서는 임야, 밭 및 논의 적정면적을 고려하여 인공습지 위치가 결정되어야 하는 것으로 나타났다.

• Journal of the Korean Society for Marine Environment & Energy
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• v.6 no.4
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• pp.24-36
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• 2003

In this study, we estimated the seasonal fluctuations of water quality and effect of small tide embankment in coastal water around the Muan Peninsula, which is located in the northern part of Mokpo city, and layer farming ground is spread around there. Some physical and chemical factors were analyzed to characterize water quality from Jan. to Oct. in 1994. The results were as follows: Dissolved oxygen was slightly under saturation in the almost areas of July, and in some bottom layer at ebb tide of October. Distribution of COD showed high values that over 2㎎/L in October and flood tide of April by the discharge of freshwater and resuspension of benthic sediment, which exceeded water quality criteria II. Maximum values of dissolved inorganic nitrogen ware appeared in surface layer during the flood tide of October, while minimum of that showed in surface layer in April. Concentration of dissolved inorganic phosphorus was higher at July than the others, which ranged from 0.24 to 2.08㎍-at/L. Mostly mean values of N/P ratio were lower than 16, it mean that nitrogen is more limiting nutrient than phosphorus for the growth of phytoplankton. The values of eutrophication index were in the range of 0.07~0.81. However, very high values due to increase of COD were estimated near the tide embankment and southern part in relation to tidal current in October. Water quality around tide embankment was suddenly changed worse within a short period after opening the water gate during the rainfall.

• Journal of Korea Water Resources Association
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• v.33 no.5
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• pp.551-559
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• 2000

In order to diagnose the water environment and assess the water quality restoration, long term trend of water environment has been surveyed at 3-R stations from 1994 to 1999 in Lake Shihwa. Annual mean values of $COD_{Mn}$, Chlorophyll a, total nitrogen, total phosphorus and Secchi depth are ranged in 5.2-15.1 mg/L, 7.3-14R.1 jlg/L, 1.50-4.84 mgN/L, 0.055-0.281 mgP/L and 0.5 -1.4 m, respectively, during the study periods. Carson's trophic state indeies were varied from mesotrophy in 1994 and 1995, hyper-eutrophy in 1996 and 1997, to meso eutrophy in 199R and 1999. After dike construction, water quality were rapidly deteriorated by allochthonous and autochthonous loading of high nutrients and organic carbon. Eutrophication phenomena were characterized by massive phytoplankton blooms and high concentration of COD. However, after onset of restoration program, lake water quality was rapidly restored to the level of just after sea-dike construction. The diversion of waste water inflowing from the Panwol and the Sihwa industrial districts which was started from March, 1997 has contributed to improve water quality in the surface layer. And the tidal mixing (sea water inflowing) through the continuous gate operation was the most effective measure to the whole lake restoration.ration.

• Journal of Animal Environmental Science
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• v.17 no.1
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• pp.11-22
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• 2011

This work was carried out to investigate the quantity of manure excreta and characteristics in growth and production phase of Holstein dairy cattle. The average manure production of dairy cattle under condition of ad libitum feeding was 41.5 kg/head/day (feces 24.9, urine 16.4 kg). The average moisture contents of feces and urine were 85.0% and 93.9%, respectively. Water pollutant concentration, $BOD_5$, $COD_{Mn}$ and SS excreted from dairy cattle were 15,444 mg/${\ell}$, 53,159 mg/${\ell}$, and 40,528 mg/${\ell}$ in feces and 8,454 mg/${\ell}$1,116 mg/${\ell}$, and 962 mg/${\ell}$in urine, respectively. And The daily loading amount of $BOD_5$, $COD_{Mn}$, SS in dairy cattle manure were 523 g, 1,416 g and 1,025 g, respectively. N, P and K contents of manure produced by dairy cattle were 0.33, 0.49 and 0.20% in feces, and 1.02, 0.27 and 1.03 in urine, respectively. In the concentrations of mineral and heavy metal of manure, Ca, Na and Mg contents were 1.56, 0.24 and 0.69%, and Zn, Cu, Cr, Pb and As were 69.23, 19.14, 2.89, 7.73 and 2.94 ppm, respectively. In conclusion, Dairy farms can be estimated optimum nutrient and pollutant balance to effectively manage the manure produced.