• Title/Summary/Keyword: COD 감소

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The Impact of Monsoon Rainfall on the Water Quality in the Upstream Watershed of Southern Han River (하절기의 집중강우가 남한강 상류수계 수질에 미치는 영향)

  • Park, Sung-Min;Shin, Yoon-Keun
    • Korean Journal of Ecology and Environment
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    • v.44 no.4
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    • pp.373-384
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    • 2011
  • The objective of this was to determine how the seasonal intensive rainfall influenced the water quality, and to analyze the long-term temporal trend of water chemistry and spatial heterogeneity in the upstream watershed of Southern Han River using water quality dataset from 1997 to 2007. The largest seasonal variability in most parameters occurred during the two month July and August and there were closely associated with a large spate of summer monsoon rain. Total phosphorus (TP), chemical oxygen demand (COD), and suspended solids (SS) were greater during summer than any other seasons, and had a direct correlation with precipitation (r>0.4, p<0.01, n-120). In addition, dissolved oxygen (DO) had and inverse function with precipitation (r=-0.542, p<0.01). Overall, the data of total phosphorus (TP) and suspended solids (SS) showed that water quality was worst in Site I1, compared to the others. This was due to continuous effluents from the highlands' fields and cattle farms within the upstream area of Doam lake (Song stream). Based on the overall dataset, an efficient water quality management is required in the highlands and farms areas for better water quality with precipitation (r.0.4, p<0.01, n=120).

Characteristics of BDD electrodes deposited on Ti substrate with TiN interlayer (TiN 중간층을 삽입하여 Ti기판 위에 증착한 BDD전극의 특성 평가)

  • Kim, Sin;Kim, Seo-Han;Kim, Wang-Ryeol;Park, Mi-Jeong;Song, Pung-Geun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.157-157
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    • 2016
  • 최근 많은 산업의 발전으로 인해 환경오염을 유발시키는 폐수가 다량으로 배출되고 있으며, 이러한 폐수 속에는 유기용매, 고분자 물질 및 각종 염 등의 난분해성 물질들이 다량으로 함유되어 있다. 이런 물질들을 분해시키기 위해 물리적, 생물학적 수처리 방법이 많이 이용되고 있지만 이 방법들은 각각 운전비용과 처리비용이 고가인 단점이 있다. 따라서 비용과 효율 측면에서 효과적인 폐수처리를 위해서 전기화학적 폐수처리 방법이 많이 사용되고 있다. 물리적, 생물학적 처리 방법에 비해 비용이 적게 들고, 처리 후 잔류물이 남지 않으며. 독성을 띄는 산화제의 첨가 없이도 높은 폐수처리 능력을 보이기 때문에 친환경적이므로, 전기화학적 폐수산화 처리에 사용되는 불용성 전극에 대한 연구가 많이 진행되어져 오고 있다. 그 중 BDD(Boron-doped diamond) 전극은 표면에서 강력한 산화제인 수산화 라디칼의 높은 발생량으로 인해 뛰어난 폐수처리 능력을 보이므로 불용성 전극 분야에서 활발한 연구가 진행 중이다. 그러나 기존에 BDD 전극의 기판 모재로 이용되던 Si, W, Pb등은 모두 기계적 강도. 폐수처리 능력 및 독성 문제로 인해 한계가 있었고, 특히 Nb기판 위에 형성시킨 BDD 전극은 뛰어난 폐수처리 능력에도 불구하고 비싼 모재 원가로 인해 상용화가 힘든 실정이다. 이런 문제점을 해결하기 위해 높은 기계적 강도와 전기화학적 안정성을 가진 Ti 기판을 사용한 BDD 전극에 대한 연구가 보고되고 있다. 그러나 BDD와 Ti 간의 lattice mismatch, BDD층 형성을 위한 고온 공정 시 탄소의 확산으로 인한 기판 표면에서의 TiC층 형성으로 인해 접착력이 감소하여 박리가 생기는 문제점이 있다. BDD와 Ti의 접착력을 향상시키기 위해 융점이 높고, 전기전도성이 우수한 TiN을 diffusion barrier layer로 삽입하면 탄소 확산에 의한 TiC층의 생성을 억제하여, 내부응력에 기인한 접착력 감소를 방지할 수 있다. 또 하나의 방법으로 Ti 기판의 전처리를 통해 BDD층의 접착력을 향상 시킬 수 있다. Sanding과 etching을 통해 기판 표면의 물리, 화학적인 표면조도를 부여하고, seeding을 통해 diamond 결정 성장에 도움을 주는 seed 입자를 분포시킴으로써, 중간층과 BDD층의 접착력을 향상시키고, BDD 결정핵 성장을 촉진시켜 고품질의 BDD박막 증착이 가능하다. 본 연구에서는 기존 Si, Nb 등의 기판 모재를 Ti로 대체함으로써 제조원가를 절감시키고, TiN 중간층을 삽입하여 접착력을 향상시킴으로써 기존의 BDD 전극과 동등한 수준의 물성 및 수처리 특성을 가진 BDD전극 제작을 목표로 하였다. $25{\times}25mm$의 Ti 기판위에 TiN 중간층을 DC magnetron sputtering을 이용하여 증착 후, BDD 전극 층을 HFCVD로 증착하였다. 전처리를 진행한 기판과 중간층 및 BDD층의 미세구조를 XRD로 분석하였고, 표면 형상을 SEM으로 확인하였다. BDD전극의 접착력 분석을 통해 TiN 중간층의 최적 조성을 도출하고, 최종적으로 BDD/TiN/Ti 전극의 CV특성과 가폐수의 COD분해능력 및 축산폐수, 선박평형수 등의 실제 폐수 처리 능력을 BDD/Si, BDD/Nb 전극과 비교 검토할 것이다.

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Biological Treatment of Processed-Leachate from Landfills by Reed (Phragmites australis)-Bed in a Continuous Flow System (갈대-상(床)을 이용한 쓰레기 매립지 침출수의 생물학적 연속흐름 처리)

  • Kim, In-Sung;Cho, Yong-Joo;Choi, Hong-Keun;Lee, Eun-Ju
    • The Korean Journal of Ecology
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    • v.27 no.6 s.122
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    • pp.375-381
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    • 2004
  • We investigate the biological treatment of processed-leachate from SUDOKWON landfill site in Korea by the reed (Phragmites australis)-bed with a continuous flow system. The reed individuals showing superior growth in processed-leachate experiment were selected among the reeds of thirteen natural habitats by means of the comparisons between the removal rates of nutrient salts, eco-physiological responses and growth. The reed-beds (combination of the reed individuals showing superior growth with helper microorganisms) were continuously supplied with processed-leachate. We monitored the effluents that passing through the reed-beds during the experiment period. After five weeks, analysis results of effluent from each reed-bed were as follows; chromaticity, total nitrogen, total phosphorus, biological oxygen demand, chemical oxygen demand, total dissolved solid and salinity decreased $29.5{\sim}36.9\%,\;49.4{\sim}67.2\%,\;42.1{\sim}94.6\%,\;74.5{\sim}88.8\%,\;15.6{\sim}20.8\%,\;17.5{\sim}35.4\%\;and\;15.3{\sim}34.7\%$, respectively. These results represented the substantial improvement of water-quality after passing through reed-bed in a continuous flow system.

Removal Efficiency of Cochiodinium polykrikoides by Yellow Loess (황토의 유해성 적조생물 Cochiodinium종의 제거효과)

  • CHOI Hee Gu;KIM Pyoung Soong;LEE Won Chan;YUN Seong Jong;KIM Hak Gyoon;LEE Hung Jae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.1
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    • pp.109-113
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    • 1998
  • The clay and yellow loess have capability to adsorb and precipitate particles. The removal efficiencyes of those flocculents on the dinoflagellate, Cochlodinium polykrikoides, have been studied in laboratory and in field near Tongyong fish farm in September, 1996. The removal efficiencyes in the laboratory experiment was $43\%$ for $2\;g/{\ell}$, $64\%$ for $6g/{\ell}$ and $88\%$ for $10\;g/{\ell}$ in one hour after dispersion. No big difference of removal efficiency was found between the raw and the acid-activated loess. In the field survey, the removal rates ranged from 72 to $80\%$ in 30 min after the dispersion. The effect of loess scattering on water quality was estimated. The concentrations of dissolved inorganic nitrogen (DIN), chemical of gen demand (COD) and chlorophyll a decreased more or less after dispersion, while the concentration of suspended solid (SS) increased. The concentrations of dissolved oxygen (DO) and dissolved inorganic phosphorous (DIP) were kept constant. These results indicated that the dispersion concentration of more than $10g/{\ell}$ has a good removal efficiency of above $80\%$ without big variation of water quality after dispersion of yellow loess.

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Environmental Changes after Timber Harvesting in (Mt.) Paekunsan (백운산(白雲山) 성숙활엽수림(成熟闊葉樹林) 개벌수확지(皆伐收穫地)에서 벌출직후(伐出直後)의 환경변화(環境變化))

  • Park, Jae-Hyeon
    • Journal of Korean Society of Forest Science
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    • v.84 no.4
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    • pp.465-478
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    • 1995
  • The objective of this study was to investigate the impacts of large-scale timber harvesting on the environment of a mature hardwood forest. To achieve the objective, the effects of harvesting on forest environmental factors were analyzed quantitatively using the field data measured in the study sites of Seoul National University Research Forests [(Mt.) Paekunsan] for two years(1993-1994) following timber harvesting. The field data include information on vegetation, soil mesofauna, physicochemical characteristics of soil, surface water runoff, water quality in the stream, and hillslope erosion. For comparison, field data for each environmental factor were collected in forest areas disturbed by logging and undisturbed, separately. The results of this study were as follows : The diversity of vegetational species increased in the harvested sites. However, the similarity index value of species between harvested and non-harvested sites was close to each other. Soil bulk density and soil hardness were increased after timber harvesting, respectively. The level of organic matter, total-N, avail $P_2O_5$, CEC($K^+$, $Na^+$, $Ca^{{+}{+}}$, $Mg^{{+}{+}}$) in the harvested area were found decreased. While the population of Colembola spp., and Acari spp. among soil mesofauna in harvested sites increased by two to seven times compared to those of non-harvested sites during the first year, the rates of increment decreased in the second year. However, those members of soil mesofauna in harvested sites were still higher than those of non-harvested sites in the second year. The results of statistical analysis using the stepwise regression method indicated that the diversity of soil mesofauna were significantly affected by soil moisture, soil bulk density, $Mg^{{+}{+}}$, CEC, and soil temperature at soil depth of 5(0~10)cm in the order of importance. The amount of surface water runoff on harvested sites was larger than that of non-harvested sites by 28% in the first year and 24.5% in the second year after timber harvesting. The level of BOD, COD, and pH in the stream water on the harvested sites reached at the level of the domestic use for drinking in the first and second year after timber harvesting. Such heavy metals as Cd, Pb, Cu, and organic P were not found. Moreover, the level of eight factors of domestic use for drinking water designated by the Ministry of Health and Welfare of Korea were within the level of the first class in the quality of drinking water standard. The study also showed that the amount of hillslope erosion in harvested sites was 4.77 ton/ha/yr in the first year after timber harvesting. In the second year, the amount decreased rapidly to 1.0 ton/ha/yr. The impact of logging on hillslope erosion in the harvested sites was larger than that in non-harvested sites by seven times in the first year and two times in the second year. The above results indicate that the large-scale timber harvesting cause significant changes in the environmental factors. However, the results are based on only two-year field observation. We should take more field observation and analyses to increase understandings on the impacts of timber harvesting on environmental changes. With the understandings, we might be able to improve the technology of timber harvesting operations to reduce the environmental impacts of large-scale timber harvesting.

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The Cause of Metalimnetic DO Minima in Andong Reservoir, Korea (안동호에서 중층 저산소층 형성의 요인 분석)

  • Park, Jung-Won;Shin, Jae-Ki;Park, Jae-Chung
    • Korean Journal of Ecology and Environment
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    • v.39 no.1 s.115
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    • pp.1-12
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    • 2006
  • Distributions of water temperature and DO profiles were investigated in Andong Reservoir from 1992 to 2004. Thermal stratification began to form from May of every year. Increasing water temperature of epilimnion, temperature difference between epilimnion and hypolimnion increased until August. Lower oxygen layer was formed at metalimnion from June or July of every year and there were 2 layers depending on each year. The two lower oxygen layers were affected by rainfall and inflow between July and September when thermal stratification was formed. The metalimnetic oxygen minima strongly formed at 2 layers, upper and lower part, when the average rainfall and inflow were ${\geqq}$ 170 mm, ${\geqq}$ 50 $m^3\;sec^{-1}$, respectively. It formed weakly when they were > 400 mm and > 200 $m^3\;sec^{-1}$ for one month. The upper part of low oxygen layers formed on the interface of epilimnion and metalimnion showed larger decreasing rate of DO than temperature and it disappeared around November. The lower part of those farmed on interface of metalimnion and hypolimnion existed until December and disappeared in January, this layer showed larger decreasing rate of temperature than DO. DO increased between the upper and lower part of the low oxygen layers. DO on hypolimnion increased under metalimnion and dramatically decreased near the bottom of the reservoir. Temperature of the inflow during rainy season was similar to that of the reservoir's metalimnion, DO was similar or higher and BOD, COD and SS increased. Density layer caused by turbidity was formed in metalimnion, and turbidity increased under the upper part (oxygen increasing layer) of metalimnetic DO minima layers reaching the maximum at the direct upper part of the lower DO minima layer. The upper part of DO minima layers formed on the interface of epilimnion and metalimnion is related to organic activity on the surface, and the lower part of those was considered to be the result of turbid water inflow to metalimnion during rainy season.

Dynamics of Phytoplankton and Periphyton in Gwangju Stream (광주천의 식물플랑크톤과 부착조류의 동태)

  • Cho, Hye-Kyung;Jung, Myoung-Hwa;Kim, Gyu-Man;Shim, Sung-Sun;Lee, Hak-Young
    • Korean Journal of Environmental Biology
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    • v.28 no.2
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    • pp.69-78
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    • 2010
  • The distributions of planktonic and periphytic algae were studied from April 2003 to February 2004 at Gwangju Stream. A total of 274 species, belongs to 8 classes, 19 orders, 6 suborders, 35 families, 4 subfamilies, 79 genera, was identified as algal flora of Gwangju Stream. The most diverse phytoplankton flora was observed at Bangrim bridge and Yangdong market sites with 137 species, and followed by Yuchon bridge site (118 species). The richness of phytoplankton fluctuated throughout the studied period from all the sampled sites. The precipitation was a major factor affected the richness of phytoplankton. The diatoms predominated the phytoplankton of Gwangju Stream with 57.7~77.0% of total phytoplankton. The maximum cells of phytoplankton was observed at Yuchon bridge site with 23,792 cells $mL^{-1}$ in August 2003, and minimum at Jeungsimsa site with 82 cells $mL^{-1}$ in April 2003. The periphyton of Gwangju Stream was predominated by the diatoms. In February 2004, all the periphyton of Yuchon bridge site were diatoms. Other sites also showed the predominance of diatoms throughout the studied period. The standing crops of phytoplankton were highly correlated with chlorophyll-a concentration with R=0.795. TN and TP also showed high relationships with phytoplankton standing crops in Yangdong market site with R=0.796 and R=0.760, respectively. The rains of 7-days ago showed high relationships with phytoplankton standing crop at Dongsan tower site with R=0.810. However, other climatic factors showed no clear relationships with phytoplankton cells.

Production and Characterization of Extracellular Polysaccharide Produced by Pseudomonas sp. GP32 (Pseudomonas sp. GP32에 의해 생산된 세포 외 다당류의 생산 및 특성)

  • Lee, Myoung Eun;Lee, Hyun Don;Suh, Hyun-Hyo
    • Journal of Life Science
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    • v.25 no.9
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    • pp.1027-1035
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    • 2015
  • A strain GP32 which produces a highly viscous extracellular polysaccharide was conducted with soil samples and identified as Pseudomonas species. The culture flask conditions for the production of extracellular polysaccharide by Pseudomonas sp. GP32 were investigated. The most suitable carbon and nitrogen source for extracellular polysaccharide production were galactose and (NH4)2SO4. The optimum carbon/nitrogen ratio for the production of extracellular polysaccharide was around 50. The optimum pH and temperature for extracellular polysaccharide production was 7.5 and 32℃, respectively. In batch fermentation using a jar fermentor, the highest extracellular polysaccharide content (15.7 g/l) was obtained after 70 hr of cultivation. The extracellular polysaccharide produced by Pseudomonas sp. GP32 (designated Biopol32) was purified by ethanol precipitation, cetylpyridinium chloride (CPC) precipitation, and gel permeation chromatography. Biopol32, which has an estimated molecular weight of over 3×107 datons, is a novel polysaccharide derived from sugar components consisting of galactose, glucose, gulcouronic acid and galactouronic acid in an approximate molar ratio of 1.85 : 3.24 : 1.00 : 1.42. The solution of Biopol32 showed non-Newtonian characteristics. The viscosity of Biopol32 exhibited appeared to be higher at all concentration compared to that of zooglan from Zoogloea ramigera. An analysis of the flocculating efficiency of Biopol32 in industry wastewater (food, textile, and paper wastewater) revealed chemical oxygen demand (COD) reduction rates 58.4-67.3% and suspended solid (SS) removal rates 82.6-91.3%. Based on these results, Biopol32 is a possible candidate for industrial applications such as wastewater treatment.

Influences of Discharge Waters from Wastewater Treatment Plants on Rice (Oryza sativa L.) Growth and Percolation Water Salinity (폐수처리장 방류수 관개가 벼생육 및 침출수 염농도에 미치는 영향)

  • Shin, Joung-Du;Lee, Jong-Sik;Kim, Won-Il;Lee, Chang-Eun;Yun, Sun-Gang;Eom, Ki-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.1
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    • pp.24-31
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    • 2003
  • Objective of this study was to assess rice growth and percolation water salinity under the irrigation of the discharge waters from the municipal wastewater treatment plant and from the industrial wastewater treatment plant as alternative water resources during transplanting season. Three kinds of waters were irrigated; the discharge water from an industrial wastewater treatment plant (DIWT), the discharge water from the municipal wastewater treatment plant (DMWT), and groundwater. Concentrations of $COD_{er}$, $NH_4{^+}_-N$, $Mn^{2+}$, and $Ni^+$ in DIWT, SS content and $PO_4-P$ concentrations in DMWT were higher than those of reuse water criteria of other country for agricultural irrigation. The plant height in the irrigation of DMWT was shorter by 2 cm than the groundwater irrigation except for 10 days irrigation. However, the number of tillerings was not significantly different between DMWT and the groundwater. For the harvest index, there were no significant difference between DMWT and DIWT for 20 days irrigation, but slightly higher in DIWT than that of DMWT for 30 days irrigation regardless of soil types. The salinity of percolation water in the rhizosphere with irrigation of DIWT had more twofold than DMWT, but SAR value from DMWT had no significantly different from the groundwater irrigation. The average $EC_i$ values in the rooting zone irrigated with DIWT and DMWT for 30 days after rice transplanting were 4.7 and $3.4dS\;m^{-1}$ in clay loam soil, and were 3.5 and $2.5dS\;m^{-1}$ in sandy loam soil, respectively. There was dramatic decrease in $EC_i$ value at 30 days after rice transplanting even though $EC_i$ of DIWT had more twofold than DMWT. However, $EC_i$ from DMWT had no significant difference from the groundwater. Therefore, it might be considered that there was limited possibility to irrigate DMWT to overcome drought injury of rice transplanting season in paddy field.

Effects of Farming on Soil Contamination and Water Quality in Keum River Districts (금강유역 농업지대의 토양 및 수질오염)

  • Han, Kang-Wan;Cho, Jae-Young;Kim, Seong-Jo
    • Korean Journal of Environmental Agriculture
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    • v.16 no.1
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    • pp.19-24
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    • 1997
  • This studies was carried out to investigate the soil contamination and water quality affected by agricultural activities in the Keum river Districts. Soil pH of the Keum river districts were $5.56{\sim}7.09$ in Keum river headwater and Namdae-cheon but that of Keumgang-lake were $5.07{\sim}7.21$ because of the cattle shed and industrial complex around. Total nitrogen contents of soils were found difference as period of fertilizer application. Total phosphorous content of soils no difference were found between the headwater and Keumgang-lake. Heavy metal contents of soils were natural background level. Water pH of the Keum river districts ranged from 6.59 to 7.80 and COD was maintain below 1.0 mg/L. Total nitrogen content affected by a livestock wastes and sewage water were the higher than that of others and total phosphorous content showed below 0.5 mg/L. Nitrate nitrogen and ortho-phosphate contents were very high according to the influence a livestock waste and sewage water in headwater region of the Keum river partly. Chlorine and sulfate contents were high according to the influence of sea water invasion. Heavy metal contents of waters were natural background level.

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