• Title/Summary/Keyword: COD 감소

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Behavior and Decomposition Velocity of Pollutants on Various Forms from Domestic Sewage in Small-scale Sewage Treatment Plant by Natural Purification Method (자연정화공법에 의한 농촌 전원독립가구 하수처리장에서 하수 중 오염물질의 존재형태별 거동과 분해속도)

  • Seo, Dong-Cheol;Kim, Hyung-Jun;Park, Woo-Young;Lim, Jong-Sir;Hwang, Seung-Ha;Park, Chan-Hoon;Choi, Jeong-Hwan;Lee, Hong-Jae;Lee, Do-Jin;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.27 no.1
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    • pp.18-26
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    • 2008
  • Behavior and decomposition velocity of pollutants on various forms from domestic sewage in sewage treatment plant were investigated in order to obtain the basic data for improving the removal efficiency of pollutants and to reduce the area in constructed wetland by natural purification method. The removal amounts of BODs and CODs in aerobic bed were significantly higher than those of the other beds. In aerobic bed, the removal amounts of IBOD and ICOD were more than those for SBOD and SCOD, respectively, whereas the removal amounts of BODs and CODs in anoxic and anaerobic beds were little different. The removal amounts of SSs in aerobic bed were also higher than those for the other beds, and the removal amounts of VSS in all beds were more than those for FSS. The removal amounts of DTN and DTP in all beds were more than those for STN and STP, respectively. In addition, the decomposition velocities of TBOD, TCOD and TSS in aerobic bed were 30.79, 17.15 and 29.96 $day^{-1}$. Moreover, the decomposition velocities of BODs, CODs and SSs in aerobic bed were very rapid than those in the other beds. On the other hand, the decomposition velocities of BODs, CODs and SSs in anoxic and anaerobic beds were a little different regardless of the forms of pollutant. The decomposition velocities constants of T-N in aerobic, anoxic and anaerobic beds were 4.78, 0.12 and 0.10 $day^{-1}$, respectively. Moreover, the decomposition velocities constants of T-P in aerobic, anoxic and anaerobic beds were 13.09, 0.12 and 0.13 $day^{-1}$ respectively. The decomposition velocity of T-Ns and T-Ps in aerobic bed were slightly rapid than those in the other beds, whereas the decomposition velocities of T-Ns and T-Ps in anoxic and anaerobic beds were slightly different regardless of the forms of pollutant.

Inhibitory Effects of Ammonium Nitrogen on the Nightsoil Digestion (분뇨(糞尿)의 혐기성(嫌氣性) 소화시(消化時)의 암모니아의 독성(毒性)에 관한 연구(硏究))

  • Choi, Eui So
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.5 no.2
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    • pp.75-81
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    • 1985
  • Inhibitory effects of ammonium nitrogen on the nightsoil digestion were investigated in this study by using laboratory digesters. Inhibitory effects were observed even at a concentration less than 1.5g/1 $NH_3N$. This would suggest dilution of influent nightsoil would be one of the applicable methods, however, increased microbial washout due to the dilution limited applicable organic loading rate. The study results indicated 1 : 1 dilution would be most likely applicable to minimize inhibitory effect up to a loading rate of $5kg\;COD/m^3/d$.

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Study on Condensation and Adsorption Characteristics of Ethanolamine for Removal COD and N (COD 및 N 제거를 위한 에탄올아민의 응축 및 흡착특성 연구)

  • Kim, Jong-Young;Jeong, Eun-Sun;Ku, Hee-Kwon;Rhee, In-Hyoung;Park, Byung-Gi
    • Proceedings of the KAIS Fall Conference
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    • 2008.11a
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    • pp.415-418
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    • 2008
  • 에탄올아민 (ETA; Ethanolamine)은 에틸렌옥시드를 진한 암모니아수와 함께 가열하여 얻어지는 물질로 흡수성이 있는 무색의 액체 또는 고체이며 탄소, 질소, 산소로 이루어진 매우 안정된 유기화합물이다. 이러한 ETA는 부식방지제, 산성가스 흡수제, 화장품 등 각종 산업에서 매우 유용하게 사용되는 물질이다. 하지만 ETA는 눈, 피부, 호흡기, 폐 등에 접촉하여 호흡기 질환 및 만성 천식을 유발하고 피부에 자극을 일으키므로 ETA를 제거하기 위한 물리화학적 연구가 필요하다. 따라서 본 연구에서는 냉각온도 및 진공펌프압력에 따른 ETA 응축 특성과, 흡착제에 따른 ETA 흡착특성을 조사하였다. 조사결과 ETA는 냉각수의 온도 및 진공펌프압력에 영향을 받았으며 냉각수 온도 및 진공펌프압력이 증가할수록 응축율은 감소하였다. ETA 흡착에서 활성탄의 경우 액상의 ETA와 상호간에 흡착력은 존재하지 않았으며, 기상의 ETA는 흡착되지만, $100^{\circ}C$이상에서 탈착 반응이 일어났다. 제올라이트의 경우 액상 및 기상의 ETA를 모두 흡착하였다.

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A Study on the Fatigue Behavior of ARALL and Manufacturing of ARALL Materials (ARALL재의 개발과 이의 피로파괴거동에 관한 연구)

  • Jang, Jeong-Won;Sohn, Se-Won;Lee, Doo-Sung
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.4 s.97
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    • pp.13-18
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    • 1999
  • 섬유강화금속적층재(Fiber Reinforced Metal Laminates. FRMLs)는 고강도금속과 섬유강화복합재료(Fiber Reinforced Composite Materials)를 적층한 새로운 종류의 하이브리드 재료이다. 국산 아라미드 섬유인 헤라크론(Heracron, 코오롱)과 국내 복합재료 제작기술(한국화이바)을 사용하여 섬유강화금속적층재를 제작하고, 이를 HERALL(Heracron Reinforced Aluminum Laminate)이라 명명하였다. HERALL(Heracron Reinforced Aluminum Laminate)의 피로균열성장특성 및 피로균열진전 방해기구를 ARALL(Aramid-fiber Reinforced Aluminum alloy Laminates) 및 Al 2024-T3과 비교해석하였다. HERALL과 ARALL은 균열진전을 저지하는 아라미드 섬유로 인해 뛰어난 피로균열성장특성 및 피로저항성을 보여주었다. 아라미드 섬유의 균열브리드징으로 인한 $K_{max}$의 감소량과 Al 2024-T3의 균열닫힘으로 인한 $K_{max}$의 증가량을 구할 수 있는 응력-COD법을 사용하여 실제로 균열성장에 영향을 준 유효응력확대계수범위를 측정하였다. 균열선단으로부터 균열을 가공하면서 COD 변화량을 측정하여 균열브리징 영역을 구하였다.

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Water environmental change by river-crossing structure (하천횡단구조물 설치에 따른 수환경 변화 분석)

  • Noh, Seon Hui;Choi, Mi Kyoung;Jung, Kwan Sue;Yi, Sang Jin
    • Proceedings of the Korea Water Resources Association Conference
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    • 2018.05a
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    • pp.478-478
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    • 2018
  • 하천의 횡단구조물은 하천을 횡단하는 시설물로 하상유지공, 보 등이 있으며 현재 국내 하천에는 수많은 보가 존재한다. 하천에 설치된 보는 하천 유황을 변화시키기 때문에 보 상 하류로부터 상당히 멀리 떨어져 있는 하도 구간에 대해서도 수환경을 변화 시키게 된다. 이로 인하여 하천을 터전으로 생활하는 다양한 생물의 서식처를 손상시키며, 어류와 야생 생물 각 개체의 생활상을 흔들어버린다. 이에 본 연구에서는 금강을 대상으로 횡단구조물 중 보 설치 이전과 이후의 수질의 변화에 따라 생태환경의 변화특성을 분석하였다. 연구대상지인 금강의 수질자료는 보 설치 이전 6년간(2003년 ~ 2008년)과 보 설치 이후 7년간(2011년 ~ 2017년)의 자료를 조사하였고 수생태환경의 변화를 분석하기 위한 부착조류, 저서성 무척추동물, 어류를 9년간(2008년 ~ 2016년) 조사하였다. 금강에 보가 설치된 이후 본류 전체적으로 BOD와 SS, T-N 등의 농도가 낮아지는 등 개선된 것으로 나타났지만 COD는 개선효과가 전혀 없었고, 보지점에서는 수온증가는 미미하지만 Chl-a가 계속적으로 증가하여 최근까지 금강에 녹조발생을 일으키고 있다고 판단된다. 금강본류 전체적으로 저서성무척추동물과 어류의 개체수가 감소하는 추세이며 수생태 건강성분석 결과 다른생물종에 비해 어류의 건강성등급이 하향하는 추세로 악화되고 있음을 확인하였다. 이는 Chl-a와 COD의 증가로 판단되며 최근들어 BOD도 증가하고 있어 앞으로 어류건강성이 저하가 우려되기 때문에 하천의 유속증가나 수문개방을 통해 건강성을 회복할 필요가 있다고 판단된다.

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Treatment of Wastewater from Agricultural Industrial Complex by Combination of Electrochemical and Activated Sludge Process Systems (전기화학적 방법과 활성오니 공정의 병합에 의한 농공단지폐수 처리)

  • Lee, Hong-Jae;Seo, Dong-Cheol;Cho, Ju-Sik;Park, Hyun-Geoun;Lee, Chun-Sik;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.20 no.4
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    • pp.289-296
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    • 2001
  • The effects of HRT and effluent time on removals of pollutants in the electrochemical pilot were investigated. COD removal after 8 hour electrochemical reaction time in HRT 30 and 60 minutes were higher than that of 15 minute HRT. Turbidity removal was 90% or greater regardless of conditions during effluent time. Removals of T-N and T-P during effluent time in HRT 30 and 60 minutes were $71{\sim}74%$ and $85{\sim}98%$, respectively. To evaluate the combination of activated sludge process and continuous electrochemical as pretreatment, the removal efficiencies of pollutants was investigated. In two treatment processes of a single activated sludge system and a electrolysis pilot plus activated sludge systems, SVI and MLSS during effluent time were kept with $82{\sim}112$ and $1,230{\sim}1,750$ mg/L, respectively. COD removal was approximately 90% at early effluent time for both treatment systems, but COD removal in a single activated sludge was slightly decreased as effluent time went by, compared with the single activated sludge COD removal was slightly increased in the early stage of the electrolysis plus activated sludge system. Turbidity removal during effluent time was higher than 95% for both treatment systems. T-N removals during effluent time in a single activated sludge system and a electrolysis pilot plus activated sludge systems were $62{\sim}74%$ and $72{\sim}86%$, respectively. T-P removal in a electrolysis pilot plus activated sludge systems was increased by 9% at early effluent time and 15% after 72 hours of effluent time in compared with a single activated sludge system.

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Treatment Efficiencies and Decomposition Velocities of Pollutants in Constructed Wetlands for Treating Hydroponic Wastewater (인공습지시스템을 이용한 폐양액처리장에서 오염물질의 정화효율 및 오염물질 분해속도)

  • Park, Jong-Hwan;Seo, Dong-Cheol;Kim, Ah-Reum;Kim, Sung-Hun;Lee, Choong-Heon;Lee, Seong-Tea;Jeong, Tae-Uk;Lee, Sang-Won;Ha, Yeong-Rae;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.937-943
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    • 2011
  • In order to develop constructed wetlands for treating hydroponic wastewater in greenhouses, removal efficiencies and decomposition velocities of pollutants in constructed wetland were investigated for treating hydroponic wastewater. Removal rates of BOD, COD, SS, T-N and T-P in effluent in constructed wetlands were 88%, 79%, 92%, 64% and 92%, respectively. The decomposition velocities (K; $day^{-1}$) of pollutants in $1^{st}$ HF bed of constructed wetlands were higher in the order of SS ($0.54day^{-1}$) > BOD ($0.39day^{-1}$) > COD ($0.27day^{-1}$) > T-P ($0.26day^{-1}$) > T-N ($0.06day^{-1}$). In $1^{st}$ HF bed of constructed wetlands, the decomposition velocity of SS was rapid than that for BOD, COD, T-N and T-P in constructed wetland for treating hydroponic wastewater. The decomposition velocity (K; $day^{-1}$) of pollutants in $2^{nd}$ HF bed of constructed wetland were higher in the order of T-P ($0.52day^{-1}$) > BOD ($0.28day^{-1}$) > COD ($0.15day^{-1}$) > T-N ($0.06day^{-1}$) > SS ($0.10day^{-1}$). In $2^{nd}$ HF bed of constructed wetlands, the decomposition velocity of T-P was rapid than that for BOD, COD, SS and T-N in constructed wetland for treating hydroponic wastewater.

Characteristics of Spatio-temporal Variation of the Water Quality in the Lower Keum River (금강 하류역에서 수질의 시공간적 변화특성)

  • YANG Han-Soeb;KIM Seong-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.3
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    • pp.225-237
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    • 1990
  • Various chemical constituents were measured from April to August 1988 at the down-ward 20 stations of Keum River, which is located in the Midwest of Korea, to understand the characteristics of water quality with respect to spatio-temporal variations of each constituent. The 24-hrs continuous measurements with 2-hrs interval were made simultaneously at station 2 near the estuary weir and station 9(Ganggyeong) of 35 km upstream from the weir in April. By the results observed for one day in April at station 2, salinity has a range of $7.88\~22.14\%_{\circ}$ and its temporal variability is identical to the pattern of tidal cycle in the neigh-bouring Kunsan Harbor. However, turbidity shows relatively high values only at an interval of 4~5 hours after the lowest salinity time, though hourly fluctuation of pH is very small. Silicate and dissolved inorganic nitrogen have inversively linear correlationships with salinity, implying the concentration of the two nutrients strongly regulated by estuarine mixing of sea and river waters. In contrast, phosphate sustains roughly a constant level over a wide salinity range and distinctly lower values than those corresponding to nitrate in the oceans. Such distributions of phosphate have been observed in some estuaries, and interpreted as driven by removal of dissolved phosphate into bottom sediments and the bufforing of phosphate by particulate matter. COD values at station 2 are relatively high in day-time(particularly afternoon) and in high-salinity periods. At station 9, saltwater intrusion was never found but water level changed to the extent of 2.5 m for one day. Although each parameter at this station exhibits very slight variations in their abundance for 24 hours compared with station 2, the contents of COD, silicate and ammonia are significantly higher than at station 2. Concentration of suspended matter is relatively high in the brackish water region up to $\~20$ km above the river mouth, probably due to strong tidal stirring of the bottom de-posits. Also, relatively high pH, COD and $O_2$ saturation at the upward stations of $40\~50$ km from the weir are presumably attributable to active photosynthesis of plants in the region. In general, COD and nutrients except phosphate are higher values at the upper stations than in the estuary zone, and show the highest abundances in July nearly at all stations. Finally, in the estuarine region tidal mixing of sea-river waters seems to be an important factor controlling the distributions of turbidity, COD, silicate and nitrate as well as salinity. However, water quality in the upward fresh-water zone is remarkably variable according to months or seasons.

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Estimation of Acidic Wastewater Toxicity on the Activated Sludge (활성슬러지에 미치는 산폐수의 독성도 예측)

  • Choi, Kwang-Soo;Ko, Joo-Hyung;Jang, Won-Ho;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2175-2185
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    • 2000
  • Respiration rate should be a reasonable state variable for the activated sludge and could be used to simulate the performance of the activated sludge process. Toxic materials are classified into three groups, competitive, noncompetitive and uncompetitive. They increase/decrease the half saturation coefficient or specific growth rate. that means decreasing of the substrate removal capacity. In this research, a pilot-scale activated sludge process was operated under extended aeration method, and a representative noncompetitive inhibitor, acidic wastewater was applied to establish a respirometry-based toxicity model. Using this model. the correlation coefficient between measured and calculated respiration rate was 0.96 when acidic wastewater(pH 3.9~5.5) was introduced continuously to the aeration tank. Even though respiration rate was decreased by toxic effect of acidic wastewater, effluent substrate concentration represented to COD was deteriorated just a little bit. It might be caused by the low ratio of readily biodegradable substrate in the input substrate. Reduction of respiration rate by decreasing of input substrate concentration was much lower than that by acidic wastewater, and hence it was estimated that the possibility of false toxic alarm caused by decreasing of substrate concentration should be low.

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The Effect of Yeast(Saccharomyces exiguus SJPAF1) on Odor Emission and Contaminants Reduction in Piggery Slurry (효모(Saccharomyces exiguus SJPAF1) 첨가에 따른 돈분뇨의 악취제거 및 오염물질 감소 효과)

  • Yoon, Deok-Hoon;Kang, Dong-Woo;Nam, Ki-Woong
    • Korean Journal of Environmental Agriculture
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    • v.28 no.1
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    • pp.47-52
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    • 2009
  • The aim of this study was to evaluate the effect of yeast(Saccharomyces exiguus SJPAF1, referred to as SA) addition on odor emission and contaminants reduction in piggery sluny. Four different rates of yeast addition were compared: no addition(SA0), 0.7L(SA0.7), 1.0L(SA1.0), and 1.5L(SA1.5) to one tone of piggery slurry. Odor emission tended to decrease with increasing the yeast application with concurrent effects of changes in temperature on outside of reactors. Particularly, reduction in ammonia emission was proportional to the yeast application rate; it reduced from 161.1 ppm in SA0 to 47.1 ppm in SA1.5 after 6 days of treatment Decomposition of piggery shiny by yeast increased to 13.8% more in SA1.5, and total amounts of piggery slurry decreased to 12.5% in SA1.5. Total coliforms were detected below 30MPN $ml^{-1}$ in SA1.5, while $8.3{\times}10^3$ MPN $ml^{-1}$ of Total coliforms were found in SA0. However, the effect of yeast addition in piggery slurry seemed to have no influence on the removal efficiency of contaminants such as BOD, COD, $NO_3^{-}-N$, $NH_4^{+}-N$, $PO_4^{-}P$. Consequently, the yeast(Saccharomyces exiguus SJPAF1) addition of 1.5% in the piggery sluny seems to have potential applicability for improving agent of pig-farm environment.