• Title/Summary/Keyword: COD/TKN ratio

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Slaughterhouse wastewater treatment in a bamboo ring anaerobic fixed-bed reactor

  • Tritt, Wolfgang P.;Kang, Ho
    • Environmental Engineering Research
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    • v.23 no.1
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    • pp.70-75
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    • 2018
  • A pilot scale anaerobic fixed-bed with a reactor volume of $2.8m^3$ was built to treat slaughterhouse wastewater. Bamboo rings were chosen as support media mainly because of their cheaper price in underdeveloped countries. Even with their lower porosity and specific surface, the reactor performance showed a maximum 95% COD removal efficiency at an organic loading rate (OLR) of $1kg\;COD/m^3-d$ with its corresponding hydraulic retention time (HRT) of 7.5 d. At a higher OLR of $4.0kg\;COD/m^3-d$, the COD removal efficiency of 75% was achieved with an HRT of 2 d. No big difference in COD removal efficiencies was found between the reactors operated in both upflow and downflow modes. Their operational behavior and effluent characteristics were similar. The effluent COD/TKN ratio of 6.67 at an OLR of $4.0kg\;COD/m^3-d$ was only marginal acceptable range for a subsequent biological denitrification process. Otherwise carbon supplementation is required at a lower OLR.

Effects of MLSS Concentration and Influent C/N Ratio on the Nitrogen Removal Efficiency of Alternately Intermittently Aerated Nonwoven Fabric Filter Bioreactors (교차 간헐 포기식 부직포 여과막 생물반응조에서 MLSS 농도 및 유입수 C/N 비가 질소 제거효율에 미치는 영향)

  • Jung, Kyoung-Eun;Bae, Min-Su;Lee, Jong-Ho;Cho, Yun-Kyung;Cho, Kwang-Myeung
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.501-510
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    • 2006
  • To investigate the effects of MLSS concentration and influent C/N ratio on the nitrogen removal efficiency of alternately intermittently aerated nonwoven fabric filter bioreactors, the MLSS concentrations of the reactors were maintained at approximately 5,500 mg/L, 10,000 mg/L and 15,000 mg/L, and the influent TCOD/TKN ratio was decreased gradually from 5 to 2 by adding $NH_4Cl$. The influent was prepared by diluting a food waste leachate to a TCOD concentration of about 300 mg/L. The results of the experiment showed F/M ratios less than 0.112 g TCOD/g MLSS-day, average TCOD removal efficiencies of above 95%, and an average observed microbial yield coefficient of 0.283 g MLSS/g COD removed. The nitrification efficiencies were computed to be always better than 96% except one case where the nitrification efficiency was 90.5% when the MLSS concentration and the influent TCOD/TKN ratio was 5,500 mg/L and 2, respectively. The denitrification efficiency deteriorated as the influent TCOD/TKN ratio decreased. The average denitrification efficiency at the MLSS concentration of 10,000 mg/L was 10.7% better than that at the MLSS concentration of 5,500 mg/L, and the denitrification rate improved at a rate of 2.66 mg NL as the MLSS concentration increased by 1,000 mg/L. When the MLSS concentration was 15,000 mg/L, however, the average denitrification efficiency was merely 4.6% higher compared to when the MLSS concentration was 5,500 mg/L, and the denitrification rate increased at a rate of 0.75 mg N/L per 1,000 mg/L MLSS increase. Therefore, no strict proportional relationship was found between MLSS concentration and endogenous denitrification rate. The average alkalinity consumption rate was 3.36 mg alkalinity/mg T-N removed, which is similar to the theoretical value of 3.57 mg alkalinity/mg T-N removed, but the rate increased as the influent TCOD/TKN ratio decreased.

Evaluation of Swine Wastewater Pretreatment Using Anaerobic Filter (Anaerobic Filter에 의한 양돈폐수의 전처리 특성 평가)

  • Kang, Ho;Moon, Seo-yeon
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.7
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    • pp.418-425
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    • 2015
  • Anaerobic Filters (AF) packed with porous ceramic floating media were operated at different operational conditions to identify the feasibility of the renewable bioenergy, methane production from swine wastewater and to verify the suitability of effluent from anaerobic filters for the subsequent biological nitrogen and phosphorus removal. Stepwise increase in organic loading rates (OLRs) or decrease in hydraulic retention times (HRTs) with influent TCOD concentration of 14,000 mg/L were utilized at mesophilic temperature. The maximum methane productivity of 1.74 volume of $CH_4$ per volume of reactor per day (v/v-d) was achieved at an hydraulic retention time (HRT) of 0.5 day (OLR 28 g TVS/L-d). Based on the biogas production, the highest total volatile solids (TVS) removal efficiency of 63% was obtained at an HRT of 3 days (OLR 4.67 g TVS/L-d), however based on the result from the effluent total chemical oxygen demand (TCOD) analysis, the highest TCOD removal efficiency of 75% was achieved. The effluent alkalinity concentration over the range of 2,050~2,980 mg/L as $CaCO_3$ at all operational conditions, could compensate the alkalinity destruction caused by nitrification. The effluent from the anaerobic filter operated under the HRT of 2 days showed the COD/TKN ratio of 15~35 and COD/TP ratio of 38~56. Therefore effluent C/N/P ratio is able to satisfy the optimum COD/TKN ratio of greater than 8.0 and COD/TP ratio of 33 for the subsequent biological nutrient removal.

Comparison of Biological Phosphorus Removal Characteristics between A/O and A2/O Process (A/O 및 A2/O공정의 생물학적 인제거 특성비교)

  • Kim, Kwang-Soo;Seo, Gyu-Tae;Lee, Kyung-Ho;Kim, Nag-Ju
    • Journal of Korean Society on Water Environment
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    • v.18 no.2
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    • pp.123-130
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    • 2002
  • Bench scale experiments were carried out with two biological nutrient removal(BNR) units, A/O and $A^2O$ processes, to investigate the behavior of phosphorus in the system and to compare the characteristics of phosphorus removal in two BNR processes. To achieve this goal, COD/T-P and COD/TKN ratios of the influent was varied in the range of 23~64 and 5~24, respectively. In A/O process, influent COD/T-P ratio should be kept higher than 44mg/L to meet the final effluent T-P concentration lower than 1mg/L and in $A^2/O$ process, influent COD/T-P and COD/TKN ratios higher than 56 and 10, respectively, were required for good phosphorus release and uptake with no influence of nitrate nitrogen in return sludge. At this conditions, the rate of phosphorus release in the anaerobic basin should be kept higher than 0.1 kg S-P/kg MLVSS d In A/O process, the phosphorus content of anaerobic and aerobic sludges was increased as SRT of total system was becoming longer resulting in decreasing the difference of phosphorus content between two sludges while phosphorus release in anaerobic basin and phosphorus uptake in aerobic basin was not incident. In $A^2/O$ process, the phosphorus content of anaerobic and aerobic sludges were not increased with higher SRT of total system due to the relatively high nitrate concentration in return sludge. However, the difference of phosphorus content between anaerobic and aerobic sludges was incident when phosphorus release and uptake was observed.

Nitrogen Removal Characteristics of Swine Wastewater when treating by MLE Process (MLE 공정을 이용한 양돈폐수의 질소 제거 특성)

  • Park, Seung Kyun;Park, Hyun Su;Lee, Ki Gong;Chung, Yoon Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.2
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    • pp.147-156
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    • 2000
  • In this study, the optimal operation parameters of MLE(Modified Ludzack-Ettinger) process treating the liquid supernatant separated from the slurry excreta of swine feedlot was studied as a promising biological treatment process. The nitrogen removal characteristics with different volume ratio between nitrification and denitrification reactor and the operational effect with different nitrogen loading rate, and different C/N($COD_{Cr}/TKN$) ratio were investigated. Based on the laboratory results, pilot MLE plant was operated to examine the effect of ambient temperature for five months including winter. The denitrification reactor which is 20% of total volume was proposed as the most optimal volume fraction for nitrification and denitrification. The optimum ratios of F/M and $F_N/M$ were increased with increase of the C/N ratio. However, optimum F/M ratio was changed more rapidly than $F_N/M$ ratio with increase of the C/N ratio. Therefore, MLE process is desirable to be controlled by F/M ratio in the range of high C/N ratio and by $F_N/M$ ratio in the range of low C/N ratio. Pilot MLE plant showed the higher removal efficiencies of COD and TKN in winter than in summer and was operated most stably at the temperature of $20{\sim}25^{\circ}C$ for mixed liqour.

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Effects of the Co-treatment of Municipal Wastewater with Microwave-Irradiated Excess Sludge on the Performance of the Activated Sludge Process (초단파조사 처리된 잉여슬러지와 하수의 병합처리가 활성슬러지공법의 성능에 미치는 영향)

  • Kim, Nam-Chul;Jang, Myung-Bae;Cho, Yun-Kyung;Cho, Kwang-Myeung
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.3
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    • pp.304-310
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    • 2007
  • The purpose of this research was to investigate the effects of the co-treatment of municipal wastewater with microwave-irradiated excess sludge on the treatment efficiency and excess sludge production of the activated sludge process. When 250 mL of excess sludge with a MLSS concentration of approximately 2,000 mg/L was microwave-irradiated at $20^{\circ}C$ for $40\sim300$ sec by a microwave oven (2,450 MHz, 700 W), the temperature of the sludge increased at a rate of approximately $20^{\circ}C/min$ and the SCOD, TKN and T-P concentrations of the sludge showed the highest increase in the irradiation time of $40\sim130$ sec. And, the oxygen uptake rate measurement of the sludge microorganism suggested most of the microorganisms in the sludge were destroyed at an irradiation time above 130 sec(above $65^{\circ}C$). When the municipal wastewater and microwave-irradiated excess sludge was co-treated by the activated sludge process, almost no effect was observed in the pH and alkalinity of both the influent and effluent, but the influent concentrations of SS, COD, T-N and T-P increased. Even though the effluent SS, BOD and T-P concentrations showed almost no effect, the COD and TKN concentrations increased. The microbial yield coefficient decreased at a rate of 0.91 g SS/g COD removed as the irradiation ratio increased at a rate of 1 g SS/g SS-day.

A Study on the Characteristics of Wastewater Treatment by Rapid Infiltration Using Sand Soil (사토(砂土)를 이용(利用)한 급속토양삼투법(急速土壤滲透法)의 폐수처리(廢水處理) 특성(特性)에 관한 연구(研究))

  • Yang, Sang Hyon;Cho, Woong Hyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.23-31
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    • 1987
  • In land treatment systems for organic waste removal, especially rapid intiltration method is well known as less climatic restrictions and less field area requirements as against the others. Therefore the present study on rapid infiltration is aimed to survey the waste removal rate, infiltration rate, variation of dissolved oxygen due to biological oxygen absorption and pH decrement using pilot infiltration column filled with permeable soil(sand) as media, also to find the waste load(COD) per unit area and nitrate conversion ratio from TKN. The results obtained here are as follows. 1) When the depth of sand layer is more than 1 meter, the COD removal would be reached steadly to 90% or more under the infiltration rate below 15~20cm/day, and would be no problem due to leached organic pollutants considering the depth of ground water table. 2) The COD removal per unit area($m^2$) can readily be expected to 10~14g/day with proper operation, and the decomposition of substrate would be attained mostly at the surface layer of the media. 3) Generally the conversion of TKN to the $NO_3{^-}$-N is seemed to be proportional to the COD removal rate if provided proper retention time.

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Characterization of Stormwater Pollutants Runoff in Industrial Complex (강우시 산업단지에서의 오염물질 유출특성)

  • Bang, Ki-Woong;Lee, Jun-Ho;Choi, Jong-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.341-353
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    • 2000
  • The purpose of this study is to investigate the characteristics of pollutants overflow on storm events and the first flush analysis in industrial complex. Eight sub-basins in the Chongju industrial complex were selected for sampling and study with different characteristics during the period from June 1997 to August 1998. Water quality parameters of stormwater runoff such as $BOD_5$, COD, SS, TKN, $NO_3-N$, $PO_4-P$, TP, n-Hexane extracts, Cr, Cu, Pb and Fe were analyzed. During the storm events, measured concentration ranges of $BOD_5$, COD, SS, $NO_3-N$, TKN, $PO_4-P$, TP, r-Hexane extracts, Cr, Cu, Pb and Fe were 2~324 mg/L, 5~810 mg/L, 1~1,110 mg/L, 0.01~10.89 mg/L, 0.1~59.8 mg/L, 0.08~7.02 mg/L, 0.1~7.8 mg/L, 0.1~1,723.6 mg/L, 0.001~0.363 mg/L, 0.001~0.488 mg/L, 0.001~1.28 mg/L, and 0.26~18.91 mg/L, respectively in the industrial complex watersheds. And a quantitative of first flush has been presented. First flush occurs more frequently as the ratio of impervious area increases.

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Removal of Ammonia Nitrogen and Organics from Piggery Wastewater Using BACC Process-II. Effect of COD/N on Removal of NItrogen and Organics (BACC를 이용한 축산폐수의 암모니아성 질소 및 유기물의 제거 II. COD/N비가 질소 및 유기물 제거에 미치는 영향)

  • 성기달;류원률;김인환;조무환
    • KSBB Journal
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    • v.16 no.2
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    • pp.140-145
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    • 2001
  • To treat piggery wastewater containing refractory compounds including nitrogen, physical treatments using zeolite and biological processes were investigated. In biogical treatment, the removal efficiencies of organics and nitrogen in bioreador using BACC (Biological Activated Carbon Cartridge) media filled with granule activated carbon were examined. The best removal efficiencies achieved for TKN and COD(sub)cr were 82% and 53% respectively, when zeolite dosage was 300 g/L. Specific nitrogen removal ability was 3.2 mg/g at a zeolite dosage of 50 g/L, whereas specific nitrogen removal ability was 1.8 mg/g at a zeolite dosage of 300 g/L. The increased of C/N ratio resulting from the removal of nitrogen using zeolite led to an increase in removal efficiency of organics. As C/N ratio was increased to 2.0, 2.44 and 6.58 at a HRT of 48 hours in a BACC bioreactor, removal efficiencies of COD(sub)cr were increased to 53.5%, 57.4% and 80.6%. The removal efficiency of wastewater using a zeolite dosage of 399 g/L was increased by 27.1% compared to that of control treatment.

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Influence of mixed liquor suspended solids on the removal efficiency of a hybrid membrane bioreactor

  • Palmarin, Matthew J.;Young, Stephanie
    • Membrane and Water Treatment
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    • v.7 no.1
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    • pp.11-22
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    • 2016
  • The characterization of treatment performance with respect to mixed liquor suspended solids (MLSS) concentration enables greater control over system performance and contaminant removal efficiency. Hybrid membrane bioreactors (HMBRs) have yet to be well characterized in this regard, particularly in the context of greywater treatment. The aim of this study, therefore, was to determine the optimal MLSS concentration for a decentralized HMBR greywater reclamation system under typical loading conditions. Treatment performance was measured at MLSS concentrations ranging from 1000 to 4000 mg/L. The treated effluent was characterized in terms of biochemical oxygen demand ($BOD_5$), chemical oxygen demand (COD), turbidity, ammonia ($NH_3$), total phosphorus (TP), total kjeldahl nitrogen (TKN), and total nitrogen (TN). An MLSS concentration ranging from 3000 to 4000 mg/L yielded optimal results, with $BOD_5$, COD, turbidity, $NH_3$, TP, TKN, and TN removals reaching 99.2%, 97.8%, 99.8%, 99.9%, 97.9%, 95.1%, and 44.8%, respectively. The corresponding food-to-microorganism ratio during these trials was approximately 0.23 to 0.28. Operation at an MLSS concentration of 1000 mg/L resulted in an irrecoverable loss of floc, and contaminant residuals exceeded typical guideline values for reuse in non-potable water applications. Therefore, it is suggested that operation at or below this threshold be avoided.