• Title/Summary/Keyword: COD/IL

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Full-scale Soil Washing and Non-discharged Washing Water Treatment Process of Soil Contaminated With Petroleum Hydrocarbon (현장규모의 유류오염 토양세척 및 무방류 세척 유출수 처리 공정)

  • Seo, Yong-Sik;Choi, Sang-Il;Kim, Jong-Min;Kim, Bo-Kyung;Kim, Sung-Gyoo;Park, Sang-Hean;Ju, Weon-Ha
    • Journal of Soil and Groundwater Environment
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    • v.14 no.1
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    • pp.61-67
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    • 2009
  • A non-discharged system of sequentially physico-chemical water treatment was used to treat the contaminated water produced from washing system of soils according to full-scale soil washing. After washing the TPH contaminated soils, the remaining concentrations of COD$_{Mn}$, SS, and n-hexane were analyzed for each compartment to estimate the treatment efficiencies of non-discharged system. Three times of sampling events were conducted for 4 different compartments (sediment tank, flocculation tank, oil/water separator, and process-water tank). In addition, soil washing efficiencies and concentrations of each parameter (COD$_{Mn}$, SS, and n-hexane) for process-water tank were analyzed for about 8 months. As results, the average efficiency of soil washing was high to have 95.9%, regardless of the condition of TPH contamination level for soils, as well as the concentrations of COD$_{Mn}$, SS, and n-hexane in the process-water tank were below the regulation limits of the Water Environmental Conserveation Act. Accordingly, the full-scale washing treatment system in this study could make the washing water 100% recycled which lead the system to be environmentally-friendly and economical.

Optimal Conditions for Treatment of Swine Wastewater using Rhodopseudomonas palustris KK14 (Rhodopseudomonas palustris KK14를 이용한 돈분폐수처리의 최적조건 검토)

  • Kim, Han-Soo;Lee, Tae-Kyung;Kim, Hyuk-Il;Cho, Hong-Yon;Yang, Han-Chul
    • Applied Biological Chemistry
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    • v.37 no.4
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    • pp.295-302
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    • 1994
  • For the development of biological wastewater treatment process using photosynthetic bacteria (PSB), photosynthetic sludge process consisted of anaerobic digestion and PSB reactor were designed for the treatment of swine wastewater and the optimal operating conditions in flask-scale were examined. Photosynthetic bacteria from soil, pond, rice field, ditch etc. were isolated in synthetic medium containing high amount of organic acids and finally isolated one strain KK14 which showed the most degradating ability of organic acids was selected for the treatment of swine wastewater. It was identified as Rhodopseudomonas palustris. In the anaerobic digestion stage, the maximum organic acid productivity was obtained at pH 5.0, $37^{\circ}C$, HRT 2 day and under anaerobic standing condition. The optimal operating conditions of PSB reactor for the treatment of swine wastewater were pH 7.0, $30^{\circ}C$ under 4,000 lux illumination, and optimal initial COD loading (kg COD/kg D. C. W of PSB) was 2 (20% v/v seeding) in the main purification stage. Maximum removal rate of COD reached 92% under the above optimal conditions for 5 days.

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Advanced Oxidation Process for the Treatment of Terephthalic Acid Wastewater using UV, H2O2 and O3 : Organic and Color Removal Studies (UV, H2O2, 오존을 이용한 고급산화공정에서의 테레프탈산 제조공정 폐수 처리 : 유기물 및 색도제거 연구)

  • Kwon, Tae-Ouk;Park, Bo-Bae;Moon, Il-Shik
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.648-655
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    • 2007
  • UV/H_2O_2$, $O_3$, $O_3/H_2O_2$, $UV/H_2O_2/O_3$ processes were tested for the removal of COD and color from terephthalic acid wastewater. COD removal efficiencies were 10, 48, 56, 63% in the $UV/H_2O_2$, $O_3$, $O_3/H_2O_2$, $UV/H_2O_2/O_3$ process respectively. Color removal efficiency of $UV/H_2O_2$ process was 80% and $O_3$, $O_3/H_2O_2$, $UV/H_2O_2/O_3$ processes were almost more than 99%. Terephthalic acid, isophthalic acid and benzoic acid were completely destructed in terephthalic wastewater within 120 min by $UV/H_2O_2/O_3$ process and shows high COD and color removal efficiencies. The optimum concentration of $H_2O_2$ dosage was found to be 0.5 M, 25 mM and 5 mM for $UV/H_2O_2$, $O_3/H_2O_2$ and $UV/H_2O_2/O_3$ processes respectively, Organic destruction efficiency was enhanced and also reducing the consumption of $H_2O_2$ dosage by combining UV, $H_2O_2$ and $O_3$ process.

Physicochemical Characteristics and Analysis of Pollution Potential in the Sediments of the Rivers Flowing into the Saemangeum Reservoir (새만금호 유입 하천 하상 퇴적물의 물리화학적 특성과 오염도 분석)

  • Oh, Kyoung-Hee;Yu, Mi-Na;Cho, Young-Cheol
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.12
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    • pp.861-867
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    • 2011
  • In order to understand the extent of contamination of the sediments on the Mankyoung and Dongjin Rivers flowing into the Saemangeum Reservoir, the concentrations of ignition loss (IL), COD, total nitrogen (T-N), total phosphorus (T-P), and heavy metals (As, Cd, Cr, Pb, Zn) were measured. The average concentrations of IL, COD, and T-P were 2.40 (${\pm}2.18$)%, 2.97 (${\pm}3.06$) mg/g sediment, 0.370 (${\pm}0.351$) mg/g sediment, respectively, showing the extent of contamination is not serious. However, the concentrations of these parameters in the samples taken in year 2009 were higher than those in year 2008, indicating the contamination of sediments goes on gradually. The concentrations of T-N were in the range of 0.59~13.11 mg/g sediment with variation of locations and seasons. It was determined that the T-N contamination is serious when the concentrations were compared with the dredging guidelines of sediments in the Korean freshwaters, indicating the countermeasures are required to maintain the water quality of the Saemangeum Reservoir. The concentrations of heavy metals except chromium did not exceed the worrisome level of soil contamination stipulated by the Soil Environment Conservation Act of Korea. The high concentration of chromium to be concerned in some samples from the upstream of Mankyoung River requires source analysis and countermeasure to control the contamination.

Environmental Characteristics of Natural Conditions of the Flat Oyster, Ostrea denselamellosa in Haechang Bay, Korea (해창만 벗굴, Ostrea denselamellosa 서식지의 환경특성)

  • 양문호;한창희;김형섭;최상덕
    • The Korean Journal of Malacology
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    • v.15 no.2
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    • pp.105-113
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    • 1999
  • This study was measured environmental factors of flat oyster habitats and biomass of flat oyster to improve the productivity of flat oyster. Water temperature and salinity of the flat oyster habitat ranged from 5.5 to 27.4$^{\circ}C$ and from 31.2 to 33.4 , respectively. Average concentrations of DO, COD, DIN and PO$\_$4/$\^$3/ -P were 7.11 mg/l, 4.55 $\mu\textrm{g}$-at./l and 0.36 $\mu\textrm{g}$-at./l respectively. Surface sediments at the sampling area were composed of coarse sand, sandy silt and silty sand. Average level of IL, COD and AVS in the surface sediments were 2.6%, 13.70 mg/g dry and 0.33 mg/g dry respectively. In each sampling station, total standing crops of phytoplankton showed peaks twice in February and August. Dominant species of phytoplankton occurred in Haechang Bay throughout the year were Skeletonema costatum, Paralia sulcata, Eucampia zodiacus, Chaetoceros curvicetus, C. affinis, C. debilis, C. decipiens, Asterionella glacialis, Pseudonitzschia longissima, Pseudonitzschia seriata, Ceratium furca and C. fusus. Ten species of the bivalves were collected at the flat oyster habitat. Most of bivalves were the eutrophic species Ostrea denselamellosa, Crassostrea gigas, Ruditapes philippinarum, Scaphraca subcrenata, Scapharca broughtonii, Atrina pectinata, Fulvia mutica, Mytilus edulis, Protothaca jedoensis and Megacardita ferruginosa. The mean density of them was 21 inds./㎡ (479.14 g/㎡), while that of the flat oyster was at 0.25 inds./㎡ (231.25 g/㎡).

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Density Dependent Growth and Survival Rates of Atrina pectinata in Duekryang Bay, Korea (득량만 키조개, Atrina pectinata의 양성밀도에 따른 성장과 생존율)

  • Kim, Dae-Hong;Yoon, Ho-Seop;An, Yun-Keun;Lee, Sa-Dong;Choi, Sang-Duk
    • The Korean Journal of Malacology
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    • v.24 no.2
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    • pp.137-142
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    • 2008
  • Growth and survival rates dependent on the density of a pen sell, Atrina pectinata were measured from Duekryang bay in Korea. Annual water temperature and salinity of the study area were ranged from 14.5 to $28.0^{\circ}C$ and from 27.98 to 31.89 psu, respectively. The pH, DO, COD, DIN, Chl-a and SPM in the study area ranged from 7.78-8.35 mg/L, 7.07-7.90 mg/L, 1.20-1.70 mg/L, 2.88-6.02 mg/L, 0.20-0.79 mg/L and 10.8-21.4 mg/L. The IL, COD and AVS in sediments ranged from 4.0-4.6%, 7.28-10.76 mg/L and 0.03-0.05 mg/L respectively. The daily growth rate of shell height and total weight were 0.27%, 0.33%(5 indiv./$m^2$), 0.26, 0.29%(10 indiv./$m^2$) and 0.21, 0.20%(35 indiv./$m^2$). The survival rate also decreased along the density gradient; highest at the lowest density of 5 indiv./$m^2$ and lowest at the maximum density of 35 indiv./$m^2$.

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Study of Characteristics of Seasonal Fluctuation of Water Quality and Sediment Environment in Kamak Bay in 2007 (2007년 가막만의 해양수질 및 저질의 계절 변동에 관한 연구)

  • Cho, Hyun-Seo;Cho, Geun-Ock;Park, Jeong-Chae;Kim, Hae-Ju
    • Proceedings of KOSOMES biannual meeting
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    • 2008.05a
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    • pp.129-132
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    • 2008
  • This study was performed to characterize the seasonal variation of water quality and sediment environment from May, 2007 to February, 2008 in 20 stations of Kamak bay. $4.83\sim11.07mg/L$ on surface and $4.70\sim11.19mg/L$ on bottom in DO, $0.16\sim2.03mg/L$ on surface and $0.10\sim1.55mg/L$ on bottom in COD, $0\sim3.04{\mu}g$-at/L on surface and $0\sim15.21{\mu}g$-at/L on bottom in DIN, $0\sim3.04{\mu}g$-at/L on surface and $0\sim2.01{\mu}g$-at/L on bottom in DIP. IN sediment the ranges were 3.80 to 9.78% in IL, $0\sim5.37mg/g$-dry in AVS and $3.09\sim41.01mg/g$-dry in COD.

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Study of Characteristics of Seasonal Fluctuation of Water Quality and Sediment Environment in Gwangyang Bay in 2007 (2007년 광양만의 해양수질 및 저질의 계절 변동에 관한 연구)

  • Yu, Jin-Ho;Cho, Hyeon-Seo;You, Young-Seok;Park, Jeong-Chae;Kim, Yong-Ok
    • Proceedings of KOSOMES biannual meeting
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    • 2008.05a
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    • pp.133-136
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    • 2008
  • This study was performed to characterize the seasonal variation of water quality and sediment environment from February, 2007 to October, 2007 in 21 stations of Gwangyang bay. $6.03\sim11.98mg/L$ on surface and $4.43\sim10.71mg/L$ on bottom in DO, $0.12\sim3.16mg/L$ on surface and $0.20\sim2.64mg/L$ on bottom in COD, $0.23\sim18.28{\mu}g$-at/L on surface and $0.33\sim9.56{\mu}g$-at/L on bottom in DIN, ND$\sim1.47{\mu}g$-at/L on surface and $0\sim4.56{\mu}g$-at/L on bottom in DIP. IN sediment the ranges were $2.86\sim21.17%$ in IL, $0\sim6.11mg/g$-dry in AVS and $2.64\sim23.23mg/g$-dry in COD.

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Contents of Inorganic Elements in Shellfish and Geochemical Characteristics of Surface sediments on the West Coast of Korea (서해연안 패류의 성분원소 함량 및 퇴적물의 지화학적 특성)

  • Choi, Yoon Seok;Park, Kwang Jae;Song, Jae Hee;Yoon, Sang Pil;Chung, Sang Ok;An, Kyoung Ho
    • The Korean Journal of Malacology
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    • v.28 no.3
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    • pp.225-232
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    • 2012
  • In order to evaluate the relationship of between the contents of inorganic elements in shellfish and surface sediments, we measured the concentration of inorganic elements (As, Ca, Cd, Cr, Fe, Hg, Li, Mn, Ni, P, Pb, Zn) in various shellfish and surface sediments of research area. The enrichment factor (EF) and the index of accumulation rate (Igeo) of the metals showed that the research areas can be classified as moderately polluted, or unpolluted. And also we measured the geochemical characteristics of surface sediments(grain size, chemical oxygen demand (COD), ignition loss (IL) and acid volatile sulfide (AVS). The grain sizes for research areas of surface sediment were similar the ratio of silt and clay in comparison with other sites. The COD and IL in surface sediment ranged from 5.41 to 14.06 mg/g. d.w. (mean $8.78{\pm}3.16$ mg/g d.w.) and from 0.92 to 3.17% (mean $2.08{\pm}0.86%$), respectively. Siginificant differences in metal concentrations also were determinated in the shellfish tissue among the different sites. However, except for metals(Mn, Zn), which showed some elevation of concentrations, the variations in the shellfish tissue were not related to variations in the sediment.

Environmental Characteristics and Distributions of Marine Bacteria in the Surface Sediments of Kamak Bay in Winter and Summer (동 . 하계 가막만 표층 퇴적물의 환경특성과 해양미생물의 분포)

  • Lee, Dae-Sung;Kim, Yun-Sook;Jeong, Seong-Yun;Kang, Chang-Keun;Lee, Won-Jae
    • Journal of Environmental Science International
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    • v.17 no.7
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    • pp.755-765
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    • 2008
  • To investigate correlation between the distribution of marine bacteria and environmental characteristics in the surface sediments of Kamak Bay, chemical oxygen demand(COD), acid volatile sulfide(AVS), ignition loss(IL), total organic carbon(TOC), and total organic nitrogen(TON) were measured and analyzed at 7 stations in winter and summer. In winter, COD and AVS ranged from 13.45 mg/g to 30.06 mg/g(average: 23.58 mg/g) and from 0.03 mg/g to 1.04 mg/g(average: 0.63 mg/g), respectively. IL, TOC, and TON ranged from 8.03% to 11.41%(average: 9.41%), from 1.17% to 2.10%(average: 1.62%), and from 0.09% to 0.18%(average 0.15%), respectively. In summer, COD, AVS, IL, TOC, and TON ranged from 14.06 mg/g to 32.19 mg/g(average: 24.71 mg/g), from 0.03 mg/g to 1.11 mg/g(average: 0.66 mg/g), from 9.00% to 12.15%(average: 10.96%), from 1.27% to 2.12%(average 1.77%), and from 0.12% to 0.19%(average: 0.16%), respectively. These values were relatively higher than those in winter. Kamak Bay had high C/N ratio that might be resulted from the input of terrestrial sewage and industrial wastewater. The number of marine viable bacteria was $8.9{\times}10^4\;cfu/g$ in winter and $9.7{\times}10^5\;cfu/g$ in summer. The most abundant species were Pseudomonas spp., Flavobacterium spp., and Vibrio spp, in the surface sediments of Kamak Bay. It was found that the concentration of organic matters and viable bacterial cells in the inner part were relatively higher than those in the outer of Kamak Bay. The distribution of viable bacterial cells was closely influenced by environmental factors.