• Title/Summary/Keyword: COD(chemical oxygen demand)

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TiO2 Combining Spherical Activated Carbon Photocatalysts and Their Physicochemical and Photocatalytic Activity

  • Oh, Won-Chun;Kim, Jong-Gyu;Kim, Hyuk;Chen, Ming-Liang;Zhang, Feng-Jun;Zhang, Kan;Choi, Jong-Geun;Meng, Ze-Da
    • Korean Journal of Materials Research
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    • v.20 no.10
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    • pp.535-542
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    • 2010
  • In this study, we used coal-based activated carbons and charcoal as startingmaterials, phenolic resin (PR) as a binder, and TOS as a titanium source to prepare $TiO_2$ combining spherical shaped activated carbon photocatalysts. The textural properties of the activated carbon photocatalysts (SACP) were characterized by specific surface area (BET), energy dispersive X-ray spectroscopy (XRD), scanning electron microscopy (SEM), iodine adsorption, strength intensity, and pressure drop. The photocatalytic activities of the SACPs were characterized by degradation of the organic dyes Methylene Blue (MB), Methylene Orange (MO), and Rhodamine B (Rh. B) and a chemical oxygen demand (COD) experiment. The surface properties are shown by SEM. The XRD patterns of the composites showed that the SACP composite contained a typical single, clear anatase phase. The EDX spectro for the elemental indentification showed the presence of C and O with Ti peaks. According to the results, the spherical activated carbon photocatalysts sample of AOP prepared with activated carbon formed the best spherical shape, a high BET surface area, iodine adsorption capability and strength value, and the lowest pressure drop, and the photocatalytic activity was better than samples prepared with charcoal. We compared the degradation effects among three kinds of dyes. MB solution degraded with the SACP is better than any other dye solutions.

A Study on the Ecology of the Golden Apple Snail, Pomacea canaliculata (Lamark) in Chungnam and Jeonbuk Province of Korea (충남 및 전북지역의 왕우렁이 생태 연구)

  • Seo, Hong-Yul;Paik, Chae-Hoon;Choi, Man-Young;Lee, Geon-Hwi;Lee, Kyeong-Bo;Noh, Tae-Hwan
    • Korean Journal of Environment and Ecology
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    • v.24 no.6
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    • pp.772-780
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    • 2010
  • The golden apple snail-Pomacea canaliculata was an alien species and introduced into Korea as table use in 1983. This species is possible pest in direct seeded rice paddy in Korea. We investigated the effects of this exotic snail on the macrophytes and the water quality in water canal. Also, the basic life cycle of this species and the overwintering ecology in Chungnam and Jeonbuk province were elucidated. A survey of natural water canal in Korea showed that high densities of the snail were associated with absences of macrophytes-Hydrilla verticillata, Ceratophyllum demersum, Spirodela polyrhiza and Lemna perpusilla. Experiments in water tank also demonstrated that the golden apple snail can cause the loss of macrophytes, and increase the EC(Electric conductivity), COD(Chemical oxygen demand), T-N(Total nitrogen) and T-P(Total phosphorus) in water.

Assessment of Water Quality in the Lower Reaches Namhan River by using Statistical Analysis and Water Quality Index (WQI) (통계분석 및 수질지수를 이용한 남한강 하류 유역의 수질 평가)

  • Cho, Yong-Chul;Choi, Hyeon-Mi;Ryu, In-Gu;Kim, Sang-hun;Shin, Dongseok;Yu, Soonju
    • Journal of Korean Society on Water Environment
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    • v.37 no.2
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    • pp.114-127
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    • 2021
  • Water pollution in the lower reaches of the Namhan River is getting worse due to drought and a decrease in water quantity due to climatic changes and hence is affecting the water quality of Paldang Lake. Accordingly, we have used a water quality index (WQI) and statistical analysis in this study to identify the characteristics of the water quality in the lower reaches of the Namhan River, the main causes of water pollution, and tributaries that need priority management. Typically, 10 items (WT, pH, EC, DO, BOD, COD, SS, T-N, T-P, and TOC) were used as the water quality factors for the statistical analysis, and the matrix of data was set as 324 × 10·1. The correlation analysis demonstrated a strong correlation between Chemical Oxygen Demand (COD) and T-P with a high statistical significance (r=0.700, p<0.01). Furthermore, the result of principal component analysis (PCA) revealed that the main factors affecting the change in water quality were T-P and organic substances introduced into the water by rainfall. Based on the Mann-Kendall test, a statistically significant increase in pH was observed in SH-1, DL, SH-2, CM, and BH, along with an increase in WQI in SH-2 and SM. BH was identified as a tributary that needs priority management in the lower reaches of the Namhan River, with a "Somewhat poor" (IV) grade in T-P, "Fair" grade in WQI, and "Marginal" grade in summer.

A Study on the Introduction of a Total Pollutant Load Management System in Gwangyang Bay, Korea (광양만 특별관리해역의 연안오염총량관리 도입에 관한 연구)

  • Kim, DoHee;Park, JongSick;Han, KiWon;Cho, HyeonSeo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.6
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    • pp.899-905
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    • 2022
  • Seawater management via Total Pollutant Load Management System (TPLMS) is crucial because it enables local governments to optimally allocate pollutant loads in order to best reduce pollutant load burden while supporting reasonable development. This study analyzed the feasibility of introducing a TPLMS on Gwangyang Bay, a specially managed sea area. We researched the inflow of pollutants and analyzed the present state of seawater quality in Gwangyang Bay and then discussed our findings and reviewed other specially managed sea area with the Gwangyang Bay Advisory Committee. We conclude that TPLMS on Gwangyang Bay is needed and suggest checking economic feasibility, ef iciency, and conducting continuous monitoring of seawater quality indicators such as chemical oxygen demand (COD), total nitrogen (TN), total phosphorus (TP), heavy metals and polcyclic aromatic hydrocarbons (PAHs) prior to introducing a TPLMS in Gwangyang Bay.

Identification of bacteria isolated from rockworm viscera and application of isolated bacteria to shrimp aquaculture wastewater treatment

  • Ja Young Cho;Kyoung Sook Cho;Chang Hoon Kim;Joong Kyun Kim
    • Korean Journal of Environmental Biology
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    • v.41 no.2
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    • pp.167-178
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    • 2023
  • Large amounts of waste and wastewater from aquaculture have negatively impacted ecosystems. Among them, shrimp aquaculture wastewater contains large amounts of nitrogen contaminants derived from feed residues in an aerobic environment. This study isolated candidate strains from adult rockworms to treat shrimp aquaculture wastewater (SAW) in an aerobic environment. Among 87 strains isolated, 25 grew well at the same temperature as the shrimp aquaculture with excellent polymer degradation ability (>0.5 cm clear zone). Six isolates (strains AL1, AL4, AL5, AL6, LA10, and PR15) were finally selected after combining strains with excellent polymer degradation ability without antagonism. 16S rRNA sequencing analysis revealed that strains AL1, AL4, AL5, AL6, LA10, and PR15 were closely related to Bacillus paramycoides, Bacillus pumilus, Stenotrophomonas rhizophila, Bacillus paranthracis, Bacillus paranthracis, and Micrococcus luteus, respectively. When these six isolates were applied to SAW, they reached a maximum cell viability of 2.06×105 CFU mL-1. Their chemical oxygen demand (CODCr) and total nitrogen(TN) removal rates for 12h were 51.0% and 44.6%, respectively, when the CODCr/TN ratio was approximately 10.0. Considering these removal rates achieved in this study under batch conditions, these six isolates could be used for aerobic denitrification. Consequently, these six isolates from rockworms are good candidates that can be applied to the field of aquaculture wastewater treatment.

Effect of Humified Straw Used as a Medium of Trickling Filter with Livestock Wastewater on the Growth of Bunching Lettuce (Lactuca sativa L., var. crispa) and Soil Chemical Properties (축산폐수(畜産廢水) 살수여상충전재(撒水濾床充塡材)인 볏짚의 부숙처리가 상추(Lactuca sativa L., var. crispa)의 생육(生育)과 토양화학성(土壤化學性)에 미치는 영향(影響))

  • Kim, Jeong-Je;Yang, Jae-E;Shin, Young-Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.2
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    • pp.137-144
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    • 1996
  • A feasible way to utilize small-scale livestock farm wastewater was explored. In place of common support materials rice straw was employed as a support medium of trickling filter for pig farm wastewater treatment. The straw medium which was humified for 20 days after wastewater treatment and mixed with soil significantly enhanced in general the development of bunching lettuce grown under greenhouse conditions. Improvement of soil chemical properties in terms of fertility was also achieved by the addition of humified straw medium after wastewater treatment. It was found that rice straw served as a satisfactory support medium of trickling filters with the wastewater treatment concerning removals of biological oxygen demand, chemical oxygen demand, and suspended solids.

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Performance of Parallel Current Air Driven Type Foam Separator in a Pilot-Scale Recirculating Aquaculture System (Pilot-scale 순환여과식 양식장에서 병류 공기구동식 포말분리장치의 성능)

  • Suh Kuen Hack;Kim Byong Jin;Kim Yong Ha;Lee Seok Hee;Suh Cha Soo;Cheon Jae Kee;Jo Jea Yoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.2
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    • pp.140-145
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    • 2002
  • The performances of a parallel current air driven type foam separator were evaluated in the pilot-scale recirculating aquaculture system. The system was stocked with Nile tilapia (Oreochromis niloticus) at an initial rearing densities of $2\%$, $5\%$ and $7\%$ of water volume of rearing tank and reared for 15, 30, 35 days, respectively. The condensated volume of effluent foam was increasing with increased rearing density. As increasing rearing density from $2\%$ to $7\%$, the protein concentration in rearing tank was increased from 16.6 g/$m^3$ to 21,9 g/$m^3$ and the removal amount of protein through foam separator as increased from 0.99 g/day to 2.5 g/day. But protein concentration ratio in the foam was decreased from 3.2 to 1.9. Changes of the removal amount and the concentration ratios of total suspended solid (TSS) and chemical oxygen demand (COD_cr.) were similar to proteins. The highest concentration ratios of TSS and COD_cr. were 10.2 and 8.4 at 2$2\%$ of rearing density.

Winter Algal Bloom and Spatial Characteristics of Water Quality in the Lower Taewha River, Ulsan, Korea (태화강 하류에서 겨울철 조류 발생과 수질의 공간적 특성)

  • Sohn, Eun Rak;Park, Jung Im;Lee, Bora;Lee, Jin Woo;Kim, Jongseol
    • Korean Journal of Microbiology
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    • v.49 no.1
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    • pp.30-37
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    • 2013
  • This study was carried out to assess the spatial and tidal effects on the water quality in the lower reaches of Taewha River, Ulsan, Korea and to understand the environmental factors affecting winter algal bloom in the river. From May, 2010 to January, 2011, water samples were collected at five locations (New Samho Bridge, Old Samho Bridge, Mungjung Stream, Taewha Bridge, and Mungchon Bridge) along the river at high and low tides of spring tide. We measured environmental parameters including salinity, dissolved oxygen (DO), biological oxygen demand (BOD), chemical oxygen demand (COD), chlorophyll a (Chl a) and various nutrient concentrations. Salinity increased towards the downstream direction. Average values of Chl a concentrations ranged $10-26mg/m^3$ at high tide and $11-53mg/m^3$ at low tide depending on sampling locations. It was noteworthy that there were strong increases in Chl a concentrations during the November 21 to December 22 sampling period especially at the Taewha Bridge. At the location, Chl a concentrations were measured as $138-296mg/m^3$ for the period; Rhodomonas lacustris of class Cryptophyceae was the dominant algal species. Chl a concentrations at the Taewha Bridge were positively correlated with such parameters as salinity, BOD, DO, COD, pH, and T-N, and negatively correlated with temperature and $NO_3{^-}$-N. On the other hand, at the Mungchon Bridge the highest concentration of Chl a was $55mg/m^3$ on August 25, and Chl a concentrations were positively correlated with $NH_3$-N, T-N, $PO_4{^{3-}}$-P, T-P, and heterotrophic plate counts. The results suggested that water quality in the lower Taewha River fluctuated a lot with the sampling locations and the patterns of algal blooms were different between Taewha Bridge and Mungchon Bridge sampling locations.

Evaluation of Treatment Efficencies of Pollutants in Juksancheon Constructed Wetlands for Treating Non-point Source Pollution (비점오염원 저감을 위한 죽산천 인공습지의 오염물질 정화효율 평가)

  • Choi, Ik-Won;Seo, Dong-Cheol;Kang, Se-Won;Lee, Sang-Gyu;Seo, Young-Jin;Lim, Byung-Jin;Park, Jong-Hwan;Kim, Kap-Soon;Heo, Jong-Soo;Cho, Ju-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.642-648
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    • 2012
  • To evaluate the water quality in Juksancheon constructed wetlands for treating non-point source pollution, the removal rates of nutrients in water and the total amounts of T-N and T-P uptakes by water plants were investigated. Chemical characteristics of T-N and T-P in sediment were investigated. The concentrations of BOD (Biochemical Oxygen Demand), COD (Chemical Oxygen Demand), SS (Suspended Solids), T-N and T-P in inflow were 0.07~1.47, 0.60~2.65, 0.50~4.60, 1.38~6.26 and $0.08{\sim}0.32mg\;L^{-1}$, respectively. The removal rates of BOD, COD, SS, T-N, and T-P were -10, 51, 66, -3 and 5%, respectively. The maximum amount of T-N uptake by water plants in August was $368.7mg\;plant^{-1}$ in the $2^{nd}$ treatment stage by Nymphoides peltata, $1314.6mg\;plant^{-1}$ in the $3^{rd}$ treatment stage by Iris pseudacorus, $1160.4mg\;plant^{-1}$ in the $4^{th}$ treatment stage by Nymphaea tetragona GEORGI, respectively. The maximum amount of T-P uptake by water plants in August was $121.7mg\;plant^{-1}$ by Nymphoides peltata in the $2^{nd}$ treatment stage, $268.7mg\;plant^{-1}$ by Iris pseudacorus in the $3^{rd}$ treatment stage and $212.0mg\;plant^{-1}$ by Nymphaea tetragona GEORGI in the $4^{th}$ treatment stage, respectively. Organic matter contents in sediments were not different. Contents of T-N and T-P in sediments were higher in spring. Microbial biomass C:N:P ratios in sediments in spring, summer, autumn and winter were 117~140:1~4:1, 86~126:5~6:1, 68~101:2~6:1 and 47~138:2~4:1, respectively. We could conclude that Juksancheon constructed wetlands show high removal efficiencies of COD and SS. However, improvements of management in winter season should be considered to improve the removal efficiencies of pollutants.

A Study on the Applicability of Soilremediation Technology for Contaminated Sediment in Agro-livestock Reservoir (농축산저수지 오염퇴적토의 토양정화기술에 대한 적용성 연구)

  • Jung, Jaeyun;Chang, Yoonyoung
    • Journal of Environmental Impact Assessment
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    • v.29 no.3
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    • pp.157-181
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    • 2020
  • Sediments from rivers, lakes and marine ports serve as end points for pollutants discharged into the water, and at the same time serve as sources of pollutants that are continuously released into the water. Until now, the contaminated sediments have been landfilled or dumped at sea. Landfilling, however, was expensive and dumping at sea was completely banned due to the London Convention. Therefore, this study applied contaminated sedimentation soil of 'Royal Palace Livestock Complex' as soil purification method. Soil remediation methods were applied to pretreatment, composting, soil washing, electrokinetics, and thermal desorption by selecting overseas application cases and domestically applicable application technologies. As a result of surveying the site for pollutant characteristics, Disolved Oxigen (DO), Suspended Solid (SS), Chemical Oxygen Demand (COD), Total Nitrogen (TN), and Total Phosphorus (TP) exceeded the discharged water quality standard, and especially SS, COD, TN, and TP exceeded the standard several tens to several hundred times. Soil showed high concentrations of copper and zinc, which promote the growth of pig feed, and cadmium exceeded 1 standard of Soil Environment Conservation Act. In the pretreatment technology, hydrocyclone was used for particle size separation, and the fine soil was separated by more than 80%. Composting was performed on organic and Total Petroleum Hydrocarbon (TPH) contaminated soils. TPH was treated within the standard of concern, and E. coli was analyzed to be high in organic matter, and the fertilizer specification was satisfied by applying the optimum composting conditions at 70℃, but the organic matter content was lower than the fertilizer specification. As a result of continuous washing test, Cd has 5 levels of residual material in fine soil. Cu and Zn were mostly composed of ion exchange properties (stage 1), carbonates (stage 2), and iron / manganese oxides (stage 3), which facilitate easy separation of contamination. As a result of applying acid dissolution and multi-stage washing step by step, hydrochloric acid, 1.0M, 1: 3, 200rpm, 60min was analyzed as the optimal washing factor. Most of the contaminated sediments were found to satisfy the Soil Environmental Conservation Act's standards. Therefore, as a result of the applicability test of this study, soil with high heavy metal contamination was used as aggregate by applying soil cleaning after pre-treatment. It was possible to verify that it was efficient to use organic and oil-contaminated soil as compost Maturity after exterminating contaminants and E. coli by applying composting.