• 제목/요약/키워드: COD$NH_3-N$

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하수의 질소제거시 컴퓨터 시뮬레이션을 이용한 UCT(University of Cape Town) 공정의 운영인자 검토 (Investigation of Operating Parameters on UCT Process for the Purpose of Nitrogen Removal Using Computer Simulation)

  • 김병군;서인석;이해군;김창원
    • 환경위생공학
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    • 제13권2호
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    • pp.66-75
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    • 1998
  • The computer simulation model was used to forecast the concentrations of COD$_{cr}$, NH$_{4}$$^{+}$-N and NO$_{3}$$^{-}$-N in each reactors. In the biological wastewater treatment system, the computer simulation model was used to observe the behavior of pollutants especially. In this research, effect of SRT, feeding pattern and recirculation rate on UCT(University of Cape Town) process was evaluated by computer simulation model. T-N removal was affected to the SRT. SRT for effective T-N removal was 15 days or longer. Feeding pattern in UCT process was affected to the T-N removal. Feeding pattern which 100% loading to the first reactor was most effective for T-N removal. The effect of recirculation rate was clear for T-N removal. The recirculation from anoxic reactor to anaerobic reactor was not need but the recirculation from oxic reactor to anoxic reactor was need. In aspect of nitrogen removal efficiency, A/O process was higher than UCT process.

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매립지 주변 지하수오염 조사

  • 이창수
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2004년도 가을 학술발표회지 제13권(제2호)
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    • pp.133-135
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    • 2004
  • 1. 침출수 수질 조사결고, pH는 $3.7\~5.0,\;COD_{Mn}$$760\~1,800mg/\ell,\;NO_3-N\;26.124\~78.150mg/\ell,\;NH_3-N$$144.5\~350mg/\ell,\;Cl^-$$13272.0\~34137.0mg/\ell$,는 $450\~1620mg/\ell$, SS는 $81.2\~652.7mg/\ell$, T-N은 $228\~430mg/\ell$, T-P는 $0.921\~1.108mg/\ell$로 분석되었으며, 중금속류는 거의 검출되지 않았다. 2. 지하수 수질조사결과, 수질상태는 지하수를 생활용수, 농업용수, 어업용수 및 공업용수로 이용하는 수질기준을 모두 만족시키고 있으며, 또한 분석을 실시한 항목에 대한 전조사지점이 대장균군을 제외한 수질조사 항목의 먹는 샘물기준을 만족시키고 있는 것을 확인할 수 있다. 3. 토양오염도 조사결과, 농경지 및 산업지역의 토양오염 우려기준을 크게 밑도는 것으로 분석되어 대상 매립지에서 발생하는 침출수 및 소각재 등의 주변지역 토양오염에 미치는 영향은 미약한 것으로 추정된다.

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Factor Analyses for Water Quality Indicators of Streams, Ground Water, and Reservoir in Agricultural Small Catchments of the Han River Basin

  • Park, C-S;Joo, J-H;Jung, Y-S;Yang, J-E
    • 한국환경농학회지
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    • 제19권5호
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    • pp.382-393
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    • 2000
  • The principal indicators contributing to water qualities was screened by factor analyses, based on the monitored chemical parameters of water quality for various water resources from 1995 to 1999 in the small agricultural catchments of the Han River Basin. Water samples of streams, groundwaters, and reservoirs were taken four times a year from upper (Daegwanryong), middle (Dunnae and Chunchon) and lower (Guri) reaches of Han River Basin. In these areas, the respective type of farming practiced was alpine agriculture and livestocks raising, typical upland and paddy cultivation, and intensive cropping in the plastic film house. Water quality was monitored for twenty-one water quality parameters, including pH, EC, SS, T-N, T-P, COD, cations, anions, and heavy metals. pH, EC and COD of the stream waters were suitable for the Korea irrigation water quality guidelines. However, T-N and T-P concentrations of water samples in four catchments far exceeded the irrigation water guideline. Concentrations of canons and heavy metals in Wangsuk stream in Guri area were higher than those in streams in other areas. Factor analysis revealed that significant correlation was observed for 81 pairs out of 231 water quality indicators of stream water among the $21\;{\times}\;21$ cross correlation matrix of stream water quality indicators. The first factor accounted for 27.01% of the total variation in stream water quality indicators, and high positive factor loadings were shown on EC, K, Na, $NH_4\;^+-N$, $PO_4\;^{3-}$, $SO_4\;^{2-}$, and COD. Fifty-three water quality indicator pairs were significant out of 190 ground water quality parameters. The first factor accounted for 28.54% of the total variation in ground water quality indicators, and high loadings were revealed on EC, Ca, Mg, K, Na, $NH_4\;^+-N$, and $SO_4$. Twenty-nine pairs of reservoir water quality indicators were significant out of 66 pairs. The first factor accounted for 37.06% of the total variation in reservoir water quality indicators, and high loadings were shown on EC, Mg, K, Na, SS, T-P, Cl, and COD. These results demonstrate that EC was the first factor contributing to water quality.

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도시폐기물 매립지 침출수의 적정처리에 관한 연구 -난지도 폐기물 매립지 침출수를 대상으로- (A Study on the Adequate Treatment of Municipal Landfill Leachate -A Case Study of Nanjido Landfill Leachate-)

  • 이병인
    • 한국환경과학회지
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    • 제4권3호
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    • pp.117-117
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    • 1995
  • An experimental research was conducted in order to study the treatability of municipal landfill leachate using a combined physio-chemical and biological treatment. The leachate was obtained from Nanjido landfill site in Seoul. Several sets of bench-scale sequencing batch reactor(SBR) and physic-chemical reactors were used as experimental apparatus. This experiment lasted for about 2 years. The results are as follows: 1. The characteristics of Nanjido landfill leachate were pH 7.4~8.2, BOD 79~450mg/L, COD 998~1460mg/L, $NH_3-N$ 1380~3412mg/L, 7-P 2.6~7.0mg/L, color 890~1992 unit, and heavy metals are a very small amount. 2. Either physio-chemical or biological treatment of Landfill leachate alone did not work well. So for the adequate treatment of leachate, it was necessary to deal with the physio-chemical pretreatment before biological treatment. And it was found that both electrolysis and ozone treatment are better pretreatments of leachate than others. 3. In this study, landfill leachate was effectively processed by two step : first by electrolysis pretreatment, and secondly by SBR treatment. Thus, the study showed considerable substrate removal of raw leachate, even though the rate of COD removal depended on HRT.

오존을 이용한 유기물 및 세균의 제거 특성에 관한 연구 (A Study on the Removal Characteristics of Organic matter and Bacteria with the Use of Ozone)

  • 이관영;박상현
    • 한국산업융합학회 논문집
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    • 제10권1호
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    • pp.15-20
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    • 2007
  • The aim of this study is to measure the removal characteristics of organic matter and bacteria with the use of ozone to reduce the problems caused by bacteria and organic matter which appear in sea-water is summer season. When the total input of ozone was $1.4mg/{\ell}O_3$, the removal rate of bacteria and E-coli from sea-water proved to be 100%. With the same input of ozone, on the other hand, the removal rate of COD turned to be relatively low, 50%, which was to the fact that sea-water consists of salt matter which is a kind of COD matter. This result supports the idea that we can keep using ozone steadily in the future to remove organic matters and bacteria from sea-water because ozone destructs relatively less salt matter in sea-water. Also, the treatment effect rate of SS, turbidity and organic matters such as $NH_3$-N, $NO_3$-N etc, was very high. As a result, we assume that the treatment of organic matter in sea-water with ozone is very effective

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사용종료매립지에서 시간경과에 따른 침출수의 특성 (Characteristics of Leachate with Passed Time in Expired Landfill)

  • 김은호;김형석;성낙창;허종수
    • 한국환경농학회지
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    • 제16권2호
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    • pp.136-141
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    • 1997
  • 부산광역시의 대표적인 사용종료 쓰레기매립지인 H. 매립지, S. 매립지와 E. 매립지의 시간에 따른 침출수의 특성을 조사한 결과를 요약하면 다음과 같다. 1. 최근에 사용종료된 E. 매립지의 경우 H. 와 S. 매립지에 비하여 pH 변화특성이 아주 급격하게 증가하는 추세를 나타내고 있는데, 이는 혐기성 분해작용으로 인하여 생성된 $NH_3$ 용해와 $NO_3$의 탈질과정으로 pH가 상승하는 것으로 추정된다. 2. BOD와 $COD_{Cr}$의 변화는 아주 크며, E.와 S. 매립지의 경우 매립초기에는 비슷한 농도로 높은 반면에 H. 매립지의 초기농도는 낮게 보이고 있는데, 이는 매립당시 쓰레기의 성상이 다른 매립지에 비하여 유기성 물질의 농도가 낮기 때문으로 판단된다. 3. 가연성 물질 중 음식물류가 차지하는 비율이 높은 E. 매립지의 경우 H.와 S. 매립지에 비하여 초기부터 전반적으로 고농도의 SS를 유지하고 있으며, 상당히 심하게 농도가 변화하는 것을 알 수 있다. 4. 매립시간이 경과할수록 T-N의 농도가 증가하는 현상을 보이지만 T-P는 비슷한 양상을 나타내고 있으며 T-N성분은 $NH_3-N$가 대부분을 차지하고 있고 질산성 질소는 거의 미량으로 존재하는 것으로 나타났다. 5. 침출수 중 대표적인 중금속은 대부분이 한계농도 보다 낮은 농도를 보이며 생물학적 처리시 미생물에 그다지 영향을 미치지 않을 것으로 사료된다.

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오존을 이용한 지하수의 철.망간 및 유기물 제거특성 (Removal Characteristics of Iron, Manganese and Organics in Ground Water Using Ozonation)

  • 선창욱;우달식;남상호
    • 환경위생공학
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    • 제12권2호
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    • pp.43-49
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    • 1997
  • Iron and manganese problems in ground water affect far more water systems than almost any other water quality concern. The purpose of this study is to find the optimum condition of ozonation for the removal of dissolved iron, manganese and other organics in the polluted ground water. We proposed 4mg/l, 8mg/l as optimum ozone dose for the removal of $Fe^{2+},{\;}Mn^{2+}$, respectively. The removal efficiencies of $COD_{Mn}$ and $COD_{Cr}$ in ozone dose of 2mg/l - 6mg/l were about 40-50%. The removal efficiency of $NH_{3}-N$ was about 30-40% at pH8.5. In conclusion, it needs further systematic study and research concerned to treatability of $Fe^{2+},{\;}Mn^{2+}$ and biodegradability of organic compounds using Ozonation followed by biological filtration process in ground water treatment train.

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교차 간헐 포기식 부직포 여과막 생물반응조에서 MLSS 농도 및 유입수 C/N 비가 질소 제거효율에 미치는 영향 (Effects of MLSS Concentration and Influent C/N Ratio on the Nitrogen Removal Efficiency of Alternately Intermittently Aerated Nonwoven Fabric Filter Bioreactors)

  • 정경은;배민수;이종호;조윤경;조광명
    • 대한환경공학회지
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    • 제28권5호
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    • pp.501-510
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    • 2006
  • 교대로 간헐적으로 포기되는 2개의 부직포 여과막 생물반응조로 폐수를 처리할 때 반응조의 MLSS 농도와 유입수의 C/N 비가 질소 제거효율에 미치는 영향을 파악하기 위하여 MLSS 농도를 약 5,500 mg/L, 10,000 mg/L 및 15,000 mg/L로 유지하면서 $NH_4Cl$을 첨가하여 유입수의 TCOD/TKN 비를 5, 4, 3 및 2로 감소시켰다. 유입수는 음식물 쓰레기 침출수를 COD농도가 약 300 mg/L되도록 희석시킨 것이었다. 실험 결과, 반응조의 F/M 비는 0.112 g COD/g MLSS-day 이하, COD 제거효율은 95% 이상, 그리고 미생물 성장계수($Y_{obs}$) 값은 평균 0.283 g MLSS/g COD로 나타났다. 질산화 효율은 MLSS 농도가 5,500 mg/L이고 유입수의 TCOD/TKN 비가 2인 경우의 90.5%를 제외하고 모두 96% 이상이었다. 탈질효율은 유입수의 TCOD/TKN 비가 감소할수록 악화되었다. MLSS 농도가 5,500 mg/L인 경우에 비하여 10,000 mg/L인 경우에 탈질효율이 평균 10.7% 더 높아, MLSS 농도가 1,000 mg/L 증가함에 따라 평균 2.66 mg N/L의 율로 탈질율이 증가하였다. 그러나, MLSS 농도가 15,000 mg/L로 유지된 경우에는 5,500 mg/L인 경우에 비하여 탈질효율이 평균 4.6%만 더 높아 MLSS 농도가 1,000 mg/L 증가함에 따라 평균 0.75 mg N/L의 율로 탈질율이 증가하였다. 따라서 MLSS 농도와 내생 탈질율 간에 비례관계가 성립되지 않았다. 알칼리도 소모량은 유입수의 TCOD/TKN 비가 5인 경우에 제거된 T-N 1 mg당 평균 3.36 mg으로서 이론값인 3.57 mg에 가까웠으나 유입수의 TCOD/TKN 비가 감소함에 따라 증가하는 경향을 나타내었다.

만경강 수계 농업용수의 시기별 수질변화 (Change in Agricultural Irrigation Water Quality in Mankyeong River)

  • 이경보;이덕배;이상복;김재덕
    • 한국환경농학회지
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    • 제18권1호
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    • pp.6-7
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    • 1999
  • The water quality at Mankyeong River was surveyed 13 sites of main stream for 6 months from April to September in 1995 and 1997. The monthly average value of $NH_4-N$, $SO_4^{2-}$ and $Cl^-$ showed the highest peak in April while that of $NO_3-N$ showed the highest peak in August. The monthly average value of COD showed the highest peak in September at high temperature season. Concentrations of $NH_4-N$ and $SO_4^{2-}$ in Mankyeong River stream exceeded the standard water quality criteria in many sites. The water quality of Mankyeong River stream was not suitable for the irrigation source excepted the sites such as Hari, Gosan stream and Soyang stream. The floodgate of Mokcheon, Yocheon, Jeonju and Samcheon stream were rapidly polluted by the sewage of city, otherwise the Iksan stream was rapidly polluted by the sewage of swine. The sum of ionic concentrations in Mankyeong River stream was the highest at floodgate of Yocheon by influence of the sewage from city and industry. The order of the major anions and cations concentration in Mankyeong River stream were $SO_4^{2-}$ > $Cl^-$ > $NO_3-N$ > $SO_4^{3-}$ and $Na^+$ > $Ca^{2+}$ > $NH_4^+$ > $Mg^{2+}$ > $K^+$, respectively.

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변형 연속회분식 반응기를 이용한 오수의 고도처리 (Advanced Sewage Treatment by the Modified SBR(Sequencing Batch Reactor) Process)

  • 김병군;서인석;홍성택;정위득
    • 환경위생공학
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    • 제17권3호
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    • pp.46-51
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    • 2002
  • This study was performed to treat a sewage at the upper stream of dam using modified sequencing batch reactor, During the operating period, average $COD_{cr}$, removal efficiency was about 85% but average T-N and ${PO_4}^{3-}-P$ removal efficiencies were 43% and 30% respectively. Because the organic matter was very low compared with nitrogen and phosphorous in influent($BOD_{5}/{NH_4}^{+}-N{\;}={\;}2,{\;}BOD_{5}/{PO_4}^{3-}-P{\;}={\;}15.6$), nitrogen and phosphorus removal efficiency was relatively low. Average nitrogen removal efficiency was 50 % at $10^{\circ}C$ or above and it was 36 % at $10^{\circ}C$ or below. As reactor was located in outdoor without any thermostat, temperature decreased at least $2.4^{\circ}C$ in the winter season. Therefore, if we would apply this modified sequencing batch reactor to sewage which concentration of organic matter was very low compared with nitrogen and phosphorous, we have to addition of external carbon and installation of any thermostat.