• Title/Summary/Keyword: COD$NH_3-N$

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Statistical Analyses of Long-Term Water Quality Variation in the Geumgang-Reservoir: Focused on the TP Load by Migrating Birds Excrement (금강호의 장기 수질 변화요인 분석: 철새배설물에 의한 TP부하의 중요성)

  • Jeong, Yong-Hoon;Kim, Hyun-Soo;Yang, Jae-Sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.4
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    • pp.223-233
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    • 2010
  • Spatio-temporal variations of long-term water qualities (COD, SS, $Chl-{\alpha}$, N-related nutrients (TN, TDN, $NO_3^-$, $NH_4^+$), P-related nutrients (TP, TDP, $PO_4^{3-}$)) at two stations (St. SD, St. GG) in the Geumgang Reservoir were investigated from August 2001 to July 2008. Statistical methods such as t-test, factor analysis, and multi-regression analysis were applied to the water quality data in the reservoir as well as mass balances on TP. From the temporal comparisons of the water qualities between 2002 and 2007, average concentrations of $NH_4^+$, $PO_4^{3-}$, and TDP gradually decreased down by 60%, 24%, 52% in 2007. However, those of TP and $Chl-{\alpha}$ increased to 99% and 423% during the period. From the spatial comparisons between the two stations, St. GG showed higher concentrations for all of the N- and P-related nutrients than in St. SD, while opposite result for the $Chl-{\alpha}$. The factor analysis showed that "the seasonal variations of N- and P-related nutrients" were the two dominant factors occupying 49% of total variances of water qualities. Based on this result, multi-regression analysis executed for the two most influential parameters (TP and $Chl-{\alpha}$) focusing on the seasonal variations of these parameters: SS and $Chl-{\alpha}$ has contributed decisively to the concentrations of TP during the wet and dry season, respectively. On the other hand, COD and TP has been important for the $Chl-{\alpha}$ during the wet and dry season, respectively. From the established mass balances of TP loadings in the Geumgang Reservoir, Other Sources (60%) occupied the greatest contribution and Fluvial Input (38%) and Sediment (1%) during the wet season. However, both Fluvial Water (48%) and Other Sources (47%) supplied comparable amount of inputs and Sediment (5%) showed significantly increased input during the dry seasons. Recently especially during the dry winter seasons, migrating bird's excretion was estimated to contribute up to 8% of total TP input and 21% of Other Sources.

Assessment on Environmental Stabilization of Used Open Dumping Landfill - A Case Study of Kamkok Landfill - (사용종료 비위생 매립지의 환경 안정성 평가 - 감곡 매립지 사례 연구 -)

  • Park, Sangchan;Cho, Byeongreal;Jeong, Jihye;Lee, Minhee;Kim, Taeyoung;Park, Jongho
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.6
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    • pp.13-19
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    • 2008
  • The objectives of this paper are to investigate states of these open dumping landfills for managing, utilizing and stabilization of a municipal solid waste landfill site in environmentally secure conditions. The result of the physical analysis of the landfill showed that it is composed of between 29.72-63.84% organic matter, 32.88% vinyl plastic. The environmental assessment of the landfill site confirmed that the landfill is at a maturation phase due to 0.18 of $BOD_5$/CODcr of leachate. VS and FS of TS Was respectively 30.37%, 32.34% and C/N ratio was 21.8. Surface water around landfill was BOD 10.7 mg/g, SS 37.8 mg/g, E-Coli 31,157(MPN/$100m{\ell}$) and Ground water was $COD_{Mn}$ 1.13-1.38 mg/g, $NO_3-N$ 1.025-4.075 mg/g. Leachat indicated T-P 0.002-0.028 mg/g, $NH_3-N$ 4.0-21.0 mg/g. The soil contamination of around landfill didn't appear as below of the regulation of Soil Environment Conservation Act. The Landfill Gas was $CH_4$ 13.25%, $CO_2$ 6.17%, H2S and CO was not detected. Also Surface Water was not detected $CO_2$, $CH_4$, $H_2S$, CO.

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Reaction Characteristics of Piggery Wastewater for Biological Nutrient Removal (생물학적 영양염류 제거를 위한 돈사폐수의 반응 특성)

  • 한동준;류재근;임연택;임재명
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.44-56
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    • 1998
  • This study was performed to investigate the reaction characteristics of piggery wastewater for biological nutrient removal. The reaction characteristics were discussed the fraction of organics, the behavior of nitrogen, nitrification, denitrification, and the behavior of phosphorus. The fraction of readily biodegradable soluble COD was 11-12 percent. The ammonia nitrogen was removed via stripping, nitrification, autotrophic cell synthesis, and heterotrophic cell synthesis. The removal percents by each step were 12.1%, 68.9%, 15.0%, and 4.0%, respectively. Nitrification inhibition of piggery wastewater was found to occur at an influent volumetric loading rate over 0.2 NH$_{3}$-N kg/m$^{3}$/d. Denitrification rates were the highest in the raw wastewater and the lowest in the anaerobic effluent. The denitritation of piggery wastewater came out to be possible, and the rate of organic carbon consumption decreased about 10 percent. The phosphorus removed was released in the form of ortho-p in the aerobic fixed biofilm reactor, it was caused by autooxidation. The synthesis and release of phosphorus were related to the ORP and the boundary value for the phase change was about 170mV. In the synthesis phase, the phosphorus removal rate per COD removed was 0.023mgP$_{syn}$/mgCOD$_{rem}$. The phosphorus contents of the microorganism were 4.3-6.0% on a dry weight basis.

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The Characteristics of Organic Degradation and Ammonia Volatilization in the Liquid Composting of Pig Slurry

  • Kim, Chang-Gyu;Oh, Seung-Yong;Yoon, Young-Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.5
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    • pp.325-335
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    • 2017
  • This study was carried out for 30 days in aeration type and agitation type reactor to characterize organic matter decomposition and ammonia volatilization during the liquid composting of pig slurry, and organic matter and nitrogen removal rate through mass balance analysis was analyzed. In the aeration type reactor, the pH increased from 7.0 to 9.13, and TS 34.5%, VS 33.4%, $BOD_5$ 71.2%, $COD_{Cr}$ 62.3% and TOC 83.2% were removed. In addition, 44.6% of TN and 65.0% of ${NH_4}^+-N$ were removed. In the agitation type reactor, the pH increased from 7.0 to 8.10, and the removal rates of TS 0.9%, VS 0.5%, $COD_{Cr}$ 27.5%, $BOD_5$ 28.9% and TOC 41.3% were obtained. And TN and ${NH_4}^+-N$ showed removal rate of 25.3% and 29.2%, respectively. The first order kinetics constant related to $BOD_5$ degradation was $-0.039day^{-1}$ for aerobic liquid composting and $-0.013day^{-1}$ for agitated reactor. Nitrogen loss in aerobic liquid composting was about 2.3 times higher than that of agitated reactor, whereas FAN/TAN in aerobic liquid composting was about 7.9 times higher than that of agitation type reactor. Therefore, despite the low FAN/TAN in the agitation type reactor, the nitrogen loss rate was relatively high.

A Study on the Variation of Nutrients and Water Quality in Suk Chon Lake (石村湖의 營養鹽類 및 수질의 動態에 관한 조사연구)

  • Choi, Han-Young;Kim, Tai-Jeon;Park, Sung-Bae
    • Journal of Environmental Health Sciences
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    • v.14 no.1
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    • pp.47-53
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    • 1988
  • This study was performed to investigate a seasonal and vertical variation of the nutrients, water temperature, pH, DO, BOD, COD in Sukchon lake from May 1985 to Jan. 1986. The results were as follows. 1. Vertical descent of water temperature was the remarkable situation on Jul. and difference between surface layer and bottom layer was 3.5$\circ$C. 2. The value of pH was average 8.0 in both lake. The value of pH in the winter was average 7.6, and Summer was average 8.3. 3. The contents of dissolved oxygen was the highest value (13.0mg/l in surface layer on Jan. and the lowest value (8.1mg/l in bottom layer on Ul. 4. The contents of PO$_4$-P, NH$_3$-N, NO$_3$-N and T-N were 0.03~O.17mg/l 0.12~0.34mg/l 0.36~0.91mg/l and 0.76~1.37mg/l respectively.

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Effects of Pig Slurry Application on the Characteristics of Runoff Water in Volcanic Ash Soil in Jeju (제주 화산회토양에서 돈분액비 시용이 유거수의 특성에 미치는 영향)

  • Park, Nam-Geon;Hwang, Kyung-Jun;Park, Hyung-Soo;Song, Sang-Teak;Kim, Moon-Cheol
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.27 no.3
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    • pp.189-196
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    • 2007
  • This study was conducted to determine the effects of application levels of pig slurry on the characteristics of runoff water in volcanic ash soil in Jeju, Korea. This study was arranged in randomized complete block design. The data represent the means of the three experiments. Experimental plots were consisted of five treatments such as no fertilizer, chemical fertilizer at 200kg N/ha/year and pig slurry levels at 200, 400 and 600kg N/ha/year. The concentrations of BOD and COD in 600kg N/ha pig slurry were significantly higher (p<0.05) than those of the other treatments at initial sampling at 12 days after application. The total nitrogen concentration in runoff water increased with increasing pig slurry. The total phosphorous concentration in runoff water was hardly influenced by application levels of pig slurry since there were no significant difference among the treatments. The concentrations of $NO_3-N\;and\;NH_4-N$ were raised (p<0.05) in proportion to application levels of pig slurry. In conclusion, pig slurry usage at 200kg N/ha to the volcanic ash soil in Jeju area can replace the chemical fertilizer. However, more than 200kg N/ha of pig slurry may not be appropriate, because it may contaminate the water environment.

Organic Matter Degradation and Nitrification Characteristics in Aerobic Digestion of Sewage Sludge (슬러지 호기성 소화공정에서의 유기물 분해 및 질산화 특성)

  • Hwang, Eung-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.10
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    • pp.865-872
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    • 2009
  • Continuous operation of aerobic sludge digestion reactor was attempted for 279 days. Anaerobic digester sludge, the target material of the experiment, was pretreated by sodium hydroxide at $40^{\circ}C$ for 120 minutes, and the pretreated sludge was fed to 5 L CSTR (continuous stirred tank reactor). Reactor performance was affected by properties of input sludge and HRT (hydraulic retention time). 6 days of HRT showed best and stable performance, and under this condition, removal rates of $NH_3$-N, SCOD, TKN, TCOD, SS, and VSS were 97.4%, 81.7%, 68.7%, 61.4%, 50.6%, and 47.0%, respectively. 73.9% of SS in anaerobic digester sludge was reduced by pretreatment and aerobic digestion. Effluent sludge had low soluble COD of 350 mg/L. This implied the sludge was stabilized and suitable for use as liquid fertilizer. Nitrification took place when HRT was higher than 4 days. $NO_3$-N concentration was as high as 658 mg/L while $NH_3$-N was as low as 20 mg/L.

An Image Processing System to Estimate Pollutant Concentration of Animal Wastes (가축 분뇨의 오염물질 농도 추정을 위한 영상처리 시스템)

  • 이대원;김현태
    • Journal of Animal Environmental Science
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    • v.7 no.3
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    • pp.177-182
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    • 2001
  • This study was conducted to find out the coefficient relationships between intensity values image processing and pollution density of slurries. Slurry images were obtained from the image processing system using personnel computer and CCD-camera. Software, written in Visual $c^{++}$, combined the functions of the image capture, image processing and image analysis. The data of image processing for slurries were analyzed by the method of regression analysis. The results are as follows. 1. Red(R)-values among image processing data were obtained the highest correlation coefficient 0.9213 for detecting COD. Also, green(G)-value were obtained the highest correlation coefficient 0.9019 fur detecting BOD. Blue(B)-value could not find significant values to detect the pollution resources density. 2. Hue(H)-values among image processing data were obtained the highest correlation coefficient 0.9466 for detecting BOD. This fact could be used in detecting BOD 3. Green(G)-value, GRAY-value, Hue(H)-value, Saturation(5)-value and Intensity(I)-value were the correlation coefficient more than 0.8 for BOD. Hue(H)-value was higher correlation coefficient than any other value. It was possible to detect pollution density of slurries by using the image processing system. 4. Red(R)-value, GRAY-value and Saturation(5)-value were obtained the correlation coefficient more than 0.8 for detecting COD. a-value had the highest correlation coefficient Among these values. It was possible to detect density indirectly by using the image processing system. 5. SS-density were obtained the correlation coefficient less than 0.8 by using the image processing system. The density of $NH_4$-N and $NO_3$-N were obtained correlation coefficient less than 0.2.

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Chemical Treatment of Leachate from Swine Manure Composting System (양돈분뇨 퇴비화공정에서 발생하는 침출액의 화학적처리)

  • 정태영;오인환;김동수
    • Journal of Animal Environmental Science
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    • v.8 no.3
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    • pp.145-152
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    • 2002
  • This experiment was conducted to investigate the efficiency and compatibility of the coagulation and settling processes of leachates from the compost of two swine farms. And results obtained are as follows : 1 In the farm A where $COD_{Cr}$, $COD_{Mn}$ and $BOD_5$ of original leachate were 4,400, 2,950 and 87mg/l, respectively, the rate of coagulation and settling process was more efficient in the leachate treated with the conjugate of Alum and cation polymer than that of Alum and anion polymer. The concentrations of BOD$_{5}$, T-N and T-P of the effluent after treatment with the conjugate of Alum and cation polymer under the optimum condition were 19, 257.5 and 0.4mg/l, respectively which are under the governmental regulation level. 2. In the farm B where $COD_{Cr}$, $COD_{Mn}$ and $BOD_5$ of original leachate were 4,720, 3,040 and 95mg/l, respectively, the conjugate of $FeCl_3$, 1,500mg/l and cation polymer 10mg/l ($FeCl_3$+FO4240) was most effective coagulation and settling agent compared with the others. The concentrations of BOD$_{5}$, T-N and T-P of the effluent after treatment with $FeCl_3$+FO4240 were 15.3, 829.4 and 2.8mg/l, respectively. And the concentration of T-N was higher than the governmental regulation level, presumably because of too high concentration of NH$_4$$^{+}$-N in the leachate.

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Evaluation of Groundwater Quality Characteristics around Uncontrolled Closed Valley Landfill (사용종료 비위생매립지 주변 지하수의 수질변화 특성)

  • Park, Joung-Ku;Kim, Tae-Dong;Choi, Dong Hyuk;Lee, Jin-Yong
    • Journal of Soil and Groundwater Environment
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    • v.12 no.3
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    • pp.75-80
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    • 2007
  • This study evaluated groundwater quality around an uncontrolled landfill in W sity, Korea, which was monitored for about two years (2005-2006). Parameters of concern include redox-sensitive indicators such as pH, DO, EC, ORP, DOC (dissolved organic carbon), NH3, NO3 and SO4. About 10 years have elapsed after closing dumping of municipal wastes in the landfill. Leachates showed widely varying concentrations in COD(136${\sim}$263 mg/L), T-N(121${\sim}$186 mg/L), and NH3-N(14${\sim}$369 mg/L). Groundwater at the immediate downgradient of the landfill showed weakly acidic pH condition but very high levels of EC (3,000-4,000 ${\mu}S/cm$), which indicated that the groundwater was largely affected by the landfill leachate. Cl, a conservative ion, showed over 200 mg/L at the landfill border, but a gradually decreasing level with distance from the landfill, representing dispersion and dilution (natural attenuation) due to mixing with surrounding groundwater and replenished rainwater. Redox potential showed negative value at the landfill border but it increased up to 350 mV at downgradient wells, which indicated conversion of redox condition from reducing oxic ones. Ammonia, was largely enriched at most of the monitoring wells and its level greatly exceeded drinking water standard. In summary, all the parameters evidenced occurrence of natural attenuation with distance and with time but further monitoring is still required.